CN102649830B - 一种阳离子有机硅改性聚丙烯酰胺的制备方法 - Google Patents
一种阳离子有机硅改性聚丙烯酰胺的制备方法 Download PDFInfo
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- CN102649830B CN102649830B CN201210153941XA CN201210153941A CN102649830B CN 102649830 B CN102649830 B CN 102649830B CN 201210153941X A CN201210153941X A CN 201210153941XA CN 201210153941 A CN201210153941 A CN 201210153941A CN 102649830 B CN102649830 B CN 102649830B
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- monomer
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- modified polyacrylamide
- positively charged
- organic silicon
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- 229920002401 polyacrylamide Polymers 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title abstract 5
- 229910052710 silicon Inorganic materials 0.000 title abstract 5
- 239000010703 silicon Substances 0.000 title abstract 5
- 150000001768 cations Chemical class 0.000 title abstract 4
- 239000000178 monomer Substances 0.000 claims abstract description 51
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 14
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003999 initiator Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 150000002500 ions Chemical class 0.000 claims description 14
- 229920001296 polysiloxane Polymers 0.000 claims description 13
- 150000001282 organosilanes Chemical class 0.000 claims description 12
- 125000002091 cationic group Chemical group 0.000 claims description 11
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- YXYZMHGSOKYZAF-UHFFFAOYSA-M [Cl-].C(C(=C)C)(=O)OCC[N+](C(C)(C)C)(C)C Chemical group [Cl-].C(C(=C)C)(=O)OCC[N+](C(C)(C)C)(C)C YXYZMHGSOKYZAF-UHFFFAOYSA-M 0.000 claims description 5
- 150000001409 amidines Chemical class 0.000 claims description 5
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 4
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 3
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical group CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 claims description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
- BITPLIXHRASDQB-UHFFFAOYSA-N ethenyl-[ethenyl(dimethyl)silyl]oxy-dimethylsilane Chemical compound C=C[Si](C)(C)O[Si](C)(C)C=C BITPLIXHRASDQB-UHFFFAOYSA-N 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 239000004160 Ammonium persulphate Substances 0.000 claims description 2
- 239000004159 Potassium persulphate Substances 0.000 claims description 2
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 230000033116 oxidation-reduction process Effects 0.000 claims description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 2
- 235000019394 potassium persulphate Nutrition 0.000 claims description 2
- 230000002829 reductive effect Effects 0.000 claims description 2
- -1 thiazolinyl cyclotetrasiloxane Chemical compound 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 14
- 230000002209 hydrophobic effect Effects 0.000 description 13
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Abstract
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CN201210153941XA CN102649830B (zh) | 2012-05-17 | 2012-05-17 | 一种阳离子有机硅改性聚丙烯酰胺的制备方法 |
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CN201210153941XA CN102649830B (zh) | 2012-05-17 | 2012-05-17 | 一种阳离子有机硅改性聚丙烯酰胺的制备方法 |
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CN102649830A CN102649830A (zh) | 2012-08-29 |
CN102649830B true CN102649830B (zh) | 2013-11-27 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109280544A (zh) * | 2018-09-21 | 2019-01-29 | 中国石油化工股份有限公司 | 一种ph值调控的含硅阳离子聚合物分子膜固砂剂及其制备方法 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105567190A (zh) * | 2014-10-17 | 2016-05-11 | 中国石油化工股份有限公司 | 一种凝胶堵漏剂及其制备方法 |
CN104844828B (zh) * | 2015-06-09 | 2017-08-08 | 汕头市源兴织造有限公司 | 一种橡胶塑料用的无机阻燃剂的制备方法 |
CN105060445B (zh) * | 2015-08-21 | 2017-01-11 | 寇斌 | 一种阳离子有机硅聚丙烯酰胺絮凝剂及其制备方法 |
CN105820808A (zh) * | 2016-04-13 | 2016-08-03 | 中国石油大学(华东) | 一种抑砂防膨剂及其制备方法 |
CN105693925B (zh) * | 2016-04-13 | 2018-02-27 | 中国石油大学(华东) | 一种油水井防砂用多支化聚合物及其制备方法 |
CN105694837B (zh) * | 2016-04-13 | 2018-08-24 | 中国石油大学(华东) | 一种聚合物固砂剂及其制备方法 |
CN107190416B (zh) * | 2017-06-27 | 2020-04-28 | 山东天海新材料工程有限公司 | 一种土工布的制备方法 |
CN108178147A (zh) * | 2018-02-05 | 2018-06-19 | 华南理工大学 | 一种带正电稳定的石墨烯水分散液及其制备方法 |
CN112624222A (zh) * | 2020-12-15 | 2021-04-09 | 陕西科技大学 | 一种破乳絮凝多功能水清洁剂及其制备方法和应用 |
CN113698530B (zh) * | 2021-10-28 | 2022-02-18 | 江苏富淼科技股份有限公司 | 一种高位阻系列阳离子固体型聚丙烯酰胺及其制备方法 |
CN115072851B (zh) * | 2022-08-19 | 2022-11-11 | 山东诺尔生物科技有限公司 | 一种垃圾渗滤液处理剂及其制备方法 |
CN115477728A (zh) * | 2022-09-20 | 2022-12-16 | 江苏永威环境科技股份有限公司 | 一种阳离子聚丙烯酰胺的制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1040015C (zh) * | 1993-04-16 | 1998-09-30 | 株式会社乐喜 | 防雾耐磨涂料组合物及用其涂覆的合成树脂制品 |
CN1528796A (zh) * | 2003-09-28 | 2004-09-15 | 石油大学(华东) | 有机硅改性聚丙烯酰胺及其制备方法 |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1040015C (zh) * | 1993-04-16 | 1998-09-30 | 株式会社乐喜 | 防雾耐磨涂料组合物及用其涂覆的合成树脂制品 |
CN1528796A (zh) * | 2003-09-28 | 2004-09-15 | 石油大学(华东) | 有机硅改性聚丙烯酰胺及其制备方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109280544A (zh) * | 2018-09-21 | 2019-01-29 | 中国石油化工股份有限公司 | 一种ph值调控的含硅阳离子聚合物分子膜固砂剂及其制备方法 |
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Effective date of registration: 20190513 Address after: 710021 Shaanxi Xi'an Economic and Technological Development Zone Weiyang Road and Fengcheng Nine Road Crossing Northeast Corner via 8 Floors of Block A of Kaiwanke Center Patentee after: Xi'an Yipu Eco-technology Co.,Ltd. Address before: No. 1, Weiyang District university garden, Xi'an, Shaanxi Province, Shaanxi Patentee before: SHAANXI University OF SCIENCE & TECHNOLOGY |
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Address after: 710021 Shaanxi Xi'an Economic and Technological Development Zone Weiyang Road and Fengcheng Nine Road Crossing Northeast Corner via 8 Floors of Block A of Kaiwanke Center Patentee after: Xi'an Yipu Digital Agriculture Co.,Ltd. Address before: 710021 Shaanxi Xi'an Economic and Technological Development Zone Weiyang Road and Fengcheng Nine Road Crossing Northeast Corner via 8 Floors of Block A of Kaiwanke Center Patentee before: Xi'an Yipu Eco-technology Co.,Ltd. |
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