CN102824283A - Environment-friendly hair-care hair dye and preparation method thereof - Google Patents

Environment-friendly hair-care hair dye and preparation method thereof Download PDF

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Publication number
CN102824283A
CN102824283A CN2012103438288A CN201210343828A CN102824283A CN 102824283 A CN102824283 A CN 102824283A CN 2012103438288 A CN2012103438288 A CN 2012103438288A CN 201210343828 A CN201210343828 A CN 201210343828A CN 102824283 A CN102824283 A CN 102824283A
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China
Prior art keywords
hair
agent
water
dye
environment
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CN2012103438288A
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Chinese (zh)
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CN102824283B (en
Inventor
张月霞
杨振华
赵艮贵
游建梅
双少敏
董川
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Zhang Hua cosmetics technology Co. Ltd.
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Shanxi University
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Abstract

The invention provides an environment-friendly hair-care hair dye which consists of three agents A, B and C. The agent A comprises the following components: L-cysteine, Na2CO3, triethanolamine, sodium carboxy methyl cellulose, glycerin and water; the agent B comprises the following components; metal salt, the sodium carboxy methyl cellulose, a surfactant, an odorant and the water; and the agent C comprises the following components: pigment, the sodium carboxy methyl cellulose, the surfactant, citric acid, fragrance and the water. The hair dye uses the plant pigment such as tea polyphenol and the like as a dye, has easily obtained raw materials, is low in cost, has no toxicity, is easy to color and also has a hair care effect.

Description

Environment-friendly type hair care hair dye and preparation method thereof
Technical field
The present invention relates to hair dye, specifically is a kind of environment-friendly type hair care hair dye and preparation method thereof.
Background technology
Natural hair dye generally is made up of for two doses A, B, and the A agent is made up of auxiliary agent and metal-chelator, and the B agent is made up of stain.The mechanism of action mainly contains two kinds: a kind of is the pigment absorbent-type.Dye molecule becomes fine particle with the cationic surfactant complexation, cover-hair surface reaches hair dyeing effect; Or present different colours after using the several plant dyestuff to mix, or present different colours with vegetable colour and water colo(u)r collocation.Because dye molecule generally ranges temporary or the semi-permanent mould hair dye only with suction type and the effect of hair scale sheet, mainly is represented as Flos Impatientis, curcumin etc.Second kind is active components of plants and metal complexed; Utilize active component and slaine formation complex in the plant; Penetrate into hair epidermis or cortex, this mode hair dyeing effect is permanent, and this active component is mainly polyhydric phenols haematoxylin and tannins material tannin.The plant of being rich in tannin is used more having in hair dye: Galla Chinensis, Pericarpium Granati etc.CN101283959B discloses the mixture of a kind of ferrous sulfate and tannin as black hair dye, and CN1923164A discloses the hair colouring methods of a kind of ferrous salt and Punica granatum L. extract.Haematein in the CN1045349A file under the effect of ferrous salt, reduced iron powder, can dye hair and is black.Curcumin is acid polyphenols, is a kind of xanthein that obtains that from rhizome such as zingiberaceous plant Rhizoma Curcumae Longae, extracts.CN101879135A find curcumin can with gallotannic acid together with the iron sulfate effect, good as the black hair dye effect.This hair dye is nontoxic, but only is used for white hair is dyed black.CN102423286 discloses a kind of brown hair dye: the hair dye of curcumin and ferrum, zinc, aluminum, copper can be dyed brownish black with hair.But disclosed method as first dose of use, causes hair dyeing inhomogeneous with the metal mordant easily in the file, influences hair dyeing effect.
Summary of the invention
The purpose of this invention is to provide a kind of environment-friendly type hair care hair dye and preparation method thereof, this hair dye raw material is easy to get, and cost is low, nontoxic and easy colouring.
A kind of environment-friendly type hair care hair dye provided by the invention, form for three doses by A, B, C:
The A agent, its components based on weight percentage:
L-cysteine 2 ~ 6%
Na 2CO 33~10%
Triethanolamine 5 ~ 20%
Sodium carboxymethyl cellulose 0.3 ~ 6%
Glycerol 0.5 ~ 5%
Water surplus
The B agent, its components based on weight percentage:
Slaine 2 ~ 10%
Sodium carboxymethyl cellulose 0.3 ~ 6%
Surfactant 1 ~ 10%
Flavouring agent 0.1 ~ 0.3%
Water 80 ~ 95%
The C agent, its components based on weight percentage:
Pigment 2 ~ 15%
Sodium carboxymethyl cellulose 0.3 ~ 6%
Surfactant 1 ~ 10%
Citric acid 1 ~ 5%
Spice 0.1 ~ 0.5%
Water 75 ~ 95%.
Described slaine is MgSO 4, FeCl 3Or CuSO 4Described pigment is hematoxylin or tea polyphenols; Described surfactant is an OPEO.
The effect of A agent can (S-S-) be reduced into the cystine linkage in the hard hair keratoprotein chain-SH; Open hair scale chip architecture closely to a certain extent; Help stain and get into the hair cortical layer smoothly; Promote that stain is deposited on the hair cortical layer, reach dye complete, the persistent purpose of color development.The main metalline mordant of B agent, as mordant, with the dye molecule colour developing, and the fixed dye molecule; The C agent is the colour former that mainly contains the platymiscium polyphenol component, with metal ion effect colour developing and fixing, thereby makes chromotrichia.The effect of citric acid is a pH value of regulating preparation, and the protection hair is not impaired, and especially the hair of the Faculty and Students of traditional blackboard chalk teaching process is participated in protection, exempts from the injury of alkaline chalk dust.And citric acid has certain bactericidal action, so citric acid has certain hair care effect among the present invention.
The hair dye method for preparing: the mixed that A agent, B agent and C agent are pressed separately respectively evenly gets final product.
The hair dye method for using: with the hair wash clean, after drying, the A agent is evenly spread upon on the hair, keep 10min, behind the hair wash clean, repaste is smeared the B agent, keeps 10min, smears the C agent after clean hair is dried and keeps 10min, promptly dyes required color.
Compared with prior art, characteristics of the present invention are following: 1. the present invention adopts tea polyphenols, hematoxylin to have hair dyed as pigment, safety, environmental protection, economy; 2. the present invention adopts the hair dyeing mode of A, B, C three dosage forms, on dye effectively, be not easy to fade; 3. the present invention can satisfy the multiple esthetic requirement of people with hair empurple, brown and blue; 4. the citric acid in the product of the present invention can protect hair not impaired, can neutralize alkaline matter on fur to the damage of body.And citric acid has certain bactericidal action, so the present invention's outbreak usefulness of not only having illicit sexual relations, and also has certain hair care effect.
The specific embodiment
Embodiment 1:
The A agent, its component and content:
L-cysteine 3g
Na 2CO 33g
Triethanolamine 10g
Sodium carboxymethyl cellulose 2g
Glycerol 2g
Water 80g
The B agent, its component and content:
MgSO 46g
Sodium carboxymethyl cellulose 1.5g
OPEO 3g
Flavouring agent 0.2g
Water 89.3g
The C agent, its component and content:
Hematoxylin 8g
Sodium carboxymethyl cellulose 3g
OPEO 4g
Citric acid 2g
Spice 0.1g
Water 82.9g
The mixed that A agent, B agent and C agent are pressed separately respectively is even.Hair is cleaned, evenly be applied on the hair, under 40 ℃, keep 10min with the A agent; Clean hair again, evenly be applied on the hair, keep 10min, clean hair again with the B agent; Evenly be applied on the hair with the C agent, keep 20min, with the residual stain of flushing with clean water, hair is by empurple.Almost do not change at 4 months color and lusters of indoor natural light held.After dyeing back hair is washed 30 times repeatedly, the color yellowing.
Embodiment 2
The A agent, its component and content:
L-cysteine 4g
Na 2CO 36g
Triethanolamine 7g
Sodium carboxymethyl cellulose 3g
Glycerol 3g
Water 77g
The B agent, its component and content:
MgSO 47g
Sodium carboxymethyl cellulose 2g
OPEO 3g
Flavouring agent 0.3g
Water 87.7g
The C agent, its component and content:
Tea polyphenols 6g
Sodium carboxymethyl cellulose 3g
OPEO 4g
Citric acid 1.5g
Spice 0.3g
Water 85.2g
The mixed that A agent, B agent and C agent are pressed separately respectively is even.Hair is cleaned, evenly be applied on the hair, under 40 ℃, keep 10min with the A agent; Clean hair again, evenly be applied on the hair, keep 10min, clean hair again with the B agent; Evenly be applied on the hair with the C agent, keep 20min, with the residual stain of flushing with clean water, hair is dyed pale brown color.Almost do not change at 4 months color and lusters of indoor natural light held.
Embodiment 3
The A agent, its component and content:
L-cysteine 4g
Na 2CO 38g
Triethanolamine 6g
Sodium carboxymethyl cellulose 3g
Glycerol 2g
Water 77g
The B agent, its component and content:
FeCl 37g
Sodium carboxymethyl cellulose 1g
OPEO 2g
Flavouring agent 0.2g
Water 89.8g
The C agent, its component and content:
Tea polyphenols 8g
Sodium carboxymethyl cellulose 3g
OPEO 4g
Citric acid 4g
Spice 0.1g
Water 80.9g
The mixed that A agent, B agent and C agent are pressed separately respectively is even.Hair is cleaned, evenly be applied on the hair, under 40 ℃, keep 10min with the A agent; Clean hair again, evenly be applied on the hair, keep 10min, clean hair again with the B agent; Evenly be applied on the hair with the C agent, keep 20min, with the residual stain of flushing with clean water, hair is dyed brownish black.Almost do not change at 4 months color and lusters of indoor natural light held.
Embodiment 4:
The A agent, its component and content:
L-cysteine 4.5g
Na 2CO 39g
Triethanolamine 4g
Sodium carboxymethyl cellulose 3g
Glycerol 4g
Water 75.5g
The B agent, its component and content:
CuSO 47g
Sodium carboxymethyl cellulose 1g
OPEO 2g
Flavouring agent 0.2g
Water 89.8g
The C agent, its component and content:
Hematoxylin 8g
Sodium carboxymethyl cellulose 2g
OPEO 3g
Spice 0.3g
Water 86.7g
The mixed that A agent, B agent and C agent are pressed separately respectively is even.Hair is cleaned, evenly be applied on the hair, under 40 ℃, keep 10min with the A agent; Clean hair again, evenly be applied on the hair, keep 10min, clean hair again with the B agent; Evenly be applied on the hair with the C agent, keep 20min, with the residual stain of flushing with clean water, hair is dyed blueness (CuSO 4It is light blue that-hematoxylin shows).
The above embodiment only is the better embodiment of part of the present invention, is not that the present invention is done any pro forma restriction.

Claims (4)

1. an environment-friendly type hair care hair dye is characterized in that, is made up of for three doses A, B, C:
The A agent, its components based on weight percentage:
L-cysteine 2 ~ 6%
Na 2CO 33~10%
Triethanolamine 5 ~ 20%
Sodium carboxymethyl cellulose 0.3 ~ 6%
Glycerol 0.5 ~ 5%
Water surplus
The B agent, its components based on weight percentage:
Slaine 2 ~ 10%
Sodium carboxymethyl cellulose 0.3 ~ 6%
Surfactant 1 ~ 10%
Flavouring agent 0.1 ~ 0.3%
Water 80 ~ 95%
The C agent, its components based on weight percentage:
Pigment 2 ~ 15%
Sodium carboxymethyl cellulose 0.3 ~ 6%
Surfactant 1 ~ 10%
Citric acid 1 ~ 5%
Spice 0.1 ~ 0.5%
Water 75 ~ 95%.
2. a kind of environment-friendly type hair care hair dye as claimed in claim 1 is characterized in that described slaine is MgSO 4, FeCl 3Or CuSO 4
3. a kind of environment-friendly type hair care hair dye as claimed in claim 1 is characterized in that described pigment is hematoxylin or tea polyphenols.
4. a kind of environment-friendly type hair care hair dye as claimed in claim 1 is characterized in that described surfactant is an OPEO.
CN 201210343828 2012-09-17 2012-09-17 Environment-friendly hair-care hair dye and preparation method thereof Active CN102824283B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105380817A (en) * 2015-12-15 2016-03-09 广州温雅日用化妆品有限公司 Three-dosage form hair dyeing agent and hair dyeing method
FR3028412A1 (en) * 2014-11-17 2016-05-20 Oreal COMPOSITION COMPRISING ORTHODIPHENOL DERIVATIVE, ALKALINE METAL BI-CARBONATE, WATER-SOLUBLE ORGANIC SOLVENT AND REDUCING AGENT
CN106176453A (en) * 2016-08-29 2016-12-07 河南染匠科技有限公司 A kind of botanical hair dye
CN106236663A (en) * 2016-08-31 2016-12-21 郭迎庆 A kind of preparation method of high colouring natural botanical hair dye
CN104398441B (en) * 2014-12-08 2017-05-10 上海海洋大学 Seaweed pigment hair dye and application method thereof
CN109674700A (en) * 2019-01-11 2019-04-26 澳宝化妆品（惠州）有限公司 A kind of hair dyeing and care promotor composition containing logwood extract
CN110393686A (en) * 2019-08-30 2019-11-01 忻州师范学院 A kind of preparation method and application of bush tealeaves compound botanical hair dye

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070202069A1 (en) * 2006-02-24 2007-08-30 Krishnan Tamareselvy Polymers Containing Silicone Copolyol Macromers and Personal Care Compositions Containing Same
CN102423286A (en) * 2011-11-24 2012-04-25 江南大学 Natural hair dye prepared by using phytochrome curcumin and hair dyeing method of natural hair dye
CN102657585A (en) * 2012-05-30 2012-09-12 江南大学 Hair dye for enhancing color fastness of natural pigment curcumin

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070202069A1 (en) * 2006-02-24 2007-08-30 Krishnan Tamareselvy Polymers Containing Silicone Copolyol Macromers and Personal Care Compositions Containing Same
CN102423286A (en) * 2011-11-24 2012-04-25 江南大学 Natural hair dye prepared by using phytochrome curcumin and hair dyeing method of natural hair dye
CN102657585A (en) * 2012-05-30 2012-09-12 江南大学 Hair dye for enhancing color fastness of natural pigment curcumin

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3028412A1 (en) * 2014-11-17 2016-05-20 Oreal COMPOSITION COMPRISING ORTHODIPHENOL DERIVATIVE, ALKALINE METAL BI-CARBONATE, WATER-SOLUBLE ORGANIC SOLVENT AND REDUCING AGENT
WO2016079055A1 (en) * 2014-11-17 2016-05-26 L'oreal Composition comprising an ortho-diphenol derivative, an alkali metal (bi)carbonate, a water-soluble organic solvent and a reducing agent
CN104398441B (en) * 2014-12-08 2017-05-10 上海海洋大学 Seaweed pigment hair dye and application method thereof
CN105380817A (en) * 2015-12-15 2016-03-09 广州温雅日用化妆品有限公司 Three-dosage form hair dyeing agent and hair dyeing method
CN105380817B (en) * 2015-12-15 2018-06-19 广州温雅日用化妆品有限公司 Three component hair dyes and hair colouring methods
CN106176453A (en) * 2016-08-29 2016-12-07 河南染匠科技有限公司 A kind of botanical hair dye
CN106236663A (en) * 2016-08-31 2016-12-21 郭迎庆 A kind of preparation method of high colouring natural botanical hair dye
CN109674700A (en) * 2019-01-11 2019-04-26 澳宝化妆品（惠州）有限公司 A kind of hair dyeing and care promotor composition containing logwood extract
CN110393686A (en) * 2019-08-30 2019-11-01 忻州师范学院 A kind of preparation method and application of bush tealeaves compound botanical hair dye

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Effective date of registration: 20181207

Address after: 310025 No. 827 Changfuhang Road, Dajiangdong Industrial Agglomeration Area, Hangzhou, Zhejiang Province

Patentee after: Zhang Hua cosmetics technology Co. Ltd.

Address before: No. 92, dock City Road, Xiaodian District, Taiyuan, Shanxi

Patentee before: Shanxi Univeristy