CN102498237B - 使用卤化烯烃发泡剂的改进的聚氨酯发泡工艺以及泡沫特性 - Google Patents

使用卤化烯烃发泡剂的改进的聚氨酯发泡工艺以及泡沫特性 Download PDF

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Publication number
CN102498237B
CN102498237B CN201080040871.6A CN201080040871A CN102498237B CN 102498237 B CN102498237 B CN 102498237B CN 201080040871 A CN201080040871 A CN 201080040871A CN 102498237 B CN102498237 B CN 102498237B
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China
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blowing agent
polyurethane foam
chf2
hfe
ch2f
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Chinese (zh)
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CN102498237A (zh
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J·S·柯斯塔
B·B·陈
P·波内特
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Arkema Inc
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Arkema Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
CN201080040871.6A 2009-09-09 2010-09-01 使用卤化烯烃发泡剂的改进的聚氨酯发泡工艺以及泡沫特性 Active CN102498237B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US24072709P 2009-09-09 2009-09-09
US61/240,727 2009-09-09
PCT/US2010/047453 WO2011031598A1 (en) 2009-09-09 2010-09-01 Improved polyurethane foaming processes and foam properties using halogenated olefin blowing agent

Publications (2)

Publication Number Publication Date
CN102498237A CN102498237A (zh) 2012-06-13
CN102498237B true CN102498237B (zh) 2014-10-01

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CN201080040871.6A Active CN102498237B (zh) 2009-09-09 2010-09-01 使用卤化烯烃发泡剂的改进的聚氨酯发泡工艺以及泡沫特性

Country Status (9)

Country Link
US (1) US20120172476A1 (enExample)
EP (1) EP2475803A4 (enExample)
JP (2) JP2013504656A (enExample)
CN (1) CN102498237B (enExample)
BR (1) BR112012005374A2 (enExample)
CA (1) CA2773366C (enExample)
IN (1) IN2012DN02082A (enExample)
WO (1) WO2011031598A1 (enExample)
ZA (1) ZA201201679B (enExample)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110152392A1 (en) * 2009-12-17 2011-06-23 Honeywell International Inc. Catalysts For Polyurethane Foam Polyol Premixes Containing Halogenated Olefin Blowing Agents
EP2250144A4 (en) * 2008-03-07 2014-06-04 Arkema Inc FORMULATED AND STABLE SYSTEMS CONTAINING CHLORO-3,3,3-TRIFLUOROPROPENE
EP2164917B1 (en) * 2008-03-07 2019-04-24 Arkema Inc. Halogenated alkene heat transfer compositions with improved oil return
BR112012005374A2 (pt) * 2009-09-09 2016-03-29 Arkema Inc processos de melhoramento de espuma de poliuretano e propriedades da espuma utilizando agentes de insuflação de olefinas halogenadas
CN106750482A (zh) 2011-03-11 2017-05-31 阿科玛股份有限公司 包含卤代烯烃发泡剂的聚氨酯多元醇共混物的改善的稳定性
EP2737006A4 (en) * 2011-07-28 2015-11-04 Honeywell Int Inc FOAMS AND FLAME-RESISTANT ARTICLES OF FOAMING WITH 1-CHLORO-3,3,3-TRIFLUORPROPENE (1233ZD)
US10308783B2 (en) 2012-09-24 2019-06-04 Arkema Inc. Stability of polyurethane polyol blends containing halogenated olefin blowing agent
US20160262490A1 (en) * 2015-03-13 2016-09-15 Honeywell International Inc. Foams, foamable compositions and methods of making integral skin foams
CN107635955A (zh) 2015-05-21 2018-01-26 科慕埃弗西有限公司 通过SbF5进行的1233xf至244bb的氢氟化
KR102433944B1 (ko) * 2016-07-29 2022-08-19 알케마 인코포레이티드 개선된 저장수명을 갖는 폴리올 프리-믹스
CN106496494B (zh) * 2016-10-28 2019-01-04 合肥华凌股份有限公司 一种低密度、低导热率的聚氨酯泡沫及其制备方法
US11370875B2 (en) 2016-12-08 2022-06-28 Sekisui Chemical Co., Ltd. Urethane resin composition
JPWO2018159430A1 (ja) * 2017-03-01 2019-12-19 パナソニックＩｐマネジメント株式会社 断熱体、断熱箱体、断熱扉及び冷凍冷蔵庫
EP3601394A1 (en) 2017-03-24 2020-02-05 INVISTA Textiles (U.K.) Limited Polyol compositions for foam insulation
JP6826191B2 (ja) * 2017-04-11 2021-02-03 オートリブ ディベロップメント エービー ポリウレタンフォーム製造方法、ステアリングホイール製造方法およびステアリングホイール
US10640600B2 (en) 2018-04-24 2020-05-05 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
US10752725B2 (en) 2018-04-24 2020-08-25 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
WO2020005270A1 (en) * 2018-06-29 2020-01-02 Boral Ip Holdings (Australia) Pty Limited Foam composites and methods of preparation thereof
US11161931B2 (en) 2019-03-08 2021-11-02 Covestro Llc Polyol blends and their use in producing PUR-PIR foam-forming compositions
US11053340B2 (en) 2019-03-08 2021-07-06 Covestro Llc HCFO-containing isocyanate-reactive compositions, related foam-forming compositions and PUR-PIR foams
US10851196B2 (en) 2019-04-29 2020-12-01 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
WO2020223059A1 (en) 2019-04-29 2020-11-05 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
US11932761B2 (en) 2021-02-08 2024-03-19 Covestro Llc HFCO-containing isocyanate-reactive compositions, polyurethane foams formed therefrom, and composite articles that include such foams
US12275815B2 (en) * 2021-03-03 2025-04-15 Natural Polymers, LLC Pest-resistant spray foam formulations
JP2025502041A (ja) * 2022-01-13 2025-01-24 ハネウェル・インターナショナル・インコーポレーテッド 改善された特性を有する低密度熱硬化性発泡体
US11827735B1 (en) 2022-09-01 2023-11-28 Covestro Llc HFO-containing isocyanate-reactive compositions, related foam-forming compositions and flame retardant PUR-PIR foams

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5506275A (en) * 1995-05-15 1996-04-09 Basf Corporation 1,1,1,2-tetrafluoroethane as a blowing agent in integral skin polyurethane shoe soles
US5684057A (en) * 1995-11-01 1997-11-04 Basf Corporation Three component polyol blend for use in insulating rigid polyurethane foams
CN101443394A (zh) * 2006-03-31 2009-05-27 阿克马法国公司 发泡剂组合物

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60235823A (ja) * 1984-05-07 1985-11-22 Kao Corp ポリウレタンフオ−ムの製造法
BR9815152A (pt) * 1997-12-04 2000-10-10 Dow Chemical Co Espumas de poliuretano de baixa densidade sopradas com co2, processo para sua obtenção e artigo obtido
JP2001181365A (ja) * 1999-12-24 2001-07-03 Nisshinbo Ind Inc 真空断熱パネル充填材用連続気泡硬質ポリウレタンフォームの製造方法
JP4058954B2 (ja) * 2002-01-31 2008-03-12 旭硝子株式会社 軟質ポリウレタンフォーム
US9796848B2 (en) * 2002-10-25 2017-10-24 Honeywell International Inc. Foaming agents and compositions containing fluorine substituted olefins and methods of foaming
US8420706B2 (en) * 2005-06-24 2013-04-16 Honeywell International Inc. Foaming agents, foamable compositions, foams and articles containing halogen substituted olefins, and methods of making same
US9000061B2 (en) * 2006-03-21 2015-04-07 Honeywell International Inc. Foams and articles made from foams containing 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd)
US9695267B2 (en) * 2009-08-11 2017-07-04 Honeywell International Inc. Foams and foamable compositions containing halogenated olefin blowing agents
US8097660B2 (en) * 2006-08-31 2012-01-17 Bayer Materialscience Llc Rigid polyurethane foams with low thermal conductivity and a process for their production
WO2008094238A1 (en) * 2007-01-30 2008-08-07 Dow Global Technologies, Inc. Ortho-cyclohexanediamine-initiated polyols and rigid polyurethane foam made therefrom
WO2008121783A1 (en) * 2007-03-29 2008-10-09 Arkema Inc. Blowing agent composition of hydrochlorofluoroolefin
US20100016457A1 (en) * 2008-07-16 2010-01-21 Bowman James M Hfo-1234ze mixed isomers with hfc-245fa as a blowing agent, aerosol, and solvent
US8163196B2 (en) * 2008-10-28 2012-04-24 Honeywell International Inc. Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene
BR112012005374A2 (pt) * 2009-09-09 2016-03-29 Arkema Inc processos de melhoramento de espuma de poliuretano e propriedades da espuma utilizando agentes de insuflação de olefinas halogenadas

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5506275A (en) * 1995-05-15 1996-04-09 Basf Corporation 1,1,1,2-tetrafluoroethane as a blowing agent in integral skin polyurethane shoe soles
US5684057A (en) * 1995-11-01 1997-11-04 Basf Corporation Three component polyol blend for use in insulating rigid polyurethane foams
CN101443394A (zh) * 2006-03-31 2009-05-27 阿克马法国公司 发泡剂组合物

Also Published As

Publication number Publication date
CA2773366C (en) 2018-03-06
ZA201201679B (en) 2012-11-28
IN2012DN02082A (enExample) 2015-08-21
CA2773366A1 (en) 2011-03-17
JP2016121363A (ja) 2016-07-07
BR112012005374A2 (pt) 2016-03-29
EP2475803A4 (en) 2017-05-24
JP2013504656A (ja) 2013-02-07
CN102498237A (zh) 2012-06-13
US20120172476A1 (en) 2012-07-05
JP6388616B2 (ja) 2018-09-12
EP2475803A1 (en) 2012-07-18
WO2011031598A1 (en) 2011-03-17

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