CN102471444B - 包括具有仲羟基端基的聚酯多元醇的聚氨酯聚合物的制备方法 - Google Patents

包括具有仲羟基端基的聚酯多元醇的聚氨酯聚合物的制备方法 Download PDF

Info

Publication number
CN102471444B
CN102471444B CN201080029612.3A CN201080029612A CN102471444B CN 102471444 B CN102471444 B CN 102471444B CN 201080029612 A CN201080029612 A CN 201080029612A CN 102471444 B CN102471444 B CN 102471444B
Authority
CN
China
Prior art keywords
acid
polyester
preparation
end groups
general formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201080029612.3A
Other languages
English (en)
Chinese (zh)
Other versions
CN102471444A (zh
Inventor
H.内夫兹格
J.霍夫曼
B.克勒切夫斯基
E.鲍尔
K.洛伦茨
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Publication of CN102471444A publication Critical patent/CN102471444A/zh
Application granted granted Critical
Publication of CN102471444B publication Critical patent/CN102471444B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4291—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from polyester forming components containing monoepoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C08G18/4241—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols from dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4261—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups prepared by oxyalkylation of polyesterpolyols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4263—Polycondensates having carboxylic or carbonic ester groups in the main chain containing carboxylic acid groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/916—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
CN201080029612.3A 2009-07-01 2010-06-29 包括具有仲羟基端基的聚酯多元醇的聚氨酯聚合物的制备方法 Expired - Fee Related CN102471444B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102009031218.8 2009-07-01
DE102009031218 2009-07-01
PCT/EP2010/003935 WO2011000546A1 (de) 2009-07-01 2010-06-29 Verfahren zur herstellung eines polyurethan-polymers mit sekundären hydroxyl-endgruppen umfassenden polyesterpolyolen

Publications (2)

Publication Number Publication Date
CN102471444A CN102471444A (zh) 2012-05-23
CN102471444B true CN102471444B (zh) 2014-05-28

Family

ID=42493120

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080029612.3A Expired - Fee Related CN102471444B (zh) 2009-07-01 2010-06-29 包括具有仲羟基端基的聚酯多元醇的聚氨酯聚合物的制备方法

Country Status (10)

Country Link
US (1) US9139685B2 (enExample)
EP (1) EP2448987B1 (enExample)
JP (1) JP5540093B2 (enExample)
CN (1) CN102471444B (enExample)
BR (1) BRPI1015039A2 (enExample)
MX (1) MX2011013703A (enExample)
PL (1) PL2448987T3 (enExample)
RU (1) RU2543383C2 (enExample)
WO (1) WO2011000546A1 (enExample)
ZA (1) ZA201108836B (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013024108A1 (de) 2011-08-16 2013-02-21 Bayer Intellectual Property Gmbh Verfahren zur herstellung eines polyurethan-polyisocyanurat-hartschaums
WO2013024107A1 (de) 2011-08-16 2013-02-21 Bayer Intellectual Property Gmbh Verfahren zur herstellung eines polyurethan-polyisocyanurat-hartschaums
DE202013004202U1 (de) * 2013-04-26 2014-08-05 Bayer Materialscience Ag Geschäumter Formkörper
AU2015231278B2 (en) 2014-03-20 2020-01-23 Alkermes Pharma Ireland Limited Aripiprazole formulations having increased injection speeds
EP3121547A1 (en) 2015-07-22 2017-01-25 ETH Zurich System and method for storing and releasing heat
EP3515957B1 (en) 2016-09-25 2023-01-11 PTT Global Chemical Public Company Limited Biorenewable high performance polyester polyols
EP3613787A1 (de) * 2018-08-24 2020-02-26 Covestro Deutschland AG Polyurethane mit verbesserter härte
EP3719046B1 (en) * 2019-04-03 2023-05-10 Henkel AG & Co. KGaA Crystalline polyesterpolyol
CN112745492B (zh) * 2021-01-15 2023-07-14 万华化学集团股份有限公司 一种用于聚氨酯热熔胶的聚酯多元醇及其制备方法和应用
CN116333285B (zh) * 2022-12-09 2025-04-01 万华化学集团股份有限公司 一种低反应活性聚酯多元醇及其制备方法和应用
CN116284716B (zh) * 2023-03-27 2025-11-25 旭川化学（苏州）有限公司 一种聚酯及其制备方法和应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1108013A (en) * 1964-05-13 1968-03-27 Ici Ltd Improvements in or relating to foamed polyurethanes
US3502601A (en) * 1966-03-07 1970-03-24 Leslie C Case Novel polyurethanes and processes of preparing the same
EP0086309A1 (en) * 1981-12-28 1983-08-24 Ford Motor Company Limited Coating compositions and polyhydroxy oligomer precursor therefor
US4647595A (en) * 1985-10-17 1987-03-03 Asahi Glass Company, Ltd. Process for producing a urethane-modified polyisocyanurate foam
NL9201868A (nl) * 1992-10-28 1994-05-16 Dsm Nv Bindmiddelsamenstelling voor poederverven op basis van een hydroxyl functioneel polymeer als bindmiddel en een isocyanaat groepen bevattende verbinding als crosslinker.

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4144395A (en) 1977-12-05 1979-03-13 Basf Wyandotte Corporation Process for the preparation of polyether-ester polyols
NL164082C (nl) 1978-10-31 1980-11-17 Unilever Nv Poederlak.
US4379906A (en) * 1981-12-28 1983-04-12 Ford Motor Company High solids urethane coatings prepared from a polylisocyanate _ and a polyhydroxy oligmer
DE3613875A1 (de) * 1986-04-24 1987-10-29 Basf Ag Verfahren zur herstellung von polyester-polyolen
DE4400300A1 (de) 1994-01-07 1995-07-13 Akzo Nobel Nv Verfahren zur Herstellung von film- und faserbildenden Polyestern und Copolyestern
DE4409043A1 (de) 1994-03-17 1995-09-21 Bayer Ag Verfahren zur Herstellung von gegebenenfalls zellförmigen Polyurethanen
EP0692507A1 (en) * 1994-07-11 1996-01-17 Basf Corporation Flexible open-cell polyurethane foam
DE19618392A1 (de) 1996-05-08 1997-11-13 Basf Ag Verfahren zur Herstellung von elastischen Polyurethan-Formkörpern mit kompakter Oberfläche und zelligem Kern
DE19949091A1 (de) 1999-10-12 2001-04-26 Basf Ag Polyester-Polyetherblockcopolymere
US6562880B1 (en) 2002-04-17 2003-05-13 Bayer Corporation Polyurethane or polyisocyanurate foams blown with hydrofluorocarbons and carbon atoms
CA2605987C (en) * 2005-04-29 2013-11-05 Zenon Lysenko Polyester polyols containing secondary alcohol groups and their use in making polyurethanes such as flexible polyurethane foams

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1108013A (en) * 1964-05-13 1968-03-27 Ici Ltd Improvements in or relating to foamed polyurethanes
US3502601A (en) * 1966-03-07 1970-03-24 Leslie C Case Novel polyurethanes and processes of preparing the same
EP0086309A1 (en) * 1981-12-28 1983-08-24 Ford Motor Company Limited Coating compositions and polyhydroxy oligomer precursor therefor
US4647595A (en) * 1985-10-17 1987-03-03 Asahi Glass Company, Ltd. Process for producing a urethane-modified polyisocyanurate foam
NL9201868A (nl) * 1992-10-28 1994-05-16 Dsm Nv Bindmiddelsamenstelling voor poederverven op basis van een hydroxyl functioneel polymeer als bindmiddel en een isocyanaat groepen bevattende verbinding als crosslinker.

Also Published As

Publication number Publication date
ZA201108836B (en) 2015-05-27
RU2543383C2 (ru) 2015-02-27
MX2011013703A (es) 2012-02-22
JP5540093B2 (ja) 2014-07-02
BRPI1015039A2 (pt) 2016-04-12
WO2011000546A1 (de) 2011-01-06
RU2012103237A (ru) 2013-08-10
CN102471444A (zh) 2012-05-23
US9139685B2 (en) 2015-09-22
JP2012531505A (ja) 2012-12-10
US20120123008A1 (en) 2012-05-17
EP2448987A1 (de) 2012-05-09
EP2448987B1 (de) 2016-03-23
PL2448987T3 (pl) 2017-08-31

Similar Documents

Publication Publication Date Title
CN102471444B (zh) 包括具有仲羟基端基的聚酯多元醇的聚氨酯聚合物的制备方法
CN102414239B (zh) 制备具有仲oh端基的聚酯多元醇的方法
JP2012531505A5 (enExample)
JP2013527281A (ja) ポリイソシアネートプレポリマーおよびその使用
KR20140143411A (ko) 폴리이소시아네이트 삼량체화 촉매 조성물
JP6563528B2 (ja) セシウム塩が添加された高分子カルボジイミドの合成方法、高分子カルボジイミド、それらの使用
JPH0144733B2 (enExample)
JP2007530751A (ja) 触媒として亜鉛化合物を使用するポリエーテルアロファネートの製造方法
JP6426091B2 (ja) イソシアナート官能性環状カルボナート
US9328196B2 (en) Process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups
US20180134836A1 (en) Polyurethane coverings having reduced water absorption and use thereof
CN103588943A (zh) 用于异氰酸酯和醇之间的反应的新的催化剂
CN107556451B (zh) 大分子型聚天门冬氨酸酯及其制备方法
JP2022151503A (ja) イソシアネート組成物、２液型ウレタン樹脂形成性組成物、およびウレタン樹脂
ES2575652T3 (es) Procedimiento para la preparación de un polímero de poliuretano con poliolésteres que comprenden grupos terminales hidroxilo secundarios
JP4529676B2 (ja) 反応性安定化ポリカーボネートポリオールの製造方法及び反応性安定化ポリカーボネートポリオールを用いたポリウレタン樹脂
RU2771386C1 (ru) Форполимер, содержащий оксазолидиндионовые концевые группы
JPH09263622A (ja) ポリウレタンウレアおよびその製造方法
JP3632967B2 (ja) ポリウレタンウレア製造用ポリオールの製造方法
JP2013525583A (ja) ポリウレタンエラストマー、その製造方法およびその使用
CN112839972A (zh) 噁唑烷二酮封端的预聚物
WO2022023229A1 (en) Curable compositions and products formed therefrom, and methods of forming the same
KR20140002060A (ko) 합성 피혁용 폴리우레탄 수지에 사용되는 강신도 향상제 그리고 이것을 사용한 폴리올 조성물 및 폴리우레탄 수지
HK1253691B (en) Method for the synthesis of polymer carbodiimides with added cesium salts, polymer carbodiimides and use thereof
JPH0684418B2 (ja) ポリ（ウレタン）ウレアアミド重合体の発泡体

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140528

Termination date: 20160629