CN102423286A - Natural hair dye prepared from plant pigment curcumin and hair dyeing method thereof - Google Patents

Natural hair dye prepared from plant pigment curcumin and hair dyeing method thereof Download PDF

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Publication number
CN102423286A
CN102423286A CN2011103764140A CN201110376414A CN102423286A CN 102423286 A CN102423286 A CN 102423286A CN 2011103764140 A CN2011103764140 A CN 2011103764140A CN 201110376414 A CN201110376414 A CN 201110376414A CN 102423286 A CN102423286 A CN 102423286A
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agent
hair
curcumin
dyeing
natural
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CN102423286B (en
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高海燕
高莉红
侯秀良
戚黎萍
蔡利
王海军
史慧
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Jiangnan University
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Jiangnan University
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Abstract

The invention relates to a hair dye, in particular to a natural hair dye prepared from plant pigment curcumin and a hair dyeing method thereof. The hair dye comprises a component A and a component B, and is characterized in that the component A comprises 0.1-10% of curcumin, 20-50% of polyhydric alcohol, 1-5% of thickening agent and 1-10% of surfactant, the pH is adjusted to 3-7, and the balance is water; the agent C comprises 1-10% of metal ion mordant, 1-5% of thickening agent, 1-10% of surfactant and 0.1-0.3% of natural essence, the pH value is adjusted to 3-7, and the balance is water, and the unit is weight percentage. When dyeing hair, uniformly applying the agent A to hair, and dyeing hair at normal temperature to 60 ℃ for 10-40 min; then uniformly coating the agent B on hair, mordanting for 10-20min, cleaning hair and drying. Curcumin has good dyeing effect and also has the effects of antibiosis and skin care. The hair dye does not use a reagent which is toxic to human bodies, does not generate substances which are toxic to human bodies in the hair dyeing process, and has good safety. The pigment curcumin adopted by the invention is insoluble in water and is not easy to fall off in the washing process, so the dyeing effect is good, and the dyed hair color can be kept for a long time.

Description

Adopt a kind of natural hair dye and the hair colouring methods thereof of the preparation of plant pigment curcumin
Technical field
The present invention relates to a kind of hair dye, particularly a kind of oil-soluble curcumin that adopts is the natural hair dye and the hair colouring methods thereof of one-component plant pigment.
Background technology
The hair dye of selling in the market mostly contains p-phenylenediamine (PPD), para-aminophenol, hydroquinone etc., and life-time service causes multiple disease, like alopecia, and skin allergy, skin carcinoma, malignant tumor etc.Progressively improving and the continuous progress of the science of improving looks of Along with people's health perception, the hair dye of natural plant pigment preparation becomes following hair dye market developing trend day by day.In the existing patent, the main pigment of botanical hair dye comprises Quercetin, hematoxylin, catechin etc.The subject matter that existing botanical hair dye exists is, the dye-uptake of hair dye is lower, and color fastness is relatively poor.
Curcumin is a kind of chemical constituent of from the zingiberaceous plant rhizome, extracting as natural pigment, and wherein, Rhizoma Curcumae Longae contains 3%~6% approximately, is the very rare pigment with diketone of plant kingdom, is cyclohexadione compounds.Curcumin is orange-yellow crystalline powder, and flavor is bitter, water insoluble slightly.Curcumin has effects such as blood fat reducing, antitumor, antiinflammatory, function of gallbladder promoting, antioxidation.In hair dye, using of curcumin has patent report now, and Chinese patent 201010225971.8 discloses a kind of method for preparing, method for using that comprises the hair dye of Rhizoma Curcumae Longae and tannic acid material, and commercial packing.It serves as the main effect component of colored hair dyeing with the Stigma Croci extract that one Chinese patent application 201110008881.8 discloses a kind of, dyes the colour hair dyeing frost that the color matching composition combines with the plant coloured silk.Wherein said plant coloured silk dyes the color matching composition to be made up of Fructus Rosae Laevigatae extract, acorn cup extract, Rhizoma Curcumae Longae extract, perhaps is made up of Madder extract, Fructus Lycopersici esculenti extract and Fructus Gardeniae extract.But these all are to adjust agent to curcumin as color, and do not consider the water-fast characteristic of curcumin.
Summary of the invention
The objective of the invention is to adopt oil-soluble natural pigment curcumin is the main pigment composition of hair dye, prepares a kind of new type natural botanical hair dye.This hair dye is formed by two doses, and agent A contains the plant pigment curcumin, and agent B contains the metal mordant.
According to technical scheme provided by the invention, adopt oil-soluble plant pigment curcumin to prepare a kind of novel natural hair dye and comprise agent A and agent B, it is characterized in that; Agent A comprises plant pigment curcumin 0.1%-10%; Polyhydric alcohol 20-50%, surfactant 1-10%, thickening agent 1-5%; All the other are water, regulate pH to 5-7; Agent B comprises and comprises metal mordant 1-5%, thickening agent 1-5%, and surfactant 1-10%, natural essence 0.1-0.3%, all the other are water, regulate pH to 5-7.Unit is a percetage by weight.
Polyhydric alcohol among the agent A is one or more in wetting agent glycerol, butanediol, the isopropyl alcohol.
The metal mordant is the salt that allows any metal ion of use in the cosmetics among the agent B, includes but not limited to ferrous sulfate, ferrous chloride, iron chloride, zinc sulfate, aluminum chloride, copper nitrate.Natural essence can adopt a kind of in Flos Rosae Rugosae essence, jasmine flower essence, the lavandula angustifolia essence.
The pH of agent A mediating recipe B regulates with phosphoric acid, acetic acid, lactic acid, tartaric acid or citric acid.
Described thickening agent includes but not limited to the one or more combination in Radix Acaciae senegalis, carboxymethyl cellulose, hydroxyethyl-cellulose, guar gum, the propylene glycol stearate.
Surfactant comprises anion, cation, both sexes or non-ionic surface active agents such as stearyl alcohol, glyceryl stearate, sodium lauryl sulfate, OPEO.
Agent A and agent B are solution or any degree thickening or the liquid that adds glue, Emulsion or cream frost form.
The hair colouring methods of the oil-soluble natural hair dye of said employing curcumin one-component plant pigment is characterized in that, during hair dyeing, at first agent B evenly is applied in hair, at room temperature to 60 ℃ following hair dyeing 10-40min; Then agent C evenly is applied in hair, behind the mordant dyeing 10-20min, hair cleaned dries up.
The curcumin that the present invention adopts is a kind of natural pigment that from rhizome such as Zingiberaceae Curcuma (Curcuma L) plant Rhizoma Curcumae Longae, Rhizoma Curcumae, Radix Curcumae, extracts, and can cooperate with the different metal ion to form various chromatic colours.And Color is good, color fastness is stronger, has effects such as antibiotic skin-care again.The present invention has solved the oil-soluble curcumin and has added the common hair dye problem of come-up easily to through adding polyhydric alcohol, realizes the good stability of product, thereby makes the hair dyeing of one-component plant pigment curcumin become a reality.Because the oil-soluble plant pigment is water insoluble, its wash resistant ability is obviously strengthened in addition.Therefore, this hair dye has safe and reliable, the advantage of Color stable and durable.
The specific embodiment
Below in conjunction with embodiment technical scheme of the present invention is further described, but protection scope of the present invention is not limited to this.
Embodiment 1
Agent A: curcumin 0.7%, isopropyl alcohol 26%, carboxymethyl cellulose 1%, propylene glycol stearate 1%, glyceryl stearate 1%,, the deionized water surplus is transferred pH to 5 with phosphoric acid.
Agent B: ferrous sulfate 2%, reduced iron powder 0.2%, Polyethylene Glycol 10%, carboxymethyl cellulose 2%, stearyl alcohol 2%, the deionized water surplus, lavandula angustifolia essence 0.1% is transferred pH to 5 with phosphoric acid.
Hair colouring methods: agent A evenly is applied in hair, and the 40min that has hair dyed at normal temperatures evenly is applied in hair with agent B then, behind the mordant dyeing 10min hair is cleaned to dry up, and hair is the more shallow brownish black of nature.
Embodiment 2
Agent A: curcumin 5%, butanediol 10%, isopropyl alcohol 25%, hydroxyethyl-cellulose 1%, propylene glycol stearate 2%, ceteareth-20 1%, the deionized water surplus is transferred pH to 6 with phosphoric acid.
Agent B: ferrous sulfate 8%, reduced iron powder 0.2%, guar gum 2%, jasmine flower essence 0.3%, the deionized water surplus is transferred pH to 5 with acetic acid.
Hair colouring methods: agent A evenly is applied in hair, at 40 ℃ of following hair dyeing 30min, then agent B evenly is applied in hair, behind the mordant dyeing 20min hair cleaned and dry up, hair is the dark brown black of nature.
Embodiment 3:
Agent A: curcumin 3%, glycerol 5%, isopropyl alcohol 30%, NATROSOL 250 0.5%, stearyl alcohol 2%, the deionized water surplus is transferred pH to 5 with acetic acid.
Agent B: iron chloride 5%, guar gum 2%, the deionized water surplus, jasmine flower essence 0.1% is transferred pH to 3 with lactic acid.
Hair colouring methods: agent A evenly is applied in hair, and the 40min that has hair dyed at normal temperatures evenly is applied in hair with agent B then, behind the mordant dyeing 20min hair is cleaned to dry up, and hair is the hestnut color of nature.
Embodiment 4
Agent A: curcumin 2%, butanediol 10%, isopropyl alcohol 15%, carboxymethyl cellulose 1%, propylene glycol stearyl alcohol 1%, the deionization surplus is transferred pH to 6 with lactic acid.
Agent B: zinc sulfate 3.5%, Polyethylene Glycol 5%, hydroxypropyl cellulose 1.5%, rose essence 0.1%, the deionized water surplus is transferred pH to 6.5 with lactic acid.
Hair colouring methods: agent A evenly is applied in hair, at 50 ℃ of following hair dyeing 20min, then agent B evenly is applied in hair, behind the mordant dyeing 15min hair cleaned and dry up, hair is the pale brown color of nature.
Embodiment 5
Agent A: curcumin 8%, isopropyl alcohol 20%, butanediol 25%, carboxymethyl cellulose 1%, stearyl alcohol 2%, the deionized water surplus is transferred pH to 5.5 with phosphoric acid.
Agent B: aluminum chloride 7%, guar gum 2%, rose essence 0.05%, the deionized water surplus is transferred pH to 3 with citric acid.
Hair colouring methods: agent A evenly is applied in hair, at 40 ℃ of following hair dyeing 20min, then agent B evenly is applied in hair, behind the mordant dyeing 15min hair cleaned and dry up, hair is the brownish black of nature.

Claims (3)

1. adopt a kind of natural hair dye of plant pigment curcumin preparation, comprise agent A and agent B, it is characterized in that agent A comprises curcumin 0.1%-10%, polyhydric alcohol 20-50%, thickening agent 1-5%, surfactant 1-10% regulates pH to 3-7, Yu Weishui; Agent C comprises metal ion mordant 1-10%, thickening agent 1-5%, and surfactant 1-10%, natural essence 0.1-0.3% regulates pH to 3-7, Yu Weishui; Unit is a percetage by weight;
Polyhydric alcohol among the agent A is one or more in wetting agent glycerol, butanediol, the isopropyl alcohol.
The metal mordant is the salt that allows any metal ion of use in the cosmetics among the agent B, includes but not limited to ferrous sulfate, ferrous chloride, iron chloride, zinc sulfate, aluminum chloride, copper nitrate.
Natural essence among the agent B can adopt a kind of in Flos Rosae Rugosae essence, jasmine flower essence, the lavandula angustifolia essence.
The pH of agent A mediating recipe B regulates with phosphoric acid, acetic acid, lactic acid, tartaric acid or citric acid.
Thickening agent among the agent A mediating recipe B includes but not limited to the one or more combination in Radix Acaciae senegalis, carboxymethyl cellulose, hydroxyethyl-cellulose, guar gum, the propylene glycol stearate.
The surfactant of agent A mediating recipe B comprises anion, cation, both sexes or non-ionic surface active agents such as stearyl alcohol, glyceryl stearate, sodium lauryl sulfate, OPEO.
2. a kind of natural hair dye of employing plant pigment curcumin preparation as claimed in claim 1 is characterized in that, described dose of A, agent B are solution or any degree thickening or the liquid that adds glue, Emulsion or cream frost form.
3. the hair colouring methods of a kind of natural hair dye of employing plant pigment curcumin preparation as claimed in claim 1 is characterized in that, agent A evenly is applied in hair, at room temperature to 60 ℃ following hair dyeing 10-40min; Then agent B evenly is applied in hair, behind the mordant dyeing 10-20min, hair cleaned dries up.
CN 201110376414 2011-11-24 2011-11-24 Natural hair dye prepared by using phytochrome curcumin and hair dyeing method of natural hair dye Expired - Fee Related CN102423286B (en)

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102824283A (en) * 2012-09-17 2012-12-19 山西大学 Environment-friendly hair-care hair dye and preparation method thereof
CN102924966A (en) * 2012-10-31 2013-02-13 常州大学 Date peel red pigment, and preparation and application thereof
CN104083307A (en) * 2014-07-28 2014-10-08 江南大学 Natural hair dye prepared by adopting plant pigment safflower pigment and hair dyeing method using natural hair dye
CN104825359A (en) * 2015-05-06 2015-08-12 江南大学 Method for preparing natural hair dye from black plum peels
CN104825360A (en) * 2015-05-06 2015-08-12 江南大学 Method for preparing natural hair dye from pumpkin
CN106309248A (en) * 2016-10-13 2017-01-11 江南大学 Natural hair dye prepared from plant pigment geranium haematochrome and hair dyeing method of natural hair dye
CN106309249A (en) * 2016-10-13 2017-01-11 江南大学 Natural hair dye prepared from plant pigment verbena hybrida haematochrome and hair dyeing method of natural hair dye
CN106420499A (en) * 2016-11-28 2017-02-22 河南工程学院 Natural hair dye prepared from fructus chebulae pigment and dyeing method thereof
CN104398441B (en) * 2014-12-08 2017-05-10 上海海洋大学 Seaweed pigment hair dye and application method thereof
CN107616925A (en) * 2017-10-11 2018-01-23 郭迎庆 A kind of preparation method of washable hair dye
CN107789241A (en) * 2017-09-22 2018-03-13 拉芳家化股份有限公司 Hair film composition with hair care colour fixation and preparation method thereof
CN107938389A (en) * 2017-12-28 2018-04-20 张永成 A kind of soft solid agent of antibacterial dyed suitable for natural dye to textile
CN108403580A (en) * 2018-03-30 2018-08-17 王敏 A kind of natural plant pigment hair dye and preparation method thereof and preparation method thereof
JP2018177754A (en) * 2017-04-06 2018-11-15 株式会社ピカソ美化学研究所 Two-pack type hair dye
CN109925205A (en) * 2019-01-31 2019-06-25 西南大学 Natural botanical hair dye and its application method of the compound common Chinese medicine effective component as dyestuff
CN110292536A (en) * 2019-06-25 2019-10-01 许雅婷 Electrochromic process for dyeing keratin fibers and device
CN111407709A (en) * 2020-03-27 2020-07-14 南京益唯森生物科技有限公司 Natural hair dye adopting plant hair dye powder and preparation method thereof
CN112870147A (en) * 2021-03-17 2021-06-01 浙江章华保健美发实业有限公司 Plant type hair dyeing and perming integrated hair beautifying agent
CN113710222A (en) * 2019-04-15 2021-11-26 联合利华知识产权控股有限公司 Personal care compositions comprising tetramethylcurcumin and methods of making the compositions

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FR2838644A1 (en) * 2002-04-23 2003-10-24 Oreal Use of derivatives of 1,7-bisphenyl heptane-3,5-dione (tetrahydrocurcuminoids) as active ingredients in deodorant or antiperspirant cosmetic compositions
US20090249563A1 (en) * 2006-05-01 2009-10-08 Erjena Greaves Composition For Dyeing Keratin Fibers and A Method of Dyeing Hair Using Same
CN101879135A (en) * 2009-11-12 2010-11-10 北京世纪博康医药科技有限公司 Curcuma plant hair dye
CN102078276A (en) * 2011-01-17 2011-06-01 肖子英 Saffron series of plant colorful hair dying cream

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Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102824283B (en) * 2012-09-17 2013-07-10 山西大学 Environment-friendly hair-care hair dye and preparation method thereof
CN102824283A (en) * 2012-09-17 2012-12-19 山西大学 Environment-friendly hair-care hair dye and preparation method thereof
CN102924966A (en) * 2012-10-31 2013-02-13 常州大学 Date peel red pigment, and preparation and application thereof
CN102924966B (en) * 2012-10-31 2014-08-13 常州大学 Date peel red pigment, and preparation and application thereof
CN104083307A (en) * 2014-07-28 2014-10-08 江南大学 Natural hair dye prepared by adopting plant pigment safflower pigment and hair dyeing method using natural hair dye
CN104398441B (en) * 2014-12-08 2017-05-10 上海海洋大学 Seaweed pigment hair dye and application method thereof
CN104825359A (en) * 2015-05-06 2015-08-12 江南大学 Method for preparing natural hair dye from black plum peels
CN104825360A (en) * 2015-05-06 2015-08-12 江南大学 Method for preparing natural hair dye from pumpkin
CN106309249A (en) * 2016-10-13 2017-01-11 江南大学 Natural hair dye prepared from plant pigment verbena hybrida haematochrome and hair dyeing method of natural hair dye
CN106309248A (en) * 2016-10-13 2017-01-11 江南大学 Natural hair dye prepared from plant pigment geranium haematochrome and hair dyeing method of natural hair dye
CN106420499A (en) * 2016-11-28 2017-02-22 河南工程学院 Natural hair dye prepared from fructus chebulae pigment and dyeing method thereof
JP2018177754A (en) * 2017-04-06 2018-11-15 株式会社ピカソ美化学研究所 Two-pack type hair dye
CN107789241A (en) * 2017-09-22 2018-03-13 拉芳家化股份有限公司 Hair film composition with hair care colour fixation and preparation method thereof
CN107616925A (en) * 2017-10-11 2018-01-23 郭迎庆 A kind of preparation method of washable hair dye
CN107938389A (en) * 2017-12-28 2018-04-20 张永成 A kind of soft solid agent of antibacterial dyed suitable for natural dye to textile
CN108403580A (en) * 2018-03-30 2018-08-17 王敏 A kind of natural plant pigment hair dye and preparation method thereof and preparation method thereof
CN109925205A (en) * 2019-01-31 2019-06-25 西南大学 Natural botanical hair dye and its application method of the compound common Chinese medicine effective component as dyestuff
CN113710222A (en) * 2019-04-15 2021-11-26 联合利华知识产权控股有限公司 Personal care compositions comprising tetramethylcurcumin and methods of making the compositions
CN110292536A (en) * 2019-06-25 2019-10-01 许雅婷 Electrochromic process for dyeing keratin fibers and device
CN110292536B (en) * 2019-06-25 2022-07-08 许雅婷 Electrochromic keratin fiber dyeing method and device
CN111407709A (en) * 2020-03-27 2020-07-14 南京益唯森生物科技有限公司 Natural hair dye adopting plant hair dye powder and preparation method thereof
CN112870147A (en) * 2021-03-17 2021-06-01 浙江章华保健美发实业有限公司 Plant type hair dyeing and perming integrated hair beautifying agent

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