CN105534785B - A kind of colouring compositions containing natural plant composition - Google Patents
A kind of colouring compositions containing natural plant composition Download PDFInfo
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- CN105534785B CN105534785B CN201511002575.8A CN201511002575A CN105534785B CN 105534785 B CN105534785 B CN 105534785B CN 201511002575 A CN201511002575 A CN 201511002575A CN 105534785 B CN105534785 B CN 105534785B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
Abstract
The present invention relates to a kind of colouring compositions containing natural plant composition, it includes oxidation base, coupling agent that the colouring compositions, which include in first dose and second dose, described first dose, contains oxidant in described second dose；The oxidation base includes 2,5- diaminotoluenes or its addition salts, and the coupling agent includes ethoxy -3,4- methylene dioxo group anilines or its addition salts, and described first dose further includes tea extract and Gotu Kola P.E；Colouring compositions provided by the invention select specific oxidation base and coupling agent and contain natural plant composition, so that the dyeing firmness of colouring compositions significantly improves, and colouring compositions provided by the invention are small to the stimulation of scalp, Small side effects, have larger popularizing value.
Description
Technical field
The invention belongs to cosmetic fields, and in particular to a kind of colouring compositions containing natural plant composition.
Background technology
In modern society, the man and Ms at various ages cover white hair or displaying individual character to have hair dyed.It is known usual
Colouring compositions for dyeing keratin fibres, particularly human hair contain oxidation dye precursor, that is, the oxidation being generally called
Develop the color bases, such as o-phenylenediamine, p-phenylenediamine, o-aminophenol class, p-Aminophenol class or heterocyclic compound etc., these oxidations
Colour developing bases is the compound of colourless or weak coloring can be generated as when being combined with oxidant via oxidative condensation process
Coloring compound, the tone obtained by these oxidative color-developing bases can be changed by adding coupling agent or colorant, such as can
With diaminobenzene class, meta-aminophenol class, resorcinol class or certain heterocyclic compounds such as pyridine compounds between selection fragrance.
Oxidising dyeing usually carries out in the presence of promoting the basifier of dyeing keratinous fibres, and oxidation dye is because of its particle
It is small and can enter hair cortex, however, be difficult to when their oxidation polymerizations after infiltration hair in, therefore, if oxidation dye
Just polymerize before penetrating into hair, hair dyeing effect will it is bad or dyeing hair color cannot be lasting, that is, the jail dyed
Soundness is bad.Basifier and hydrogen peroxide can stimulate scalp or skin, and can damage the albumen in hair, skin sensitive people
To in hair dye usually with oxidising dyeing bases and coupling agent have allergic reaction, can by scalp irritation, itch or inflammation
Can even scalp be caused to fester；If increasing the dosage of alkaline agent and obtaining vivider color, degree and hair damage are stimulated
Wound is consequently increased.In general, acid dyes or transient dyes are selected for the scalp irritation problem for avoiding oxidation dye from bringing,
But the firmness of the coloring of acid dyes or transient dyes, dyeing can not show a candle to permanent hairdye, and this kind of dye
Material is not fully solved the stimulation problem to scalp yet.Currently, it is good while correct not occur a dyeing firmness also in the market
The bland colouring compositions of skin；Therefore, it still needs to study a kind of, Small side effects small to scalp irritation while to dye firmness good
Colouring compositions.
Invention content
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of dyeing compositions containing natural plant composition
Object, colouring compositions provided by the invention select specific oxidation base and coupling agent and contain natural plant composition so that
The dyeing firmness of colouring compositions significantly improves, and colouring compositions provided by the invention are small to the stimulation of scalp, and pair is made
With small, there is larger popularizing value.
To achieve the above object, the present invention adopts the following technical scheme that：
A kind of colouring compositions containing natural plant composition, the colouring compositions include first dose and second dose, institute
It includes oxidation base, coupling agent to state in first dose, contains oxidant in described second dose；The oxidation base includes 2,5-
Diaminotoluene or its addition salts, the coupling agent include ethoxy -3,4- methylene dioxo group anilines or its addition salts, and described
One further includes tea extract and Gotu Kola P.E.
The dyeing firmness of colouring compositions and be to consider the primary concern of colouring compositions quality to the irritation of scalp
Factor, inventor have found after by numerous trials when selection 2,5- diaminotoluenes or its addition salts are as oxidative color-developing
Alkali, ethoxy -3,4- methylene dioxo group aniline or its addition salts as coupling agent come when being dyed, the resistance to shampoo of colouring compositions
Dyeing firmness after washing and resistance to solar radiation is preferably and smaller to the stimulation of the scalp of user, and selects it
Colouring compositions that his oxidation base and coupling agent are prepared dyeing firmness is poor or irritation to scalp
It is larger, preferable dyeing firmness and smaller scalp irritation can not be all taken into account simultaneously.
Inventor also found, suitable tea extract and Gotu Kola P.E is added into first dose of colouring compositions
There is facilitation to dyeing afterwards, this, which is primarily due to tea extract and Gotu Kola P.E, can promote oxidation base and idol
Connection agent infiltrates through hair hair core before chemically reacting, while delaying the oxygen in oxidation base and coupling agent and second dose
The speed reacted after agent mixing so that oxidation base and coupling agent can have more times to infiltrate through hair core, and generate
Effective chemical staining reaction, generates dyestuff macromolecular to be dyed；For those of ordinary skill in the art, only
It infiltrates through the oxidation base of hair core and coupling agent has occurred the color generated after reaction and permanent can just be maintained in hair, jail
Soundness is more preferable, the dye molecule only generated in hair epidermis or the chemical reaction occurred in hair surface without infiltrating through hair core
It can be rinsed out quickly by shampoo, that is, it is poor to dye firmness.Moreover, both tea extract and Gotu Kola P.E lack one not
Can, the collaboration that cooperates plays a role to improve the firmness of dyeing；In addition, tea extract have anti-oxidant, anti-inflammatory effect,
Health can be promoted, Gotu Kola P.E helps to solve cutis laxa phenomenon, keeps skin smooth flexible, promotes corium
Collagen is formed in layer, and fibrin is made to regenerate and connect, and so that skin is achieved the effect that compact smooth, is also assisted in impaired
Organization healing and consolidation skin；Tea extract and Gotu Kola P.E are applied can also alleviate it in colouring compositions
Stimulation of its component to scalp, the colouring compositions that the present invention is prepared are non-stimulated to scalp, Small side effects.
In the present invention, the amount of oxidation base accounts for 0.01 weight %~10% of colouring compositions total amount；The amount of each coupling agent
Account for 0.01 weight %~10% of colouring compositions total amount；The amount of tea extract accounts for 0.01 weight %~10% of colouring compositions total amount；
The amount of Gotu Kola P.E accounts for 0.01 weight %~10% of colouring compositions total amount.
Inventor has found that the dosage of tea extract and Gotu Kola P.E is very little, improves dyeing firmness and reduces scalp
The effect unobvious of stimulation, and when its dosage is too many, plant extracts has negative effect to dyeing instead too much, main to show
The substances such as polysaccharide present in excessive plant extracts can significantly delay oxidising dyeing alkali and coupling agent to infiltrate through hair hair
The speed of core, is unfavorable for hair-dyeing；Preferably, the gross mass of the tea extract and Gotu Kola P.E and described 2,5-
The ratio between gross mass of diaminotoluene or its addition salts and ethoxy -3,4- methylene dioxo group anilines or its addition salts is 1:25~
20: 1。
The final state of above-mentioned tea extract and Gotu Kola P.E can be adjusted as needed, can be solid
, the either gel gel type of liquid；The tea extract is tea extract, density 1.0 in the present invention
~1.06g/ml3；The Gotu Kola P.E is centella extracting solution, and density is 1.0~1.06g/ml3。
It is further preferred that the gross mass of the tea extract and Gotu Kola P.E and 2, the 5- diaminotoluenes
Or the ratio between gross mass of its addition salts and ethoxy -3,4- methylene dioxo group anilines or its addition salts is 1:5~10: 1.
Preferably, the mass ratio of the tea extract and Gotu Kola P.E is 1:10~10: 1；Further preferably
The mass ratio of ground, the tea extract and Gotu Kola P.E is 1:3~3: 1.Tea extract and Gotu Kola P.E exist
There is facilitation for dyeing in colouring compositions, and have coordination synergistic effect at the mild aspect of product, presses between the two
Suitable ratio addition, synergistic effect is preferable, and ratio difference is too big between the two, and trade-off effect is very weak, or even cannot play association
Adjust effect.
Tea extract and Gotu Kola P.E of the present invention are to utilize extraction principle, containing appropriate polynary
It extracts and obtains in alcohol solution, polyalcohol includes propylene glycol, glycerine, butanediol, methyl propanediol, ethyl alcohol etc..It is preferred that with micro-
Wave extraction, extraction microwave frequency are 400~250000MHz.
The mechanism of microwave abstracting can be from the aspect of two, and one side microwave radiation process is that frequency electromagnetic waves penetrate extraction Jie
Matter reaches vascular bundle and glandular cell's system inside material.Due to absorbing microwave energy, cell interior temperature rises rapidly, makes its cell
Internal pressure is more than cell wall expansion ability to bear, cell rupture.Intracellular active ingredient freely flows out, in lower temperature strip
Spe medium is captured and is dissolved under part.By further filtering and detaching, extraction material is just obtained.On the other hand, microwave is produced
Raw electromagnetic field acceleration is extracted fractions to extractant interface diffusion rate, when with aqueous extractant, in microwave
Off field, hydrone high-speed rotation is known as excitation state, this is a kind of high-energy unstable state or hydrone vaporization, reinforces extraction
Take the power of component；Or hydrone itself releases energy and returns to ground state, the energy transmission discharged gives other material molecules, adds
Its fast warm-up movement shortens the molecule of extracted component by being diffused into time at extractant interface inside material, to keep extraction fast
Rate improves several times, while also reducing extraction temperature, ensures the quality of extraction to greatest extent.
Preferably, the oxidation base also contains p-phenylenediamine, 2- chlorine p-phenylenediamine, para-aminophenol, 4- amino -3-
Methylphenol, N, N- are bis-（Beta-hydroxy ethyl）P-phenylenediamine, p-methylaminophenol, o-aminophenol, 2,4- diaminobenzenes
Phenol, 4,5- dimethyl -1（2- ethoxys）One or more of pyrazoles, 4-aminodiphenylamine and its salt.
Preferably, the coupling agent also contains dimethyl phenylene diamine, 2,4- diaminophenoxy ethanols, methylaminophenol, 2-
Methyl -5- amino-phenols, 2- amino -4- oxyethylamines methyl phenyl ethers anisole, 2- amino -3- Hydroxy-pyridines, 4- chloro resorcinols, 2- methyl
Resorcinol, 5- amino -6- chlorine o-cresol, 2- methyl -5- (2- hydroxyethylaminos) phenol, resorcinol, 1- naphthols, 1,5- bis-
One or more of hydroxyl naphthalene, 1- phenyl -3- methylpyrazole -5- ketone or quinhydrones.
In first dose of the colouring compositions of the present invention, suitable direct dyes can also be selected as needed, it is described
Direct dyes can be the known acid dyes of field of hairdye, basic dye, disperse dyes, chemically-reactive dyes etc..
As acid dyes, such as blue 1, purple 401, black 401, No. 205 orange, red can be enumerated
No. 227, No. 106 red, yellow 203, acid orange 3 etc..
As basic dye, such as it can enumerate that alkali blue 99, bismarck brown 16, bismarck brown 17, alkalinity is red 76, basic yellow
57 etc..
As the direct dyes other than acid dyes and basic dye, such as 2- nitros-can be enumerated to benzene two
The chloro- 4- nitrophenols of amine, 2- amino -6-, 3- nitros-are to hydroxyethylaminophenol, 4-nitro-o-phenylenediamine, 4- amino -3-
Nitrophenol, 4- hydroxypropyl -3- nitrophenols, N, N- bis- (2- ethoxys) -2- nitro p-phenylenediamines, divide at disperse violet 1
Dissipate that indigo plant 1, dispersion black 9, HC indigo plants 2, HC oranges 1, HC are red 1, HC is red 3, HC Huangs 2, HC Huangs 4, HC Huangs 5 etc..
Above-mentioned direct dyes can be used alone or in combination of two or more, and content is colouring compositions gross mass
0.001~5%, it is preferably 0.01~4%.
The oxidant selected in the present invention be oxidant commonly used in the art, it is preferable that the oxidant be hydrogen peroxide,
One or more of urea peroxide, alkali metal bromate or peroxy salt.
Preferably, the pH of the colouring compositions is 7~12.
The colouring compositions of the present invention can also include that can be used for the various adjuvants of hair colouring compositions, as anion,
Cation, nonionic, both sexes or zwitterionic surfactant or their mixture, such as anion, cation, it is non-from
Sub, both sexes or amphoteric ion polymer or their mixture, inorganic or organic thickening agent, especially such as anion,
Cation, nonionic and the aggregation syndication thickener of both sexes, antioxidant, bleeding agent, chelating agent, fragrance, caching agent, dispersion
Agent, conditioning agent, such as volatility or non-volatile, modified or non-modified silicone, film forming agent, ceramide, preservative and screening
Photo etching.
Preferably, the amount of above-mentioned adjuvant accounts for 0.01 weight of weight %~50 % of colouring compositions gross mass.
The pH value of the colouring compositions of the present invention is between 3~12, preferably 7~12, more preferably 7.5~11；This hair
The bright acidulant or basifier that may be used commonly used in dyeing keratin fibres, or adjusted using the buffer system of standard
PH value, to reach the value of needs.
In the present invention, the acidulant can select inorganic acid or organic acid, for example such as hydrochloric acid, phosphoric acid, sulfuric acid, carboxylic acid
Acetic acid, tartaric acid, citric acid or lactic acid, sulfonic acid etc..
In the present invention, the basifier can be ammonium hydroxide, basic carbonate, alkanolamine such as monoethanolamine, diethanol amine
With triethanolamine and their derivative or sodium hydroxide, potassium hydroxide.
The colouring compositions of the present invention can exist in a variety of manners, such as liquid, lotion or gel form, or with arbitrary
The other forms that one kind being suitable for dyeing keratin fibres, especially human hair exist.Final administration in keratin fiber i.e.
Composition can be various forms of, and such as liquid, paste or gel or any type are suitable for keratin fiber and spy
It is not the other forms of coloring human hair.
The colouring compositions of the present invention may be present in any medium for being suitable for dyeing, i.e. dye carrier, generally include water,
Or the mixture of water and at least one organic solvent composition that the compound being not completely soluble in water can be dissolved.It is described organic
Solvent includes the lower alcohol of C1~C4, such as ethyl alcohol and isopropanol；Polyalcohol and polyol ethers, as butoxy ethanol, propylene glycol,
Propylene glycol monomethyl ether, diethylene glycol monoethyl ether and monomethyl ether；Or aromatic alcohol, such as benzyl alcohol or phenoxetol and its mixture；?
In the present invention, the content of the organic solvent accounts for 1~40 % of colouring compositions gross mass, and preferably 5~30%.
The present invention still further provides a kind of multiple compartmental device or is colouration box, its first Room includes the dyeing group of the present invention
Object is closed, second Room contains oxidant.Before use, the colouring compositions of the first Room and second Room oxidant are uniformly mixed, it is used in combination
Suitable mode is applied in keratin fiber especially human hair, is stayed for some time and is carried out keratin fiber and contaminated
Color.
Compared with prior art, the present invention has the advantages that：
The present invention selects 2,5- diaminotoluenes or its addition salts as oxidation base, ethoxy -3,4- (methylenedioxy)
Base aniline or its addition salts are dyed as coupling agent, and addition tea extract and centella carry in colouring compositions
Object is taken, the dyeing firmness after the resistance to shampoo washing of the colouring compositions being prepared and resistance to solar radiation is preferable, and to making
The stimulation of the scalp of user is smaller；Colouring compositions provided by the invention can be very good to cover white hair, solve common dye
Stimulation of the agent to scalp is sent out, allergy rate is reduced, improves hair dyeing effect and color durability, and mitigate hair damage；The present invention can
With the long-term hair dyeing personage of satisfaction, hair dyeing demand of to hair, scalp injury small, low allergy mild to hair dye, has wide
Market prospects.
Specific implementation mode
With reference to embodiment, the present invention will be further described.These embodiments are retouched to the typical case of the present invention
It states, however, the present invention is not limited thereto.Test method as used in the following examples unless otherwise specified, is conventional method, is made
Raw material, reagent etc. are unless otherwise specified the raw materials and reagents that can be obtained from commercial sources such as conventional markets.
Embodiment
The preparation of tea extract
Dry green tea is ground, is sieved, the green powder (d50=100-100 μm, 10kg) of preparation is dissolved in
In 50% (v/v) butanediol aqueous solution 150L, and stir at room temperature；In batches by microwave extracting apparatus, in microwave frequency
Under the conditions of 5000MHz, extracts 3 hours, obtain extract liquor, it is spare.
The preparation of Gotu Kola P.E
Dry green tea is ground, is sieved, the green powder (d50=100-100 μm, 10kg) of preparation is dissolved in
In 50% (v/v) methyl propanediol aqueous solution 150L, and stir at room temperature；In batches by microwave extracting apparatus, in Microwave Frequency
Under the conditions of rate 3000MHz, extracts 3 hours, obtain extract liquor, it is spare.
Table 1：The formula of the colouring compositions of Examples 1 to 9 and reference examples 1~7
。
In upper table 1, dyeing carrier（*）For conventional dyeing carrier, in the present invention, concrete composition is as follows：
Cetostearyl alcohol 6g
Hexadecyltrimethylammonium chloride 2g
Isopropyl palmitate 2g
Stearic acid list glyceride 2g
Propylene glycol 5g
Oleyl alcohol 3g
- 20 2g of ceteareth
Hydroxyethyl cellulose 0.3g
Antioxidant 0.2g
Chelating agent 0.3g
Monoethanolamine 4g；
The peroxidating for being 3 by the pH of embodiment in upper table 1 or 20 volumes of each component in reference examples and equivalent when use
Hydrogen solution mixes, and so that the pH of the composition obtained after mixing is 9.7.
Hair dyeing experiment
（1）Experiment tuftlet hair-dyeing operation sequence：
The topknot for being mixed with 80% white hair is taken, be administered on topknot using the amount of 8g mixtures by 10g hairs and is kept for 30 points
Clock.Then it rinses, rinsed with standard shampoo and dries.
（2）True man, which have hair dyed, to be tested：
The volunteer that 32 skins are responsive type is divided into 7 groups, every group of 4 people distinguish trial dyeing Examples 1 to 8 sample.Specifically
Behaviour is taken as having hair dyed to every group of 4 people for the hair coloring preparation composition of Examples 1 to 8, and every group of 4 people use identical
Hair coloring preparation composition, difference group use different hair coloring preparation compositions；Then, being inquired to them is improved with assessing stimulation
Degree, and give a mark, degree that stimulation improves indicated with the height of the average mark of 4 people；
Inquire that each group improves situation with 1~5 point and 0.05 point for interval assessment stimulation after hair dyeing.When they feel to pierce
To 1 point when swashing improvement degree very little, 5 points are given when feeling that scalp irritation has clear improvement.Finally integrate the score of 4 people
And average, result of calculation is shown in Table 2.
（3）The hair firmness of resistance to shampoo is tested after dyeing：
After dyeing 24 hours, colorimetric measurement is carried out with Minolta CM-2600D colorimeters in laboratory system, surveys L
Value.The hair of dyeing is immersed in shampoo solution later, with oscillator with 200rpm speed oscillations 30 minutes, stream
Water rinses 1 minute, then then electricity consumption blowing drying measures L values with colorimeter.Δ L=L0- L1 are calculated, L0 represents dye back
The brightness value of the color of hair, L1 represents the brightness value of hair color after shampoo is washed after dye, according to the discrepancy delta L of brightness value
Numerical evaluation color durability, smaller Δ L values refer to preferable color durability, and test result is shown in Table 3.
（4）Hair hand valuation method
Hair sense of touch：Hair is gently clamped with index finger and thumb, hair tail portion position, sense are gently slided to from the root of hair position of topknot
Feel smooth feeling, the moisture feeling of hair, and scores：0 is excellent, and 1 is good, and 2 is general, and 3 is very poor；Test result is shown in Table.
Table 2：True man's hair dyeing test experiments data
。
As shown in Table 2, the colouring compositions that various embodiments of the present invention are prepared can be obviously improved the stimulation to scalp,
And conventional colouring compositions（Reference examples 4）, do not add plant extracts and only add specific oxidation base and coupling agent（It is right
As usual 1）, do not add oxidation base（Reference examples 2）And only add plant extracts（Reference examples 3）Obtained colouring compositions
There are different degrees of stimulation, effect poor to the skin of responsive type user.
Table 3：Hair shampoo washs firmness test result after dyeing
。
By upper table 3 it is found that the colouring compositions that are prepared of various embodiments of the present invention are after shampoo is washed, firmness is dyed
Preferably, Δ L * values are smaller, are below 3；And the dyeing firmness for the colouring compositions that each reference examples are prepared is poor, Δ L *
Value is all higher than 4.0.
Table 4：Hair lesion assessment test result after dye
。
By upper table 4 it is found that the colouring compositions of various embodiments of the present invention offer are smaller to the degree of hair damage, hair ratio
Compared with lubrication and moisture feeling it is good, show as good, and the hair dyeing product that the composition in each reference examples is prepared is to hair damage
Degree it is larger.
Claims (7)
1. a kind of colouring compositions containing natural plant composition, the colouring compositions include first dose and second dose, described
Include oxidation base, coupling agent in first dose, contains oxidant in described second dose；It is characterized in that, the oxidative color-developing
Alkali includes 2,5- diaminotoluenes or its addition salts, and the coupling agent includes ethoxy -3,4- methylene dioxo group anilines or it adds
At salt, described first dose further includes tea extract and Gotu Kola P.E；The tea extract and Gotu Kola P.E
Gross mass and the 2,5- diaminotoluenes or its addition salts and ethoxy -3,4- methylene dioxo group anilines or its addition salts it is total
Mass ratio is 1:25~20:1；The mass ratio of the tea extract and Gotu Kola P.E is 1:10~10:1.
2. the colouring compositions containing natural plant composition according to claim 1, which is characterized in that the tea extract
With the gross mass and the 2,5- diaminotoluenes or its addition salts and ethoxy -3,4- methylenedioxybenzenes of Gotu Kola P.E
The ratio between gross mass of amine or its addition salts is 1:5~10:1.
3. the colouring compositions containing natural plant composition according to claim 1, which is characterized in that the tea extract
Mass ratio with Gotu Kola P.E is 1:3~3:1.
4. the colouring compositions containing natural plant composition according to claim 1, which is characterized in that the oxidation base
Also contain p-phenylenediamine, 2- chlorine p-phenylenediamine, para-aminophenol, 4- amino -3- methylphenols, N, N- bis- (beta-hydroxy ethyls) is right
Phenylenediamine, p-methylaminophenol, o-aminophenol, 2,4- diaminophenols, 4,5- dimethyl -1 (2- ethoxys) pyrazoles, N-
One or more of diphenyl-para-phenylene diamine and its salt.
5. the colouring compositions containing natural plant composition according to claim 1, which is characterized in that the coupling agent also contains
There are dimethyl phenylene diamine, 2,4- diaminophenoxy ethanols, methylaminophenol, 2- methyl -5- amino-phenols, 2- amino -4- hydroxyl second
Amine methyl phenyl ethers anisole, 2- amino -3- Hydroxy-pyridines, 4- chloro resorcinols, 2- methyl resorcinols, 5- amino -6- chlorine o-cresol, 2-
Methyl -5- (2- hydroxyethylaminos) phenol, resorcinol, 1- naphthols, 1,5- dihydroxy naphthlenes, 1- phenyl -3- methylpyrazole -5- ketone
Or one or more of quinhydrones.
6. the colouring compositions containing natural plant composition according to claim 1, which is characterized in that the oxidant was
One or more of hydrogen oxide, urea peroxide, alkali metal bromate or peroxy salt.
7. the colouring compositions containing natural plant composition according to claim 1, which is characterized in that the colouring compositions
PH be 7~12.
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| JP7085355B2 (en) | 2018-01-25 | 2022-06-16 | 日華化学株式会社 | Dyes and hair dyes |
| CN108670903A (en) * | 2018-06-14 | 2018-10-19 | 广州植境生物科技有限公司 | A kind of draft Haircare composition of the root extract containing the fleece-flower root |
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| CN102258438A (en) * | 2010-11-19 | 2011-11-30 | 浙江养生堂天然药物研究所有限公司 | Use of tea polyphenol and/or tea pigment as dye and product of tea polyphenol and/or tea pigment |
| US20140048093A1 (en) * | 2011-03-28 | 2014-02-20 | Dow Corning Corporation | Solid Coloring Compositions |
| JP4993396B1 (en) * | 2011-09-26 | 2012-08-08 | 株式会社Ｉｃｔｂグローバル | Hair dyeing method and hair dye set used for the hair dyeing method |
| CN103251521B (en) * | 2013-05-03 | 2015-06-10 | 肇庆迪彩日化科技有限公司 | Hair-dyeing composition and hair dyeing method |
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