CN102198058A - Herbal hair dye - Google Patents
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- CN102198058A CN102198058A CN 201010132584 CN201010132584A CN102198058A CN 102198058 A CN102198058 A CN 102198058A CN 201010132584 CN201010132584 CN 201010132584 CN 201010132584 A CN201010132584 A CN 201010132584A CN 102198058 A CN102198058 A CN 102198058A
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Abstract
The invention discloses a natural herbal hair dye. The dye components consist of Henna, tannic acid and ferrite. The invention further discloses a using method of the hair dye. Compared with the prior art, the hair dye provided by the invention can dye hair into various colors including pure black; and the dyeing time is shorter, the color of the dyed hair lasts longer, and side effect on human body is smaller.
Description
Technical field
The invention discloses a kind of hair dye, is staining components with Hai Na, tannic acid material and ferrous salt, belongs to cosmetic field.
Background technology
Existing in the market hair dye product mostly is the oxidized form stain, adopts p-phenylenediamine (PPD) or Benzodiazepines compounds to show black through hydrogen peroxide oxidation.The multinomial correct leatherware of this oxidized form dyestuff hair dye that studies confirm that has certain infringement, and toxicity is big, causes skin to produce sense of discomfort, life-time service even cause cancers such as redness, twinge easily.
Hai Na has another name called Flos Impatientis, mignonettetree, Lythraceae Lawsonia (or claiming mignonettetree to belong to again) plant, about high 1m, Hua Jixiang, adularescent, pink colour or purple etc., Hai Na is a kind of natural dye, because the character of its Nantural non-toxic, its leaf, flower or whole plant all can be used as the raw material of hair dye.
(2008,31 (8): 45-48) disclose Hai Nazhong and contained 2-hydroxyl-1, the 4-naphthoquinone can be dyed hair hestnut color or bronzing to Zhao Qian for the natural batching of hair dye, household chemicals science.Yet, only adopt extra large Na hair color more single.Jia Lifeng (Hai Na and other Arabic vegetable colour Study on dyeing, wool spinning science and technology, 2008,11:21-24) Color of Hai Na is studied, prove that Hai Na can dye palm fibre-sepia with Pilus Caprae seu Ovis through 3-10 hour.But when dyeing, required time is long, and need be heated to 100 degree.
Tannic acid, claim tannin, tannin, tannin again, it is the polyhydric phenols that is present in the intravital a kind of structure more complicated of plant, it is found that in actual applications tannic acid is applied in and to make hair colouring on the hair, constant color under the chelation of metal ion, thus in existing botanical hair dye, have extensive use.
But adopt the hair dye of tannic acid merely, as Chinese patent 200810037717.8 disclosed a kind of hair dyes, comprise compositions such as tannin (gallotannic acid), green vitriol, glacial acetic acid, diethanolamine, surfactant, the problem that this technical scheme exists is independent tannin (tannic acid) and ferrous ion reaction products therefrom hair dyeing effect instability, long-time fading easily later.
Chinese patent 01127328 discloses a kind of hair dye that adopts inorganic agent, dying agent, chelating agen, thus iron ion wherein and the colouring of gallic acid generation chelatropic reaction.It is brown to purple that but the material that ferric ion and gallic acid are combined into is, and with black apparent in view difference arranged equally.The used ferrum sulfuricum oxydatum solutum of its chelating agen is easy to generate precipitation, need get its supernatant during actual preparation and add thickening agent etc. then and make the solid state powder packing, is mixed with solution or thickness unguentum during use temporarily, is not suitable for ordinary consumer and uses in the family.
Therefore, still need a kind of safety non-toxic, easy and simple to handle, colouring time is short, color is abundant more hair dye in the prior art.
Summary of the invention
The applicant has furtherd investigate multiple natural plant composition Color and dye stability, delightedly find Hai Na, tannins material and ferrous salt are used in combination as staining components, not only can shorten the hair dyeing time with respect to existing product, and the color of institute's dyeing hair is compared with the extra large Na dyeing of independent usefulness, its color gamut is very different, and can dye the hair of black, stable, the difficult decolouring of hair dyeing effect.Based on this discovery, the applicant has finished the present invention.
The invention provides a kind of hair dye, comprise Hai Na, tannic acid material and ferrous salt.
Among the present invention, extra large Na can be the fine powder that grinds gained with position such as extra large Na flower, leaf or whole plant, also can be the extract of gained after fine powder water after extra large Na flower, leaf or plant are ground or the alcohol extraction.When the present invention adopted extra large Na to grind the gained fine powder, the granularity of used fine powder was between 0.01-1000um; When the present invention adopts the water of Hai Na or alcohol extract, preferably adopt the ethanol of 30-95% to extract.
Among the present invention, tannic acid claims tannin, tannin, tannin again, be the wider polyhydric phenols of molecule weight range, be divided into condensed tannins and hydrolyzable tannic acid, adopt suitable condition to be hydrolyzed the hydrolyzable tannic acid and can obtain micromolecule tannic acid and gallic acid monomer.Tannic acid material of the present invention comprises macromolecular tannic acid, also comprises micromolecule tannic acid and gallic acid.Industrial, above-mentioned tannic acid material all can adopt the synthetic method of chemical industry to obtain, and also can be that the fine powder that the plant of extracting from the plant that contains this type of material or will contain this type of material grinds to form obtains.These plants include but not limited to Galla Chinensis, Herba Ecliptae, Fructus rhois chinensis, Pericarpium Granati, Chinese gall Beihua, Fructus Musae neck, preferred Galla Chinensis; Preferred, tannic acid material of the present invention is a Galla Chinensis extract.
Being used for from the method for above-mentioned plant extraction tannic acid material can be this area extracting method commonly used, and water or alcohol are extracted, and preferred use 30-95% ethanol extracts.
Among the present invention, ferrous salt is the water soluble salt of ferrous ion, includes but not limited to one or more the mixture in sulfate, hydrochlorate, the nitrate, preferably adopts ferrous sulfate.
Among the present invention, hair dye is such series products, by changing the color of hair on the hair that it is spread upon the people according to certain step, becomes coloured differently effects such as palm fibre, poliosis blackening thereby produce poliosis.
In the hair dye of the present invention, the mass ratio of Hai Na and tannic acid material is 100: 1-1: 100, preferred 50: 1-1: 50, more preferably 20: 1-1: 20.In hair dye, the content range of Hai Na is 0.1%-90%, preferred 0.2%-70%, more preferably 0.5-40%; The content range of tannic acid material is 0.1%-90%, preferred 0.2%-70%, more preferably 0.5-40%; The content range of ferrous salt is 0.01%-80%, preferred 0.05%-50%, more preferably 0.1%-20%.Most preferred, the content sum of Hai Na and tannic acid material is that the content of 0.5%-40%, ferrous salt is 0.1%-20% (by weight percentage) in the hair dye.
On basis of the present invention, can also add Flos Caryophylli in the hair dye further increases dyeing kinetics, and the poliosis color is deepened rapidly.
Used Flos Caryophylli can be powder, the water of Flos Caryophylli or the extract of alcohol that the Flos Caryophylli medical material grinds, and can also be the effective ingredient ligustrin in the Flos Caryophylli.Flos Caryophylli preferred of the present invention is adopted water or the alcohol extract of Flos Caryophylli.The Flos Caryophylli of adopting among preferred the present invention is its alcohol extract, the ethanol extraction of most preferred its 30-95% of employing.
On the mentioned component basis, can also add an amount of hair dye adjuvant in the hair dye, include but not limited to that thickening agent, surfactant and water etc. make final products.These hair dye adjuvants are that the hair dye industry is generally used, and are not subjected to special restriction.
Used thickening agent can be one or more the mixture in sodium carboxymethyl cellulose, xanthan gum, gelatin, Guar gum, Radix Acaciae senegalis, methylcellulose, hydroxy methocel, hydroxyethyl-cellulose, the hydroxypropyl cellulose.
Used surfactant can be cation, anion, both sexes or a nonionic surfactant commonly used in the hair dye, includes but not limited to a kind of in polyoxyethylenated alcohol sodium sulfate, glyceryl monostearate, alkyl sulfate salt, the sorbitol monostearate etc. or more than one mixture.
Each composition can be the form that is mixed into mixture in the hair dye of the present invention, also can be the form of separate dosage forms, preferably the mixture form.
In actual use,, improve and infiltrate and hair dyeing effect, can also before using hair dye of the present invention, adopt softening inorganic agent handle hair in order better to improve Hai Na, tannic acid material, ferrous salt permeability to hair.Hair dyeing industry softening processing class material commonly used all can use in the present invention, as sodium thioglycolate, sodium thiosulfate, cysteine class material etc., preferably adopts the softening inorganic agent before cysteine class material is had hair dyed as hair dye of the present invention in conjunction with organic base.
Cysteine class material of the present invention can be one or more the mixture in cysteine, homocysteine, carbamyl cysteine, the N-acetylcysteine, also can be the hydrochlorate of these materials.
Organic base of the present invention is the small molecule alkaline organic, its carbochain is short, comprise ethanolamine, ethylenediamine, diethylamine, triethylamine, dimethylamine, hydroxyethylethylene diamine, aminoethanolamine, sodium ethylene diamine tetracetate etc., preferably adopt ethanolamine, ethylenediamine or its mixture.
On the mentioned component basis, can also add an amount of hair dye adjuvant in the softening inorganic agent, include but not limited to that thickening agent, surfactant and water etc. make final products.These hair dye adjuvants are that the hair dye industry is generally used, and are not subjected to special restriction.
Used thickening agent can be one or more the mixture in sodium carboxymethyl cellulose, xanthan gum, gelatin, Guar gum, Radix Acaciae senegalis, methylcellulose, hydroxy methocel, hydroxyethyl-cellulose, the hydroxypropyl cellulose.
Used surfactant can be cation, anion, both sexes or a nonionic surfactant commonly used in the hair dye, includes but not limited to a kind of in polyoxyethylenated alcohol sodium sulfate, glyceryl monostearate, alkyl sulfate salt, the sorbitol monostearate etc. or more than one mixture.
On the other hand, the present invention also provides a kind of hair dyeing commercial packing, comprises the 1. part: the hair dye that contains Hai Na, tannic acid material and ferrous salt; The 2. part: hair softens inorganic agent.This packing can further include the description of how to have hair dyed.Wherein, Hai Na, tannic acid material, ferrous salt may be mixed together, and also the form of separate dosage forms exists separately.
In this commercial packing, described extra large Na can adopt position such as extra large Na flower, leaf or whole plant to grind the fine powder of gained, also can be the extract that grinds fine powder water or alcohol extraction gained, preferably adopts extra large Na extract.When adopting extra large Na to grind the gained fine powder, the granularity of used fine powder is between 0.01-1000um; When water that adopts Hai Na or alcohol extract, preferably adopt the ethanol of 30-95% to extract.
In this commercial packing, described tannic acid material comprises macromolecular tannic acid, also comprises micromolecule tannic acid and gallic acid.Industrial, above-mentioned tannic acid material can adopt the synthetic method of chemical industry to obtain, and also can be that the fine powder that the plant of extracting from the plant that contains this type of material or will contain this type of material grinds to form obtains.These plants include but not limited to Galla Chinensis, Herba Ecliptae, Fructus rhois chinensis, Pericarpium Granati, Chinese gall Beihua, Fructus Musae neck, preferred Galla Chinensis.Preferred, tannic acid material of the present invention is a Galla Chinensis extract.The present invention does not limit the source and the preparation method of used tannic acid.Being used for from the extracting method of above-mentioned plant extraction tannic acid can be this area extracting method commonly used, and water or alcohol are extracted, and preferred use 30-95% ethanol extracts.
In this commercial packing, described ferrous salt is the water soluble salt of ferrous ion, comprises one or more the mixture in sulfate, hydrochlorate, the nitrate, preferably adopts ferrous sulfate.
In this commercial packing; the softening inorganic agent of described hair can comprise this area conventional substances; as sodium thioglycolate; sodium thiosulfate; cysteine class material etc.; the preferred inorganic agent that adopts before cysteine class material is had hair dyed as hair dye of the present invention in conjunction with organic base; described cysteine class material can be a cysteine; homocysteine; the carbamyl cysteine; the mixture of one or more in the N-acetylcysteine; it also can be the hydrochlorate of these materials; described organic base is the small molecule alkaline organic; its carbochain is short; comprise ethanolamine; ethylenediamine; diethylamine; triethylamine; dimethylamine; hydroxyethylethylene diamine; aminoethanolamine; sodium ethylene diamine tetracetates etc. preferably adopt ethanolamine; ethylenediamine or its mixture.
In this commercial packing, the mass ratio of Hai Na and tannic acid material can be 100: 1-1: 100, preferred 50: 1-1: 50, more preferably 20: 1-1: 20.In hair dye, the content range of Hai Na can be 0.1%-90%, preferred 0.2%-70%, more preferably 0.5-40%; The content range of tannic acid can be 0.1%-90%, preferred 0.2%-70%, more preferably 0.5-40%; The content range of ferrous salt can be 0.01%-80%, preferred 0.05%-50%, more preferably 0.1%-20%.Most preferred, the content sum of Hai Na and tannic acid material is that the content of 0.5%-40%, ferrous salt is 0.1%-20% (by weight percentage) in the hair dye.
In the hair dye of this commercial packing, can also add Flos Caryophylli further increases dyeing kinetics.Used Flos Caryophylli can be powder, the water of Flos Caryophylli or the extract of alcohol that the Flos Caryophylli medical material grinds, it can also be the effective ingredient ligustrin in the Flos Caryophylli, Flos Caryophylli preferred of the present invention is adopted water or the alcohol extract of Flos Caryophylli, and the Flos Caryophylli of adopting among preferred the present invention is the ethanol extraction of its 30-95%.
Can also further add an amount of hair dye adjuvant in hair dye or the softening inorganic agent, these adjuvants are that the hair dye industry is generally used, and include but not limited to thickening agent, surfactant and water.Described thickening agent can be one or more the mixture in sodium carboxymethyl cellulose, xanthan gum, gelatin, Guar gum, Radix Acaciae senegalis, methylcellulose, hydroxy methocel, hydroxyethyl-cellulose, the hydroxypropyl cellulose, described surfactant can be cation, anion, both sexes or a nonionic surfactant commonly used in the hair dye, includes but not limited to a kind of in polyoxyethylenated alcohol sodium sulfate, glyceryl monostearate, alkyl sulfate salt, the sorbitol monostearate etc. or more than one mixture.
In an embodiment of the invention, disclose a kind of hair dye, comprised
Sea Na 0.5%-40%
Tannic acid material 0.5%-40%
Ferrous salt 0.1%-20%
Flos Caryophylli 0-10%
In another embodiment, provide a kind of hair dyeing commercial packing, having comprised:
The hair dye that contains following composition:
Sea Na 0.5%-40%
Tannic acid material 0.5%-40%
Ferrous salt 0.1%-20%
Flos Caryophylli 0-10%
The softening inorganic agent of hair that contains following composition:
Cysteine and derivant thereof and salt 2%-20%
Organic base 1%-30%
At last, the invention provides the using method of above-mentioned hair dyeing product, comprise with Hai Na, tannic acid material, ferrous join in the aqueous solution and be aided be stirred to various component mix homogeneously, smear to the step on the hair, or with Hai Na, tannic acid material, ferrously join in the aqueous solution separately, mix the back earlier with the ferrous hair that smears to, again with Hai Na, the tannic acid applying materials step to the hair.
Randomly, can also before above-mentioned steps, add the step of softening hair, comprise cysteine and derivant thereof and/or its salt and organic base are joined in the aqueous solution, and be aided with stirring,, evenly spread upon on the hair until the complete mix homogeneously of various components.
Described aqueous solution can be a water, also can be the solution that has dissolved the hair dye adjuvant, especially can be the solution that contains surfactant, thickening agent.
The color that hair dye of the present invention dyed depends on the time that contacts with hair.According to the difference of time of contact, hair dye of the present invention can dye brown hair to the black color scope, as brown, brown, puce, atropurpureus, black etc.The inventor shows by the extensive experimentation of carrying out on different white hair samples, keep hair dye and hair that arranged the time of contact of half an hour to two hour, then can dye brown hair between black according to the difference of time of contact, along with the increase of contact retention time, hair color is darker.After adding Flos Caryophylli, dye same color, required time obviously shortens, and for example can be to dye brown hair between black in 30 minutes to 1.5 hours.Using softening agent before hair dyeing, can unexpectedly more further shorten the time of hair dyeing, for example can be to dye brown hair between black in 20 minutes to 1 hour.The experiment of the hair-dyeing by routine can obtain time of contact and corresponding painted relation.The test that the applicant carries out shows, adopts compositions of the present invention under some preferred situations, keeps 20 minutes to 1 hour time of contact, can visually be satisfied the Color that people require.The experiment confirm that the applicant carries out, hair dye Color of the present invention can keep not fading the Color lasting stability in two months.
When hair dye of the present invention uses, with the hair wash clean, after drying inorganic agent is evenly spread upon on the hair, keep 15-40min; Again with the hair wash clean, hair dye is evenly spread upon maintenance on the hair required the color that dyes suitable time of contact to obtain, the wash clean hair gets final product then.
Hair dye of the present invention and hair dyeing commercial packing do not need heating when hair dyeing, at room temperature can reach above-mentioned good hair dyeing effect.Certainly, if in advance hair dye is heated or hair heats, for example be heated to 35 degrees centigrade, minimizing time of contact that can be suitable.
The specific embodiment
Following embodiment is intended to illustrate specific embodiments of the present invention.
It is to be noted, below the extra large Na extract described in the preparation embodiment, Galla Chinensis extract, Herba Ecliptae extract, Flos Caryophylli extract etc. can adopt extracting method provided by the invention to prepare, and also can adopt extracting method conventional in the prior art to obtain.Extracting method provided by the present invention only is used for a kind of implementation that obtains these extracts is described, is not used for limiting invention.
Extra large Na extract in the following example can adopt following method preparation:
Get the powder that 10g Hai Nahua grinds to form, join and be condensed into extractum after heated and stirred 40min adopts the method for distilling under reduced pressure to remove ethanol in 95% the ethanol of 80ml, drying and crushing gets final product.
Galla Chinensis extract among the following embodiment can adopt following method preparation:
Get the 10g gallnut extract and be broken into powder, join in 50ml 90% ethanol and soaked 1 hour, be heated to 50 ℃ of hot refluxs 1 hour, behind the concentrated filtrate distillation ethanol, the pulverizing of gained extract dry is got final product.
Herba Ecliptae extract among the following embodiment can adopt following method preparation:
Get the 10g Herba Ecliptae, join and heat decoction in the 40g water after one hour, filter, concentrate, drying, gained extractum is pulverized promptly.
Used Flos Caryophylli extract can adopt following method preparation in the following example:
Folium Caryophylli is ground into powder, decocts three times each 1 hour with 5 times of water gagings.With crossing macroporous resin treatment behind the gained filtrate hybrid filtering, wash with water after colourless and discard washing liquid, use 80% ethanol elution.Behind the distilling under reduced pressure ethanol its concentrate drying is obtained Flos Caryophylli extract.
Tannic acid among the following embodiment, the chemical compound pure product of gallic acid for buying from chemical raw material market.
Embodiment 1
Hair dye:
The powder 7g that Hai Nahua grinds
Galla Chinensis extract 2g
Ferrous sulfate 5g
Sodium carboxymethyl cellulose 10g
Powder (granularity 0.1um), ferrous sulfate, Galla Chinensis extract, the sodium carboxymethyl cellulose of getting the Hai Nahua grinding join in the 26g water, and it is thick to be stirred well to homogeneous, promptly gets hair dye of the present invention;
White hair wash clean with collecting evenly spreads upon hair dye on the hair after drying, and keeps 30 minutes-1.5 hours, and the wash clean hair gets final product.The hair color that is dyed is respectively brown (30 minutes), brown (45 minutes), puce (70 minutes), atropurpureus (90 minutes).
Embodiment 2
Hair dye:
The powder 10g that Hai Naye grinds
Tannic acid 0.5g
Ferrous chloride 3g
Sodium carboxymethyl cellulose 8g
Powder (granularity 0.5um), ferrous chloride, tannic acid, the sodium carboxymethyl cellulose of getting the Hai Naye grinding join in the 28g water, are stirred well to even pastel, promptly get hair dye of the present invention;
White hair wash clean with collecting evenly spreads upon hair dye on the hair after drying, and keeps 30 minutes-1.5 hours, and the wash clean hair gets final product.The variation in time that is dyed is respectively brown (30 minutes), brown (40 minutes), puce (70 minutes), atropurpureus (90 minutes).
Embodiment 3
Hair dye:
Sea Na extract 20g
Galla Chinensis extract 5g
Ferrous sulfate 1g
Flos Caryophylli extract 1g
Gelatin 5g
Softening inorganic agent:
Cysteine 5g
Dimethylamine 4g
Aminoethanolamine 5g
Sodium carboxymethyl cellulose 10g
Get cysteine 5g, dimethylamine 4g, aminoethanolamine 5g joins in the 26g water and stirs, and adds the 10g sodium carboxymethyl cellulose again and continues to be stirred to fully dissolving evenly, promptly gets inorganic agent of the present invention;
Get extra large Na extract, ferrous sulfate, Galla Chinensis extract, Flos Caryophylli extract, gelatin and join in the 80g water, stir, promptly get hair dye of the present invention;
With the hair wash clean, will soften inorganic agent after drying and evenly spread upon on the hair, keep 20min; With the hair wash clean, hair dye is evenly spread upon on the hair, kept 20 minutes-1.5 hours, the wash clean hair gets final product.The hair color that is dyed is respectively brown (20 minutes), brown (30 minutes), puce (50 minutes), atropurpureus (60 minutes), black (90 minutes).
Embodiment 4
Hair dye:
Sea Na abrasive flour 2g
Galla Chinensis extract 15g
Ferrous sulfate 20g
Ligustrin 0.2g
Sodium lauryl sulphate 1g
Gelatin 5g
Softening inorganic agent:
N-acetylcysteine 10g
Ethylenediamine 7g
Sodium carboxymethyl cellulose 10g
Glyceryl monostearate 1g
Get N-acetylcysteine, ethylenediamine, sodium carboxymethyl cellulose, glyceryl monostearate and join in the 22g water and stir, promptly get inorganic agent of the present invention;
Get ferrous sulfate and be added in the 5g water and stir, copperas solution.Get extra large Na stem and grind fine powder (granularity 0.5um), Galla Chinensis extract, ligustrin, sodium lauryl sulphate, gelatin and join in the 10g water, stir promptly, as the hair dye of separate dosage forms.
White hair wash clean with collecting evenly spreads upon inorganic agent on the hair after drying, and keeps 30min; With the hair wash clean, copperas solution is evenly spread upon on the hair, hair dye is evenly smeared the back after 10 minutes again and kept 60 minutes on hair, the wash clean hair gets final product, and the hair color that is dyed is a black.
Embodiment 5
Hair dye:
Sea Na extract 7g
Herba Ecliptae extract 10g
Ferrous sulfate 5g
Sodium carboxymethyl cellulose 10g
Softening inorganic agent:
Carbamyl cysteine 15g
Diethylamine 5g
Gelatin 5g
Get carbamyl cysteine, diethylamine, gelatin and join in the 25g water and stir, promptly get inorganic agent of the present invention;
Get extra large Na extract, ferrous sulfate, Herba Ecliptae extract, sodium carboxymethyl cellulose and join in the 18g water, stir, promptly get hair dye of the present invention;
With the white hair wash clean, after drying inorganic agent is evenly spread upon on the hair, keep 20min; With the hair wash clean, hair dye is evenly spread upon on the hair, kept 20 minutes-1.5 hours, the wash clean hair gets final product.According to the difference of retention time, the variation in time of the color that dyes is respectively brown (20 minutes), brown (30 minutes), puce (50 minutes), atropurpureus (70 minutes), black (90 minutes).
Embodiment 6
Hair dye:
Sea Na extract 3g
Galla Chinensis extract 4g
Ferrous chloride 5g
Sodium lauryl sulphate 1g
Gelatin 5g
Softening inorganic agent:
N-acetylcysteine 10g
Ethylenediamine 8g
Sodium carboxymethyl cellulose 10g
Get N-acetylcysteine, ethylenediamine, sodium carboxymethyl cellulose and join in the 22g water and stir, promptly get inorganic agent of the present invention;
Get extra large Na extract, Galla Chinensis extract, ferrous chloride, sodium lauryl sulphate, gelatin and join in the 32g water, fully mix homogeneously promptly gets hair dye of the present invention;
White hair wash clean with collecting evenly spreads upon inorganic agent on the hair after drying, and keeps 30min; Again with the hair wash clean, hair dye evenly spread upon keep 90min wash clean hair to get final product on the hair, the color that is dyed is a black.
Embodiment 7
Hair dye:
Sea Na extract 10g
Gallic acid 0.5g
Flos Caryophylli extract 1g
Ferrous sulfate 5g
Sodium lauryl sulphate 1g
Gelatin 3g
Softening inorganic agent:
N-acetylcysteine 10g
Ethylenediamine 10g
Sodium carboxymethyl cellulose 10g
Get N-acetylcysteine, ethylenediamine, sodium carboxymethyl cellulose and join in the 20g water and stir, promptly get inorganic agent of the present invention;
Get extra large Na extract, gallic acid, ferrous sulfate, Flos Caryophylli extract, sodium lauryl sulphate, gelatin and join in the 30g water, stir, promptly get hair dye of the present invention;
White hair wash clean with collecting evenly spreads upon inorganic agent on the hair after drying, and keeps 30min; Again with the hair wash clean, hair dye evenly spread upon keep 60min wash clean hair to get final product on the hair, the color that is dyed is a black.
The comparative example 1
Take by weighing sodium thioglycolate 7.75g, sodium thiosulfate 0.18g, sodium carboxymethyl cellulose 1.3g, disodium salt disodium 0.25g, monoethanolamine 7.75g, join in the refining purified water of 32.77g and stir, as inorganic agent.
Take by weighing extra large Na pollen abrasive flour 10g, sodium carboxymethyl cellulose 1.6g, sodium lauryl sulphate 2.0g, join successively in the refining purified water of 36.4g, stir, as hair dye.
With the white hair wash clean of collecting, grouping evenly spreads upon inorganic agent on the hair after drying, and keeps 20min; Wash clean hair more evenly spreads upon hair dye after drying and keeps certain hour on the hair, and the wash clean hair gets final product.Found that the time of adopting present embodiment product dyeing hair to need is longer, needed 3-4 hour just can dye color comparatively uniformly approximately, the color that dyes is a rufous
The comparative example 2
Be prepared as follows hair dye according to China's application 2005101123796 technical schemes that provide:
Ferrous sulfate 15g, azone 12g, hydroxyethyl-cellulose 0.5g join in the 72.5g deionized water as the A agent;
Galla Chinensis extract 15g, silicone oil 8g, Lignum Sappan extract 1g join in the 76g deionized water as the B agent.
Using method: the A agent is brushed on hair with small brushes, at room temperature left standstill 8-10 minute; The B agent in kind being brushed on hair room temperature leaves standstill and got final product in 8-10 minute again.
Dyeing back finds that the hair that dyes is brown, and the hair that dyes continues washing according to normal washing frequency and promptly found that the color large tracts of land faded in two months, illustrates that this product dye stability is bad.
Experimental example 1
The hair that embodiment of the invention 1-7 is dyed is according to normal person's hair washing frequency respectively, and per two days with the warm water washing once.Continued to wash two months, and do not see to have obviously and fade.Compare with the hair that newly dyes with quadrat method, color is not seen obvious difference, illustrates that hair dye Color of the present invention is stable lasting.
Experimental example 2
Hair dyeing product with the embodiment of the invention 1,3 and comparative example's 1,2 preparations carries out Color relatively, and the hair dyeing time of hair dye is 1 hour, and the sampling number is 100 people.Its statistical result such as following table:
As can be seen from the above experimental data, hair dyeing product safety provided by the invention does not have irritated and other side effect, compare with comparative example's product, in 1 hour, do not have the hair that to paint, it is obviously darker to dye, and the color that dyes was not faded the color lasting stability yet after 2 months.
Experimental example 3
Choose 100 poliosis volunteers, carry out Color research with the embodiment of the invention 4, the dyeing retention time of hair dye was respectively 15 minutes, 30 minutes, 40 minutes, 50 minutes, 60 minutes.That the hair color that is dyed is about respectively is brown, brown, puce, atropurpureus, black.
This shows that hair dye of the present invention can dye brown to black, has overcome the drawback that single extra large Na or tannic acid can only dye rufous-brown color scope.
Claims (24)
1. a hair dye comprises Hai Na, tannic acid material and ferrous salt.
2. according to the hair dye of claim 1, described Hai Na is extra large Na abrasive flour, extra large Na extract or its mixture.
3. according to the hair dye of claim 2, alcohol extract and/or water extract that described extra large Na extract is Hai Na.
4. according to the hair dye of claim 1, described tannic acid material comprises extract synthetic with chemical industry from plant.
5. according to the hair dye of claim 4, described tannic acid material comprises gallic acid.
6. according to the hair dye of claim 4, described tannic acid material is one or more the extract in Galla Chinensis, Herba Ecliptae, Fructus rhois chinensis, Pericarpium Granati, Chinese gall Beihua, the Fructus Musae neck.
7. according to the hair dye of claim 6, described tannic acid material is one or more alcohol extract and/or the water extract in Galla Chinensis, Herba Ecliptae, Fructus rhois chinensis, Pericarpium Granati, Chinese gall Beihua, the Fructus Musae neck.
8. according to the hair dye of claim 7, described tannic acid material is gallic alcohol extract.
9. according to the hair dye of claim 1, described ferrous salt is the water soluble salt of ferrous ion.
10. according to the hair dye of claim 9, described ferrous salt is hydrochlorate, sulfate, nitrate or its mixture of ferrous ion.
11. according to the hair dye of claim 10, described ferrous salt is a ferrous sulfate.
12., also further comprise Flos Caryophylli according to the hair dye of claim 1.
13. according to the hair dye of claim 12, described Flos Caryophylli is Flos Caryophylli abrasive flour, Flos Caryophylli water or alcohol extract, ligustrin or its mixture.
14. according to the hair dye of each claim among the claim 1-13, it mixes the mixture form that the back forms for each composition.
15. according to the hair dye of each claim among the claim 1-13, wherein each composition is the form of separate dosage forms.
16. a hair dyeing commercial packing comprises the hair dye of each claim among the 1. claim 1-15; 2. hair softens inorganic agent.
17. according to the commercial packing of claim 16, softening inorganic agent wherein contains cysteine compounds, organic base.
18. according to the commercial packing of claim 17, described cysteine compounds is one or more the mixture in cysteine, homocysteine, carbamyl cysteine, the N-acetylcysteine.
19. according to the commercial packing of claim 17, described organic base is a kind of in ethanolamine, ethylenediamine, diethylamine, triethylamine, dimethylamine, hydroxyethylethylene diamine, aminoethanolamine, the sodium ethylene diamine tetracetate and/or more than one mixture.
20., wherein also comprise conventional hair dyeing adjuvant in hair dye, the softening inorganic agent according to the commercial packing of claim 16.
21. the commercial packing according to each claim among the claim 16-20 also comprises operation instructions.
22. the using method of the hair dye of the arbitrary claim of claim 1-15 comprises joining Hai Na, tannic acid, ferrous salt in water or the aqueous solution and being aided with stirring, smears to the step of hair.
23. the using method of the hair dyeing commercial packing of each claim of claim 16-21 comprises the steps:
A) behind the hair wash clean inorganic agent is evenly coated on the hair, keeps in touch 15-40min;
B) behind the hair wash clean of a step hair dye is evenly coated on the hair;
C) keep the contact of b step, its time of keeping in touch reach the color that will dye after the wash clean hair get final product.
24. according to the using method of claim 23, the described c step time of keeping in touch is 20 minutes to two hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010132584 CN102198058A (en) | 2010-03-24 | 2010-03-24 | Herbal hair dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010132584 CN102198058A (en) | 2010-03-24 | 2010-03-24 | Herbal hair dye |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102198058A true CN102198058A (en) | 2011-09-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010132584 Pending CN102198058A (en) | 2010-03-24 | 2010-03-24 | Herbal hair dye |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102198058A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103505396A (en) * | 2013-10-16 | 2014-01-15 | 李敬文 | Powdery impatiens hair dye |
| WO2014139163A1 (en) * | 2013-03-15 | 2014-09-18 | 北京世纪博康医药科技有限公司 | Composition for hair dyeing and hair dye prepared thereby |
| WO2014139171A1 (en) * | 2013-03-15 | 2014-09-18 | 北京世纪博康医药科技有限公司 | Henna hair dye |
| WO2014139153A1 (en) * | 2013-03-15 | 2014-09-18 | 北京世纪博康医药科技有限公司 | Composition for hair dyeing and application thereof |
| US9345654B2 (en) | 2012-08-24 | 2016-05-24 | Natural Medicine Institute Of Zhejiang Yangshengtang Co., Ltd. | Hair dye product |
| CN105625057A (en) * | 2014-10-27 | 2016-06-01 | 恒源祥（集团）有限公司 | Processing method used for dyeing wool fabric with natural dye with high colour fastness |
| CN105625058A (en) * | 2014-10-27 | 2016-06-01 | 恒源祥（集团）有限公司 | Processing method used for dyeing wool fabric with natural dye |
| CN107693408A (en) * | 2017-07-21 | 2018-02-16 | 张学记 | A kind of phytochrome hair dye and preparation method thereof and application method |
| CN111803388A (en) * | 2020-07-20 | 2020-10-23 | 西安幸福未来化妆品有限公司 | Pure natural hair dye and application thereof |
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| CN101032456A (en) * | 2007-04-29 | 2007-09-12 | 路天章 | Hairdressing combination made of natural vegetable and preparing method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US9345654B2 (en) | 2012-08-24 | 2016-05-24 | Natural Medicine Institute Of Zhejiang Yangshengtang Co., Ltd. | Hair dye product |
| WO2014139163A1 (en) * | 2013-03-15 | 2014-09-18 | 北京世纪博康医药科技有限公司 | Composition for hair dyeing and hair dye prepared thereby |
| WO2014139171A1 (en) * | 2013-03-15 | 2014-09-18 | 北京世纪博康医药科技有限公司 | Henna hair dye |
| WO2014139153A1 (en) * | 2013-03-15 | 2014-09-18 | 北京世纪博康医药科技有限公司 | Composition for hair dyeing and application thereof |
| CN103505396A (en) * | 2013-10-16 | 2014-01-15 | 李敬文 | Powdery impatiens hair dye |
| CN105625057A (en) * | 2014-10-27 | 2016-06-01 | 恒源祥（集团）有限公司 | Processing method used for dyeing wool fabric with natural dye with high colour fastness |
| CN105625058A (en) * | 2014-10-27 | 2016-06-01 | 恒源祥（集团）有限公司 | Processing method used for dyeing wool fabric with natural dye |
| CN107693408A (en) * | 2017-07-21 | 2018-02-16 | 张学记 | A kind of phytochrome hair dye and preparation method thereof and application method |
| CN111803388A (en) * | 2020-07-20 | 2020-10-23 | 西安幸福未来化妆品有限公司 | Pure natural hair dye and application thereof |
| CN111803388B (en) * | 2020-07-20 | 2023-08-11 | 西安幸福未来化妆品有限公司 | Pure natural hair dye powder and application thereof |
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Application publication date: 20110928 |