CN101812246B

CN101812246B - Mordant and hair dyeing product containing same

Info

Publication number: CN101812246B
Application number: CN201010108036.3A
Authority: CN
Inventors: 薛莲; 胡柳; 蓝红英; 黄志明; 刘玉兰; 廖玉华
Original assignee: Zhejiang Yangshengtang Institute of Natural Medication Co Ltd
Current assignee: Zhejiang Yangshengtang Institute of Natural Medication Co Ltd
Priority date: 2009-02-20
Filing date: 2010-01-28
Publication date: 2014-10-01
Anticipated expiration: 2030-01-28
Also published as: CN101812246A

Abstract

The invention relates to a mordant for a hair dyeing product and the hair dyeing product containing the same. The mordant comprises effective amounts of ferrite, antioxygen and water; and the hair dyeing product of the invention comprises three parts, i.e. softener, dye solvent and mordant. The mordant and the hair dyeing product containing the same, provided by the invention, do not contain mercaptoacetic acid, aromatic amine compounds, such as p-phenylenediamine and the like as well as hydrogen peroxide, so that the mordant and the hair dyeing product containing the same are safe and have no stimulation. The hair dyeing product of the invention has favorable hair dyeing chroma, firmness, product stability and using convenience.

Description

Mordant and the hair dyeing product that comprises it

Technical field

The invention belongs to cosmetic industry technical field, be specifically related to a kind of mordant for hair dyeing product, the invention still further relates to the hair dyeing product that comprises described mordant, particularly comprise the natural darkener of the non-oxidative permanent of described mordant.

Background technology

The hair dyeing product overwhelming majority of selling on market at present, be using Thiovanic acid as the aromatic amine compounds such as permeate agent, Ursol D as dyestuff and hydrogen peroxide the oxidized form hair dyeing product as oxygenant.Large quantity research and report proof, the components such as Thiovanic acid, oxidation and hydrogen peroxide all have certain toxicity and sensitization.Therefore, develop the concern that safe hair dyeing product has more and more caused people.On market, there are in recent years many natural hair dyeing products, but there are respectively following two problems in this series products, the one, in some what is called " pure natural " or " organic's " hair dyeing product, be only to have added some vegetal conceptual elements, the same harmful chemical Ursol D etc. that contains, still there is larger side effect in life-time service; The 2nd, because natural hair dye ingredient molecule is larger, be difficult for colouring and maintain color clear, so in its hair dyeing effect, product stability and ease of use, still having many not as people's will part.In addition, the many natural hair dyeing product of reported in literature, CN1401310A (Chinese Patent Application No. 01127328.3 for example, open day) and CN1593375A (Chinese Patent Application No. 200410009258.4, open day 2005-03-16) the natural hair dyeing product of mentioning in, according to the preparation and application of mentioning in embodiment, the hair dyeing of finding their these natural hair dyeing products particularly white hair to dye black effect poor, and the poor stability of its mordant part, cause iron concentration free in the final product forming low, affect the particularly hair dyeing effect of the interior product of shelf-lives of product, and these products all need repeatedly have one's hair wash and repeatedly smear before hair dyeing and in hair dyeing process, convenience is not good enough.Therefore, good, the good stability of exploitation safety, hair dyeing effect and easy-to-use pure natural hair dyeing product are imperative.

Summary of the invention

The natural hair dyeing product that the object of this invention is to provide a kind of non-oxidative permanent particularly dyes black product, and the inventor finds that a kind of composition with specific composition has gratifying hair dyeing effect, the present invention is based on above-mentioned discovery and is accomplished.

summary of the invention:

General introduction ground is said, the invention provides following items:

1, for the mordant of hair dyeing product, the ferrous salt that it comprises significant quantity and oxidation inhibitor.

2, the mordant of project 1, wherein said ferrous salt is selected from ferrous sulfate, iron protochloride, Iron nitrate, Ferrous Gluconate, iron lactate, Ferrous Fumarate.

3, the mordant of project 2, wherein said ferrous salt accounts for 0.5～10% (weight) of described mordant gross weight.

4, the mordant of project 1, wherein said oxidation inhibitor is selected from xitix or its salt, halfcystine or derivatives thereof and salt thereof, for example xitix, sodium ascorbate, halfcystine, cysteine hydrochloride, N-acetylcystein, reduced glutathion, for example D-Cys, Cys, DL-cysteine, N-acetylcystein and salt thereof.

5, the mordant of project 4, wherein said oxidation inhibitor accounts for 0.1～2% (weight) of described mordant gross weight.

6, the mordant of project 1 to 5 any one, it also comprises and is selected from one or more following compositions: water, short permeate agent, thickening material and sanitas.

7, a hair dyeing product, it comprises three parts of mordant of tenderizer, dying agent and project 1 to 6 any one.

8, the hair dyeing product of project 7, wherein said dying agent partly comprises the dye activity thing of significant quantity and optional water.

9, the hair dyeing product of project 8, the dye activity thing in wherein said dying agent part is selected from one or more the arbitrary combination in gallic acid and salt or ester, for example, be selected from methyl esters, ethyl ester or the propyl ester of gallic acid and gallic acid.

10, the hair dyeing product of project 9, the dye activity thing in wherein said dying agent part accounts for 0.5～15% (weight) of described dying agent part gross weight.

11, the hair dyeing product of project 8, wherein said dying agent partly also comprises and is selected from one or more following compositions: stablizer, short permeate agent and thickening material.

12, the hair dyeing product of project 7 to 11 any one, wherein said tenderizer partly comprises disulfide bond reducing agent and the basifier of significant quantity.

13, the hair dyeing product of project 12, is characterized in that:

I) disulfide bond reducing agent in described tenderizer part is selected from one or more the arbitrary combination in halfcystine or derivatives thereof and their salt, urea, thiosulphate, sulphite, hydrosulphite;

Ii) basifier in described tenderizer part is the following basifier of being selected from of one or more arbitrary combination: ornithine, arginine, Methionin, ammoniacal liquor, ethanolamines (for example monoethanolamine, diethanolamine, trolamine), alkylol amide, oxyhydroxide or carbonato composition; And/or

Iii) described tenderizer partly also comprises and is selected from one or more following compositions: water, short permeate agent and thickening material.

14, the hair dyeing product of project 7 to 13 any one, it also comprises the information material that comprises the method for using this hair dyeing product.

15, the hair dyeing product of project 14, wherein said information material at least comprises following information:

A) described tenderizer is spread upon to the step of on hair, hair being processed; With

B) in any order described mordant and dying agent are successively spread upon to the step of on hair, hair being processed.

16, the hair dyeing product of project 14, wherein said information material at least comprises at least one information in following i to iii:

I (1) spreads upon described tenderizer the step of on hair, hair being processed, and (2) spread upon the step of on hair, hair being processed after described mordant and dying agent are mixed before use again; Or

Ii (1) spreads upon the step of on hair, hair being processed after described tenderizer is mixed before use with described mordant again, and (2) spread upon described dying agent the step of on hair, hair being processed; Or

Iii (1) spreads upon the step of on hair, hair being processed after described tenderizer is mixed before use with described dying agent again, and (2) spread upon described mordant the step of on hair, hair being processed.

17, a dying agent, the dye activity thing that it comprises significant quantity, and optional be selected from one or more following compositions: water, stablizer, short permeate agent and thickening material.

18, the dying agent of project 17, wherein said dye activity thing is selected from one or more the arbitrary combination in gallic acid and salt or ester, for example, be selected from methyl esters, ethyl ester or the propyl ester of gallic acid and gallic acid.

19, the method that the hair dyeing product described in use project 7 to 16 any one is had hair dyed, it comprises

20, the method that the hair dyeing product described in use project 7 to 16 any one is had hair dyed, it also comprises the treatment step of at least one in following i to iii:

detailed Description Of The Invention:

All documents that the present invention quotes from, their full content is incorporated to herein by reference, and if when the expressed implication of these documents and the present invention are inconsistent, be as the criterion with statement of the present invention.In addition, various terms and phrase that the present invention uses have the general sense of well known to a person skilled in the art, nonetheless, the present invention still wishes at this, these terms and phrase to be described in more detail and to be explained, the term of mentioning and phrase, if any inconsistent with known implication, are as the criterion with the implication that the present invention was explained.

The natural hair dyeing product that the object of this invention is to provide a kind of non-oxidative permanent particularly dyes black product, and this natural hair dyeing product is not only safe and non-stimulating, and hair dyeing chroma and firmness are good, and product stability and ease of use all good.The inventor finds, adopts divalent iron salt can obtain stable mordant as the activeconstituents of mordant; Also find to use to be naturally present in gallic acid in tannin not only security is good as dyestuff, and can make hair reach good hair dyeing chroma and firmness with complex compound that iron ion forms in hair.For this reason, first the present invention provides a kind of mordant for hair dyeing product, and it has the advantages that to have good stability; The present invention also provides a kind of hair dyeing product that comprises above-mentioned mordant.

Gallic acid is the monomer of tannin class hydrolysable tannin, and natural being present in tannin, its structural formula is:

Molecular weight is 170.12, is used as astringent matter and hemostatic agent in medicine.The outward appearance of gallic acid is white or faint yellow needle crystal powder, owing to having the structure of a plurality of ortho positions phenolic hydroxyl group in molecule, can be used as a kind of poly-hydroxy part and iron ion generation complex reaction generation black and stablizes fine and close inner complex---gallic acid iron.According to the present invention, can also use gallic acid ester compounds, this gallic acid ester compounds is by the carboxyl of gallic acid, to be formed the compound of ester structure.

Generally, hair skin has covered the hair scale sheet consisting of multilayer angle albumen, the osmotic effect of gallic acid and metal ion is poor, in an example of the present invention, can be with acetylcysteine as disulfide bond reducing agent (sometimes also can be described as " permeate agent "), by hair stratum corneum keratic-be reduced into-SH of S-S-, make hair softening, tension recovery, hair scale sheet is opened to a certain extent, ferrous ion penetrates into lamina corticalis and the medullary substance layer of hair inside, and form iron ion by atmospheric oxidation, thereby with the dyestuff macromole that penetrates into the gallic acid complexing formation black of hair inside

Make hair be black, hair scale sheet is closed, forms permanent type hair dyeing product.

Put it briefly, first aspect present invention provides a kind of mordant for hair dyeing product, the ferrous salt that it comprises significant quantity and oxidation inhibitor.

According to the mordant described in first aspect present invention any one, wherein also comprise water.The consumption of water can be for example the sufficient quantity adding when preparation, can make the principal constituent in mordant reach expectation and/or predetermined concentration after this sufficient quantity adds.In addition, although mordant provided by the invention can not contain water, but for the convenience on using, the preferred embodiment of the invention is to provide the deployed mordant of water, can be for example the instant mordant that can directly use without any need for aftertreatment, can also be to need before use the suitably concentrated type mordant of dilution.

According to the mordant described in first aspect present invention any one, wherein said ferrous salt includes but not limited to ferrous sulfate, iron protochloride, Iron nitrate, Ferrous Gluconate, iron lactate, Ferrous Fumarate etc.In an embodiment of mordant of the present invention, wherein said ferrous salt is selected from ferrous sulfate, iron protochloride.In an embodiment of mordant of the present invention, wherein said ferrous salt is ferrous sulfate.According to mordant of the present invention, wherein said ferrous salt can be a kind of ferrous salt, can be also the arbitrary combination of multiple ferrous salt.According to the mordant described in first aspect present invention any one, wherein said ferrous salt accounts for 0.5～10% (weight) of described mordant gross weight.In an embodiment of mordant of the present invention, wherein said ferrous salt accounts for 2～8% (weight) of described mordant gross weight.

According to the mordant described in first aspect present invention any one, wherein said oxidation inhibitor comprises but is not limited to xitix or its salt, halfcystine or derivatives thereof and salt thereof, such as xitix, sodium ascorbate, halfcystine, cysteine hydrochloride, N-acetylcystein, reduced glutathion etc.In an embodiment of mordant of the present invention, wherein said oxidation inhibitor is selected from halfcystine or derivatives thereof and salt thereof.In an embodiment of mordant of the present invention, wherein said oxidation inhibitor is selected from D-Cys, Cys, DL-cysteine, N-acetylcystein and salt thereof.In an embodiment of mordant of the present invention, wherein said oxidation inhibitor is selected from cysteine hydrochloride.According to mordant of the present invention, wherein said oxidation inhibitor can be a kind of oxidation inhibitor, can be also the arbitrary combination of multiple oxidation inhibitor.According to the mordant described in first aspect present invention any one, wherein said oxidation inhibitor accounts for 0.1～2% (weight) of described mordant gross weight.In an embodiment of mordant of the present invention, wherein said oxidation inhibitor accounts for 0.2～1% (weight) of described mordant gross weight.

According to the mordant described in first aspect present invention any one, wherein also comprise short permeate agent (that is, penetration enhancer).In an embodiment of mordant of the present invention, described short permeate agent includes but not limited to chemosmosis promotor: azone and homologue thereof, organic acid and ester class thereof, organic solvent class, surfactant-based such as anion surfactant, nonionogenic tenside and amphoterics etc.; Traditional Chinese medicine permeation promotor: comprise terpene, essential oil and lactone etc.; And their arbitrary combination.In an embodiment of mordant of the present invention; described short permeate agent can be the arbitrary combination that is selected from following one or more: oleyl alcohol, dodecyl sulfate, dodecane sulfonate or other anion surfactant; nonionogenic tenside, cocoyl CAB or other amphotericses such as fatty alcohol ethers.In an embodiment of mordant of the present invention; described short permeate agent can be oleyl alcohol, dodecyl sulfate or other anion surfactant independent or that mix; the nonionogenic tensides such as fatty alcohol-ether, the composition of cocoyl CAB or other amphoterics.According to mordant of the present invention, wherein said short permeate agent can be a kind of short permeate agent, can be also the arbitrary combination of multiple short permeate agent.In an embodiment of mordant of the present invention, wherein said short permeate agent accounts for 1～10% (weight) of described mordant gross weight.In an embodiment of mordant of the present invention, wherein said short permeate agent accounts for 2～8% (weight) of described mordant gross weight.

According to the mordant described in first aspect present invention any one, wherein also comprise thickening material (that is, for regulating the viscosity modifier of fluid (such as liquid, semisolid etc.) state).In an embodiment of mordant of the present invention, described thickening material includes but not limited to one or more in the high molecular polymers such as aliphatic alcohols or Carbomer, Natvosol, HPMC.In an embodiment of mordant of the present invention, the weight percent of described thickening material in described mordant is that those skilled in the art instruct according to the present invention and are confirmable in conjunction with prior art.Preferably, in an embodiment of mordant of the present invention, described thickening material accounts for 1～10% (weight) of described mordant gross weight.In an embodiment of mordant of the present invention, wherein said thickening material accounts for 2～8% (weight) of described mordant gross weight.

According to the mordant described in first aspect present invention any one, wherein also comprise sanitas.In an embodiment of mordant of the present invention, described sanitas includes but not limited to parabens, for example Tegosept M, ethyl p-hydroxybenzoate, propylben and Tegosept B.Described sanitas can be a kind of sanitas, can be also the arbitrary combination of Determination of Preservatives, and for example Tegosept M and propylben are with the combination of arbitrary proportion.In an embodiment of mordant of the present invention, the weight percent of described sanitas in described mordant is that those skilled in the art instruct according to the present invention and are confirmable in conjunction with prior art.Preferably, in an embodiment of mordant of the present invention, described sanitas accounts for 0.1～0.8% (weight) of described mordant gross weight.In an embodiment of mordant of the present invention, wherein said sanitas accounts for 0.2～0.6% (weight) of described mordant gross weight.

According to the mordant described in first aspect present invention any one, it is emulsus, paste or gel.

Second aspect present invention provides a kind of hair dyeing product, it comprises that tenderizer (for simplicity, can be described as the first component), dying agent (for simplicity, can be described as the 3rd component) and first aspect present invention any one described in three parts of mordant (for simplicity, can be described as second component).According to the present invention, described three parts are preferably separate physically, only according to a graded, are used in hair dyeing in use and process; Therefore, say in a certain sense, hair dyeing product of the present invention can be a kind of multi-component hair dyeing product.

According to the hair dyeing product described in second aspect present invention any one, wherein said dying agent partly comprises the dye activity thing of significant quantity.According to the hair dyeing product described in second aspect present invention any one, wherein said dying agent part can also comprise water.The consumption of water can be for example the sufficient quantity adding when preparation, can make the principal constituent in dying agent part reach predetermined concentration after this sufficient quantity adds.In addition, although dying agent part provided by the invention can not contain water, but for the convenience on using, the preferred embodiment of the invention is to provide the deployed dying agent part of water, can be for example the instant dying agent part that can directly use without any need for aftertreatment, can also be to need before use the suitably concentrated type dying agent part of dilution.

In an embodiment of second aspect present invention hair dyeing product, the dye activity thing in wherein said dying agent part includes but not limited to one or more the arbitrary combination in gallic acid and salt or ester.Gallic acid ester can be for example methyl esters, ethyl ester, the propyl ester of gallic acid.In an embodiment of second aspect present invention hair dyeing product, the dye activity thing in wherein said dying agent part is gallic acid.In an embodiment of hair dyeing product of the present invention, the dye activity thing in wherein said dying agent part accounts for 0.5～15% (weight) of described dying agent part gross weight.In an embodiment of hair dyeing product of the present invention, the dye activity thing in wherein said dying agent part accounts for 1～10% (weight) of described dying agent part gross weight.

According to the hair dyeing product described in second aspect present invention any one, wherein said dying agent part also comprises for keeping the stable stablizer of described dye activity thing, and described stablizer comprises but is not limited to one or more in EDTA-sodium salt, sulphite, hydrosulphite, ascorbate salt, halfcystine and its salt or derivative.In an embodiment of hair dyeing product of the present invention, the weight percent of described stablizer in described dying agent part is that those skilled in the art instruct according to the present invention and are confirmable in conjunction with prior art.Preferably, in an embodiment of hair dyeing product of the present invention, the stablizer in described dying agent part accounts for 0.1～1.5% (weight) of described dying agent part gross weight.In an embodiment of hair dyeing product of the present invention, the stablizer in wherein said dying agent part accounts for 0.2～1% (weight) of described dying agent part gross weight.

According to the hair dyeing product described in second aspect present invention any one, wherein said dying agent part also comprises short permeate agent (that is, penetration enhancer).In an embodiment of hair dyeing product of the present invention, the short permeate agent in described dying agent part includes but not limited to chemosmosis promotor: azone and homologue thereof, organic acid and ester class thereof, organic solvent class, surfactant-based such as anion surfactant, nonionogenic tenside and amphoterics etc.; Traditional Chinese medicine permeation promotor: comprise terpene, essential oil and lactone etc.; And their arbitrary combination.In an embodiment of hair dyeing product of the present invention; short permeate agent in described dying agent part can be the arbitrary combination that is selected from following one or more: oleyl alcohol, dodecyl sulfate, dodecane sulfonate or other anion surfactant; nonionogenic tenside, cocoyl CAB or other amphotericses such as fatty alcohol ethers.In an embodiment of hair dyeing product of the present invention; short permeate agent in described dying agent part can be oleyl alcohol, dodecyl sulfate or other anion surfactant independent or that mix; the nonionogenic tensides such as fatty alcohol-ether, the composition of cocoyl CAB or other amphoterics.According to hair dyeing product of the present invention, the short permeate agent in wherein said dying agent part can be a kind of short permeate agent, can be also the arbitrary combination of multiple short permeate agent.In an embodiment of hair dyeing product of the present invention, the short permeate agent in wherein said dying agent part accounts for 2～15% (weight) of described dying agent part gross weight.In an embodiment of hair dyeing product of the present invention, wherein said short permeate agent accounts for 3～10% (weight) of described dying agent part gross weight.

According to the hair dyeing product described in second aspect present invention any one, wherein said dying agent part also comprises thickening material (that is, for regulating the viscosity modifier of fluid (such as liquid, semisolid etc.) state).In an embodiment of hair dyeing product of the present invention, the thickening material in described dying agent part includes but not limited to one or more in the high molecular polymers such as aliphatic alcohols or Carbomer, Natvosol, HPMC.In an embodiment of hair dyeing product of the present invention, the weight percent of the thickening material in described dying agent part in the dying agent part of described hair dyeing product is that those skilled in the art instruct according to the present invention and are confirmable in conjunction with prior art.Preferably, in an embodiment of hair dyeing product of the present invention, the thickening material in described dying agent part accounts for 1～10% (weight) of described dying agent part gross weight.In an embodiment of hair dyeing product of the present invention, the thickening material in wherein said dying agent part accounts for 2～8% (weight) of described dying agent part gross weight.

According to the hair dyeing product described in second aspect present invention any one, wherein said dying agent is partly emulsus, paste or gel.

According to the hair dyeing product described in second aspect present invention any one, wherein said tenderizer partly comprises disulfide bond reducing agent and the basifier of significant quantity.According to the hair dyeing product described in second aspect present invention any one, wherein said tenderizer part can also comprise water.The consumption of water can be for example the sufficient quantity adding when preparation, can make the principal constituent in tenderizer part reach predetermined concentration after this sufficient quantity adds.In addition, although tenderizer part provided by the invention can not contain water, but for the convenience on using, the preferred embodiment of the invention is to provide the deployed tenderizer part of water, can be for example the instant tenderizer part that can directly use without any need for aftertreatment, can also be to need before use the suitably concentrated type tenderizer part of dilution.

In an embodiment of second aspect present invention hair dyeing product, the disulfide bond reducing agent in wherein said tenderizer part includes but not limited to one or more the arbitrary combination in acetylcysteine or derivatives thereof and their salt, urea, thiosulphate, sulphite, hydrosulphite.In an embodiment of second aspect present invention hair dyeing product, the disulfide bond reducing agent in wherein said tenderizer part is selected from acetylcysteine or its salt, halfcystine or its hydrochloride, reduced glutathion, sulphite, hydrosulphite.In an embodiment of hair dyeing product of the present invention, the disulfide bond reducing agent in wherein said tenderizer part accounts for 2～25% (weight) of described tenderizer part gross weight.In an embodiment of hair dyeing product of the present invention, the disulfide bond reducing agent in wherein said tenderizer part accounts for 4～15% (weight) of described tenderizer part gross weight.

In an embodiment of second aspect present invention hair dyeing product, the basifier in wherein said tenderizer part is the following basifier of being selected from of one or more arbitrary combination: ornithine, arginine, Methionin, ammoniacal liquor, ethanolamines (for example monoethanolamine, diethanolamine, trolamine), alkylol amide, oxyhydroxide or carbonato composition.In an embodiment of hair dyeing product of the present invention, the basifier in wherein said tenderizer part accounts for 0.5～20% (weight) of described tenderizer part gross weight.In an embodiment of hair dyeing product of the present invention, the basifier in wherein said tenderizer part accounts for 2～18% (weight) of described tenderizer part gross weight.

According to the hair dyeing product described in second aspect present invention any one, wherein said tenderizer part also comprises short permeate agent (that is, penetration enhancer).In an embodiment of hair dyeing product of the present invention, the short permeate agent in described tenderizer part includes but not limited to chemosmosis promotor: azone and homologue thereof, organic acid and ester class thereof, organic solvent class, surfactant-based such as anion surfactant, nonionogenic tenside and amphoterics etc.; Traditional Chinese medicine permeation promotor: comprise terpene, essential oil and lactone etc.; And their arbitrary combination.In an embodiment of hair dyeing product of the present invention; short permeate agent in described tenderizer part can be the arbitrary combination that is selected from following one or more: oleyl alcohol, dodecyl sulfate, dodecane sulfonate or other anion surfactant; nonionogenic tenside, cocoyl CAB or other amphotericses such as fatty alcohol ethers.In an embodiment of hair dyeing product of the present invention; short permeate agent in described tenderizer part can be oleyl alcohol, dodecyl sulfate or other anion surfactant independent or that mix; the nonionogenic tensides such as fatty alcohol-ether, the composition of cocoyl CAB or other amphoterics.According to hair dyeing product of the present invention, the short permeate agent in wherein said tenderizer part can be a kind of short permeate agent, can be also the arbitrary combination of multiple short permeate agent.According to hair dyeing product of the present invention, the short permeate agent in wherein said tenderizer part can be used and comprise one or more the combination being selected from following ingredients: sodium lauryl sulphate, lauryl alcohol sulfuric ester sodium salt, cocoyl CAB.In an embodiment of hair dyeing product of the present invention, the short permeate agent in wherein said tenderizer part accounts for 1～10% (weight) of described tenderizer part gross weight.In an embodiment of hair dyeing product of the present invention, wherein said short permeate agent accounts for 2～8% (weight) of described tenderizer part gross weight.

According to the hair dyeing product described in second aspect present invention any one, wherein said tenderizer part also comprises thickening material (that is, for regulating the viscosity modifier of fluid (such as liquid, semisolid etc.) state).In an embodiment of hair dyeing product of the present invention, the thickening material in described tenderizer part includes but not limited to one or more in the high molecular polymers such as aliphatic alcohols or Carbomer, Natvosol.In an embodiment of hair dyeing product of the present invention, the weight percent of the thickening material in described tenderizer part in the tenderizer part of described hair dyeing product is that those skilled in the art instruct according to the present invention and are confirmable in conjunction with prior art.Preferably, in an embodiment of hair dyeing product of the present invention, the thickening material in described tenderizer part accounts for 0.1～2% (weight) of described tenderizer part gross weight.In an embodiment of hair dyeing product of the present invention, the thickening material in wherein said tenderizer part accounts for 0.2～1% (weight) of described tenderizer part gross weight.

According to the hair dyeing product described in second aspect present invention any one, wherein said tenderizer is partly emulsus, paste or gel.

According to the hair dyeing product described in second aspect present invention any one, it also comprises the information material that comprises the method for using this hair dyeing product.In one embodiment, described information material is the form that is selected from product description, working instructions, technical specification, publicity single page etc.

According to the hair dyeing product described in second aspect present invention any one, wherein said information material at least comprises following information:

According to the hair dyeing product described in second aspect present invention any one, a) item in wherein said information material keeps reasonable time after also comprising that the tenderizer described in making spreads upon on hair at suitable temperature.In one embodiment, a) item in described information material also comprise make described tenderizer spread upon on hair after at the temperature of 15～60 ℃ (preferably 20～40 ℃), the time that keeps 5～60min (preferably 20～40min, preferably 20～30min).

According to the hair dyeing product described in second aspect present invention any one, the b in wherein said information material) after item also comprises and make described mordant spread upon on hair, at suitable temperature, keep reasonable time.In one embodiment, b in described information material) item also comprise make described mordant spread upon on hair after at the temperature of 15～60 ℃ (preferably 20～40 ℃), the time that keeps 5～30min (preferably 5～25min, preferably 10～20min).

According to the hair dying product unit described in second aspect present invention any one, the b in wherein said information material) after item also comprises and make described dying agent spread upon on hair, at suitable temperature, keep reasonable time.In one embodiment, b in described information material) item also comprise make described dying agent spread upon on hair after at the temperature of 15～60 ℃ (preferably 20～40 ℃), the time that keeps 2～20min (preferably 5～15min, preferably 8～12min).

According to the hair dyeing product described in second aspect present invention any one, wherein said information material at least comprises at least one information in following i to iii:

In above information i to iii, its step (1) separately comprise make the described mixture of tenderizer, tenderizer and mordant or the mixture of tenderizer and dying agent spread upon on hair after at the temperature of 15～60 ℃ (preferably 20～40 ℃), the time that keeps 10～40min (preferably 15～35min, preferably 20～30min).

In above information i to iii, its step (2) separately comprise make mixture, dying agent or the mordant of described mordant and dying agent spread upon on hair after at the temperature of 15～60 ℃ (preferably 20～40 ℃), the time that keeps 2～30min (preferably 5～25min, preferably 10～20min).

According to the hair dyeing product described in second aspect present invention any one, in wherein said information material, also comprise following one or more information:

Described tenderizer is applied in to the step of processing on hair repeatedly equably, and the optional step that washes hair after processing finishes;

Described mordant is applied in to the step of processing on hair repeatedly equably, and the optional step that washes hair after processing finishes;

Described dying agent is applied in to the step of processing on hair repeatedly equably, and the optional step that washes hair after processing finishes;

The mixture of described tenderizer and dying agent is applied in to the step of processing on hair repeatedly equably, and the optional step that washes hair after processing finishes;

The mixture of described tenderizer and mordant is applied in to the step of processing on hair repeatedly equably, and the optional step that washes hair after processing finishes; With

The mixture of described mordant and dying agent is applied in to the step of processing on hair repeatedly equably, and the optional step that washes hair after processing finishes.

According to the hair dyeing product described in second aspect present invention, can also provide a kind of dying agent of the dying agent part based in this hair dyeing product.Therefore, third aspect present invention provides a kind of dying agent for hair dyeing product, the dye activity thing that it comprises significant quantity.Dying agent according to described in third aspect present invention any one, wherein can also comprise water.The consumption of water can be for example the sufficient quantity adding when preparation, can make the principal constituent in dying agent reach predetermined concentration after this sufficient quantity adds.In addition, although dying agent provided by the invention can not contain water, but for the convenience on using, the preferred embodiment of the invention is to provide the deployed dying agent of water, can be for example the instant dying agent that can directly use without any need for aftertreatment, can also be to need before use the suitably concentrated type dying agent of dilution.

In an embodiment of third aspect present invention dying agent, wherein said dye activity thing includes but not limited to one or more the arbitrary combination in gallic acid and salt or ester.Gallic acid ester can be for example methyl esters, ethyl ester, the propyl ester of gallic acid.In an embodiment of third aspect present invention dying agent, wherein said dye activity thing is gallic acid.In an embodiment of third aspect present invention dying agent, wherein said dye activity thing accounts for 0.5～15% (weight) of described dying agent gross weight.In an embodiment of third aspect present invention dying agent, wherein said dye activity thing accounts for 1～10% (weight) of described dying agent gross weight.

According to the dying agent described in third aspect present invention any one, wherein also comprise for keeping the stable stablizer of described dye activity thing, described stablizer comprises but is not limited to one or more in EDTA-sodium salt, sulphite, hydrosulphite, ascorbate salt, halfcystine and its salt or derivative.In an embodiment of dying agent of the present invention, the weight percent of described stablizer in described dying agent is that those skilled in the art instruct according to the present invention and are confirmable in conjunction with prior art.Preferably, in an embodiment of dying agent of the present invention, described stablizer accounts for 0.1～1.5% (weight) of described dying agent gross weight.In an embodiment of dying agent of the present invention, wherein said stablizer accounts for 0.2～1% (weight) of described dying agent gross weight.

According to the dying agent described in third aspect present invention any one, wherein also comprise short permeate agent (that is, penetration enhancer).In an embodiment of dying agent of the present invention, described short permeate agent includes but not limited to chemosmosis promotor: azone and homologue thereof, organic acid and ester class thereof, organic solvent class, surfactant-based such as anion surfactant, nonionogenic tenside and amphoterics etc.); Traditional Chinese medicine permeation promotor: comprise terpene, essential oil and lactone etc.; And their arbitrary combination.In an embodiment of dying agent of the present invention; described short permeate agent can be the arbitrary combination that is selected from following one or more: oleyl alcohol, dodecyl sulfate, dodecane sulfonate or other anion surfactant; nonionogenic tenside, cocoyl CAB or other amphotericses such as fatty alcohol ethers.In an embodiment of dying agent of the present invention; described short permeate agent can be oleyl alcohol, dodecyl sulfate or other anion surfactant independent or that mix; the nonionogenic tensides such as fatty alcohol-ether, the composition of cocoyl CAB or other amphoterics.According to dying agent of the present invention, short permeate agent wherein can be a kind of short permeate agent, can be also the arbitrary combination of multiple short permeate agent.In an embodiment of dying agent of the present invention, short permeate agent wherein accounts for 2～15% (weight) of described dying agent gross weight.In an embodiment of dying agent of the present invention, wherein said short permeate agent accounts for 3～10% (weight) of described dying agent gross weight.

According to the dying agent described in third aspect present invention any one, wherein also comprise thickening material (that is, for regulating the viscosity modifier of fluid (such as liquid, semisolid etc.) state).In an embodiment of dying agent of the present invention, described thickening material includes but not limited to one or more in the high molecular polymers such as aliphatic alcohols or Carbomer, Natvosol, HPMC.In an embodiment of dying agent of the present invention, the weight percent of described thickening material in described dying agent is that those skilled in the art instruct according to the present invention and are confirmable in conjunction with prior art.Preferably, in an embodiment of dying agent of the present invention, described thickening material accounts for 1～10% (weight) of described dying agent gross weight.In an embodiment of dying agent of the present invention, wherein said thickening material accounts for 2～8% (weight) of described dying agent gross weight.

According to the dying agent described in third aspect present invention any one, it is emulsus, paste or gel.

The method that fourth aspect present invention provides the hair dyeing product described in use second aspect present invention any one to have hair dyed, it comprises

According to the method described in fourth aspect present invention any one, wherein said a) item keeps reasonable time after also comprising that the tenderizer described in making spreads upon on hair at suitable temperature.In one embodiment, described a) item also comprise make described tenderizer spread upon on hair after at the temperature of 15～60 ℃ (preferably 20～40 ℃), keep the time of 5～60min (preferably 20～40min, preferably 20～30min).

According to the method described in fourth aspect present invention any one, wherein said b) after item also comprises and make described mordant spread upon on hair, at suitable temperature, keep reasonable time.In one embodiment, described b) item also comprise make described mordant spread upon on hair after at the temperature of 15～60 ℃ (preferably 20～40 ℃), keep the time of 5～30min (preferably 5～25min, preferably 10～20min).

According to the method described in fourth aspect present invention any one, wherein said b) after item also comprises and make described dying agent spread upon on hair, at suitable temperature, keep reasonable time.In one embodiment, described b) item also comprise make described dying agent spread upon on hair after at the temperature of 15～60 ℃ (preferably 20～40 ℃), keep the time of 2～20min (preferably 5～15min, preferably 8～12min).

According to the method described in fourth aspect present invention any one, it comprises the treatment step of following at least one:

Described mordant is applied in to the step of processing on hair repeatedly equably, and the optional step that washes hair after processing finishes; With

Described dying agent is applied in to the step of processing on hair repeatedly equably, and the optional step that washes hair after processing finishes.

The method that fifth aspect present invention provides the hair dyeing product described in use second aspect present invention any one to have hair dyed, it also comprises the treatment step of at least one in following i to iii:

According to the method described in fifth aspect present invention any one, wherein the step of at least one (1) in i to iii comprise make the described mixture of tenderizer, tenderizer and mordant or the mixture of tenderizer and dying agent spread upon on hair after at the temperature of 15～60 ℃ (preferably 20～40 ℃), the time that keeps 10～40min (preferably 15～35min, preferably 20～30min).

According to the method described in fifth aspect present invention any one, wherein the step of at least one (2) in i to iii comprise make mixture, dying agent or the mordant of described mordant and dying agent spread upon on hair after at the temperature of 15～60 ℃ (preferably 20～40 ℃), the time that keeps 2～30min (preferably 5～25min, preferably 10～20min).

According to the method described in fifth aspect present invention any one, it also comprises the treatment step of following at least one:

In the present invention, each term used has its general implication in the art.And especially, except as otherwise noted, the present invention hereinafter described term has with undefined implication.

As used herein, term " is sent out ", " hair ", " hair " etc. generally refer to the hair that all can refer to animal (for example Mammals is as pet and people people particularly).Particularly can refer to the hair of described animal head, more especially can refer to the hair of people's head.

As used herein, term " hair dyeing product " generally refers to a kind of for example, for giving animal (Mammals be'ss as pet and people people particularly) chromotrichial product.For the present invention, because dyestuff (gallic acid iron) is black, therefore " hair dyeing product " also can be described as " dying black product " in the present invention.

As used herein, phrase " successively spreads upon by described mordant and dying agent the step of on hair, hair being processed in any order " and refers to when using mordant and dying agent to process hair, and the precedence of the two processing hair of mordant and dying agent is arbitrarily.

As used herein, term " mordant " generally refers to and dyestuff can be reached to dyeing object composition used by for example dying in certain vehicle, in article to be dyed (fabric and hair).For the present invention, because the iron ion that forms pigment with the complexing of dye molecule gallic acid is to be formed by atmospheric oxidation by ferrous ion, therefore can at interior composition, be called " mordant " by comprising ferrous ion in the present invention.For simplicity, described mordant also can be described as second component, usings and is different from as the first component of tenderizer with as the 3rd component of dying agent.In addition, above-mentioned the first component, second component and the 3rd component are only used to for difference mutually between three parts, before and after there is no between them, successively, the relation such as size, how many, significance level, but three parts that are called the first component, second component and the 3rd component can in to the operating process of coloring hairs, produce respectively soften, the effect of mordant dyeing and dyestuff.In addition, the hair dyeing product providing according to second aspect present invention, it is before the final users such as production, storage, transportation, sale use, three parts of above-mentioned the first component, second component and the 3rd component are mutually to isolate physically, three can be when final use, according to the method for fourth aspect present invention or the 5th aspect, mix, and then use.Generally speaking, the spirit according to the present invention, the hair dyeing product that second aspect present invention provides can adopt two class modes to use, and the first kind is that three parts of above-mentioned the first component, second component and the 3rd component are processed hair respectively according to a graded; Equations of The Second Kind be by three parts of above-mentioned the first component, second component and the 3rd component appoint both face with before again hair is processed after mixing, then a remaining part is processed hair.In a kind of exemplary process of using hair dyeing product of the present invention to have hair dyed, the tenderizer of hair dyeing product of the present invention, mordant, dying agent three's hair dyeing array mode at least comprises following several:

The first: the first step, described tenderizer is spread upon on hair, stop 20～30 minutes, have one's hair wash or do not have one's hair wash; Second step, spreads upon mordant on hair, stops hair washing 10～20 minutes; The 3rd step, spreads upon dying agent on hair, stops hair washing 10 minutes;

The second, the first step, spreads upon described tenderizer on hair, stops 20～30 minutes, has one's hair wash or does not have one's hair wash; Second step, spreads upon dying agent on hair, stops hair washing 10～20 minutes; The 3rd step, spreads upon mordant on hair, stops hair washing 10 minutes;

The third, the first step, spreads upon described tenderizer on hair, stops 20～30 minutes, has one's hair wash or does not have one's hair wash; Second step, by mixing according to a certain percentage before described mordant and dying agent use, then spreads upon on hair, stops hair washing 10～20 minutes;

The 4th kind, the first step, by mixing according to a certain percentage before described tenderizer and mordant use, then spreads upon on hair, stops hair washing 20～30 minutes; Second step, spreads upon described dying agent on hair, stops hair washing 10～20 minutes;

The 5th kind, the first step, by mixing according to a certain percentage before described tenderizer and dying agent use, then spreads upon on hair, stops hair washing 20～30 minutes; Second step, spreads upon described mordant on hair, stops hair washing 10～20 minutes.

In addition, in three parts of above-mentioned the first component, second component and the 3rd component by the present invention appoint both facing with before while mixing, ratio of mixture (by weight) between two kinds of components can be (0.1～10): 1, be preferably (0.2～8): 1, be preferably (0.5～5): 1, be preferably (0.8～2): 1, for example approximately 0.5: 1, approximately 0.8: 1, approximately 1: 1, approximately 1.2: 1, approximately 1.5: 1, approximately 1.8: 1, approximately 2: 1.

As used herein, term " ferrous salt " generally refers to the salt forming with ferrous ion (that is, ferrous ion), and the exemplary ferrous salt of the present invention comprises ferrous sulfate, iron protochloride, Iron nitrate.Those skilled in the art know that, the ferrous salt that described ferrous salt also can prolong and be formed through chemical conversion in position by ferrous compound, be that ferrous salt of the present invention also prolongs and described ferrous compound, for example iron protoxide can transform in position formation iron protochloride and form ferrous salt with hydrochloric acid, and this iron protoxide also can be used as ferrous salt of the present invention.

As used herein, term " significant quantity " generally refers to discussed amount of substance, the amount of ferrous salt in mordant for example, and this amount conventionally can obtain the hair dyeing effect that is satisfied in the main or expects under general application conditions.

As used herein, term " oxidation inhibitor " generally refers to for preventing the material of readily oxidizable substance oxidation.For example in mordant of the present invention, oxidation inhibitor used can prevent ferrous salt oxidation wherein.

As used herein, term " short permeate agent " generally refers to for impelling the material of other material infiltration, also can be described as penetration enhancer.For example in mordant of the present invention, short permeate agent used can be accelerated the speed that ferrous salt enters hair inside.

As used herein, term " thickening material " generally refers to for regulating the material of fluid (such as liquid, semisolid etc.) viscous state, is generally to produce the effect that increases fluid viscosity, also can be described as viscosity modifier.

Mordant of the present invention, tenderizer, three parts of dying agent can be emulsus, paste or gel respectively.According to the present invention, these three parts can be other form certainly, for example, be solution form.

As used herein, term " tenderizer " generally refers to can be by the softening composition of hair stratum corneum Keratin sulfate, in the present invention, and by comprising disulfide bond reducing agent, basifier is called " tenderizer " at the interior softening composition expanding of hair that can make.

As used herein, term " dying agent " generally refers to and can make fiber and the painted composition of other materials, in the present invention, the auxiliary that comprises dye activity thing, raising Color is called to " dying agent " at the interior chromotrichial composition that can make.

As used herein, term " dye activity thing " generally refers to the activeconstituents that can make fiber, hair and other materials painted, and it is different from as making the present invention obtain the auxiliary that better effect is used.In the present invention, dye activity thing refers to that itself is not containing the metal ion that is useful on mordant dyeing, need before dyeing or after dyeing, hair be processed and obtain metal ion through mordant, through with complexing of metal ion after by the material of coloring hairs, " dye activity thing " refers to the materials such as gallic acid and ester thereof especially in this article.

As used herein, term " stablizer " generally refers to for making the stable material of other material, for example for " stablizer " of dying agent part of the present invention can make dye activity thing wherein for example gallic acid keep physics or chemically more stable.

As used herein, term " disulfide bond reducing agent " generally refers to a kind of reductive agent, it can make the be reduced into-SH of disulfide linkage (S-S-) in hair, make hair softening, tension recovery, be conducive to actives and penetrate into hair inside, for example acetylcysteine or derivatives thereof in the present invention.The example of disulfide bond reducing agent is open in detail herein.

As used herein, particularly in tenderizer part of the present invention, use, term " basifier " is generally to instigate the goods of making to reach the material of certain acid-basicity.For example, in an embodiment of hair dyeing product of the present invention, the basifier in wherein said tenderizer part makes the pH value of described tenderizer part be less than 7; Or for example, the basifier in described tenderizer part makes the pH value of described tenderizer part be less than 8; Or for example, the basifier in described tenderizer part makes the pH value of described tenderizer part be less than 9; Or for example, the basifier in described tenderizer part makes the pH value of described tenderizer part be less than 10; Or for example, the basifier in described tenderizer part makes the pH value of described tenderizer part be less than 11.Described pH value can directly be measured with pH test paper, also can use method well known in the art, and for example pH meter assay method, measures after optionally sample being done suitably to process, and for example water suitably dilutes rear mensuration.

As used herein, term " principal constituent " generally refers to the activeconstituents for composition, for example, the mordant for hair dyeing product that first aspect present invention provides, ferrous salt is wherein exactly " principal constituent " activeconstituents that can be defined as.For " principal constituent ", other composition in composition is " ancillary component ", and for example the oxidation inhibitor in mordant of the present invention just can be called " ancillary component ".

Tenderizer part in relevant mordant of the present invention and hair dyeing product of the present invention, dying agent part, their preparation method is that those skilled in the art can easily implement with reference to relevant textbook, such as being prepared by operating process such as mixing, heating, stirring, grinding, emulsification, constant volume, packing.Also for example can be referring to < < pharmaceutics > > (pharmaceutics, Xi Nianzhu chief editor. Beijing, People's Health Publisher, 1994) in, about the method for instructing in the related Sections such as solution, emulsion, paste, prepare, the document is incorporated to herein by reference.

Mordant provided by the invention and the hair dyeing product that comprises this mordant are containing aromatic amine compounds and hydrogen peroxide such as Thiovanic acid, Ursol D, safe and non-stimulating, do not have potential carcinogenic possibility.Result of study shows, the person that is applied to white hair, and sensitization rate is 0%; After hair dyeing, hair presents nature black, and can keep 45 days left and right colour-fast.In addition, mordant of the present invention is usingd ferrous ion as mordant actives, has guaranteed stability and the interior hair dyeing effect using of shelf-lives of product.And, hair dyeing product of the present invention can add respectively the composition of hair washing and hair care in tenderizer and dying agent, in hair dyeing process, can not need repeatedly to have one's hair wash, therefore, use the hair that hair dyeing product of the present invention dyed, not only hair dyeing chroma and firmness are good, and light, and product stability naturally and ease of use are all very good.

Embodiment

Below by specific embodiment, reference examples and test example, further illustrate the present invention, but, should be understood to, these embodiment, reference examples and test example are only used for the use specifically describing more in detail, and should not be construed as for limiting in any form the present invention.

The present invention carries out generality and/or concrete description to the material and the test method that use in test.Although be well known in the art for realizing many materials and the working method that the object of the invention used, the present invention still does to describe in detail as far as possible at this.It will be apparent to those skilled in the art that hereinafter, if not specified, material therefor of the present invention and working method are well known in the art.

embodiment 1

1) tenderizer part (or be called the first component, prepare by total amount 100g):by N-acetylcystein 6g, S-WAT 1g, sodium lauryl sulphate 4g, carbomer 0.5g, hydantoin 0.2g fully mixes, and then adds the mixture [arginine: monoethanolamine=1: 1 (weight ratio)] of arginine and monoethanolamine to regulate in right amount potential of hydrogen, make product final pH=9.5 (test paper), then add the deionized water of surplus to 100g, mixing and stirring, makes gelifying agent.

2) mordant part (or be called second component, prepare by total amount 100g):by 16/stearyl alcohol 5g, cetearyl alcohol alcohol ether-6 are 5g, Tegosept M 0.25g, and propylben 0.15g, ferrous sulfate 5g, cysteine hydrochloride 0.5g fully mixes, and then adds the deionized water of surplus, and mixing and stirring, makes paste.

3) dying agent part (or be called the 3rd component, prepare by total amount 100g):by 16/stearyl alcohol 5g, cetearyl alcohol alcohol ether-6 are 5g, sodium lauryl sulphate 2g, wool grease 2g, white vaseline 2g, gallic acid 6g, S-WAT 0.2g, disodium ethylene diamine tetraacetate 0.2g, Tegosept M 0.25g, propylben 0.15g fully mixes, and then adds the deionized water of surplus, mixing and stirring, makes paste.

4) hair dyeing of topknot experiment:during use, do not need hair washing, with hair comb, tenderizer is directly applied on hair, after repeatedly smearing evenly, stop 20～30 minutes.Need not have one's hair wash, according to the using method of tenderizer, mordant evenly be spread upon on hair, stop 10～20 minutes.Then use a small amount of warm water washing hair, wipe to not dripping.According to the using method of first two doses, dying agent is evenly spread upon on hair, stop 10 minutes, use warm water washing hair, air-dry or dry up.Result shows, the topknot colourity firmness that the hair dyeing product of the present embodiment dyes is good, preparation stabilization.

Following examples 1-1,2,2-1,3,3-1,4,5 etc. have only listed the formula of tenderizer, mordant and dying agent three parts, and their compound method can reference example 1 be carried out.

embodiment 1-1

1) tenderizer part (or be called the first component, prepare by total amount 100g):n-acetylcystein 6g, S-WAT 1g, sodium lauryl sulphate 4g, carbomer 0.5g, arginine: monoethanolamine=1: 1 (weight ratio), product final pH=9.5 (test paper), and all the other are deionized water, mix and blend, makes gelifying agent.

2) mordant part (or be called second component, prepare by total amount 100g):16/stearyl alcohol 5g, cetearyl alcohol alcohol ether-6 are 5g, Tegosept M 0.25g, propylben 0.15g, ferrous sulfate 5g, cysteine hydrochloride 0.5g, all the other are deionized water, mix and blend, makes paste.

3) dying agent part (or be called the 3rd component, prepare by total amount 100g):16/stearyl alcohol 5g, cetearyl alcohol alcohol ether-6 are 5g, sodium lauryl sulphate 2g, wool grease 2g, white vaseline 2g, gallic acid 6g, S-WAT 0.2g, disodium ethylene diamine tetraacetate 0.2g, Tegosept M 0.25g, propylben 0.15g, all the other are deionized water, make paste.

embodiment 2

1) tenderizer part (or be called the first component, prepare by total amount 100g):halfcystine 1.5g, S-WAT 0.5g, sodium lauryl sulphate 4g, lauryl alcohol sulfuric ester sodium salt 6g, carbomer 0.5g, hydantoin 0.2g, arginine: monoethanolamine=1: 1 (weight ratio), its consumption is the pH=10.5 (test paper) that makes product final, and all the other are deionized water.

2) mordant part (or be called second component, prepare by total amount 100g):16/stearyl alcohol 1g, cetearyl alcohol alcohol ether-6 are 10g, iron protochloride 10g, acetylcysteine 2g, Tegosept M 0.25g, propylben 0.15g, all the other are deionized water.

3) dying agent part (or be called the 3rd component, prepare by total amount 100g):16/stearyl alcohol 5g, cetearyl alcohol alcohol ether-6 are 5g, sodium lauryl sulphate 2g, wool grease 2g, white vaseline 2g, Tenox PG 15g, S-WAT 1g, disodium ethylene diamine tetraacetate 0.5g, Tegosept M 0.25g, propylben 0.15g, all the other are deionized water.

4) hair dyeing of topknot experiment:during use, do not need hair washing, with hair comb, tenderizer is directly applied on hair, after repeatedly smearing evenly, stop 20～30 minutes.Need not have one's hair wash, according to the using method of tenderizer, dying agent evenly be spread upon on hair, stop 10～20 minutes.Then use a small amount of warm water washing hair, wipe to not dripping.According to the using method of first two doses, mordant is evenly spread upon on hair, stop 10 minutes, use warm water washing hair, air-dry or dry up.

Result shows, the topknot colourity firmness that the hair dyeing product of the present embodiment dyes is good, preparation stabilization.

embodiment 2-1

1) tenderizer part (or be called the first component, prepare by total amount 100g):halfcystine 1.5g, S-WAT 0.5g, sodium lauryl sulphate 4g, lauryl alcohol sulfuric ester sodium salt 6g, carbomer 0.5g, arginine: monoethanolamine=1: 1 (weight ratio), its consumption is the pH=10.5 (test paper) that makes product final, and all the other are deionized water.

embodiment 3

1) tenderizer part (or be called the first component, prepare by total amount 100g):n-acetylcystein 24g; S-WAT 1g; sodium lauryl sulphate 2g; cocoyl CAB 2g; carbomer 0.5g, hydantoin 0.2g, arginine: monoethanolamine=1: 1 (weight ratio); its consumption is the pH=8.5 (test paper) that makes product final, and all the other are deionized water.

2) mordant part (or be called second component, prepare by total amount 100g):16/stearyl alcohol 10g, cetearyl alcohol alcohol ether-6 are 1g, Iron nitrate 0.5g, cysteine hydrochloride 0.1g, Tegosept M 0.25g, propylben 0.15g, all the other are deionized water.

3) dying agent part (or be called the 3rd component, prepare by total amount 100g):16/stearyl alcohol 5g, cetearyl alcohol alcohol ether-6 are 5g, sodium lauryl sulphate 2g, wool grease 2g, white vaseline 2g, Tegosept M 0.25g, propylben 0.15g, gallic acid 0.5g, S-WAT 0.05g, disodium ethylene diamine tetraacetate 0.05g, all the other are deionized water.

4) hair dyeing of topknot experiment:during use, do not need hair washing, with hair comb, tenderizer is directly applied on hair, after repeatedly smearing evenly, stop 20～30 minutes.After hair washing, mordant and dying agent are mixed in the ratio of 1: 1, according to the using method of tenderizer, it is evenly spread upon on hair, stop 10～20 minutes, use warm water washing hair, air-dry or dry up.

embodiment 3-1

1) tenderizer part (or be called the first component, prepare by total amount 100g):n-acetylcystein 24g, S-WAT 1g, sodium lauryl sulphate 2g; cocoyl CAB 2g, Natvosol 0.5g, arginine: monoethanolamine=1: 1 (weight ratio); its consumption is the pH=8.5 (test paper) that makes product final, and all the other are deionized water.Print

embodiment 4

1) tenderizer part (or be called the first component, prepare by total amount 100g):n-acetylcystein 24g, S-WAT 1g, sodium lauryl sulphate 1g, xanthan gum (that is xanthan gum) 2g, arginine: monoethanolamine=1: 1 (weight ratio), its consumption is the pH=9.5 (test paper) that makes product final, all the other are deionized water.

2) mordant part (or be called second component, prepare by total amount 100g):16/stearyl alcohol 10g, cetearyl alcohol alcohol ether-6 are 5g, Ferrous Gluconate 5g, cysteine hydrochloride 0.8g, Tegosept M 0.25g, propylben 0.15g, all the other are deionized water.

3) dying agent part (or be called the 3rd component, prepare by total amount 100g):16/stearyl alcohol 5g, cetearyl alcohol alcohol ether-6 are 1g, sodium lauryl sulphate 2g, wool grease 2g, white vaseline 2g, Tegosept M 0.25g, propylben 0.15g, Tenox PG 0.5g, S-WAT 0.05g, disodium ethylene diamine tetraacetate 0.05g, all the other are deionized water.

4) hair dyeing of topknot experiment:during use, do not need hair washing, use the front ratio in 1: 1 to mix tenderizer and mordant, with hair comb, it is directly applied on hair, after repeatedly smearing evenly, stop 20～30 minutes.Hair washing, evenly spreads upon dying agent on hair with hair comb, stops 10～20 minutes, uses warm water washing hair, air-dry or dry up.

embodiment 5

1) tenderizer part (or be called the first component, prepare by total amount 100g):n-acetylcystein 24g, S-WAT 1g, cocoyl CAB 1g; HPMC 0.1g; arginine: monoethanolamine=1: 1 (weight ratio), its consumption is the pH=10.5 (test paper) that makes product final, all the other are deionized water.

2) mordant part (or be called second component, prepare by total amount 100g):16/stearyl alcohol 10g, cetearyl alcohol alcohol ether-6 are 3g, iron lactate 0.5g, cysteine hydrochloride 0.1g, Tegosept M 0.25g, propylben 0.15g, all the other are deionized water.

3) dying agent part (or be called the 3rd component, prepare by total amount 100g):16/stearyl alcohol 5g, cetearyl alcohol alcohol ether-6 are 3g, sodium lauryl sulphate 2g, wool grease 2g, white vaseline 2g, Tegosept M 0.25g, propylben 0.15g, methyl gallate 0.5g, S-WAT 0.05g, disodium ethylene diamine tetraacetate 0.05g, all the other are deionized water.

4) hair dyeing of topknot experiment: during use,do not need hair washing, use the front ratio in 1: 1 to mix tenderizer and dying agent, with hair comb, it is directly applied on hair, after repeatedly smearing evenly, stop 20～30 minutes.Hair washing, evenly spreads upon coal stain on hair with hair comb, stops 10～20 minutes, uses warm water washing hair, air-dry or dry up.

reference examples 1, with reference to the method preparation hair dyeing product in CN1593375A

1) tenderizer part (by total amount 100g preparation):n-acetylcystein 2.0g, S-WAT 0.5g, Xylo-Mucine 2.0g, disodium ethylene diamine tetraacetate 0.1g, monoethanolamine 10.0g, 85.4g deionized water, is stirred to and dissolves completely.

2) dying agent part (by total amount 100g preparation):gardenia Yellow 2.0g, Xylo-Mucine 5.0g, sodium lauryl sulphate 1.0g, 92g deionized water, is stirred to and dissolves completely.

3) mordant part (by total amount 100g preparation):iron(ic) chloride 3g, xanthan gum 3g, deionized water 94g, is stirred to and dissolves completely, obtains mordant.

4) hair dyeing of topknot experiment:hair is cleaned, dry the moisture on hair, treatment agent is evenly spread upon on hair, be heated to 35～45 degree, keep 15～25 minutes, again dying agent is evenly applied on hair, is heated to 35～45 degree, keep 5～10 minutes, finally mordant is applied on hair, be heated to 35～45 degree, keep 4～8 minutes, with warm water cleaning.

method preparation hair dyeing product in reference examples 2, ginseng person CN1401310A

1) tenderizer part (by total amount 100g preparation):dL-cysteine hydrochloride 10g, thanomin 4g, fatty alcohol 2g, white mineral oil 3g, fatty alcohol-polyoxyethylene ether 1g, Tween-60 3g, alkyl sulfuric ester salt 1g, glyceryl monostearate 3g, sorbitan monostearate 3g, Purified Water 70g, mix and blend.

2) mordant part (by total amount 100g preparation):ferric sulfate 5g, carboxymethyl cellulose 4g, Purified Water 91g, is stirred to and dissolves completely.

3) dying agent part (by total amount 100g preparation):gallic acid 6g, thanomin 4g, white mineral oil 3g, fatty alcohol-polyoxyethylene ether 1g, Tween-60 2g, glyceryl monostearate 3g, sorbitan monostearate 3g, Purified Water 76g, mix and blend.

4) hair dyeing of topknot experiment:the moistening hair of water, dries the moisture on hair, with hair comb, tenderizer is directly applied on hair, after repeatedly smearing evenly, stops 20～30 minutes.Need not have one's hair wash, according to the using method of tenderizer, mordant evenly be spread upon on hair, stop 15～30 minutes.Then use a small amount of warm water washing hair, wipe to not dripping.According to the using method of first two doses, dying agent is evenly spread upon on hair, stop 10～20 minutes, use warm water washing hair, air-dry or dry up.

the colourity of test example 1, topknot and firmness experiment and preparation stability test

1) test method:

topknot colourity:dye rear hair and detect through chromascope, visual inspection simultaneously.

topknot firmness:dye back and provide to be placed under daylight and irradiate, investigate its firmness of resistance to daylight; Dye the commercially available shampoo washing of rear Hair grooming, investigate its wash resistant firmness.

preparation stability:by specimen storage in the baking oven of 45 ℃ two weeks, take out in the refrigerator that is stored in again-10 ℃ observation sample state the test of having hair dyed after two weeks.

2) test-results:

According to the using method of embodiment 1, reference examples 1, reference examples 2, have hair dyed respectively and investigate the stability of three preparations:

The topknot hair dyeing result of embodiment 1 hair dyeing product is: chromascope measurement result is black, and visual inspection is black; Firmness experimental result shows, irradiates 45 days under daylight, colour-fast through 45 washings.Tenderizer, mordant and dying agent three parts are all carried out stability experiment, and its outward appearance is investigated front and back without considerable change at stability experiment; And hair dyeing result self-consistentency.

The topknot hair dyeing result of reference examples 1 hair dyeing product is: chromascope measurement result is non-black, partially yellow, and visual inspection is yellow; Firmness experimental result shows, irradiates and fade for 10 days under daylight, through 5 washings, fades.Tenderizer, mordant and dying agent three parts are all carried out stability experiment, and tenderizer and dying agent outward appearance are without considerable change before and after stability experiment is investigated, and mordant part is actives because using ferric iron, in this agent, there is precipitation to produce, As time goes on, it is many that precipitation becomes, and darkens; Hair dyeing result is light yellow.

The topknot hair dyeing result of reference examples 2 hair dyeing products is: chromascope measurement result is non-black, partially blue look, and visual inspection is lilac; Firmness experimental result shows, irradiates and fade for 10 days under daylight, through 10 washings, fades.Tenderizer, mordant and dying agent three parts are all carried out stability experiment, and tenderizer and dying agent outward appearance are without considerable change before and after stability experiment is investigated, and mordant part is actives because using ferric iron, in this agent, there is precipitation to produce, As time goes on, it is many that precipitation becomes, and darkens; Hair dyeing result is more shallow purple.

In addition, by the hair dyeing product of the embodiment of the present invention 1 person that is applied to white hair, result shows, after hair dyeing, hair presents nature black, and can keep 45 days left and right colour-fast, and sensitization rate is 0%.

The inventor also finds, sample prepared by other embodiment of the present invention is tested according to the method for above test example 1, obtained equally gratifying, and the similar result of embodiment 1 sample.

Claims

1. the mordant for hair dyeing product, the ferrous salt that it comprises significant quantity and oxidation inhibitor, wherein said oxidation inhibitor is selected from halfcystine, cysteine hydrochloride, N-acetylcystein, reduced glutathion and salt thereof, wherein said ferrous salt is selected from ferrous sulfate, iron protochloride, Iron nitrate, Ferrous Gluconate, iron lactate, Ferrous Fumarate, and wherein said oxidation inhibitor accounts for 0.1～2% (weight) of described mordant gross weight.

2. the mordant of claim 1, wherein said ferrous salt accounts for 0.5～10% (weight) of described mordant gross weight.

3. the mordant of claim 1, wherein said oxidation inhibitor is selected from D-Cys, Cys, DL-cysteine, N-acetylcystein and salt thereof.

4. the mordant of claims 1 to 3 any one, it also comprises and is selected from one or more following compositions: water, short permeate agent, thickening material and sanitas.

5. a hair dyeing product, it comprises three parts of coal stain of tenderizer, dying agent and claim 1 to 4 any one, wherein said dying agent partly comprises the dye activity thing of significant quantity and optional water, and the dye activity thing in wherein said dying agent part is selected from one or more the arbitrary combination in gallic acid and salt or ester.

6. the hair dyeing product of claim 5, the dye activity thing in wherein said dying agent part is selected from methyl esters, ethyl ester or the propyl ester of gallic acid and gallic acid.

7. the hair dyeing product of claim 5, the dye activity thing in wherein said dying agent part accounts for 0.5～15% (weight) of described dying agent part gross weight.

8. the hair dyeing product of claim 5, wherein said dying agent part also comprises and is selected from one or more following compositions: stablizer, short permeate agent and thickening material.

9. the hair dyeing product of claim 5, wherein said tenderizer partly comprises disulfide bond reducing agent and the basifier of significant quantity.

10. the hair dyeing product of claim 9, is characterized in that:

I) disulfide bond reducing agent in described tenderizer part is selected from one or more the arbitrary combination in halfcystine or derivatives thereof and their salt, acetylcysteine or derivatives thereof and their salt, sulphite, hydrosulphite;

Ii) basifier in described tenderizer part is the following basifier of being selected from of one or more arbitrary combination: ornithine, arginine, Methionin, ammoniacal liquor, ethanolamines, alkylol amide or carbonato composition; And/or

The hair dyeing product of 11. claims 10, wherein said ethanolamines basifier is selected from monoethanolamine, diethanolamine, trolamine.

The hair dyeing product of 12. claim 5 to 11 any one, it also comprises the information material that comprises the method for using this hair dyeing product.

The hair dyeing product of 13. claims 12, wherein said information material at least comprises following information:

The hair dyeing product of 14. claims 12, wherein said information material at least comprises at least one information in following i to iii:

The method that 15. rights to use require the hair dyeing product described in 5 to 14 any one to have hair dyed, it comprises

The method that 16. rights to use require the hair dyeing product described in 5 to 14 any one to have hair dyed, it also comprises the treatment step of at least one in following i to iii: