CN103237540A - Mixed metal-plant-based hair dye composition including cysteine, and method for dyeing hair using same - Google Patents
Mixed metal-plant-based hair dye composition including cysteine, and method for dyeing hair using same Download PDFInfo
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- A61K2800/4322—Direct dyes in preparations for temporarily coloring the hair further containing an oxidizing agent
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Abstract
The present invention relates to a hair dye composition which consists of a dye extracted or derived from a plant, and cysteine or a hydrochloride thereof. The problem with conventional natural hair dye compositions which are plant-based dyes containing metal salts is that the dyeing time is a tedious 40 minutes or more. Since the hair dye composition of the present invention contains cysteine or a hydrochloride thereof, the dyeing time can be reduced to 10-20 minutes.
Description
[technical field]
The present invention relates to comprise the hair colouring methods that the metal of cysteine-plant mixes hair coloring preparation composition and utilizes it.
[background technology]
But the hair dye the earth is divided into 3 kinds.Provisional dyeing is semipermanent dyeing and permanent stain.Such classification is dyestuff to be decided (fastness) to extent of hair according to disposable.
Permanent hair dye under the present invention can be divided into the permanent hair dye of vegetalitas according to the dyestuff that uses with its color development reaction principle, and the permanent hair dye of oxidized form and metal-plant mix permanent hair dye etc.，，，，
The colouring method that the permanent hair dye of vegetalitas just used from ancient times quite remote utilizes Lignum Sappan, and indigo, Flos Chrysanthemi and mignonettetree etc. is dyeed.Though but the permanent hair dye of vegetalitas does not have skin allergy, color development power and vitality very a little less than, thereby use vegetable dyes recently hardly separately, use mainly as the auxiliary element of the permanent hair dye of oxidized form or the permanent hair dye of metallicity etc.
The permanent hair dye of oxidized form is the most normal hair dye of seeing around us, is called " dyeing medicine " again.The permanent hair dye of oxidized form is made into oxidized form dyestuff penetration hair epidermis (Cuticle) and pigment molecular is deposited in the hair cortex (Cortex).The effect of appending by infiltration and oxidant makes these stain decolourings or " painted.Oxidative dyestuff (Oxidation tints) is the synthetic organism dyestuff of deriving from aniline (Aniline), and hair dyeing power and the classic advantage of color and luster vitality in hair colouring methods are arranged, and has been developed at present and can have made about tone more than 60,000 kinds.The permanent hair dye of oxidized form is by being 1 dose of hair dye and being that 2 doses of oxidant constitute.1 dose contains oxidized form dyestuff and alkaline agent, mainly uses the alkaline agent of ammonia (Ammonia) and monoethanolamine (Monoethanolamine) etc. that hair shaft is expanded, and the oxidized form dyestuff intermediate helps deciding in hair cortex by the hair epidermis of hair shaft part.2 doses are called as oxidant, contain hydrogen peroxide.When 1 dose of the permanent hair dye of oxidized form and 2 doses was mixed, dyestuff began reaction with the oxygen molecule that is generated by hydrogen peroxide.The mutual oxidation reaction of this oxidized form dyestuff and color occurs at hair.And, mutually combine reaction and dyestuff polymer that molecular weight increases through the time become insoluble solid, thereby can't between narrow hair epidermis, spill, so original written or printed documents is stayed hair cortex inside, principle and have the very outstanding advantage of color and luster vitality thus.But so the permanent hair dye of oxidized form has by the alkaline agent that uses and hydrogen peroxide and the albumen of hair sustains damage, the shortcoming that is caused allergic reaction at skin by the oxidation reaction of dyestuff.Usually be called this anaphylaxis of burning lacquer and be the immunologic function by our health, brought out pruritus and erythema at scalp, rubescent etc., when serious not only scalp, also bring out blister and pruritus at whole body.The persistence of the permanent hair dye color and luster of oxidized form is outstanding, implement the short but hair dye very easily of time ratio, but this anaphylaxis implements that then allergic symptom is serious all the more whenever once dyeing, and therefore the permanent hair dye of oxidized form being presented the people that anaphylaxis is has the shortcoming that can't utilize the permanent hair dye of oxidized form for 2 times.
Metal under the present invention-plant mixes hair dye and also is called the plant containing natural dyestuff hair dye that contains slaine, and coloring hairs does not bring out the skin allergy of scalp etc. but can't use the useful hair dye of people of the permanent hair dye of oxidized form for oxidized form dyestuff (aniline based dye intermediate) is had anaphylaxis when implementing.
The plant containing natural dyestuff hair dye that contains slaine is by containing 1 dose of the plant containing natural dyestuff and contain 2 doses of mordant dyeing mode hair dyes that constitute of mordant of slaine.(mordant dyeing Mordanting) refers to can't dyed and arrive pollutant when dyestuff, and namely when hair or fiber etc., media is dying and making 1 side of mordant be attached to pollutant neatly, and opposite side is combined with dyestuff and generates coloured insoluble compound in mordant dyeing.
The plant containing natural dyestuff hair dye that contains slaine like this has and does not use as the synthetic oxidized form dyestuff of the permanent hair dye of oxidized form and do not have skin allergy, the harm of bringing to human body is few advantage also, but the dyeing enforcement time of using the permanent hair dye of oxidized form of hyperergic oxidized form dyestuff is about 10 minutes～30 minutes and shorter, in contrast to this, the plant containing natural dyestuff hair dye weak point that contains slaine then needs 40 minutes, long then consume more than 2 hours, thereby the very long inconvenience of dyeing enforcement time is arranged, and near hair surface, form the dyeing theory of complex salt with the slaine that is mordant because of vegetable dyes, has the color and luster of dyeing by daylight, washing, the external condition of friction and antiperspirant etc. and the color that dyes changes or shortcoming that can not long term maintenance.Generally speaking, be about about 4 weeks during the keeping of the color and luster of the dyeing of the permanent hair dye of oxidized form, and the plant containing natural dyestuff hair dye that contains slaine in the past is about 7～12 days and very short, thereby covering under the situation of covering graying preparation dyeing of white hair, having needs the about inconvenience more than 3 times of dyeing in 1 month.
[summary of the invention]
[technical task that invention will solve]
The present invention aims to provide the plant containing natural dyestuff hair dye of comparing in the past can make the dyeing enforcement time shorten, and the dyeing firmness is compared the outstanding plant containing natural dyestuff hair dye of plant containing natural dyestuff hair dye in the past.
[solving the technical scheme of problem]
Mix hair coloring preparation composition for reaching described purpose, the invention provides the metal-plant that comprises from the hydrochlorate of the dye well cysteine in plant extract or source or cysteine.
Described hair coloring preparation composition contains the hydrochlorate of cysteine or cysteine, thereby the very long dyeing enforcement time of consumption more than 40 minutes as the problem of in the past the vegetable dyes natural hair dye compositions that contains slaine can be shortened to 10～20 minutes.
In addition, provide to have solved because of vegetable dyes and near hair surface, form color and luster that the dyeing theory of complex salt dyes by daylight with the slaine that is mordant, washing, the external condition of friction and antiperspirant etc. and the color that dyes changes or shortcoming that can not long term maintenance, and do not injure the hair coloring preparation composition of functional advantage of the plant containing natural dyestuff hair dye that contains slaine of no skin allergy.
[invention effect]
The natural hair dye compositions of no skin allergy of the present invention contains the hydrochlorate of cysteine or cysteine, thus can expect metal ion as the cystine of the side chain key of hair and mordant to form powerful key and will dye the enforcement time from the past shorten to facility about 10～20 minutes more than 40 minutes.
In addition, because the use of described composition, the firmness of also can expecting to dye is kept the effect more than 30 days, and the firmness that has solved natural hair dye in the past thus is very short and need the problem of the about inconvenience more than 3 times of dyeing in 1 month etc. in the situation of covering achromachia agent dyeing about 7～12 days.
[description of drawings]
Fig. 1 is the photo of the power of relatively having hair dyed in experimental example 1.
Fig. 2 is the photo of the power of relatively having hair dyed in experimental example 2.
Fig. 3 is the photo of the power of relatively having hair dyed in experimental example 3.
Fig. 4 is the photo of firmness of relatively dyeing in experimental example 4.
[embodiment]
The present invention below is described in further detail.
The present invention relates to comprise from metal-plant of the hydrochlorate of the natural dye of plant extract or source (origin) and cysteine or cysteine and mix hair coloring preparation composition.
Described cysteine is unique sulfydryl that comprises in 20 kinds of primary amino acids, the i.e. neutral amino acid of sulfur (S).The sulfydryl of cysteine carries out the oxidized cystine (Cystine) that then forms, and is reduced the reversibility redox reaction that then forms cysteine again.Its infra shown in the Chemical formula 1 describe.
［ Chemical formula 1 ］
［ chemical formula 0001 ］
Cysteine is as the formation fingernail, and the main material of the albumen of the keratin of the main component of hair (Keratin) is important key element in the structure that determines albumen.In the situation of the keratin works of hair, the spiral peptide bond as main chain key vertical with the length direction of hair (Peptide bond) by with as with the crosslinked and stabilisation of the disulfide bond (Disulfide bond) of the side chain key of hair level or cystine linkage (Cystine bond).On these crosslinked hair fibers of being everlasting, the most normal is cystine linkages of per 4 helical rotating parts (Helical turn) (Cystine bond).
The sulfydryl of cysteine has strong affinity to heavy metal in addition, thus cysteine and ferrum, nickel, combination such as chelate (Chelate) such as powerful formation such as the metal of lead and silver etc.This chelate adhesion is very powerful, has the dynamics more about about 100 times than general chemical bond.So using cysteine or its hydrochlorate will be cystine linkage (S S) reduction of the side chain key of hair, cut-out and formation sulfhydryl are (SH) afterwards, herein in conjunction with form powerful chelate conjugate as the metallic compound of mordant, thereby the dyeing enforcement time is shortened, but and the color and luster long term maintenance of dyeing.
Can use from Lignum Sappan from the dyestuff of described plant extract or source (origin), Cortex Phellodendri, Rhizoma Coptidis, Radix Arnebiae (Radix Lithospermi), carmine, Flos Carthami, Rhizoma Curcumae Longae, indigo, persimmon, chesnut, the dyestuff that robur or Fructus Gardeniae are extracted or originate.More specifically, the dyestuff from described plant extract or source (origin) can comprise pyrogallol, gallic acid, hematoxylin, hematein, tannic acid or these ester.The structure of described plant containing natural dyestuff comprises a plurality of hydroxyls and (OH), this hydroxyl is formed complex with forming coordinate bond as the metal ingredient of mordant and develops the color, be attached to hair and will have hair dyed.Its infra is shown in Chemical formula 2～4, in plant containing natural is originated described dyestuff, represent pyrogallol (C typically
6H
6O
3, MW; 126.11, Pyrogallol), gallic acid (C
7H
6O
5, MW; 170.12, Gallic Acid), and hematein (C
16H
12O
6, MW; 300.26, Hematein).
［ Chemical formula 2 ］
［ chemical formula 0002 ］
［ chemical formula 3 ］
［ chemical formula 0003 ］
［ chemical formula 4 ］
［ chemical formula 0004 ］
The use amount of the hydrochlorate of described cysteine or cysteine preferably hair coloring preparation composition all in 0.02～20 weight %.The use amount of the hydrochlorate of cysteine or cysteine surpasses 20 weight %, and then the side chain key of hair etc. is cut off too much and causes hair damages and distortion, thereby does not preferably break away from described scope.
In addition, 0.01～10 weight % uses from the dyestuff of described plant extract or source (origin) is preferably all with hair coloring preparation composition.
In described hair dye, except the hydrochlorate of described plant containing natural dye well cysteine or cysteine, can adopt the composition of composition except oxidized form dye well aquae hydrogenii dioxidi that is used for the permanent hair dye of oxidized form routinely, the dosage form of hair coloring preparation composition be liquid state also paste also can, need not limit especially.
Particularly, except from the hydrochlorate of the dye well cysteine in described plant extract or source or cysteine, also can comprise antioxidant, fatty acid or aliphatic alcohol, swelling agent, buffer agent, surfactant, pH regulator agent and water.The content of each concrete constituent can be: from dyestuff 0.01～10 weight % of plant extract or source (origin), hydrochlorate 0.02～20 weight % of cysteine or cysteine, antioxidant 0.1～5 weight %, fatty acid or aliphatic alcohol 1～10 weight %, swelling agent 1～10 weight %, buffer agent 0.1～15 weight %, surfactant 1～20 weight %, pH regulator agent 0.1～6 weight % and water 25～as 95 weight %.
Described antioxidant can use sodium sulfite (Sodium Sulfite), sodium ascorbate (Sodium Ascorbate) or ascorbic acid (Ascorbic Acid) etc.
Can use the saturated or unsaturated fatty acid of carbon number 16～22 as described fatty acid, especially preferably use oleic acid (Oleic Acid).Can use cetyl alcohol (Cetyl Alcohol) as aliphatic alcohol, the aliphatic alcohol of stearyl alcohol (Stearyl Alcohol) and mountain Yu base alcohol carbon number 16～22 scopes such as (Behenyl Alcohol).
Can use molecular weight little and be penetrated into hair inside easily as described swelling agent, has the carbamide (Urea) of amino of hydrogen bond that cuts off one of the side chain key be hair, thio urea (Thiourea), carbamide peroxide (Urea Peroxide), polyoxyethylene methylene carbamide (Polyoxymethylene Urea), hydroxyethyl urea (Hydroxyethyl Urea), ammonia (Ammonia) and salt etc.
(buffer Buffer) can use salicylic acid (Salicylic Acid) and sodium salicylate (Sodium Salicylate), lactic acid (Lactic Acid) and sodium lactate (Sodium Lactate) etc. as described buffer agent.
Can use as cationic as described surfactant, anionic property and nonionic surfactant and be used for the surfactant of conventional hair dye, concrete example can be lifted alkyl trimethylammonium chloride (Alkytrimethylammonium Chloride), polyoxyethylene lauryl ether sodium sulfate (Sodium Polyoxyethylene Laurylether Sulfate), polyoxyethylene cetyl base ether (Polyoxyethylene Cetylether), polyoxyethylene spermaceti stearyl ether (Polyoxyethylene Cetostearylether), polyoxyethylene oleyl ether (Polyoxyethylene Oleylether) etc.
In addition, described pH regulator agent can be used ammonia (Ammonia), ammonium bicarbonate (Ammonium Bicarbonate), monoethanolamine (Monoethanolamine) and triethanolamine (Triethanolamine) etc.
In addition, the present invention relates to comprise the hair dye that described metal-plant mixes hair coloring preparation composition and comprises the mordant compositions of slaine.
The dosage form of described hair dye be liquid state also can, be paste also can, need not limit especially.
Described mordant compositions can comprise slaine, fatty acid or aliphatic alcohol, surfactant, pH regulator agent and water.More specifically can comprise slaine 0.1～20.0 weight %, fatty acid or aliphatic alcohol 1.0～20.0 weight %, surfactant 1.0～20.0 weight %, pH regulator agent 0.1～10.0 weight % and water 25.0～97.8 weight %.
As described slaine use is the water-soluble metal salt of divalent or 3 valencys.Metal ion has the ion of the arm that can be combined with other material more.This brachium conjunctivum is different with general ioni valence, is called ligancy, and its number is 2～8.Using as mordant is the metal ion of 4 ligancies or 6 ligancies, and 4 coordinations are nickel ion (Ni+2) and zinc ion (Zn+2) degree.In contrast to this, 6 coordinations have ferrous ion (Fe+2), ferric ion (Fe+3), aluminium ion (Al+3), chromium ion (Cr+3), copper ion (Cu+2), cobalt ion (Co+2), divalent tin ion (Sn+2), tetravalent tin ion (Sn+4), magnesium ion (Mg+2) etc.The metal ion of 6 coordinations is so all stretched out arm to positive 8 body directions centered by metal ion.Thereby mordant dyeing then metal ion is combined with very complicated form with pigment molecular and fiber in all directions.Pigment molecular is that medium is combined with other molecule with such metal ion, presents then that electronics moves phenomenon and tone becomes darkly indigo the time, and degree of stability increases.In addition, follow the phenomenon that is called as resonance of electronics, count with intensity and overlapping slightly different tone according to it.So the tone after the mordant dyeing becomes obscure, present black when especially work as the concentration rising by the mordant dyeing of iron ion owing to tone overlapping many.
Can utilize copper (Cu) as described slaine, cadmium (Cd), arsenic (As), hydrargyrum (Ag), plumbous (Pb), chromium (Cr), ferrum (Fe), the salt of stannum metals such as (Sn), but because copper, cadmium, arsenic, hydrargyrum, plumbous and 6 valency chromium are the heavy metal pollution materials that people's health had the influence of disliking, and preferably contain the ferrous sulfate of the big iron ion of the coordination binding ability that forms 6 ligand complex agent, iron sulfate, hydrochloric acid is ferrous, hydrochloric acid ferrum and hydrate etc. be fit to.
Show that down chemical formula 5 shows by the disulfide bond of the cystine of cysteine or the cut-out of its hydrochlorate and the coordination bonding mechanism of iron ion (Fe+3), following showing shown in the chemical formula 5, (a), (b), (c), (d) and (e) part be with other part (Ligand) namely, hair, the part of combination such as dyestuff or hydrone, can obtain hair dyeing power when this part forms all disulfide bond increases, and the hair coloring preparation composition of color long term maintenance.
［ chemical formula 5 ］
［ chemical formula 0005 ］
The mordant dyeing method has after pair hair mordant dyeing mixes with dyestuff with the back mordant dyeing of mordant dyeing after the first mordant dyeing of natural origin dyeing and the dyeing and with mordant and 3 kinds of mordant dyeings etc. when dyeing.But compare mordant with by the mordant dyeing thing, i.e. the speed of hair combination, the quicker generation of the speed of being combined with dyestuff is so the dyeing firmness reduces in the situation of carrying out first mordant dyeing or mordant dyeing simultaneously.
Thereby utilize the back mordant dyeing in the present invention and utilize cysteine or its hydrochlorate etc. cut off more main side chain keys as hair cystine disulfide bond (Disulfide bond) afterwards, form powerful conjugate and shorten the dyeing enforcement time with iron ion herein, but improve hair dyeing power and cause the color and luster long term maintenance of the dyeing of hair.
Particularly, hair colouring methods of the present invention is coated on hair with described hair coloring preparation composition, after placing 3～20 minutes, applies and describedly comprises the mordant compositions of slaine and placed 3～20 minutes.Be more preferably, hair coloring preparation composition is coated on hair, after placing 5～10 minutes, apply and describedly comprise the mordant compositions of slaine and placed 5～10 minutes.When using hair coloring preparation composition of the present invention, even with hair coloring preparation composition below 10 minutes, the mordant compositions total implement stain below 20 minutes, also can obtain sufficient Color below 10 minutes.
The described mordant compositions that comprises slaine can comprise slaine, fatty acid or aliphatic alcohol, surfactant, pH regulator agent and water.Specifically can comprise slaine 0.1～20.0 weight %, fatty acid or aliphatic alcohol 1.0～20.0 weight %, surfactant 1.0～20.0 weight %, pH regulator agent 0.1～10.0 weight % and water 25.0～97.8 weight %.
Below at length the present invention will be described for concrete embodiment, interest field of the present invention is not limited to these embodiment.
[embodiment 1]
As hair coloring preparation composition, will be from dyestuff or the pyrogallol (trade name: RODOL PG of plant extract or source (origin), manufacturer: Jos.H.Lowenstein Sons, Inc.) 2 weight %, cysteine 4 weight %, as antioxidant, sodium ascorbate 0.5 weight %, as swelling agent, carbamide 5 weight %, as buffer agent, salicylic acid 1 weight % and sodium salicylate 2.0 weight % mix with purified water 59.5 weight % and are warmed to 75～85 ℃ and dissolve, will be as aliphatic alcohol, and cetyl alcohol 8 weight %, as surfactant, polyoxyethylene spermaceti stearyl ether 15 weight % are warmed to 75～85 ℃ and dissolve.Described dissolved substances is cooled to 50～55 ℃ after mixing, after adding ammonium bicarbonate 3 weight % as the pH regulator agent here, stirs and metal-plant mixing hair coloring preparation composition of preparation paste.
[embodiment 2]
As hair coloring preparation composition, will be from dyestuff or the pyrogallol (trade name: RODOL PG of plant extract or source (origin), manufacturer: Jos.H.Lowenstein Sons, Inc.) 2 weight %, cysteine 2 weight %, as antioxidant, sodium ascorbate 0.5 weight %, as swelling agent, carbamide 5 weight %, as buffer agent, salicylic acid 1 weight % and sodium salicylate 2 weight % mix with purified water 61.5 weight % and are warmed to 75～85 ℃ and dissolve, will be as aliphatic alcohol, and cetyl alcohol 8 weight %, as surfactant, polyoxyethylene spermaceti stearyl ether 15 weight % are warmed to 75～85 ℃ and dissolve.Described dissolved substances is cooled to 50～55 ℃ after mixing, after adding ammonium bicarbonate 3 weight % as the pH regulator agent here, stirs and metal-plant mixing hair coloring preparation composition of preparation paste.
[comparative example]
Implement as described embodiment 1, but do not use cysteine, use 63.5 weight % purified water.Metal in described embodiment 1,2 and the comparative example-content of plant mixing hair coloring preparation composition is summarized in down and shows table 1.
［ table 1 ］
[preparation example: mordant preparation of compositions]
As the mordant compositions, will be as slaine, ferrous sulfate 3 weight %, as the pH regulator agent, ascorbic acid 1 weight % mixes with purified water 90 weight % and is warmed to 75～85 ℃ and dissolve, will be as aliphatic alcohol, and stearyl alcohol 5 weight %, as surfactant, polyoxyethylene spermaceti stearyl ether 2 weight % are warmed to 75～85 ℃ and dissolve.Described dissolved substances mixed and prepare the mordant compositions of paste.
[experimental example 1]
Be the hair dyeing power of test to the dyeing of hair, with the standard white hair weight 1.0g length 8.0cm that respectively asks for, be coated in described embodiment 1,2 and comparative example in place 20 minutes after the hair coloring preparation composition for preparing after, be coated in the mordant compositions for preparing in the described preparation example thereon again and place and utilize shampoo in flowing water, wash dry and observation hair dyeing power after 2 minutes after 20 minutes.Its result is taken a picture and be shown in Fig. 1.Hair dyeing power test evaluation is to utilize tintometer (model name; Spectrophotometer CM-508C, manufacturer; MINOLTA CO.LTD., JAPAN) measure the brightness value (L*) of sample separately as reference value with the standard white hair.With shown in the numerical value, the more big color of L* value is more bright with brightness for the L* value.Hair dyeing power test evaluation the results are shown in down and shows table 3.Shown in Fig. 1 and table 3, embodiment 1,2 compares comparative example can confirm more deep dyed color.
[experimental example 2]
As described experimental example 1 experiment, but after applying hair coloring preparation composition and mordant compositions, placed 10 minutes.Its result is taken a picture and be shown in Fig. 2, have hair dyed the power test evaluation and be shown in down in the mode identical with experimental example 1 and show table 3.Shown in Fig. 2 and table 3, embodiment 1,2 compares with comparative example can confirm more deep dyed color.
[experimental example 3]
As described experimental example 1 experiment, but after applying hair coloring preparation composition and mordant compositions, placed 5 minutes.Its result is taken a picture and be shown in Fig. 3, have hair dyed the power test evaluation and be shown in down in the mode identical with experimental example 1 and show table 3.Shown in Fig. 3 and table 3, embodiment 1,2 compares with comparative example can confirm more deep dyed color.
［ table 2 ］
| ? | Hair dye standing time | Mordant standing time | Total standing time |
| Experimental example 1 | 20 minutes | 20 minutes | 40 minutes |
| Experimental example 2 | 10 minutes | 10 minutes | 20 minutes |
| Experimental example 3 | 5 minutes | 5 minutes | 10 minutes |
［ table 3 ］
| ? | Standard white hair (L*) | Embodiment 1 (L*) | Embodiment 2 (L*) | Comparative example (L*) |
| Experimental example 1 | 95.48 | 15.81 | 17.87 | 27.57 |
| Experimental example 2 | 95.48 | 16.62 | 24.44 | 38.02 |
| Experimental example 3 | 95.48 | 22.64 | 37.92 | 53.20 |
[experimental example 4: dyeing firmness experiment]
With the standard white hair weight 1.0g length 8.0cm that respectively asks for, be coated in described embodiment 1,2 and comparative example in place 10 minutes after the hair coloring preparation composition for preparing after, be coated in the mordant compositions for preparing in the described preparation example thereon again and place and utilize shampoo in flowing water, wash drying after 2 minutes after 10 minutes.As a comparison, apply place 20 minutes after the hair coloring preparation composition of embodiment 3 after, repaste covers the mordant compositions and places and utilize after 20 minutes shampoo dry and prepare sample after 2 minutes with the flowing water washing thereon.
The influence that the dyeing firmness is brought for the cysteine confirming to point out among the present invention and hydrochlorate thereof, the hair sample of described dyeing is exposed to observed result after the sunlight 7 days at 4 in 10 institutes afternoon in the morning from, the brightness value of its result and Fig. 4 mensuration is measured in the mode identical with described experimental example 1 and is shown in down and shows table 4.
As can Fig. 4 and table 4 confirm, at embodiment 1, in 2 the situation, with the experimental example 2 no big variations before the conduct washing, but anti-therewith, in the situation of comparative example, be not only embodiment 1,2, even wash preceding experimental example 2 relatively with conduct, big-difference is also arranged, can confirm that dyeing firmness of the present invention is outstanding.
［ table 4 ］
| ? | Standard white hair (L*) | Embodiment 1 (L*) | Embodiment 2 (L*) | Comparative example (L*) |
| Just after the dyeing | 95.48 | 16.08 | 23.55 | 29.85 |
| Wash after 7 days | 95.48 | 34.76 | 47.80 | 73.04 |
Claims (19)
1. metal-plant mixes 1 dose of compositions of hair dye, and it comprises:
Comprise from Lignum Sappan, Cortex Phellodendri, Rhizoma Coptidis, Radix Arnebiae (Radix Lithospermi), carmine, Flos Carthami, Rhizoma Curcumae Longae, indigo, persimmon, chesnut, the pyrogallol that robur or Fructus Gardeniae are extracted or originate, gallic acid, hematoxylin, hematein, the dyestuff of tannic acid or these ester; And
The hydrochlorate of cysteine or cysteine.
2. the metal of claim 1-plant mixes 1 dose of compositions of hair dye, wherein comprises the hydrochlorate of the described cysteine of 0.02～20.0 weight % or cysteine.
3. the metal of claim 1-plant mixes 1 dose of compositions of hair dye, and it comprises, and 0.01～10.0 weight % is described to comprise from Lignum Sappan Cortex Phellodendri, Rhizoma Coptidis, Radix Arnebiae (Radix Lithospermi), carmine, Flos Carthami, Rhizoma Curcumae Longae, indigo, persimmon, chesnut, the pyrogallol that robur or Fructus Gardeniae are extracted or originate, gallic acid, hematoxylin, hematein, the dyestuff of tannic acid or these ester.
4. the metal of claim 1-plant mixes 1 dose of compositions of hair dye, and it also comprises antioxidant, fatty acid or aliphatic alcohol, swelling agent, buffer agent, surfactant, pH regulator agent or water.
5. the metal of claim 4-plant mixes 1 dose of compositions of hair dye, is that benchmark also comprises with all weight of 1 dose of compositions of described hair dye:
Antioxidant 0.1～5 weight %,
Fatty acid or aliphatic alcohol 1～10 weight %,
Swelling agent 1～10 weight %,
Buffer agent 0.1～15 weight %,
Surfactant 1～20 weight %,
PH regulator agent 0.1～6 weight %, or
Water 25～95 weight %.
6. the metal of claim 4-plant mixes 1 dose of compositions of hair dye, and wherein said antioxidant is sodium sulfite, sodium ascorbate or ascorbic acid.
7. the metal of claim 4-plant mixes 1 dose of compositions of hair dye, and wherein said fatty acid or aliphatic alcohol are oleic acid, cetyl alcohol, stearyl alcohol or mountain Yu base alcohol.
8. the metal of claim 4-plant mixes 1 dose of compositions of hair dye, and wherein said swelling agent is carbamide, thio urea, carbamide peroxide, polyoxyethylene methylene carbamide, hydroxyethyl urea, ammonia or these salt.
9. the metal of claim 4-plant mixes 1 dose of compositions of hair dye, and wherein said buffer agent is salicylic acid, sodium salicylate, lactic acid or sodium lactate.
10. the metal of claim 4-plant mixes 1 dose of compositions of hair dye, and wherein said surfactant is alkyl trimethylammonium chloride, polyoxyethylene lauryl ether sodium sulfate, polyoxyethylene cetyl base ether, polyoxyethylene spermaceti stearyl ether or polyoxyethylene oleyl ether.
11. the metal of claim 4-plant mixes 1 dose of compositions of hair dye, wherein said pH regulator agent is ammonia, ammonium bicarbonate, monoethanolamine or triethanolamine.
12. hair dye, it comprises:
The metal of each of claim 1～11-plant mixes 1 dose of compositions of hair dye and comprises the metal of slaine-2 doses of compositionss of plant mixing mordant.
13. the hair dye of claim 12, wherein said metal-plant mixes 2 doses of compositionss of mordant and comprises slaine, fatty acid or aliphatic alcohol, surfactant, pH regulator agent and water.
14. the hair dye of claim 13, wherein said metal-plant mixes 2 doses of compositionss of mordant and comprises:
Slaine 0.1～20.0 weight %,
Fatty acid or aliphatic alcohol 1.0～20.0 weight %,
Surfactant 1.0～20.0 weight %,
PH regulator agent 0.1～10.0 weight %, and
Water 25.0～97.8 weight %.
15. the hair dye of claim 13, wherein said slaine are to be selected from ferrous sulfate, iron sulfate, and hydrochloric acid is ferrous, more than a kind of hydrochloric acid ferrum and these hydrate.
16. hair colouring methods, it comprises the following steps:
Each metal-plant of claim 1～11 is mixed 1 dose of compositions of hair dye be coated on hair and placed 3～20 minutes, afterwards
Coating comprises metal-plant mixing 2 doses of compositionss of mordant of slaine and placed 3～20 minutes.
17. the hair colouring methods of claim 16, it comprises the following steps:
Described metal-plant is mixed 1 dose of compositions of hair dye be coated on hair and placed 5～10 minutes, afterwards
Coating comprises metal-plant mixing 2 doses of compositionss of mordant of slaine and placed 5～10 minutes.
18. the hair colouring methods of claim 16, wherein said metal-plant mixes 2 doses of compositionss of mordant and comprises: slaine, fatty acid or aliphatic alcohol, surfactant, pH regulator agent and water.
19. the hair colouring methods of claim 16, wherein said metal-plant mixes 2 doses of compositionss of mordant and comprises:
Slaine 0.1～20.0 weight %,
Fatty acid or aliphatic alcohol 1.0～20.0 weight %,
Surfactant 1.0～20.0 weight %,
PH regulator agent 0.1～10.0 weight %, and
Water 25.0～97.8 weight %.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2010-0134945 | 2010-12-24 | ||
| KR1020100134945A KR101076913B1 (en) | 2010-12-24 | 2010-12-24 | Hair coloring composition comprising amino acid and hair coloring method using the same |
| PCT/KR2011/006400 WO2012086898A1 (en) | 2010-12-24 | 2011-08-30 | Mixed metal-plant-based hair dye composition including cysteine, and method for dyeing hair using same |
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| CN103237540A true CN103237540A (en) | 2013-08-07 |
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| CN201180057466XA Pending CN103237540A (en) | 2010-12-24 | 2011-08-30 | Mixed metal-plant-based hair dye composition including cysteine, and method for dyeing hair using same |
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| Country | Link |
|---|---|
| JP (1) | JP2014500309A (en) |
| KR (1) | KR101076913B1 (en) |
| CN (1) | CN103237540A (en) |
| WO (1) | WO2012086898A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103479549A (en) * | 2013-09-17 | 2014-01-01 | 常州大学 | Chestnut shell hair colorant and method for coloring hair |
| CN103497535A (en) * | 2013-10-10 | 2014-01-08 | 西南科技大学 | Animal melanin extraction method and application of extraction product thereof |
| CN104970989A (en) * | 2015-07-21 | 2015-10-14 | 青岛慧生惠众生物科技有限公司 | Natural hair dye composition |
| CN106265333A (en) * | 2016-09-11 | 2017-01-04 | 桂林理工大学 | A kind of Chinese medicament hair dye and preparation and application thereof |
| CN108158940A (en) * | 2018-02-23 | 2018-06-15 | 广州市骄子日化有限公司 | A kind of natural botanical hair dye and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP6468699B2 (en) * | 2013-11-08 | 2019-02-13 | ホーユー株式会社 | Two-component hair dye |
| JP2016160260A (en) * | 2015-02-26 | 2016-09-05 | 株式会社ピカソ美化学研究所 | Hair dye composition |
| KR102169115B1 (en) | 2019-02-22 | 2020-10-22 | 주식회사 엘지생활건강 | Composition Comprising Phosphoserine for Inhibiting Color Loss of Dyed Hair |
| US11298308B1 (en) * | 2021-05-13 | 2022-04-12 | Elc Management Llc | Hair bleaching compositions and methods of use |
| CN114541154B (en) * | 2022-02-24 | 2024-04-30 | 常州大学 | Method for regulating and controlling color of plant dye dyed fabric by using ligand |
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| JP4605947B2 (en) * | 2001-07-10 | 2011-01-05 | ホーユー株式会社 | Hair dye |
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| US8313537B2 (en) * | 2009-02-20 | 2012-11-20 | Natural Medicine Institute Of Zhejiang Yangshengtang Co. Ltd. | Mordant and hair coloring products containing the same |
| KR100998694B1 (en) * | 2010-02-09 | 2010-12-07 | 이승인 | Dye composition for hair coating and dying |
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- 2010-12-24 KR KR1020100134945A patent/KR101076913B1/en active IP Right Grant
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- 2011-08-30 WO PCT/KR2011/006400 patent/WO2012086898A1/en active Application Filing
- 2011-08-30 CN CN201180057466XA patent/CN103237540A/en active Pending
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Patent Citations (1)
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| CN101879135A (en) * | 2009-11-12 | 2010-11-10 | 北京世纪博康医药科技有限公司 | Curcuma plant hair dye |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103479549A (en) * | 2013-09-17 | 2014-01-01 | 常州大学 | Chestnut shell hair colorant and method for coloring hair |
| CN103479549B (en) * | 2013-09-17 | 2016-04-06 | 常州大学 | Chestnut shell hair colorant and hair colouring methods thereof |
| CN103497535A (en) * | 2013-10-10 | 2014-01-08 | 西南科技大学 | Animal melanin extraction method and application of extraction product thereof |
| CN103497535B (en) * | 2013-10-10 | 2016-03-30 | 西南科技大学 | A kind of extracting method of Animal melanin and the application of extraction product thereof |
| CN104970989A (en) * | 2015-07-21 | 2015-10-14 | 青岛慧生惠众生物科技有限公司 | Natural hair dye composition |
| CN106265333A (en) * | 2016-09-11 | 2017-01-04 | 桂林理工大学 | A kind of Chinese medicament hair dye and preparation and application thereof |
| CN108158940A (en) * | 2018-02-23 | 2018-06-15 | 广州市骄子日化有限公司 | A kind of natural botanical hair dye and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2014500309A (en) | 2014-01-09 |
| KR101076913B1 (en) | 2011-10-25 |
| WO2012086898A1 (en) | 2012-06-28 |
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