CN102666932B - 阴极、碱金属氯化物的电解用电解槽和阴极的制造方法 - Google Patents

阴极、碱金属氯化物的电解用电解槽和阴极的制造方法 Download PDF

Info

Publication number
CN102666932B
CN102666932B CN201080058712.9A CN201080058712A CN102666932B CN 102666932 B CN102666932 B CN 102666932B CN 201080058712 A CN201080058712 A CN 201080058712A CN 102666932 B CN102666932 B CN 102666932B
Authority
CN
China
Prior art keywords
layer
platinum
cathode
iridium
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201080058712.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN102666932A (zh
Inventor
船川明恭
蜂谷敏德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Original Assignee
Asahi Kasei Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Chemicals Corp filed Critical Asahi Kasei Chemicals Corp
Publication of CN102666932A publication Critical patent/CN102666932A/zh
Application granted granted Critical
Publication of CN102666932B publication Critical patent/CN102666932B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/08Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of metallic material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1204Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
    • C23C18/1208Oxides, e.g. ceramics
    • C23C18/1216Metal oxides
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/34Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C25B1/46Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/097Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds comprising two or more noble metals or noble metal alloys
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1646Characteristics of the product obtained
    • C23C18/165Multilayered product
    • C23C18/1651Two or more layers only obtained by electroless plating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrolytic Production Of Metals (AREA)
CN201080058712.9A 2009-12-25 2010-12-24 阴极、碱金属氯化物的电解用电解槽和阴极的制造方法 Expired - Fee Related CN102666932B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2009295846 2009-12-25
JP2009-295846 2009-12-25
PCT/JP2010/073410 WO2011078353A1 (ja) 2009-12-25 2010-12-24 陰極、アルカリ金属塩化物の電気分解用電解槽、及び陰極の製造方法

Publications (2)

Publication Number Publication Date
CN102666932A CN102666932A (zh) 2012-09-12
CN102666932B true CN102666932B (zh) 2015-08-05

Family

ID=44195878

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080058712.9A Expired - Fee Related CN102666932B (zh) 2009-12-25 2010-12-24 阴极、碱金属氯化物的电解用电解槽和阴极的制造方法

Country Status (7)

Country Link
US (1) US20120279853A1 (enExample)
EP (1) EP2518185B1 (enExample)
JP (1) JP5518900B2 (enExample)
CN (1) CN102666932B (enExample)
NO (1) NO2518185T3 (enExample)
TW (1) TWI432608B (enExample)
WO (1) WO2011078353A1 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2012361469A1 (en) * 2011-12-26 2014-06-26 Industrie De Nora S.P.A. Anode for oxygen generation and manufacturing method for the same
WO2013100162A2 (en) * 2011-12-26 2013-07-04 Permelec Electrode Ltd. Anode for oxygen generation and manufacturing method for the same
PE20142157A1 (es) * 2011-12-26 2015-01-17 Industrie De Nora Spa Anodo duradero de carga elevada para generacion de oxigeno y procedimiento de fabricacion del mismo
US9506157B2 (en) * 2012-03-19 2016-11-29 Asahi Kasei Kabushiki Kaisha Electrolysis cell and electrolysis tank
GB2508795A (en) * 2012-09-21 2014-06-18 Ucl Business Plc Electrolysis electrocatalyst comprising palladium and iridium
ITMI20122030A1 (it) * 2012-11-29 2014-05-30 Industrie De Nora Spa Catodo per evoluzione elettrolitica di idrogeno
WO2018151228A1 (ja) * 2017-02-15 2018-08-23 旭化成株式会社 陰極、その製造方法、およびそれを用いた電解槽、水素製造方法
US11339484B2 (en) * 2017-03-13 2022-05-24 Asahi Kasei Kabushiki Kaisha Electrolytic cell and electrolyzer
IT201900009753A1 (it) * 2019-06-21 2020-12-21 Fondazione St Italiano Tecnologia STABLE HYDROGEN EVOLUTION ELECTROCATALYST BASED ON 3D METAL NANOSTRUCTURES ON A Ti SUBSTRATE
JP7218263B2 (ja) * 2019-09-18 2023-02-06 株式会社東芝 積層触媒、電極、膜電極複合体、電気化学セル、スタック、燃料電池及び水電解の可逆装置、車両及び飛翔体
CN114959767B (zh) * 2021-02-26 2024-03-19 蓝星(北京)化工机械有限公司 镍基活性阴极及其制备方法
JP7706693B2 (ja) * 2021-08-31 2025-07-14 株式会社大阪ソーダ 塩素発生用電極およびその製造方法
WO2024091510A1 (en) * 2022-10-24 2024-05-02 West Virginia University Board of Governors on behalf of West Virginia University Methods and compositions for nanocomposites on electrode surfaces

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85108093A (zh) * 1984-11-07 1986-08-20 奥罗茨奥·诺拉电化学工厂联合股票公司 用于电化学过程的电极,制造此电极的方法及电极在电解槽中的应用
US4874735A (en) * 1987-02-27 1989-10-17 University Of Victoria Bilayer electronically conductive polymers and process for their production
CN1014534B (zh) * 1985-04-12 1991-10-30 奥多茨奥·诺拉电化学工厂联合股票公司 电化学过程中应用的电极及其制备的方法
US5227030A (en) * 1990-05-29 1993-07-13 The Dow Chemical Company Electrocatalytic cathodes and methods of preparation
CN101222049A (zh) * 2006-05-16 2008-07-16 三星Sdi株式会社 催化剂涂布膜,包括它的膜电极组件,其制备方法,及包括该膜电极组件的燃料电池

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3775284A (en) * 1970-03-23 1973-11-27 J Bennett Non-passivating barrier layer electrodes
US3801490A (en) * 1972-07-18 1974-04-02 Ppg Industries Inc Pyrochlore electrodes
US3992271A (en) * 1973-02-21 1976-11-16 General Electric Company Method for gas generation
US4457824A (en) * 1982-06-28 1984-07-03 General Electric Company Method and device for evolution of oxygen with ternary electrocatalysts containing valve metals
JPS5713189A (en) * 1980-06-26 1982-01-23 Osaka Soda Co Ltd Cathode for electrolysis
US4331528A (en) * 1980-10-06 1982-05-25 Diamond Shamrock Corporation Coated metal electrode with improved barrier layer
JPS5861286A (ja) * 1981-10-08 1983-04-12 Tdk Corp 電解用電極およびその製造方法
US4444897A (en) * 1982-05-05 1984-04-24 Exxon Research And Engineering Co. Reactivating iridium-containing catalysts with hydrogen halide and oxygen
GB8316778D0 (en) * 1983-06-21 1983-07-27 Ici Plc Cathode
JPH108281A (ja) * 1996-06-14 1998-01-13 Jonan Denki Kogyosho:Kk 電解槽
JP4142191B2 (ja) 1999-02-24 2008-08-27 ペルメレック電極株式会社 活性化陰極の製造方法
US8216956B2 (en) * 2003-10-10 2012-07-10 Ohio University Layered electrocatalyst for oxidation of ammonia and ethanol
JP4882218B2 (ja) 2004-04-23 2012-02-22 東ソー株式会社 水素発生用電極およびその製造方法並びにこれを用いた電解方法
ITMI20061947A1 (it) 2006-10-11 2008-04-12 Industrie De Nora Spa Catodo per processi elettrolitici
KR101261247B1 (ko) * 2008-04-09 2013-05-07 스미토모덴키고교가부시키가이샤 가스 분해 방법
JP5395791B2 (ja) * 2008-07-03 2014-01-22 旭化成ケミカルズ株式会社 水素発生用陰極およびその製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85108093A (zh) * 1984-11-07 1986-08-20 奥罗茨奥·诺拉电化学工厂联合股票公司 用于电化学过程的电极,制造此电极的方法及电极在电解槽中的应用
CN1014534B (zh) * 1985-04-12 1991-10-30 奥多茨奥·诺拉电化学工厂联合股票公司 电化学过程中应用的电极及其制备的方法
US4874735A (en) * 1987-02-27 1989-10-17 University Of Victoria Bilayer electronically conductive polymers and process for their production
US5227030A (en) * 1990-05-29 1993-07-13 The Dow Chemical Company Electrocatalytic cathodes and methods of preparation
CN101222049A (zh) * 2006-05-16 2008-07-16 三星Sdi株式会社 催化剂涂布膜,包括它的膜电极组件,其制备方法,及包括该膜电极组件的燃料电池

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Iridium Oxide/Platinum Electrocatalysts for Unitized Regenerative Polymer Electrolyte Fuel Cells;Tsutomu Ioroi,et al.;《Journal of The Electrochemical Society》;20001231;第147卷(第6期);第2018-2022页 *
Yining Zhang,et al..A novel bifunctional electrocatalyst for unitized regenerative fuel cell.《Journal of Power Sources》.2009,第195卷 *

Also Published As

Publication number Publication date
TW201131022A (en) 2011-09-16
US20120279853A1 (en) 2012-11-08
WO2011078353A1 (ja) 2011-06-30
EP2518185A1 (en) 2012-10-31
JPWO2011078353A1 (ja) 2013-05-09
CN102666932A (zh) 2012-09-12
NO2518185T3 (enExample) 2018-02-10
TWI432608B (zh) 2014-04-01
EP2518185B1 (en) 2017-09-13
EP2518185A4 (en) 2016-04-06
JP5518900B2 (ja) 2014-06-11

Similar Documents

Publication Publication Date Title
CN102666932B (zh) 阴极、碱金属氯化物的电解用电解槽和阴极的制造方法
CN102046851B (zh) 氢产生用阴极及其制造方法
JP5189781B2 (ja) 水素発生用電極
CN103261485B (zh) 电解用电极、电解槽和电解用电极的制造方法
CN103255434B (zh) 电解用电极、电解槽以及电解用电极的制造方法
TW200304503A (en) Electrode for generation of hydrogen
JP4354821B2 (ja) 酸性媒質における電気分解用の電極
JP5681343B2 (ja) 電解用電極
JP2016148074A (ja) 水素発生用陰極およびその製造方法
WO2013005252A1 (ja) 電気分解用電極及びその作製方法、並びに電気分解装置
US12428742B2 (en) Electrode for electrolysis
JP5462460B2 (ja) 電解用電極
CN104278290A (zh) 用于制备运输和储存稳定的耗氧电极的方法
JP7522928B2 (ja) 電気分解用電極の製造方法
JP7786869B2 (ja) 水素発生用陰極
KR102894887B1 (ko) 전기분해용 전극
JP2019210541A (ja) 水素発生用電極の製造方法及び水素発生用電極を用いた電気分解方法
CN113748230A (zh) 电解用电极

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20160429

Address after: Tokyo, Japan

Patentee after: ASAHI KASEI Kabushiki Kaisha

Address before: Tokyo, Japan

Patentee before: Asahi Kasei Chemicals Corp.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150805