CN102604358B - 一种导热抗静电pc/abs材料及其制备方法 - Google Patents
一种导热抗静电pc/abs材料及其制备方法 Download PDFInfo
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- CN102604358B CN102604358B CN201210072062.4A CN201210072062A CN102604358B CN 102604358 B CN102604358 B CN 102604358B CN 201210072062 A CN201210072062 A CN 201210072062A CN 102604358 B CN102604358 B CN 102604358B
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- coupling agent
- conductive powder
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- 239000000463 material Substances 0.000 title claims abstract description 38
- 229920007019 PC/ABS Polymers 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title abstract description 10
- 239000004417 polycarbonate Substances 0.000 title abstract 3
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title abstract 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title abstract 2
- 229920000515 polycarbonate Polymers 0.000 title abstract 2
- 239000000843 powder Substances 0.000 claims abstract description 34
- 239000007822 coupling agent Substances 0.000 claims abstract description 32
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 239000000945 filler Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims description 14
- 239000003112 inhibitor Substances 0.000 claims description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- -1 oleic acid acyloxy titanic acid ester Chemical class 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 230000003068 static effect Effects 0.000 claims description 8
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 7
- 238000013019 agitation Methods 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 229910002804 graphite Inorganic materials 0.000 claims description 7
- 239000010439 graphite Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 238000005453 pelletization Methods 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 238000004945 emulsification Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000009775 high-speed stirring Methods 0.000 claims description 6
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- ICKWICRCANNIBI-UHFFFAOYSA-N 2,4-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1 ICKWICRCANNIBI-UHFFFAOYSA-N 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052582 BN Inorganic materials 0.000 claims description 3
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical group CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- 229910017083 AlN Inorganic materials 0.000 claims description 2
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 230000009977 dual effect Effects 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 239000004611 light stabiliser Substances 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- 150000003918 triazines Chemical class 0.000 claims description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims 1
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 claims 1
- 239000000314 lubricant Substances 0.000 abstract description 7
- 239000011347 resin Substances 0.000 abstract description 7
- 229920005989 resin Polymers 0.000 abstract description 7
- 239000002216 antistatic agent Substances 0.000 abstract 2
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
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- B29C47/92—
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
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Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102807706A (zh) * | 2012-07-27 | 2012-12-05 | 深圳市科聚新材料有限公司 | 一种聚丙烯复合材料及其制备方法 |
CN103073886A (zh) * | 2012-12-25 | 2013-05-01 | 安徽科聚新材料有限公司 | 一种尼龙66复合材料及其制备方法和电子装置 |
CN103224692A (zh) * | 2013-05-09 | 2013-07-31 | 江门市道生工程塑料有限公司 | 填充型聚合物基导热塑料及其制备方法 |
CN103333481B (zh) * | 2013-07-19 | 2015-10-28 | 上海锦湖日丽塑料有限公司 | 一种耐磨pc/abs合金材料及其制备方法 |
CN103627131A (zh) * | 2013-11-12 | 2014-03-12 | 青岛广联达精密机械有限公司 | 一种abs刚性环保材料 |
CN103740085B (zh) * | 2013-12-30 | 2016-03-02 | 安徽科聚新材料有限公司 | 一种抗静电矿物增强无卤阻燃pc/abs材料及其制备方法 |
CN103951958B (zh) * | 2014-05-12 | 2016-08-17 | 宁波高新区卓尔化工科技有限公司 | 家电用塑料及其制备方法 |
CN104151771A (zh) * | 2014-09-01 | 2014-11-19 | 苏州卓越工程塑料有限公司 | 一种导热型注塑材料 |
CN105385092A (zh) * | 2015-12-10 | 2016-03-09 | 苏州爱盟机械有限公司 | 一种高强度金属光泽塑料材料 |
CN105385091A (zh) * | 2015-12-10 | 2016-03-09 | 苏州爱盟机械有限公司 | 一种阻燃型金属光泽塑料材料 |
CN106280219A (zh) * | 2016-08-15 | 2017-01-04 | 温州任和教育科技有限责任公司 | 一种高强度高韧性pc/abs塑料合金材料及其制备方法 |
CN106433067B (zh) * | 2016-09-29 | 2018-07-13 | 东莞市彩隆塑胶科技有限公司 | 一种环保型pc/abs合金材料的配方及其制备方法 |
CN106280227A (zh) * | 2016-10-21 | 2017-01-04 | 安徽江淮汽车股份有限公司 | 一种抗静电高韧性abs复合材料及其制备方法 |
CN106674957A (zh) * | 2016-12-13 | 2017-05-17 | 上海锦湖日丽塑料有限公司 | 一种抗菌抗静电增强型聚碳酸酯材料及其制备方法 |
CN106947231A (zh) * | 2017-03-22 | 2017-07-14 | 合肥仁德电子科技有限公司 | 一种充电器外壳材料及其制备方法 |
CN107163489A (zh) * | 2017-06-13 | 2017-09-15 | 泉州盈创新材料技术开发有限公司 | 一种高强度高导热pc/abs塑料及其制备方法 |
CN109575551B (zh) * | 2017-09-29 | 2021-12-28 | 中国石油化工股份有限公司 | 用于导热散热的改性树脂材料及其制备方法和应用 |
CN108070197A (zh) * | 2017-12-15 | 2018-05-25 | 广西汇智生产力促进中心有限公司 | 改性高岭土-abs耐腐蚀、防爆裂复合材料的制备方法 |
CN108410115A (zh) * | 2018-03-31 | 2018-08-17 | 安徽路明光电科技有限公司 | 一种led阻燃灯罩及其制备方法 |
CN108641325A (zh) * | 2018-05-07 | 2018-10-12 | 苏州润佳工程塑料股份有限公司 | 一种抗静电pc/abs复合材料及其制备方法 |
CN109439192A (zh) * | 2018-10-31 | 2019-03-08 | 宁波市凯迪森照明科技有限公司 | 一种lde灯外壳 |
CN112480635B (zh) * | 2020-12-09 | 2022-09-16 | 上海锦湖日丽塑料有限公司 | 一种透明pc/abs合金及其制备方法 |
CN112876832A (zh) * | 2021-03-03 | 2021-06-01 | 安徽威普达材料科技有限公司 | 一种增强型导热pc材料及其制备方法 |
CN116289336B (zh) * | 2023-03-31 | 2024-04-02 | 杭州永晶科技有限公司 | 一种基于淀粉胶的抗静电瓦楞纸板及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101397396A (zh) * | 2007-09-27 | 2009-04-01 | 上海金发科技发展有限公司 | 聚碳酸酯和丙烯腈-丁二烯-苯乙烯接枝共聚物耐热阻燃合金 |
CN101418116B (zh) * | 2007-10-22 | 2011-04-27 | 广东银禧科技股份有限公司 | 一种导热聚碳酸酯组合物及其制备方法 |
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