CN102586800A - 一种纳米铜粉的制备方法 - Google Patents
一种纳米铜粉的制备方法 Download PDFInfo
- Publication number
- CN102586800A CN102586800A CN2011100094433A CN201110009443A CN102586800A CN 102586800 A CN102586800 A CN 102586800A CN 2011100094433 A CN2011100094433 A CN 2011100094433A CN 201110009443 A CN201110009443 A CN 201110009443A CN 102586800 A CN102586800 A CN 102586800A
- Authority
- CN
- China
- Prior art keywords
- copper
- nano
- copper nanoparticle
- copper powder
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 102
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000010949 copper Substances 0.000 claims abstract description 109
- 229910052802 copper Inorganic materials 0.000 claims abstract description 87
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 44
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 11
- 238000001291 vacuum drying Methods 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 239000004020 conductor Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000003960 organic solvent Substances 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims abstract description 4
- 239000002105 nanoparticle Substances 0.000 claims description 60
- 238000000034 method Methods 0.000 claims description 35
- 239000008151 electrolyte solution Substances 0.000 claims description 12
- 238000003487 electrochemical reaction Methods 0.000 claims description 10
- 238000009461 vacuum packaging Methods 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910021397 glassy carbon Inorganic materials 0.000 claims description 5
- 238000012856 packing Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000011084 recovery Methods 0.000 claims description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- 238000002848 electrochemical method Methods 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 238000000703 high-speed centrifugation Methods 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 230000000630 rising effect Effects 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 239000002243 precursor Substances 0.000 abstract description 9
- 230000002829 reductive effect Effects 0.000 abstract description 7
- 238000009826 distribution Methods 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000003792 electrolyte Substances 0.000 abstract 3
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract 1
- 238000007789 sealing Methods 0.000 abstract 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical group [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 6
- 239000010985 leather Substances 0.000 description 6
- 101000760658 Cupiennius salei Cupiennin-2e Proteins 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- SRUKOJDGOUUFRB-UHFFFAOYSA-N heptylazanium;chloride Chemical class Cl.CCCCCCCN SRUKOJDGOUUFRB-UHFFFAOYSA-N 0.000 description 3
- 238000000643 oven drying Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 235000015096 spirit Nutrition 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 150000001879 copper Chemical class 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- -1 Virahol Chemical compound 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000002498 deadly effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 1
- YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Landscapes
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110009443.3A CN102586800B (zh) | 2011-01-17 | 2011-01-17 | 一种纳米铜粉的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110009443.3A CN102586800B (zh) | 2011-01-17 | 2011-01-17 | 一种纳米铜粉的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102586800A true CN102586800A (zh) | 2012-07-18 |
CN102586800B CN102586800B (zh) | 2015-05-13 |
Family
ID=46476010
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201110009443.3A Active CN102586800B (zh) | 2011-01-17 | 2011-01-17 | 一种纳米铜粉的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102586800B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104550993A (zh) * | 2014-12-31 | 2015-04-29 | 黄冈师范学院 | 单分散纳米铜粉的制备方法 |
CN105177696A (zh) * | 2015-08-26 | 2015-12-23 | 湖北工程学院 | 一种形貌可控的铜纳米结构材料的制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4615736A (en) * | 1985-05-01 | 1986-10-07 | Allied Corporation | Preparation of metal powders |
CN1827266A (zh) * | 2006-04-10 | 2006-09-06 | 李小毛 | 一种纳米镍粉的制备方法 |
CN101580944A (zh) * | 2009-06-25 | 2009-11-18 | 中南大学 | 一种电化学合成金属醇、胺类化合物的装置 |
-
2011
- 2011-01-17 CN CN201110009443.3A patent/CN102586800B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4615736A (en) * | 1985-05-01 | 1986-10-07 | Allied Corporation | Preparation of metal powders |
CN1827266A (zh) * | 2006-04-10 | 2006-09-06 | 李小毛 | 一种纳米镍粉的制备方法 |
CN101580944A (zh) * | 2009-06-25 | 2009-11-18 | 中南大学 | 一种电化学合成金属醇、胺类化合物的装置 |
Non-Patent Citations (2)
Title |
---|
周幸福,韩爱杰,褚道葆,顾家山: ""阳极溶解法"制备金属醇盐及其影响因素", 《安徽师范大学学报(自然科学版)》, vol. 24, no. 3, 30 September 2001 (2001-09-30), pages 228 - 230 * |
株洲冶炼厂《冶金读本》编写小组: "《铜的精炼》", 30 September 1973, article "铜的精炼", pages: 126-127 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104550993A (zh) * | 2014-12-31 | 2015-04-29 | 黄冈师范学院 | 单分散纳米铜粉的制备方法 |
CN105177696A (zh) * | 2015-08-26 | 2015-12-23 | 湖北工程学院 | 一种形貌可控的铜纳米结构材料的制备方法 |
CN105177696B (zh) * | 2015-08-26 | 2017-10-17 | 湖北工程学院 | 一种形貌可控的铜纳米结构材料的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN102586800B (zh) | 2015-05-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104209526B (zh) | 一种微细球形钛合金粉体的制备方法 | |
CN102888630B (zh) | 一种离子液体/添加剂体系低温电沉积制备纳米铝或纳米铝镀层的方法 | |
CN103122465B (zh) | 一种片状金属粉末的制备方法 | |
CN102757036A (zh) | 多孔石墨烯的制备方法 | |
CN100391663C (zh) | 一种纳米镍粉的制备方法 | |
CN106994347B (zh) | 一种制备方形铜纳米粒子-石墨烯-泡沫镍材料的方法 | |
CN103962570A (zh) | 一种纳米镍粉的制备方法 | |
CN103407989A (zh) | 一种氮边缘掺杂石墨烯的低温环保制备方法 | |
CN102737863B (zh) | 银镍石墨复合触头材料及其加工方法 | |
CN102502610A (zh) | 一种大量制备石墨烯的简单方法 | |
CN114787084B (zh) | 一种γ-Ga2O3纳米材料的制备方法 | |
CN107904570B (zh) | 一种制备镍纳米粒子-石墨烯-泡沫镍材料的方法 | |
CN105562704A (zh) | 水热合成法制备钴纳米磁性材料的方法 | |
CN110527943B (zh) | 用超临界二氧化碳对镁及镁合金防腐蚀处理的装置及方法 | |
CN106549146B (zh) | 一种原位复合制备石墨烯基富锂层状锰酸锂电极材料的方法 | |
CN102586800B (zh) | 一种纳米铜粉的制备方法 | |
CN106379889A (zh) | 一种制备氟化石墨烯副产高纯氟化锂的方法和设备 | |
CN103484889A (zh) | 一种大量制备高质量少层石墨烯粉末的方法 | |
CN109371446A (zh) | 一种c3n4薄膜的制备方法 | |
CN109052380A (zh) | 全液态水相物理剥离制备石墨烯的方法 | |
CN105355839B (zh) | 一种石墨烯‑金复合电极及其制备方法和应用 | |
CN103950925B (zh) | 一种纳米级石墨片的制备方法 | |
CN102634816A (zh) | 一种纳米氧化铟锡粉的制备方法 | |
CN107032338A (zh) | 一种连续电爆炸解裂石墨制备石墨烯的方法 | |
CN103288074A (zh) | 一种纳米新金刚石粉体的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20120718 Assignee: Hefei quantum source nano Polytron Technologies Inc Assignor: Li Xiaomao Contract record no.: 2019340000006 Denomination of invention: Method for preparing nano copper powder Granted publication date: 20150513 License type: Exclusive License Record date: 20190513 |
|
DD01 | Delivery of document by public notice | ||
DD01 | Delivery of document by public notice |
Addressee: Li Xiaomao Document name: Notice of termination of patent |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201020 Address after: 244000 office building, No. 618 Hengsheng Road, suburb of Tongling City, Anhui Province Patentee after: Anhui nalomite New Material Technology Co., Ltd Address before: Jinzhai road in Baohe District of Hefei city in Anhui province 230022 96 Building No. 5 No. 301 Patentee before: Li Xiaomao |