CN103479549A - Chestnut shell hair colorant and method for coloring hair - Google Patents
Chestnut shell hair colorant and method for coloring hair Download PDFInfo
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- CN103479549A CN103479549A CN201310425294.8A CN201310425294A CN103479549A CN 103479549 A CN103479549 A CN 103479549A CN 201310425294 A CN201310425294 A CN 201310425294A CN 103479549 A CN103479549 A CN 103479549A
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- chestnut shell
- hair
- agent
- deionized water
- hair dye
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- 241001070941 Castanea Species 0.000 title claims abstract description 49
- 235000014036 Castanea Nutrition 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 11
- 238000004040 coloring Methods 0.000 title claims abstract description 6
- 239000003086 colorant Substances 0.000 title abstract 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000004094 surface-active agent Substances 0.000 claims abstract description 18
- 239000002562 thickening agent Substances 0.000 claims abstract description 18
- 239000008367 deionised water Substances 0.000 claims abstract description 17
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 17
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 239000000118 hair dye Substances 0.000 claims description 27
- 239000000284 extract Substances 0.000 claims description 19
- 238000004043 dyeing Methods 0.000 claims description 18
- 238000000605 extraction Methods 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 13
- -1 Rare-earth salts Chemical class 0.000 claims description 11
- 239000000706 filtrate Substances 0.000 claims description 10
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 10
- 230000003213 activating effect Effects 0.000 claims description 9
- 239000000049 pigment Substances 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 238000001694 spray drying Methods 0.000 claims description 6
- 239000012043 crude product Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 229920003091 Methocel™ Polymers 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 2
- 229940043264 dodecyl sulfate Drugs 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 229940014259 gelatin Drugs 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 230000037308 hair color Effects 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical group [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 2
- 238000010979 pH adjustment Methods 0.000 claims description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 239000000230 xanthan gum Substances 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 235000010493 xanthan gum Nutrition 0.000 claims description 2
- 229940082509 xanthan gum Drugs 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 231100000252 nontoxic Toxicity 0.000 abstract description 5
- 230000003000 nontoxic effect Effects 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 239000013543 active substance Substances 0.000 abstract 1
- 238000009210 therapy by ultrasound Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 4
- 238000010668 complexation reaction Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 210000000582 semen Anatomy 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- NTYJJOPFIAHURM-UHFFFAOYSA-N Histamine Chemical compound NCCC1=CN=CN1 NTYJJOPFIAHURM-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 244000208060 Lawsonia inermis Species 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 201000011510 cancer Diseases 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000037307 sensitive skin Effects 0.000 description 2
- 230000000638 stimulation Effects 0.000 description 2
- 235000018553 tannin Nutrition 0.000 description 2
- 229920001864 tannin Polymers 0.000 description 2
- 239000001648 tannin Substances 0.000 description 2
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical class OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 1
- GYVYGTTZKLHDON-UHFFFAOYSA-N 2-anilinophenol Chemical compound OC1=CC=CC=C1NC1=CC=CC=C1 GYVYGTTZKLHDON-UHFFFAOYSA-N 0.000 description 1
- 206010049865 Achromotrichia acquired Diseases 0.000 description 1
- 244000136475 Aleurites moluccana Species 0.000 description 1
- 235000006667 Aleurites moluccana Nutrition 0.000 description 1
- 229930091051 Arenine Natural products 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000018244 Castanea mollissima Nutrition 0.000 description 1
- 150000000703 Cerium Chemical class 0.000 description 1
- 108010014095 Histidine decarboxylase Proteins 0.000 description 1
- 102100037095 Histidine decarboxylase Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- 150000001206 Neodymium Chemical class 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GAMYVSCDDLXAQW-AOIWZFSPSA-N Thermopsosid Natural products O(C)c1c(O)ccc(C=2Oc3c(c(O)cc(O[C@H]4[C@H](O)[C@@H](O)[C@H](O)[C@H](CO)O4)c3)C(=O)C=2)c1 GAMYVSCDDLXAQW-AOIWZFSPSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 238000006701 autoxidation reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000001058 brown pigment Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000001465 calcium Nutrition 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229930003944 flavone Natural products 0.000 description 1
- 235000011949 flavones Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 231100000025 genetic toxicology Toxicity 0.000 description 1
- 230000001738 genotoxic effect Effects 0.000 description 1
- 235000013402 health food Nutrition 0.000 description 1
- 229960001340 histamine Drugs 0.000 description 1
- 230000000774 hypoallergenic effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 150000002603 lanthanum Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
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- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 235000014786 phosphorus Nutrition 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000007686 potassium Nutrition 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
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- 239000011734 sodium Substances 0.000 description 1
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- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
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- 229940088594 vitamin Drugs 0.000 description 1
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- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- VHBFFQKBGNRLFZ-UHFFFAOYSA-N vitamin p Natural products O1C2=CC=CC=C2C(=O)C=C1C1=CC=CC=C1 VHBFFQKBGNRLFZ-UHFFFAOYSA-N 0.000 description 1
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- Cosmetics (AREA)
Abstract
The invention provides a chestnut shell hair colorant which comprises a treating agent and a coloring agent. The treating agent comprises 2-15% of histidine, 1-5% of thickening agents, 5-10% of surface active agents, and the balance deionized water, and the pH of the treating agent is adjusted to be 8-9. The coloring agent comprises 10-30% of chestnut shell extractives, 3-10% of rear-earth salt mordanting active agents, 1.5-5 % of thickening agents, 5-10% of surface active agents, and the balance deionized water. The method for coloring hair by means of the chestnut shell hair colorant comprises the steps of evenly smearing the treating agent on the hair, cleaning the hair after the infrared heating, adding the chestnut shell extractives into the deionized water, adopting ultrasonic treatment, after disaggregation and even scattering of the chestnut shell extractives, adding the other components to be mixed into paste, evenly smearing the paste on the hair, conducting the infrared heating, and if a user needs the deeper color, repeatedly conducting the step two, wherein the color of the obtained dyed hair can be deepened as time passes. The chestnut shell hair colorant is safe, non-toxic, stable in color and high in coloring rate.
Description
Technical field
The invention belongs to field of hairdye, especially natural plant hair dye.
Background technology
Semen Castaneae, have another name called chestnut, Chinese Chestnut, is the plant of Fagaceae Castanea, and nutritive value is very abundant and sweet fragrant, is a kind of common health food.Contain the mineral such as abundant starch, protein and vitamin and calcium, phosphorus, potassium in Semen Castaneae.Chinese medicine is thought: the sweet temperature of chestnut, and nontoxic, the spleen invigorating tonifying liver is arranged, the medical function of physique enhancing and bone strengthening.And will produce a large amount of chestnut shell garbages in the Semen Castaneae course of processing.Be rich in natural dye and a certain amount of tannin in chestnut shell, and the chestnut shell pigment has the biological activitys such as antibacterial and antioxidation, it has prospect preferably on the directions such as printing and dyeing and food.
Hair dyeing is to follow the fashion, pursue beautiful a kind of mode.The hair dye of selling on Vehicles Collected from Market mostly contains p-phenylenediamine (PPD) and diphenol compounds, has toxicity, sensitization, carcinogenecity.And oxidative hair dyes with the most use contains more than 20 and plants chemical composition, wherein there are nine kinds can cause cell mutation, if long-term a large amount of the use do not noted again cleaning, may cause cancer.The natural plant dye security feature unique with it more and more is subject to people's attention, and becomes the development trend in hair dye market, but all also barely satisfactory at safety and the final hair dyeing effect of natural plants hair dyeing process.
(application number 201010134137.8, CN102058503) disclose a kind of natural botanical hair dye be comprised of Hai Na and ferrous salt to Hao Shouzhu, has the stable characteristics of rapid dyeing and Color, can dye black.But contain Henna powder in this formula, skin is had to zest, wherein contain HNQ, be a kind of carcinogenic, mutagenesis, cause the material of genotoxicity.The result of use of sea Na hair dye has caused a lot of disputes.(application number 201210206888.5, CN102885730A) disclose a kind of botanical hair dye to Chen Hao, forgives the Henna powder of 80%-90%wt.Add simultaneously and have and will, with the plant extract of usefulness, make hair dye there is the effect of hair care hair care.Though can reach to dying black effect, it has used p-phenylenediamine (PPD) and, to phenylamino phenol, life-time service can increase suffers from the cancer probability.
Summary of the invention
The present invention overcomes in prior art hair dye containing carcinogen, uses unsafe deficiency that a kind of safety non-toxic, color and luster is stable, dye-uptake is high chestnut shell hair dye are provided.Chestnut shell extract is rich in the yellowish-brown pigment, not only contains abundant flavone compound, has good antibacterial effect simultaneously.Chestnut shell extract contains a certain amount of tannin, chance ferrum can form the complex of three-fold coordination, in complexation, autoxidation becomes quinone and shows black-and-blue, chestnut shell natural hair dye disclosed by the invention also avoids using the material that skin is had to stimulation in the hair dyeing process simultaneously, especially applicable for the sensitive skin people.
Technical scheme that the present invention adopts is: described chestnut shell hair dye is divided into two doses of inorganic agent and stains; Two agent prescriptions are respectively:
Inorganic agent (mass percent amounts to 100%):
Histidine 2%-15%,
Thickening agent: 1%-5%,
Surfactant: 5%-10%,
Surplus is deionized water, and adjusting pH is 8～9;
Stain (mass percent amounts to 100%):
Chestnut shell extract: 10%-30%,
Rare-earth salts mordant dyeing activating agent: 3%-10%,
Thickening agent: 1.5%-5%,
Surfactant: 5%-10%,
Surplus is deionized water.
The present invention adopts alkaline histidine to carry out pre-treatment to poliosis.Histidine is a kind of half necessary aminoacid, imidazole radicals energy and the Fe of histidine
2+form coordination compound, promote the absorption of ferrum.Under the effect of histidine decarboxylase, form histamine, it has very strong vasorelaxation action, can treat irritated.The histidine that utilizes Nantural non-toxic by hair-be reduced into-S-H of S-S-key, the hair scale sheet is opened, be conducive to absorption and the infiltration of chestnut shell dyestuff on hair.And alkali liquor can make keratin main chain fracture, the disulfide bond in making laterally to connect and salt type bond etc. break to form new key simultaneously.Wherein alkaline agent can be one or more in sodium hydroxide, sodium carbonate, monoethanolamine.
Further, described thickening agent is one or more mixture in sodium carboxymethyl cellulose, sodium polyacrylate, xanthan gum, gelatin, guar gum, Radix Acaciae senegalis or hydroxy methocel.
Further, described surfactant is one or more mixture in silicone oil, glyceryl monostearate, lauryl sulfate or polyoxyethylenated alcohol sodium sulfate.
Further, described adjusting pH alkali used is one or more in sodium hydroxide, sodium carbonate or monoethanolamine.
As preferably, the chloride that described rare-earth salts mordant dyeing activating agent is lanthanum or cerium or one or more mixing in carbonate, when rare earth carbonate is used, usable acid dissolves.Rare earth ion can be used as central ion and as the dyestuff ion complexation of ligand.In addition, it also has electrolytelike effect, and short metachromia is arranged.Rare earth ion can enter hair scale sheet depths, with dye molecule and cellulosic molecule, forms polynary complexation, thereby improves dyefastness.
Further, described chestnut shell extract adopts the procedure extraction of chestnut shell remove impurity → supersound extraction → filtration → filtrate → merging filtrate in water → concentrated → spray drying → pigment crude product; Extracting temperature is 80 ℃, and extraction time is 1-3h, and pH value is 9, and extracting solid-to-liquid ratio is 1:10～15(mass ratio), spray-dired intake air temperature 130-170 ℃, air outlet temperature 70-90 ℃.
As preferably, described two agent prescriptions are respectively:
Inorganic agent (mass percent amounts to 100%):
Alkalescence histidine 10%-15%,
Thickening agent: 3%-5%,
Surfactant: 8%-10%,
Deionized water: surplus, and adjusting pH is 8～9;
Stain (mass percent amounts to 100%):
Chestnut shell extract: 20%-30%,
Mordant dyeing activating agent (rare-earth salts): 5%-10%,
Thickening agent: 4%-5%,
Surfactant: 8%-10%,
Deionized water: surplus.
Use the hair colouring methods of above-mentioned chestnut shell hair dye, step is, the first step, get histidine, add deionized water, with lye pH adjustment=8-9, and add thickening agent and surfactant to be adjusted to pulp, evenly smear on hair 30～35 ℃ of Infrared Heating 15～30min afterwash;
Second step, chestnut shell extract is added in deionized water, adopt supersound process, after the chestnut shell extract disaggregation is uniformly dispersed, add mordant dyeing activating agent, thickening agent and surfactant furnishing pulpous state, evenly smear on hair, 30～35 ℃ of Infrared Heating 60～120min, the gained hair color increases in time and deepens, if more dark colour demand is arranged, repeats second step.
Beneficial effect of the present invention: chestnut shell hair dye safety non-toxic of the present invention, color and luster are stablized, dye-uptake is high; Skin is had no stimulation, there is hypo-allergenic effect, especially applicable for the sensitive skin people.
The specific embodiment
Below with embodiment, be described further, but do not do restriction of the present invention:
Extract embodiment mono-
Chestnut shell extract, its preparation method: temperature is 80 ℃, and the supersound extraction time is 1h, and pH value is 9, and the extraction solid-to-liquid ratio is 1:15, extractant is water.
Chestnut shell remove impurity → extractant supersound extraction → filtration → filtrate → merging filtrate → concentrated → spray drying (inlet temperature is 130 ℃, and outlet temperature is 70 ℃) → pigment crude product.
Extract embodiment bis-
Chestnut shell extract, its preparation method: temperature is 80 ℃, and the supersound extraction time is 2h, and pH value is 9, and the extraction solid-to-liquid ratio is 1:10, extractant is water.
Chestnut shell remove impurity → extractant supersound extraction → filtration → filtrate → merging filtrate → concentrated → spray drying (inlet temperature is 170 ℃, and outlet temperature is 90 ℃) → pigment crude product.
Extract embodiment tri-
Chestnut shell extract, its preparation method: temperature is 80 ℃, and the supersound extraction time is 3h, and pH value is 9, and the extraction solid-to-liquid ratio is 1:15, extractant is water.
Chestnut shell remove impurity → extractant supersound extraction → filtration → filtrate → merging filtrate → concentrated → spray drying (inlet temperature is 150 ℃, and outlet temperature is 80 ℃) → pigment crude product.
Hair dye and hair dyeing embodiment
As can be seen from the above table, formula of the present invention is: inorganic agent (mass percent amounts to 100%): alkaline histidine 10%-15%, and thickening agent: 3%-5%, surfactant: 8%-10%, deionized water: surplus, and adjusting pH is 8～9; Stain (mass percent, amount to 100%): chestnut shell extract: 20%-30%, mordant dyeing activating agent (rare-earth salts): 5%-10%, thickening agent: 4%-5%, surfactant: 8%-10%, deionized water: surplus, the time hair dye dye-uptake and color stability more outstanding (the same dose hair dyeing effect is darker, and Color is more lasting).
In addition, when the use cysteine replaces histidine of the present invention or replaces cerium salt of the present invention and lanthanum salt with neodymium salt, under the condition of using same dose to be had hair dyed, hair dyeing effect and persistence are all effective not as of the present invention.
Claims (8)
1. a chestnut shell hair dye is characterized in that: hair dye is divided into two doses of inorganic agent and stains; Two agent prescriptions are respectively:
Inorganic agent (mass percent amounts to 100%):
Histidine 2%-15%,
Thickening agent: 1%-5%,
Surfactant: 5%-10%,
Surplus is deionized water, and adjusting pH is 8～9;
Stain (mass percent amounts to 100%):
Chestnut shell extract: 10%-30%,
Rare-earth salts mordant dyeing activating agent: 3%-10%,
Thickening agent: 1.5%-5%,
Surfactant: 5%-10%,
Surplus is deionized water.
2. chestnut shell hair dye according to claim 1 is characterized in that: described thickening agent is one or more mixture in sodium carboxymethyl cellulose, sodium polyacrylate, xanthan gum, gelatin, guar gum, Radix Acaciae senegalis or hydroxy methocel.
3. chestnut shell hair dye according to claim 1, it is characterized in that: described surfactant is one or more mixture in silicone oil, glyceryl monostearate, lauryl sulfate or polyoxyethylenated alcohol sodium sulfate.
4. chestnut shell hair dye according to claim 1 is characterized in that: described adjusting pH alkali used is one or more in sodium hydroxide, sodium carbonate or monoethanolamine.
5. chestnut shell hair dye according to claim 1, is characterized in that: the chloride that described rare-earth salts mordant dyeing activating agent is lanthanum or cerium or one or more mixing in carbonate.
6. chestnut shell hair dye according to claim 1, is characterized in that: the procedure extraction of described chestnut shell extract employing chestnut shell remove impurity → supersound extraction → filtration → filtrate → merging filtrate in water → concentrated → spray drying → pigment crude product; Extracting temperature is 80 ℃, and extraction time is 1-3h, and pH value is 9, and extracting the solid-liquid mass ratio is 1:10～15, spray drying intake air temperature 130-170 ℃, air outlet temperature 70-90 ℃.
7. chestnut shell hair dye according to claim 1, it is characterized in that: described two agent prescriptions are respectively: inorganic agent (mass percent amounts to 100%):
Alkalescence histidine 10%-15%,
Thickening agent: 3%-5%,
Surfactant: 8%-10%,
Deionized water: surplus, and adjusting pH is 8～9;
Stain (mass percent amounts to 100%):
Chestnut shell extract: 20%-30%,
Mordant dyeing activating agent (rare-earth salts): 5%-10%,
Thickening agent: 4%-5%,
Surfactant: 8%-10%,
Deionized water: surplus.
8. according to the hair colouring methods of the described chestnut shell hair dye of claim 1～7 any one, it is characterized in that: step is, the first step, get appropriate histidine, add deionized water, with lye pH adjustment=8-9, and add thickening agent and surfactant to be adjusted to pulp, evenly smear on hair 30～35 ℃ of Infrared Heating 15～30min afterwash;
Second step, chestnut shell extract is added in deionized water, adopt supersound process, after the chestnut shell extract disaggregation is uniformly dispersed, add mordant dyeing activating agent, thickening agent and surfactant furnishing pulpous state, evenly smear on hair, 30～35 ℃ of Infrared Heating 60～120min, the gained hair color increases in time and deepens, if more dark colour demand is arranged, repeats second step.
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| CN106474035A (en) * | 2016-10-27 | 2017-03-08 | 常州大学 | A kind of lac hair dye and its hair colouring methods |
| CN106491421A (en) * | 2016-11-03 | 2017-03-15 | 江城中澳农业科技发展有限公司 | A kind of macadamia shell natural hair dye and preparation method thereof |
| CN107156408A (en) * | 2017-04-24 | 2017-09-15 | 广西柳州中嘉知识产权服务有限公司 | Method for processing chestnut in syrup |
| CN107964809A (en) * | 2017-11-09 | 2018-04-27 | 安徽美德发艺有限责任公司 | A kind of environmentally friendly coloring agent for U-shaped nail sending and receiving |
| CN111021104A (en) * | 2019-12-12 | 2020-04-17 | 苏州麻朵纺织科技有限公司 | Natural dyeing auxiliary for dyeing medium and light color series and dyeing method thereof |
| CN113527905A (en) * | 2021-06-24 | 2021-10-22 | 华中农业大学 | Method for extracting chestnut shell brown pigment from chestnut shells and application of chestnut shells brown pigment in hair dye |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106474035A (en) * | 2016-10-27 | 2017-03-08 | 常州大学 | A kind of lac hair dye and its hair colouring methods |
| CN106491421A (en) * | 2016-11-03 | 2017-03-15 | 江城中澳农业科技发展有限公司 | A kind of macadamia shell natural hair dye and preparation method thereof |
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| CN113527905A (en) * | 2021-06-24 | 2021-10-22 | 华中农业大学 | Method for extracting chestnut shell brown pigment from chestnut shells and application of chestnut shells brown pigment in hair dye |
| CN113527905B (en) * | 2021-06-24 | 2022-07-29 | 华中农业大学 | Method for extracting chestnut shell brown pigment from chestnut shells and application of chestnut shells brown pigment in hair dye |
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