CN102470356B - 包括被固定的分子催化剂的杂化无机/有机高分子催化膜材料及其制备 - Google Patents

包括被固定的分子催化剂的杂化无机/有机高分子催化膜材料及其制备 Download PDF

Info

Publication number
CN102470356B
CN102470356B CN201080029981.2A CN201080029981A CN102470356B CN 102470356 B CN102470356 B CN 102470356B CN 201080029981 A CN201080029981 A CN 201080029981A CN 102470356 B CN102470356 B CN 102470356B
Authority
CN
China
Prior art keywords
catalyst
catalysis material
hybrid inorganic
catalysis
preformed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201080029981.2A
Other languages
English (en)
Chinese (zh)
Other versions
CN102470356A (zh
Inventor
P·巴巴洛
C·比安奇尼
F·利果里
泽春夫
F·维扎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kodoshi Corp
Original Assignee
Nippon Kodoshi Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kodoshi Corp filed Critical Nippon Kodoshi Corp
Publication of CN102470356A publication Critical patent/CN102470356A/zh
Application granted granted Critical
Publication of CN102470356B publication Critical patent/CN102470356B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/069—Hybrid organic-inorganic polymers, e.g. silica derivatized with organic groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • B01J31/1683—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins the linkage being to a soluble polymer, e.g. PEG or dendrimer, i.e. molecular weight enlarged complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
    • B01J31/2466—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/16—Preparation of optical isomers
    • C07C231/18—Preparation of optical isomers by stereospecific synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0269—Complexes comprising ligands derived from the natural chiral pool or otherwise having a characteristic structure or geometry
    • B01J2531/0272—Complexes comprising ligands derived from the natural chiral pool or otherwise having a characteristic structure or geometry derived from carbohydrates, including e.g. tartrates or DIOP
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/18—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201080029981.2A 2010-03-31 2010-03-31 包括被固定的分子催化剂的杂化无机/有机高分子催化膜材料及其制备 Expired - Fee Related CN102470356B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2010/056288 WO2011121797A1 (en) 2010-03-31 2010-03-31 Hybrid inorganic/organic polymer catalytic membrane materials comprising immobilized molecular catalysts and their preparation

Publications (2)

Publication Number Publication Date
CN102470356A CN102470356A (zh) 2012-05-23
CN102470356B true CN102470356B (zh) 2016-08-03

Family

ID=43334512

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080029981.2A Expired - Fee Related CN102470356B (zh) 2010-03-31 2010-03-31 包括被固定的分子催化剂的杂化无机/有机高分子催化膜材料及其制备

Country Status (11)

Country Link
US (1) US20130035225A1 (pt)
EP (1) EP2393594A1 (pt)
JP (1) JP5713910B2 (pt)
KR (1) KR101671845B1 (pt)
CN (1) CN102470356B (pt)
BR (1) BRPI1014094A2 (pt)
CA (1) CA2735200C (pt)
HK (1) HK1166035A1 (pt)
RU (1) RU2542364C2 (pt)
TW (1) TWI526249B (pt)
WO (1) WO2011121797A1 (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103619479B (zh) * 2011-06-24 2017-02-15 日本高度纸工业株式会社 包含金属纳米颗粒的无机/聚合物的杂化催化材料
CA2860959A1 (en) * 2012-02-14 2013-08-22 Nippon Kodoshi Corporation Inorganic / polymeric hybrid catalytic materials with high activity in various solvents
JP6011768B2 (ja) * 2012-03-08 2016-10-19 国立大学法人京都大学 連続的な不斉合成法及びその方法に用いるｄｎａを含有するハイブリッド触媒
TWI586693B (zh) 2013-07-23 2017-06-11 財團法人工業技術研究院 選擇性氫化共聚物的方法
CN103570554A (zh) * 2013-10-26 2014-02-12 合肥禾味食品有限公司 Ru-Binap催化剂在催化特定结构底物的异构化反应方面的应用
US9242432B1 (en) * 2014-12-30 2016-01-26 Owens Corning Intellectual Capital, Llc Roofing material with locally applied fire resistant material
WO2016171572A1 (en) * 2015-04-24 2016-10-27 Auckland Uniservices Limited Oxidation method
CN105457677B (zh) * 2015-12-03 2017-09-15 广东南海普锐斯科技有限公司 一种基于聚合物电解质载体的有序贵金属催化剂层及其制备方法
CN106854159B (zh) * 2015-12-09 2019-01-04 中国科学院大连化学物理研究所 一种苯乙炔羰基化合成不饱和芳香酯的方法
US11224853B2 (en) 2018-04-11 2022-01-18 W. L. Gore & Associates, Inc. Metal supported powder catalyst matrix and processes for multiphase chemical reactions
CN111454136A (zh) * 2019-01-22 2020-07-28 中国科学院上海高等研究院 用于催化偕二取代芳香烯烃的氢甲酰化反应的催化剂及其制备方法和用途
JP2023052710A (ja) * 2020-03-04 2023-04-12 国立大学法人 東京大学 触媒及び光学活性アミド化合物の製造方法
CN111545247B (zh) * 2020-03-25 2023-06-09 华东师范大学 一种sba-15负载的多相手性膦金催化剂及其制备方法和应用
CN115055208B (zh) * 2022-06-24 2024-05-10 安庆市长三角未来产业研究院 两相流催化膜的制备方法、两相流催化膜及其应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998028074A1 (en) * 1996-12-23 1998-07-02 Seton Hall University Novel supported catalysts
CN1706885A (zh) * 2004-06-10 2005-12-14 日本高度纸工业株式会社 固体电解质以及使用该固体电解质的电化学系统
CN1822901A (zh) * 2003-07-14 2006-08-23 上游纳动股份有限公司 具有受控配位结构的负载型催化剂以及制备该催化剂的方法
CN101076492A (zh) * 2004-10-27 2007-11-21 阿科塔（共同）股份公司 用于制备合成气和富氢气体混合物的纳米结构金属催化剂的用途

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69920642T2 (de) * 1998-12-28 2006-02-23 Orient Chemical Industries, Ltd. Organische/anorganische Hybridmaterialien und Verfahren zu deren Herstellung
CN1134459C (zh) * 2000-12-27 2004-01-14 中国科学院长春应用化学研究所 有机-无机纳米杂化复合载体茂金属催化剂及其在苯乙烯聚合中的应用
JP3889605B2 (ja) * 2001-10-31 2007-03-07 ニッポン高度紙工業株式会社 高イオン伝導性固体電解質及び該固体電解質を使用した電気化学システム
RU2255805C2 (ru) * 2003-02-25 2005-07-10 Кочетков Алексей Юрьевич Гетерогенный катализатор окисления неорганических и/или органических соединений на полимерном носителе
DE102005040189B4 (de) * 2005-06-28 2011-08-18 Blücher GmbH, 40699 Trägermaterial mit katalytisch aktiven Polymerpartikeln

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998028074A1 (en) * 1996-12-23 1998-07-02 Seton Hall University Novel supported catalysts
CN1822901A (zh) * 2003-07-14 2006-08-23 上游纳动股份有限公司 具有受控配位结构的负载型催化剂以及制备该催化剂的方法
CN1706885A (zh) * 2004-06-10 2005-12-14 日本高度纸工业株式会社 固体电解质以及使用该固体电解质的电化学系统
CN101076492A (zh) * 2004-10-27 2007-11-21 阿科塔（共同）股份公司 用于制备合成气和富氢气体混合物的纳米结构金属催化剂的用途

Non-Patent Citations (10)

* Cited by examiner, † Cited by third party
Title
"catalytic polymeric membranes：preparation and application";ozdemir s s etal.;《applied catalysis A：general》;20060703;第206卷(第2期);第233-241页 *
"anchored homogeneous catalysts：high turnover number applications";Simons C etal.;《journal of molecular catalysis A: chemical》;20040424;第216卷(第2期);第189-197页 *
"Aspects of Immobilisation of Catalysts on Polymeric Supports";Dioos B M L etal.;《advanced synthesis and catalysis》;20060811;第348卷(第12-13期);第1413-1446页 *
"Comparision of supports for the electrostatic immobilization of asymmetric homogeneous catalysts";Simons C etal.;《Journal of catalysis》;20060401;第239卷(第1期);第212-219页 *
"First heterogenisation of Ru-MeDuPHOS by occlusion in PDMS (polydimethylsiloxane) membrane";Ivo Vankelecom etal.;《Chem.Commun.》;19991231;第1999卷(第23期);第2407页左栏第3段，右栏第1段，图1-2，流程图1 *
"Noncovalent immobilization of enantioselective catalysts";Fraile JM etal.;《Chem.Rev.》;20081217;第109卷(第2期);第402-404页，图66，表25-30 *
"Palladium modified porous polymeric membranes and their performance in selective hydrogenation of propyne";Ziegler etal.;《Journal of membrane science》;20010615;第187卷(第1-2期);第71-84页 *
"Recycling asymmetric hydrogenation catalysts by their immobilization onto ion-exchange resins";Barbaro P etal.;《Dalton transactions》;20040519;第2004卷(第12期);第1783-1784页 *
"study on catalytic membranes of H3PW12O40entrapped in PVA";Qinglin Liu etal.;《Membrane Science》;19990701;第159卷(第1-2期);第233-241页 *
"The acid-catalysed reaction of α-pinene over molybdophosphoric acid immobilized in dense polymeric membranes";J E Castanheiro etal.;《Catalysis Today》;20030626;第82卷(第1-4期);第187页右栏第2段，第188页左栏第3段，第188页2.1，第190页3.2，4结论 *

Also Published As

Publication number Publication date
EP2393594A1 (en) 2011-12-14
KR101671845B1 (ko) 2016-11-02
RU2011143940A (ru) 2013-05-10
JP2013523416A (ja) 2013-06-17
HK1166035A1 (zh) 2012-10-19
KR20130048125A (ko) 2013-05-09
JP5713910B2 (ja) 2015-05-07
BRPI1014094A2 (pt) 2016-04-19
US20130035225A1 (en) 2013-02-07
CN102470356A (zh) 2012-05-23
TW201141607A (en) 2011-12-01
CA2735200A1 (en) 2011-09-30
TWI526249B (zh) 2016-03-21
CA2735200C (en) 2017-09-19
RU2542364C2 (ru) 2015-02-20
WO2011121797A1 (en) 2011-10-06

Similar Documents

Publication Publication Date Title
CN102470356B (zh) 包括被固定的分子催化剂的杂化无机/有机高分子催化膜材料及其制备
Bianchini et al. Recent aspects of asymmetric catalysis by immobilized chiral metal catalysts
Trindade et al. Recyclable stereoselective catalysts
Yasukawa et al. Chiral ligand-modified metal nanoparticles as unique catalysts for asymmetric C–C bond-forming reactions: how are active species generated?
Bergbreiter Using soluble polymers to recover catalysts and ligands
van Heerbeek et al. Dendrimers as support for recoverable catalysts and reagents
Fan et al. Recoverable catalysts for asymmetric organic synthesis
Pugin et al. More than 100,000 turnovers with immobilized Ir‐diphosphine catalysts in an enantioselective imine hydrogenation
CN103619479B (zh) 包含金属纳米颗粒的无机/聚合物的杂化催化材料
Bianchini et al. Immobilization of Optically Active Rhodium‐Diphosphine Complexes on Porous Silica via Hydrogen Bonding
JP2001507621A (ja) 新規な担持触媒
Nomura et al. Use of pyridine-coated star-shaped ROMP polymer as the supporting ligand for ruthenium-catalyzed chemoselective hydrogen transfer reduction of ketones
KR101797091B1 (ko) 다양한 용매 내에서 높은 활성을 가지는 무기/폴리머계 혼성 촉매 물질
Jamis et al. Aqueous enantioselective hydrogenations involving silica-heterogenised catalysts
Barbaro et al. Enantioselective hydrogenation of prochiral substrates in catalytic membrane reactors
Zsigmond et al. Chemoselective and enantioselective hydrogenations on immobilized complexes
WO2006030202A1 (en) “heterogenised” homogeneous catalysts
Sinou During the last 20 years there have been very important advances in asymmetric synthesis via the use of a soluble chiral organometallic catalyst [1]. Now enantiose-lectivities higher than 95% have been obtained currently in reactions such as hy-drogenation, isomerization, epoxidation, hydroxylation, and allylic substitution. Al

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1166035

Country of ref document: HK

C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
REG Reference to a national code

Ref country code: HK

Ref legal event code: GR

Ref document number: 1166035

Country of ref document: HK

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160803

Termination date: 20190331

CF01 Termination of patent right due to non-payment of annual fee