JP2013504656A - ハロゲン化オレフィン発泡剤を使用した、改良されたポリウレタン発泡プロセス、およびフォームの性質 - Google Patents

ハロゲン化オレフィン発泡剤を使用した、改良されたポリウレタン発泡プロセス、およびフォームの性質 Download PDF

Info

Publication number
JP2013504656A
JP2013504656A JP2012528829A JP2012528829A JP2013504656A JP 2013504656 A JP2013504656 A JP 2013504656A JP 2012528829 A JP2012528829 A JP 2012528829A JP 2012528829 A JP2012528829 A JP 2012528829A JP 2013504656 A JP2013504656 A JP 2013504656A
Authority
JP
Japan
Prior art keywords
chf
hfe
blowing agent
isomers
agent composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2012528829A
Other languages
English (en)
Japanese (ja)
Inventor
ジョセフ・エス・コスタ
ベンジャミン・ビー・チェン
フィリップ・ボネット
Original Assignee
アーケマ・インコーポレイテッド
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by アーケマ・インコーポレイテッド filed Critical アーケマ・インコーポレイテッド
Publication of JP2013504656A publication Critical patent/JP2013504656A/ja
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
JP2012528829A 2009-09-09 2010-09-01 ハロゲン化オレフィン発泡剤を使用した、改良されたポリウレタン発泡プロセス、およびフォームの性質 Pending JP2013504656A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US24072709P 2009-09-09 2009-09-09
US61/240,727 2009-09-09
PCT/US2010/047453 WO2011031598A1 (en) 2009-09-09 2010-09-01 Improved polyurethane foaming processes and foam properties using halogenated olefin blowing agent

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2016057230A Division JP6388616B2 (ja) 2009-09-09 2016-03-22 ハロゲン化オレフィン発泡剤を使用した、改良されたポリウレタン発泡プロセス、およびフォームの性質

Publications (1)

Publication Number Publication Date
JP2013504656A true JP2013504656A (ja) 2013-02-07

Family

ID=43732755

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2012528829A Pending JP2013504656A (ja) 2009-09-09 2010-09-01 ハロゲン化オレフィン発泡剤を使用した、改良されたポリウレタン発泡プロセス、およびフォームの性質
JP2016057230A Active JP6388616B2 (ja) 2009-09-09 2016-03-22 ハロゲン化オレフィン発泡剤を使用した、改良されたポリウレタン発泡プロセス、およびフォームの性質

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2016057230A Active JP6388616B2 (ja) 2009-09-09 2016-03-22 ハロゲン化オレフィン発泡剤を使用した、改良されたポリウレタン発泡プロセス、およびフォームの性質

Country Status (9)

Country Link
US (1) US20120172476A1 (enExample)
EP (1) EP2475803A4 (enExample)
JP (2) JP2013504656A (enExample)
CN (1) CN102498237B (enExample)
BR (1) BR112012005374A2 (enExample)
CA (1) CA2773366C (enExample)
IN (1) IN2012DN02082A (enExample)
WO (1) WO2011031598A1 (enExample)
ZA (1) ZA201201679B (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016121363A (ja) * 2009-09-09 2016-07-07 アーケマ・インコーポレイテッド ハロゲン化オレフィン発泡剤を使用した、改良されたポリウレタン発泡プロセス、およびフォームの性質
WO2018189972A1 (ja) * 2017-04-11 2018-10-18 オートリブ ディベロップメント エービー ポリウレタンフォーム製造方法、ステアリングホイール製造方法およびステアリングホイール
JPWO2018105730A1 (ja) * 2016-12-08 2019-07-25 積水化学工業株式会社 ウレタン樹脂組成物

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110152392A1 (en) * 2009-12-17 2011-06-23 Honeywell International Inc. Catalysts For Polyurethane Foam Polyol Premixes Containing Halogenated Olefin Blowing Agents
JP6134470B2 (ja) * 2008-03-07 2017-05-24 アーケマ・インコーポレイテッド クロロ−３，３，３−トリフルオロプロペンによる安定した処方系
CN105505323A (zh) * 2008-03-07 2016-04-20 阿科玛股份有限公司 具有改进的油返回的卤代烯热传输组合物
BR112013023254B1 (pt) 2011-03-11 2020-12-15 Arkema Inc Composição pré-mistura de poliol e método para estabilizar uma mistura de espuma termofixa
JP2014527553A (ja) * 2011-07-28 2014-10-16 ハネウェル・インターナショナル・インコーポレーテッド １−クロロ−３，３，３−トリフルオロプロペン（１２３３ｚｄ）を含むフォーム、及びフォームから製造される耐炎性物品
EP2898038A4 (en) * 2012-09-24 2016-04-27 Arkema Inc IMPROVED STABILITY OF MIXTURES OF POLYOLS AND POLYURETHANE CONTAINING HALOGENATED OLEFIN BLOWING AGENT
US20160262490A1 (en) * 2015-03-13 2016-09-15 Honeywell International Inc. Foams, foamable compositions and methods of making integral skin foams
CN107635955A (zh) 2015-05-21 2018-01-26 科慕埃弗西有限公司 通过SbF5进行的1233xf至244bb的氢氟化
CA3032272A1 (en) * 2016-07-29 2018-02-01 Arkema Inc. Polyol pre-mixes having improved shelf life
CN106496494B (zh) * 2016-10-28 2019-01-04 合肥华凌股份有限公司 一种低密度、低导热率的聚氨酯泡沫及其制备方法
JPWO2018159430A1 (ja) * 2017-03-01 2019-12-19 パナソニックＩｐマネジメント株式会社 断熱体、断熱箱体、断熱扉及び冷凍冷蔵庫
US20200392279A1 (en) 2017-03-24 2020-12-17 Invista North America S.A.R.L. Polyol compositions for foam insulation
US10752725B2 (en) 2018-04-24 2020-08-25 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
US10640600B2 (en) 2018-04-24 2020-05-05 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
WO2020005270A1 (en) 2018-06-29 2020-01-02 Boral Ip Holdings (Australia) Pty Limited Foam composites and methods of preparation thereof
WO2020146442A1 (en) 2019-01-11 2020-07-16 Covestro Llc Hcfo-containing isocyanate-reactive compositions, related foam-forming compositions and polyurethane foams
US11161931B2 (en) 2019-03-08 2021-11-02 Covestro Llc Polyol blends and their use in producing PUR-PIR foam-forming compositions
US11053340B2 (en) 2019-03-08 2021-07-06 Covestro Llc HCFO-containing isocyanate-reactive compositions, related foam-forming compositions and PUR-PIR foams
US10851196B2 (en) 2019-04-29 2020-12-01 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
JP2022531217A (ja) 2019-04-29 2022-07-06 コベストロ・エルエルシー パネル断熱材としての使用に適した硬質ポリウレタンフォーム
US11932761B2 (en) 2021-02-08 2024-03-19 Covestro Llc HFCO-containing isocyanate-reactive compositions, polyurethane foams formed therefrom, and composite articles that include such foams
US12275815B2 (en) * 2021-03-03 2025-04-15 Natural Polymers, LLC Pest-resistant spray foam formulations
WO2023137148A1 (en) * 2022-01-13 2023-07-20 Honeywell International Inc. Low density thermosetting foams having improved properties
US11827735B1 (en) 2022-09-01 2023-11-28 Covestro Llc HFO-containing isocyanate-reactive compositions, related foam-forming compositions and flame retardant PUR-PIR foams

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60235823A (ja) * 1984-05-07 1985-11-22 Kao Corp ポリウレタンフオ−ムの製造法
JP2001181365A (ja) * 1999-12-24 2001-07-03 Nisshinbo Ind Inc 真空断熱パネル充填材用連続気泡硬質ポリウレタンフォームの製造方法
JP2003221427A (ja) * 2002-01-31 2003-08-05 Asahi Glass Co Ltd 軟質ポリウレタンフォーム
WO2008121783A1 (en) * 2007-03-29 2008-10-09 Arkema Inc. Blowing agent composition of hydrochlorofluoroolefin
WO2010062572A2 (en) * 2008-10-28 2010-06-03 Honeywell International Inc. Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5506275A (en) * 1995-05-15 1996-04-09 Basf Corporation 1,1,1,2-tetrafluoroethane as a blowing agent in integral skin polyurethane shoe soles
US5648019A (en) * 1995-11-01 1997-07-15 Basf Corporation Three component polyol blend for use in insulating rigid polyurethane foams
CN1283208A (zh) * 1997-12-04 2001-02-07 陶氏化学公司 低密度co2吹制聚氨酯泡沫材料及其制备方法
US9796848B2 (en) * 2002-10-25 2017-10-24 Honeywell International Inc. Foaming agents and compositions containing fluorine substituted olefins and methods of foaming
US8420706B2 (en) * 2005-06-24 2013-04-16 Honeywell International Inc. Foaming agents, foamable compositions, foams and articles containing halogen substituted olefins, and methods of making same
US9000061B2 (en) * 2006-03-21 2015-04-07 Honeywell International Inc. Foams and articles made from foams containing 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd)
US9695267B2 (en) * 2009-08-11 2017-07-04 Honeywell International Inc. Foams and foamable compositions containing halogenated olefin blowing agents
FR2899233B1 (fr) * 2006-03-31 2010-03-12 Arkema Composition d'agent d'expansion
US8097660B2 (en) * 2006-08-31 2012-01-17 Bayer Materialscience Llc Rigid polyurethane foams with low thermal conductivity and a process for their production
WO2008094238A1 (en) * 2007-01-30 2008-08-07 Dow Global Technologies, Inc. Ortho-cyclohexanediamine-initiated polyols and rigid polyurethane foam made therefrom
US20100016457A1 (en) * 2008-07-16 2010-01-21 Bowman James M Hfo-1234ze mixed isomers with hfc-245fa as a blowing agent, aerosol, and solvent
IN2012DN02082A (enExample) * 2009-09-09 2015-08-21 Arkema Inc

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60235823A (ja) * 1984-05-07 1985-11-22 Kao Corp ポリウレタンフオ−ムの製造法
JP2001181365A (ja) * 1999-12-24 2001-07-03 Nisshinbo Ind Inc 真空断熱パネル充填材用連続気泡硬質ポリウレタンフォームの製造方法
JP2003221427A (ja) * 2002-01-31 2003-08-05 Asahi Glass Co Ltd 軟質ポリウレタンフォーム
WO2008121783A1 (en) * 2007-03-29 2008-10-09 Arkema Inc. Blowing agent composition of hydrochlorofluoroolefin
WO2010062572A2 (en) * 2008-10-28 2010-06-03 Honeywell International Inc. Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016121363A (ja) * 2009-09-09 2016-07-07 アーケマ・インコーポレイテッド ハロゲン化オレフィン発泡剤を使用した、改良されたポリウレタン発泡プロセス、およびフォームの性質
JPWO2018105730A1 (ja) * 2016-12-08 2019-07-25 積水化学工業株式会社 ウレタン樹脂組成物
JP6993238B2 (ja) 2016-12-08 2022-01-13 積水化学工業株式会社 ウレタン樹脂組成物
US11370875B2 (en) 2016-12-08 2022-06-28 Sekisui Chemical Co., Ltd. Urethane resin composition
WO2018189972A1 (ja) * 2017-04-11 2018-10-18 オートリブ ディベロップメント エービー ポリウレタンフォーム製造方法、ステアリングホイール製造方法およびステアリングホイール
JPWO2018189972A1 (ja) * 2017-04-11 2020-01-09 オートリブ ディベロップメント エービー ポリウレタンフォーム製造方法、ステアリングホイール製造方法およびステアリングホイール

Also Published As

Publication number Publication date
EP2475803A4 (en) 2017-05-24
EP2475803A1 (en) 2012-07-18
CN102498237B (zh) 2014-10-01
BR112012005374A2 (pt) 2016-03-29
JP2016121363A (ja) 2016-07-07
ZA201201679B (en) 2012-11-28
CA2773366C (en) 2018-03-06
CA2773366A1 (en) 2011-03-17
CN102498237A (zh) 2012-06-13
US20120172476A1 (en) 2012-07-05
JP6388616B2 (ja) 2018-09-12
WO2011031598A1 (en) 2011-03-17
IN2012DN02082A (enExample) 2015-08-21

Similar Documents

Publication Publication Date Title
JP6388616B2 (ja) ハロゲン化オレフィン発泡剤を使用した、改良されたポリウレタン発泡プロセス、およびフォームの性質
JP6373894B2 (ja) ポリウレタンフォームのためのテトラフルオロブテン発泡剤組成物
JP5947788B2 (ja) ハロゲン化オレフィン発泡剤を含むポリウレタンポリオールブレンド物の安定性を改良する方法
JP6594297B2 (ja) ハロゲン化オレフィン発泡剤を含有する安定化ポリウレタンポリオールブレンド
US8314159B2 (en) Blowing agent composition of hydrochlorofluoroolefin
JP5890895B2 (ja) ハロゲン化オレフィン発泡剤を含有するポリウレタンポリオールブレンドの安定性の向上
CN109476979B (zh) 具有改善的存储寿命的多元醇预混物
US20240150536A1 (en) Blowing agents comprising z-1-chloro-2,3,3,3-tetrafluoropentene (hcfo-1224yd(z))

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20130808

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20131210

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20131217

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20140310

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20140317

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20140617

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20150106

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20150403

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20150703

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20151201