CN102634692B - 用于镍氢电池的储氢合金材料及其制备方法 - Google Patents
用于镍氢电池的储氢合金材料及其制备方法 Download PDFInfo
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- CN102634692B CN102634692B CN2012101173579A CN201210117357A CN102634692B CN 102634692 B CN102634692 B CN 102634692B CN 2012101173579 A CN2012101173579 A CN 2012101173579A CN 201210117357 A CN201210117357 A CN 201210117357A CN 102634692 B CN102634692 B CN 102634692B
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- nickel
- alloy material
- material storing
- storing hydrogen
- cerium
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- 239000000956 alloy Substances 0.000 title claims abstract description 171
- 239000001257 hydrogen Substances 0.000 title claims abstract description 143
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 143
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 128
- 238000002360 preparation method Methods 0.000 title claims description 9
- 238000003860 storage Methods 0.000 title abstract description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 178
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 88
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 53
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 53
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 53
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims abstract description 53
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 47
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000010941 cobalt Substances 0.000 claims abstract description 47
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 47
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229910052777 Praseodymium Inorganic materials 0.000 claims abstract description 44
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910052779 Neodymium Inorganic materials 0.000 claims abstract description 43
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 43
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229910045601 alloy Inorganic materials 0.000 claims description 72
- 239000000203 mixture Substances 0.000 claims description 55
- 239000004411 aluminium Substances 0.000 claims description 46
- 239000011572 manganese Substances 0.000 claims description 46
- 229910052987 metal hydride Inorganic materials 0.000 claims description 41
- -1 nickel metal hydride Chemical class 0.000 claims description 41
- 239000007789 gas Substances 0.000 claims description 34
- 238000002844 melting Methods 0.000 claims description 16
- 230000008018 melting Effects 0.000 claims description 16
- 238000001816 cooling Methods 0.000 claims description 15
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 8
- 150000002910 rare earth metals Chemical class 0.000 abstract description 8
- 238000005259 measurement Methods 0.000 abstract 1
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 54
- 229910052786 argon Inorganic materials 0.000 description 27
- 239000012467 final product Substances 0.000 description 13
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910018661 Ni(OH) Inorganic materials 0.000 description 1
- 229910002640 NiOOH Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- WMOHXRDWCVHXGS-UHFFFAOYSA-N [La].[Ce] Chemical compound [La].[Ce] WMOHXRDWCVHXGS-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
Description
A:B | 循环寿命(1C) | 克容量(mAh/g) | 平衡氢压(atm,H/M=0.4, |
45度测量 | |||
5.043 | 520 | 345 | 0.128 |
Claims (9)
Priority Applications (1)
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CN2012101173579A CN102634692B (zh) | 2012-04-19 | 2012-04-19 | 用于镍氢电池的储氢合金材料及其制备方法 |
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CN2012101173579A CN102634692B (zh) | 2012-04-19 | 2012-04-19 | 用于镍氢电池的储氢合金材料及其制备方法 |
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CN102634692A CN102634692A (zh) | 2012-08-15 |
CN102634692B true CN102634692B (zh) | 2013-11-27 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102888539B (zh) * | 2012-10-25 | 2015-07-29 | 厦门钨业股份有限公司 | 一种具有超高容量特性的低成本ab5型贮氢合金及其制法和应用 |
CN106602048B (zh) * | 2017-03-02 | 2019-03-22 | 辽宁九夷能源科技有限公司 | 一种耐深放电镍氢电池及其制备方法 |
CN108183267A (zh) * | 2017-12-29 | 2018-06-19 | 东莞市朗泰通实业有限公司 | 一种耐高温镍氢电池及其电极的制作方法 |
CN111129615A (zh) * | 2019-12-24 | 2020-05-08 | 惠州时代电池有限公司 | 可多次循环的高容量镍氢电池 |
CN115261677A (zh) * | 2022-08-08 | 2022-11-01 | 内蒙古稀奥科贮氢合金有限公司 | 一种低钴无镨钕ab5型储氢合金及其低自放电镍氢电池 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102104146A (zh) * | 2010-12-31 | 2011-06-22 | 北京浩运金能科技有限公司 | 一种镍氢电池用无钴ab3.5型储氢合金负极材料及其制备方法 |
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US7344677B2 (en) * | 2004-04-02 | 2008-03-18 | Ovonic Battery Company, Inc. | Hydrogen storage alloys having improved cycle life and low temperature operating characteristics |
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CN102104146A (zh) * | 2010-12-31 | 2011-06-22 | 北京浩运金能科技有限公司 | 一种镍氢电池用无钴ab3.5型储氢合金负极材料及其制备方法 |
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Effective date of registration: 20121123 Address after: The streets of Pinghu new road in Longgang District of Shenzhen City, Guangdong Province, the first building No. 68 518111 Applicant after: SHENZHEN HIGHPOWER TECHNOLOGY Co.,Ltd. Applicant after: XIAMEN TUNGSTEN Co.,Ltd. Address before: The streets of Pinghu new road in Longgang District of Shenzhen City, Guangdong Province, the first building No. 68 518111 Applicant before: SHENZHEN HIGHPOWER TECHNOLOGY Co.,Ltd. |
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Address after: The streets of Pinghu new road in Longgang District of Shenzhen City, Guangdong Province, the first building No. 68 518111 Patentee after: Shenzhen haopeng Technology Co.,Ltd. Patentee after: XIAMEN TUNGSTEN Co.,Ltd. Address before: The streets of Pinghu new road in Longgang District of Shenzhen City, Guangdong Province, the first building No. 68 518111 Patentee before: SHENZHEN HIGHPOWER TECHNOLOGY Co.,Ltd. Patentee before: XIAMEN TUNGSTEN Co.,Ltd. |
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Effective date of registration: 20230613 Address after: 518111 Building 1, 68 Xinxia Avenue, Pinghu street, Longgang District, Shenzhen City, Guangdong Province Patentee after: Shenzhen haopeng Technology Co.,Ltd. Patentee after: Xiamen Xiamen Tungsten Hydrogen Energy Technology Co.,Ltd. Address before: 518111 Building 1, 68 Xinxia Avenue, Pinghu street, Longgang District, Shenzhen City, Guangdong Province Patentee before: Shenzhen haopeng Technology Co.,Ltd. Patentee before: XIAMEN TUNGSTEN Co.,Ltd. |