CN104083307A - Natural hair dye prepared by adopting plant pigment safflower pigment and hair dyeing method using natural hair dye - Google Patents
Natural hair dye prepared by adopting plant pigment safflower pigment and hair dyeing method using natural hair dye Download PDFInfo
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- CN104083307A CN104083307A CN201410362590.2A CN201410362590A CN104083307A CN 104083307 A CN104083307 A CN 104083307A CN 201410362590 A CN201410362590 A CN 201410362590A CN 104083307 A CN104083307 A CN 104083307A
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Abstract
The invention relates to a hair dye, and in particular relates to a natural hair dye prepared by adopting plant pigment safflower pigment and a hair dyeing method using the natural hair dye. The hair dye disclosed by the invention comprises agents A and B and is characterized in that the agent A comprises the following components in percentage by weight: 0.1-10% of safflower pigment, 1-5% of a thickening agent, 1-10% of a surface active agent and the balance of water and the pH of the agent A is regulated to 3-7; and the agent B comprises the following components in percentage by weight:1-10% of metal ion mordant, 1-5% of a thickening agent, 1-10% of a surface active agent, 0.1-0.3% of natural essence and the balance of water and the pH of the agent B is regulated to 3-7. The hair dyeing method comprises the following steps: during hair dyeing, uniformly smearing the agent A on hair and dyeing for 10-40 minutes at the temperature of normal temperature to 60 DEG C; and uniformly smearing the agent B on the hair and mordanting for 10-20 minutes, washing and drying the hair. The safflower pigment is good in dyeing effect and has the efficacies of antibiosis and skin protection as well as hair dyeing and scalp protection.
Description
Technical field
The invention discloses a kind of natural botanical hair dye, take Flos Carthami and metal ion as active component, belong to cosmetic field.
Background technology
Raising along with people's living standard, people more and more note the image problem of self, and especially youngster, is usually used colored hair dye, hair dye conventional on market mostly is oxidative hair dyes, adopts p-phenylenediamine (PPD) or diphenol compounds to show black through hydrogen peroxide oxidation.Multinomially studies confirm that this oxidized form dyestuff hair dye has certain infringement to hair, toxicity is large, easily causes skin allergy, and life-time service can cause poisoning, and brings out various cancers.Along with progressively improving and the continuous progress of the science of improving looks of health of people consciousness, hair dye prepared by natural plant pigment becomes the development trend in following hair dye market day by day.The problem that existing botanical hair dye exists is that the hair color that can dye is less, can not meet people's individual demand, and therefore various botanical hair dyes occur in succession.
In the botanical hair dye of red colour system, Chinese patent application 201110008881.8 discloses a kind ofly take Stigma Croci extract and is the main effect component of colored hair dyeing to dye with plant coloured silk the colour hair dyeing frost that color matching composition combines.Stigma Croci belongs to Monocotyledonae Liliales Iridaceae class plant, and the main component of Stigma Croci extract contains crocetin, crocin, safranal, aminoacid, vitamin B
1, vitamin B
2, oils and fats and quintessence oil etc.But Stigma Croci is expensive, make prepared hair dye expensive.Flos Carthami belongs to Dicotyledoneae chrysanthemum order Compositae class plant, and the main component of Flos Carthami extract contains Safflor yellow A, carthamin, 6-hydroxyl kaempferol, kaempferol, Palmic acid, myristic acid, lauric acid, oleic acid, linoleic acid and monoglyceride thereof etc.
Although Flos Carthami is different from croceous composition, Flos Carthami and Stigma Croci have the effect of blood circulation promoting and blood stasis dispelling equally, and low price is easy to get.Flos Carthami is a kind of natural dye, in ancient times period widespread just, more very has carthamin is immersed and in starch, makees kermes, so the present invention is using Flos Carthami as hair dye main constituent, to increase the color category of botanical hair dye, and scalp is played a role in health care simultaneously.Flos Carthami is as the main constituent of hair dyeing, and existing problem is that dye uptake is low, and color is too shallow, and reason is that the colloid in pigment Flos Carthami can be preferentially adsorbed on hair, has hindered painted on hair of carthamin.
The present invention adopts the pigment in ethanol extraction Flos Carthami plant, and by column chromatography separation, colloid wherein is separated, and the carthamin after purification can be used as main constituent and makes hair colouring.
Summary of the invention
The present invention adopts the ethanol water of 30～50wt% as solvent, the solution extracting is separated through silica gel column chromatography, coloured moiety is merged to distillation, resulting carthamin is as the hair dye formula of hair dye main constituent, discovery is had hair dyed Flos Carthami separately or Flos Carthami and mordant is used in combination as upper colour content, hair can be dyed to different colors.
According to technical scheme provided by the invention, adopt oil-soluble plant pigment carthamin to prepare a kind of novel natural hair dye and comprise agent A and agent B, it is characterized in that, agent A comprises plant pigment carthamin 0.1%-10%, polyhydric alcohol 20-50%, surfactant 1-10%, thickening agent 1-5%, all the other are water, regulate pH to 5-7; Agent B comprises and comprises metal salt mordant 1-5%, thickening agent 1-5%, and surfactant 1-10%, natural essence 0.1-0.3%, all the other are water, regulate pH to 5-7.Unit is percetage by weight.
Polyhydric alcohol in agent A is one or more in wetting agent glycerol, butanediol, isopropyl alcohol.
In agent B, metal salt mordant is in cosmetics, to allow the salt of any metal ion of use, includes but not limited to ferrous sulfate, ferrous chloride, iron chloride, zinc sulfate, aluminum chloride, copper nitrate.Natural essence can adopt a kind of in Flos Rosae Rugosae essence, jasmine flower essence, lavandula angustifolia essence.
The pH of agent A mediating recipe B regulates with phosphoric acid, acetic acid, lactic acid, tartaric acid or citric acid.
Described thickening agent includes but not limited to the one or more combination in Radix Acaciae senegalis, carboxymethyl cellulose, hydroxyethyl-cellulose, guar gum, propylene glycol stearate.
Surfactant comprises anion, cation, both sexes or the non-ionic surface active agents such as stearyl alcohol, glyceryl stearate, sodium lauryl sulfate, OPEO.
Agent A and agent B are solution or any degree thickening or the liquid that adds glue, Emulsion or cream frost form.
Hair dye of the present invention can dye orange hair within the scope of Citrullus vulgaris red color, and as orange, orange red, Citrullus vulgaris is red etc.
Generally, what colour was had hair dyed is youngster mostly, before coloured silk dyes, uses inorganic agent to process hair.The conventional softening inorganic agent of hair dyeing industry all can be used in the present invention, as sodium thiosulfate, cysteine class material, sodium thioglycolate etc., preferentially adopts the inorganic agent before cysteine class material is had hair dyed as hair dye of the present invention in conjunction with organic base.
Cysteine class material of the present invention can be one or more the mixture in cysteine, homocysteine, amino A-wire cysteine, NAC.
Organic base of the present invention is small molecule, short carbon chain, alkaline organic, comprises ethanolamine, ethylenediamine, diethylamine, dimethylamine, hydroxyethylethylene diamine, aminoethanolamine, sodium ethylene diamine tetracetate etc.
Antiseptic used can be one or more the mixture in KF88, parabens, Glydant series etc.
On the basis of the above, can also appropriate amount of auxiliary materials in soft agent, include but not limited to that thickening agent, surfactant, antiseptic and water etc. make final products.These hair dye adjuvants are generally to use in hair dye industry, are not subject to special restriction.
In a preferred embodiment, the invention discloses a kind of hair dye, comprise
Flos Carthami extract 5wt%-80wt%
Mordant 0.1wt%-10wt%
Soft the inorganic agent of hair that contains following composition:
Cysteine and derivant thereof and salt 1wt%-10wt%
Organic base 1wt%-10wt%
The specific embodiment
Below in conjunction with embodiment, technical scheme of the present invention is described further, but protection scope of the present invention is not limited to this.
Embodiment mono-
Get supersound extraction 30min in 50% ethanol that 300 ɡ Flos Carthamis join 1000ml, sucking filtration obtains extracting solution.Filtrate is separated at silica gel column chromatography, and 20wt% methanol is mobile phase, merges coloured component, and concentrated distillation is dry.
Hair dye
Oil phase
Water
1,3 butylene glycol 2 ɡ
Glycerol 2 ɡ
Deionized water 75 ɡ
Oil phase and water are heated to respectively to 100 ℃, under agitation water are joined to oil phase mixing and emulsifying, homogenizing 3min, continues to stir, until 45 ℃ of left and right add essence 0.2 ɡ, continues to stir 30min, obtains stain mastic.
Soft inorganic agent
Above-mentioned raw materials is mixed to completely and is uniformly dissolved under stirring state, obtain inorganic agent of the present invention.
By hair wash clean, after drying, the softening inorganic agent of hair is evenly spread upon on hair, keep 20min; By hair wash clean, hair dye is evenly spread upon on hair again, keep wash clean hair 1 hour-3 hours.The hair color dyeing is respectively orange (1 hour), orange red (2 hours), Citrullus vulgaris red (3 hours).
Embodiment bis-
Get supersound extraction 60min in 20% ethanol that 500 ɡ Flos Carthamis join 1000ml, sucking filtration obtains extracting solution.Filtrate is separated at silica gel column chromatography, and 30wt% methanol is mobile phase, merges coloured component, and concentrated distillation is dry.
Hair dye
Oil phase
Water
Oil phase and water are heated to respectively to 100 ℃, under agitation water are joined to oil phase mixing and emulsifying, homogenizing 3min, continues to stir, until 45 ℃ of left and right add essence 0.2 ɡ, continues to stir 30min, obtains stain mastic.
Soft inorganic agent
Above-mentioned raw materials is mixed to completely and is uniformly dissolved under stirring state, obtain inorganic agent of the present invention.
By hair wash clean, after drying, the softening inorganic agent of hair is evenly spread upon on hair, keep 20min; By hair wash clean, hair dye is evenly spread upon on hair again, keep 1 hour-3 hours, wash clean hair, hair presents brownish red.
Claims (1)
1. an a kind of natural hair dye that adopts plant pigment carthamin to prepare, it is characterized in that, adopt the ethanol water of 30～50wt% as solvent, Flos Carthami is carried out to supersound extraction 20～60min, the solution extracting is separated through silica gel column chromatography, with the methanol aqueous solution of 10～30wt%, as mobile phase, coloured moiety is merged to distillation, resulting carthamin is as the hair dye formula of hair dye main constituent;
A kind of natural hair dye that adopts plant pigment carthamin to prepare, comprises agent A and agent B, it is characterized in that, agent A comprises carthamin 0.1%-10%, thickening agent 1-5%, and surfactant 1-10%, regulates pH to 3-7, Yu Weishui; Agent C comprises metal ion mordant 1-10%, thickening agent 1-5%, and surfactant 1-10%, natural essence 0.1-0.3%, regulates pH to 3-7, Yu Weishui; Unit is percetage by weight;
In agent B, metal salt mordant is in cosmetics, to allow the salt of any metal ion of use, includes but not limited to ferrous sulfate, ferrous chloride, iron chloride, zinc sulfate, aluminum chloride, copper nitrate;
Natural essence in agent B can adopt a kind of in Flos Rosae Rugosae essence, jasmine flower essence, lavandula angustifolia essence;
The pH of agent A mediating recipe B regulates with phosphoric acid, acetic acid, lactic acid, tartaric acid or citric acid;
Thickening agent in agent A mediating recipe B includes but not limited to the one or more combination in Radix Acaciae senegalis, carboxymethyl cellulose, hydroxyethyl-cellulose, guar gum, propylene glycol stearate;
The surfactant of agent A mediating recipe B comprises anion, cation, both sexes or the non-ionic surface active agents such as stearyl alcohol, glyceryl stearate, sodium lauryl sulfate, OPEO.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410362590.2A CN104083307B (en) | 2014-07-28 | 2014-07-28 | Use a kind of natural hair dye of preparing of plant pigment carthamin and hair colouring methods thereof |
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| CN201410362590.2A CN104083307B (en) | 2014-07-28 | 2014-07-28 | Use a kind of natural hair dye of preparing of plant pigment carthamin and hair colouring methods thereof |
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| CN104083307A true CN104083307A (en) | 2014-10-08 |
| CN104083307B CN104083307B (en) | 2016-08-17 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106309249A (en) * | 2016-10-13 | 2017-01-11 | 江南大学 | Natural hair dye prepared from plant pigment verbena hybrida haematochrome and hair dyeing method of natural hair dye |
| CN106309248A (en) * | 2016-10-13 | 2017-01-11 | 江南大学 | Natural hair dye prepared from plant pigment geranium haematochrome and hair dyeing method of natural hair dye |
| CN108066197A (en) * | 2016-11-11 | 2018-05-25 | 齐齐哈尔大学 | A kind of carthamin yellow juice with healthcare function is to hair-dyeing method |
| CN109577028A (en) * | 2018-11-30 | 2019-04-05 | 泉州市正域数码科技有限公司 | A kind of red jet ink and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106309249A (en) * | 2016-10-13 | 2017-01-11 | 江南大学 | Natural hair dye prepared from plant pigment verbena hybrida haematochrome and hair dyeing method of natural hair dye |
| CN106309248A (en) * | 2016-10-13 | 2017-01-11 | 江南大学 | Natural hair dye prepared from plant pigment geranium haematochrome and hair dyeing method of natural hair dye |
| CN108066197A (en) * | 2016-11-11 | 2018-05-25 | 齐齐哈尔大学 | A kind of carthamin yellow juice with healthcare function is to hair-dyeing method |
| CN109577028A (en) * | 2018-11-30 | 2019-04-05 | 泉州市正域数码科技有限公司 | A kind of red jet ink and preparation method thereof |
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| CN104083307B (en) | 2016-08-17 |
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Effective date of registration: 20170425 Address after: 334205 Jiangxi city of Dexing Province Zhang Cun Sha Lu Cun Cun Xiang Zhang No. 55 Patentee after: Tao Minghui Address before: No. 1800 road 214122 Jiangsu Lihu Binhu District City of Wuxi Province Patentee before: Jiangnan University |
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Inventor after: Gao Haiyan Inventor after: Li Ming Inventor after: Chen Qinjun Inventor after: Yue Juan Inventor after: Xu Yu Inventor before: Gao Haiyan Inventor before: Chen Qinjun Inventor before: Yue Juan Inventor before: Xu Yu |
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Effective date of registration: 20170509 Address after: Baiyun District and the town of Donghua village in Guangzhou City, Guangdong province 510000 China Road No. 25 by building A No. 1 building one or two layer two layer B Patentee after: Guangzhou Chu Yan cosmetics Co., Ltd. Address before: 334205 Jiangxi city of Dexing Province Zhang Cun Sha Lu Cun Cun Xiang Zhang No. 55 Patentee before: Tao Minghui |