CN102648229A - 基于二乙烯基芳烃氧化物的加合物 - Google Patents
基于二乙烯基芳烃氧化物的加合物 Download PDFInfo
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- CN102648229A CN102648229A CN2010800551521A CN201080055152A CN102648229A CN 102648229 A CN102648229 A CN 102648229A CN 2010800551521 A CN2010800551521 A CN 2010800551521A CN 201080055152 A CN201080055152 A CN 201080055152A CN 102648229 A CN102648229 A CN 102648229A
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- epoxy resin
- polyamine
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- HPILSDOMLLYBQF-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)butoxymethyl]oxirane Chemical class C1OC1COC(CCC)OCC1CO1 HPILSDOMLLYBQF-UHFFFAOYSA-N 0.000 description 2
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- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- GLPDXGJXUWGMQJ-UHFFFAOYSA-N 4-ethenyl-7-(4-ethenylphenyl)-3,8-dioxatricyclo[5.1.0.02,4]oct-5-ene Chemical compound C(=C)C1=CC=C(C=C1)C12C(C3C(C=C1)(C=C)O3)O2 GLPDXGJXUWGMQJ-UHFFFAOYSA-N 0.000 description 1
- BWHLFAZDBDUSDO-UHFFFAOYSA-N 6-ethenyl-1-ethyl-7-oxabicyclo[4.1.0]hepta-2,4-diene Chemical compound C1=CC=CC2(CC)C1(C=C)O2 BWHLFAZDBDUSDO-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/182—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents
- C08G59/184—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26637609P | 2009-12-03 | 2009-12-03 | |
| US61/266,376 | 2009-12-03 | ||
| PCT/US2010/058543 WO2011068858A1 (en) | 2009-12-03 | 2010-12-01 | Adducts based on divinylarene oxides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102648229A true CN102648229A (zh) | 2012-08-22 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010800551521A Pending CN102648229A (zh) | 2009-12-03 | 2010-12-01 | 基于二乙烯基芳烃氧化物的加合物 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20120245306A1 (https=) |
| EP (1) | EP2507284A1 (https=) |
| JP (1) | JP2013512997A (https=) |
| KR (1) | KR20120089367A (https=) |
| CN (1) | CN102648229A (https=) |
| BR (1) | BR112012011527A2 (https=) |
| TW (1) | TW201136974A (https=) |
| WO (1) | WO2011068858A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109401200A (zh) * | 2018-10-29 | 2019-03-01 | 江苏宏鹏电气科技有限公司 | 一种用于母线槽内绝缘衬垫材料的制备配方 |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011163100A2 (en) * | 2010-06-23 | 2011-12-29 | Dow Global Technologies Llc | Powder coatings compositions |
| WO2013043363A2 (en) * | 2011-09-21 | 2013-03-28 | Dow Global Technologies Llc | Epoxy-functional resin compositions |
| RU2015101136A (ru) * | 2012-06-15 | 2016-08-10 | БЛЮ КЬЮБ АйПи ЭлЭлСи | Композиция углеродного прекурсора |
| CN104364298B (zh) * | 2012-06-15 | 2016-08-17 | 蓝立方知识产权有限责任公司 | 导电碳化层状制品 |
| WO2025075950A1 (en) * | 2023-10-03 | 2025-04-10 | Westlake Epoxy Inc. | Epoxy renin compositions and methods of producing thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB854679A (en) * | 1958-10-11 | 1960-11-23 | Union Carbide Corp | Improvements in and relating to polymerisable epoxide compositions |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2901461A (en) | 1955-05-05 | 1959-08-25 | Union Carbide Corp | Curable glycidyl polyether-polyamine compositions |
| US3018262A (en) | 1957-05-01 | 1962-01-23 | Shell Oil Co | Curing polyepoxides with certain metal salts of inorganic acids |
| US2912389A (en) | 1957-08-08 | 1959-11-10 | Union Carbide Corp | Polymers of divinylbenzene dioxide |
| US2924580A (en) * | 1957-08-08 | 1960-02-09 | Union Carbide Corp | Divinyl benzene dioxide compositions |
| US3496138A (en) * | 1966-08-01 | 1970-02-17 | Union Carbide Corp | Adducts of polyglycol diamines and curable compositions comprising polyepoxides and said adducts |
| US3773790A (en) * | 1969-11-26 | 1973-11-20 | Ajinomoto Kk | Spiroacetal diamine-epoxide liquid as curing agent for epoxy resins |
| DE3328134C2 (de) * | 1983-08-04 | 1986-08-07 | Hüls AG, 4370 Marl | EP-Pulverlacke und Verfahren zur Herstellung matter Überzüge |
| US4925901A (en) | 1988-02-12 | 1990-05-15 | The Dow Chemical Company | Latent, curable, catalyzed mixtures of epoxy-containing and phenolic hydroxyl-containing compounds |
| US5135993A (en) | 1990-09-11 | 1992-08-04 | Dow Corning Corporation | High modulus silicones as toughening agents for epoxy resins |
| GB9411367D0 (en) | 1994-06-07 | 1994-07-27 | Ici Composites Inc | Curable Composites |
| US6153719A (en) | 1998-02-04 | 2000-11-28 | Lord Corporation | Thiol-cured epoxy composition |
| US6632893B2 (en) | 1999-05-28 | 2003-10-14 | Henkel Loctite Corporation | Composition of epoxy resin, cyanate ester, imidazole and polysulfide tougheners |
| IL138474A0 (en) | 2000-09-14 | 2001-10-31 | Epox Ltd | Highly branched water-soluble polyamine oligomers, process for their preparation and applications thereof |
| US6572971B2 (en) | 2001-02-26 | 2003-06-03 | Ashland Chemical | Structural modified epoxy adhesive compositions |
| US6632860B1 (en) | 2001-08-24 | 2003-10-14 | Texas Research International, Inc. | Coating with primer and topcoat both containing polysulfide, epoxy resin and rubber toughener |
| GB0212062D0 (en) | 2002-05-24 | 2002-07-03 | Vantico Ag | Jetable compositions |
| US7163973B2 (en) | 2002-08-08 | 2007-01-16 | Henkel Corporation | Composition of bulk filler and epoxy-clay nanocomposite |
| US7001938B2 (en) | 2003-01-27 | 2006-02-21 | Resolution Performance Products Llc | Epoxy resin curing compositions and resin compositions including same |
| US6887574B2 (en) | 2003-06-06 | 2005-05-03 | Dow Global Technologies Inc. | Curable flame retardant epoxy compositions |
| EP1753772B1 (en) | 2004-05-28 | 2016-12-28 | Blue Cube IP LLC | Phosphorus-containing compounds useful for making halogen-free, ignition-resistant polymers |
| RU2395545C2 (ru) | 2004-11-10 | 2010-07-27 | Дау Глобал Текнолоджиз Инк. | Эпоксидные смолы, упрочненные амфифильными блок-сополимерами, и электроизоляционные ламинаты, выполненные с ними |
| US8048819B2 (en) | 2005-06-23 | 2011-11-01 | Momentive Performance Materials Inc. | Cure catalyst, composition, electronic device and associated method |
| CA2744063A1 (en) * | 2008-12-30 | 2010-07-08 | Dow Global Technologies Llc | Divinylarene dioxide formulations for vacuum resin infusion molding |
-
2010
- 2010-12-01 BR BR112012011527A patent/BR112012011527A2/pt not_active IP Right Cessation
- 2010-12-01 EP EP10787239A patent/EP2507284A1/en not_active Withdrawn
- 2010-12-01 JP JP2012542155A patent/JP2013512997A/ja not_active Ceased
- 2010-12-01 WO PCT/US2010/058543 patent/WO2011068858A1/en not_active Ceased
- 2010-12-01 US US13/503,662 patent/US20120245306A1/en not_active Abandoned
- 2010-12-01 KR KR1020127017208A patent/KR20120089367A/ko not_active Withdrawn
- 2010-12-01 CN CN2010800551521A patent/CN102648229A/zh active Pending
- 2010-12-02 TW TW099141872A patent/TW201136974A/zh unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB854679A (en) * | 1958-10-11 | 1960-11-23 | Union Carbide Corp | Improvements in and relating to polymerisable epoxide compositions |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109401200A (zh) * | 2018-10-29 | 2019-03-01 | 江苏宏鹏电气科技有限公司 | 一种用于母线槽内绝缘衬垫材料的制备配方 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013512997A (ja) | 2013-04-18 |
| EP2507284A1 (en) | 2012-10-10 |
| WO2011068858A1 (en) | 2011-06-09 |
| TW201136974A (en) | 2011-11-01 |
| BR112012011527A2 (pt) | 2019-09-24 |
| KR20120089367A (ko) | 2012-08-09 |
| US20120245306A1 (en) | 2012-09-27 |
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