CA2773366C - Improved polyurethane foaming processes and foam properties using halogenated olefin blowing agent - Google Patents

Improved polyurethane foaming processes and foam properties using halogenated olefin blowing agent Download PDF

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Publication number
CA2773366C
CA2773366C CA2773366A CA2773366A CA2773366C CA 2773366 C CA2773366 C CA 2773366C CA 2773366 A CA2773366 A CA 2773366A CA 2773366 A CA2773366 A CA 2773366A CA 2773366 C CA2773366 C CA 2773366C
Authority
CA
Canada
Prior art keywords
polyurethane foam
isomers
blowing agent
foam
trifluoropropene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2773366A
Other languages
English (en)
French (fr)
Other versions
CA2773366A1 (en
Inventor
Joseph S. Costa
Benjamin B. Chen
Philippe Bonnet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema Inc
Original Assignee
Arkema Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema Inc filed Critical Arkema Inc
Publication of CA2773366A1 publication Critical patent/CA2773366A1/en
Application granted granted Critical
Publication of CA2773366C publication Critical patent/CA2773366C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
CA2773366A 2009-09-09 2010-09-01 Improved polyurethane foaming processes and foam properties using halogenated olefin blowing agent Active CA2773366C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US24072709P 2009-09-09 2009-09-09
US61/240,727 2009-09-09
PCT/US2010/047453 WO2011031598A1 (en) 2009-09-09 2010-09-01 Improved polyurethane foaming processes and foam properties using halogenated olefin blowing agent

Publications (2)

Publication Number Publication Date
CA2773366A1 CA2773366A1 (en) 2011-03-17
CA2773366C true CA2773366C (en) 2018-03-06

Family

ID=43732755

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2773366A Active CA2773366C (en) 2009-09-09 2010-09-01 Improved polyurethane foaming processes and foam properties using halogenated olefin blowing agent

Country Status (9)

Country Link
US (1) US20120172476A1 (enExample)
EP (1) EP2475803A4 (enExample)
JP (2) JP2013504656A (enExample)
CN (1) CN102498237B (enExample)
BR (1) BR112012005374A2 (enExample)
CA (1) CA2773366C (enExample)
IN (1) IN2012DN02082A (enExample)
WO (1) WO2011031598A1 (enExample)
ZA (1) ZA201201679B (enExample)

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US20110152392A1 (en) * 2009-12-17 2011-06-23 Honeywell International Inc. Catalysts For Polyurethane Foam Polyol Premixes Containing Halogenated Olefin Blowing Agents
ES2727525T3 (es) * 2008-03-07 2019-10-16 Arkema Inc Composiciones de transferencia térmica de alqueno halogenado con retorno de aceite mejorado
US20110001080A1 (en) * 2008-03-07 2011-01-06 Arkema Inc. Stable formulated systems with chloro-3,3,3-trifluoropropene
BR112012005374A2 (pt) * 2009-09-09 2016-03-29 Arkema Inc processos de melhoramento de espuma de poliuretano e propriedades da espuma utilizando agentes de insuflação de olefinas halogenadas
JP6512541B2 (ja) 2011-03-11 2019-05-15 アーケマ・インコーポレイテッド ハロゲン化オレフィン発泡剤を含有するポリウレタンポリオールブレンドの安定性の向上
MX353653B (es) * 2011-07-28 2018-01-23 Honeywell Int Inc Espumas y articulos pirorresistentes fabricados a partir de las espumas que contienen 1 - cloro - 3,3,3 - trifluoropropeno (1233zd).
CA2885423C (en) * 2012-09-24 2020-09-22 Arkema Inc. Improved stability of polyurethane polyol blends containing halogenated olefin blowing agent
US20160262490A1 (en) * 2015-03-13 2016-09-15 Honeywell International Inc. Foams, foamable compositions and methods of making integral skin foams
US10301236B2 (en) 2015-05-21 2019-05-28 The Chemours Company Fc, Llc Hydrofluorination of a halogenated olefin with SbF5 in the liquid phase
WO2018022419A1 (en) * 2016-07-29 2018-02-01 Arkema Inc. Polyol pre-mixes having improved shelf life
CN106496494B (zh) * 2016-10-28 2019-01-04 合肥华凌股份有限公司 一种低密度、低导热率的聚氨酯泡沫及其制备方法
CN110062781B (zh) * 2016-12-08 2021-10-22 积水化学工业株式会社 氨基甲酸酯树脂组合物
JPWO2018159430A1 (ja) * 2017-03-01 2019-12-19 パナソニックＩｐマネジメント株式会社 断熱体、断熱箱体、断熱扉及び冷凍冷蔵庫
US20200392279A1 (en) 2017-03-24 2020-12-17 Invista North America S.A.R.L. Polyol compositions for foam insulation
JP6826191B2 (ja) * 2017-04-11 2021-02-03 オートリブ ディベロップメント エービー ポリウレタンフォーム製造方法、ステアリングホイール製造方法およびステアリングホイール
US10640600B2 (en) 2018-04-24 2020-05-05 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
US10752725B2 (en) 2018-04-24 2020-08-25 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
WO2020005270A1 (en) * 2018-06-29 2020-01-02 Boral Ip Holdings (Australia) Pty Limited Foam composites and methods of preparation thereof
US12540214B2 (en) 2019-01-11 2026-02-03 Covestro Llc HCFO-containing isocyanate-reactive compositions, related foam-forming compositions and polyurethane foams
US11053340B2 (en) 2019-03-08 2021-07-06 Covestro Llc HCFO-containing isocyanate-reactive compositions, related foam-forming compositions and PUR-PIR foams
US11161931B2 (en) 2019-03-08 2021-11-02 Covestro Llc Polyol blends and their use in producing PUR-PIR foam-forming compositions
CN113748150A (zh) 2019-04-29 2021-12-03 科思创有限公司 适合用作板隔热材料的硬质聚氨酯泡沫
US10851196B2 (en) 2019-04-29 2020-12-01 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
US11932761B2 (en) 2021-02-08 2024-03-19 Covestro Llc HFCO-containing isocyanate-reactive compositions, polyurethane foams formed therefrom, and composite articles that include such foams
US12275815B2 (en) * 2021-03-03 2025-04-15 Natural Polymers, LLC Pest-resistant spray foam formulations
US20230265234A1 (en) * 2022-01-13 2023-08-24 Honeywell International Inc. Low density thermosetting foams having improved properties
US11827735B1 (en) 2022-09-01 2023-11-28 Covestro Llc HFO-containing isocyanate-reactive compositions, related foam-forming compositions and flame retardant PUR-PIR foams

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JPS60235823A (ja) * 1984-05-07 1985-11-22 Kao Corp ポリウレタンフオ−ムの製造法
US5506275A (en) * 1995-05-15 1996-04-09 Basf Corporation 1,1,1,2-tetrafluoroethane as a blowing agent in integral skin polyurethane shoe soles
US5648019A (en) * 1995-11-01 1997-07-15 Basf Corporation Three component polyol blend for use in insulating rigid polyurethane foams
AU737063B2 (en) * 1997-12-04 2001-08-09 Dow Chemical Company, The Low density CO2-blown polyurethane foams and a process of preparing same
JP2001181365A (ja) * 1999-12-24 2001-07-03 Nisshinbo Ind Inc 真空断熱パネル充填材用連続気泡硬質ポリウレタンフォームの製造方法
JP4058954B2 (ja) * 2002-01-31 2008-03-12 旭硝子株式会社 軟質ポリウレタンフォーム
US9796848B2 (en) * 2002-10-25 2017-10-24 Honeywell International Inc. Foaming agents and compositions containing fluorine substituted olefins and methods of foaming
US8420706B2 (en) * 2005-06-24 2013-04-16 Honeywell International Inc. Foaming agents, foamable compositions, foams and articles containing halogen substituted olefins, and methods of making same
US9000061B2 (en) * 2006-03-21 2015-04-07 Honeywell International Inc. Foams and articles made from foams containing 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd)
US9695267B2 (en) * 2009-08-11 2017-07-04 Honeywell International Inc. Foams and foamable compositions containing halogenated olefin blowing agents
FR2899233B1 (fr) * 2006-03-31 2010-03-12 Arkema Composition d'agent d'expansion
US8097660B2 (en) * 2006-08-31 2012-01-17 Bayer Materialscience Llc Rigid polyurethane foams with low thermal conductivity and a process for their production
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WO2008121783A1 (en) * 2007-03-29 2008-10-09 Arkema Inc. Blowing agent composition of hydrochlorofluoroolefin
US20100016457A1 (en) * 2008-07-16 2010-01-21 Bowman James M Hfo-1234ze mixed isomers with hfc-245fa as a blowing agent, aerosol, and solvent
US8163196B2 (en) * 2008-10-28 2012-04-24 Honeywell International Inc. Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene
BR112012005374A2 (pt) * 2009-09-09 2016-03-29 Arkema Inc processos de melhoramento de espuma de poliuretano e propriedades da espuma utilizando agentes de insuflação de olefinas halogenadas

Also Published As

Publication number Publication date
JP6388616B2 (ja) 2018-09-12
EP2475803A1 (en) 2012-07-18
CN102498237B (zh) 2014-10-01
WO2011031598A1 (en) 2011-03-17
BR112012005374A2 (pt) 2016-03-29
ZA201201679B (en) 2012-11-28
CN102498237A (zh) 2012-06-13
EP2475803A4 (en) 2017-05-24
CA2773366A1 (en) 2011-03-17
JP2016121363A (ja) 2016-07-07
US20120172476A1 (en) 2012-07-05
JP2013504656A (ja) 2013-02-07
IN2012DN02082A (enExample) 2015-08-21

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