CN1593375A - Hair dyeing, hairdressing agent and its making method - Google Patents

Hair dyeing, hairdressing agent and its making method Download PDF

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Publication number
CN1593375A
CN1593375A CN 200410009258 CN200410009258A CN1593375A CN 1593375 A CN1593375 A CN 1593375A CN 200410009258 CN200410009258 CN 200410009258 CN 200410009258 A CN200410009258 A CN 200410009258A CN 1593375 A CN1593375 A CN 1593375A
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China
Prior art keywords
agent
deionized water
hair
following weight
hair dyeing
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CN 200410009258
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Chinese (zh)
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CN1242737C (en
Inventor
阎征
尚建国
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SANJING CHINESE MEDICINE DAILY CHEMISTRY CO Ltd BEIJING
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SANJING CHINESE MEDICINE DAILY CHEMISTRY CO Ltd BEIJING
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Priority to CN 200410009258 priority Critical patent/CN1242737C/en
Publication of CN1593375A publication Critical patent/CN1593375A/en
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Publication of CN1242737C publication Critical patent/CN1242737C/en
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Abstract

Disclosed is a hair dyeing, hairdressing agent and its making method, which comprises additive, dyestuff agent and metallic chelating agent, wherein the additive comprises the following raw materials, acetylcysteine hydrazine derivative, homologue and salts, sodium sulfite, sodium carboxymethylcellulose, disodium ethylenediamine tetraacetate, monoethanol-amine, and balancing deionized water.

Description

A kind of hair dyeing, agent for permanent hair waving and preparation method thereof
Technical field:
The present invention relates to a kind of hair dyeing, agent for permanent hair waving and preparation method thereof.
Technical background:
At present, the hair dye overwhelming majority of selling on the market is to adopt the p-phenylenediamine (PPD) of chemosynthesis and other band benzene ring type compounds to make, a large amount of research and report proof, p-phenylenediamine (PPD) and other band benzene ring type compounds have zest to skin, cause anaphylaxis, and easily by skin absorbs, accumulate and in body, cause poisoning, and can bring out various cancers.The rat percutaneous is the injection p-phenylenediamine (PPD) down, and minimum lethal dose is 600 mg/kg body weight; The oral minimum lethal dose of rabbit is 250 mg/kg body weight.Prove after deliberation that in addition this class material also has the mutagenicity toxic and side effects to human body, and scalp is caused damage, and hair is tarnished, colour-darkening, embrittlement is easily broken.Therefore, the safety issue of hair dye product more and more causes people's attention.
Summary of the invention:
The objective of the invention is to improve the prior art shortcoming and provide a kind of that have no side effect, make submissive natural, the hair dyeing of bright in color of hair quality, agent for permanent hair waving after using.
Another object of the present invention is to provide a kind of preparation method of above-mentioned hair dyeing, agent for permanent hair waving.
For achieving the above object, the present invention adopts following technical proposals: hair dye of the present invention is made up of inorganic agent, dying agent and metal-chelate mixture three parts.The prescription and the percentage by weight thereof of described three parts are as follows.
Described inorganic agent is made by following weight percentages:
Mucolyticum acid derivative, homologue and its esters 2.0-10%
Sodium sulfite 0.1-2.0%
Sodium carboxymethyl cellulose 1.0-10%
Disodiumedetate 0.1-0.5%
Monoethanolamine 1.0-20%
The deionized water surplus
Described dying agent is made by following weight percentages:
Food coloring 1.0-20%
Thickening agent 1.0-30%
Surfactant 1.0-3.0%
The deionized water surplus
Described metal ion intercalating agent is made by following weight percentages:
Metal cation salt 0.5-10%
Thickening agent 1.0-30%
The deionized water surplus
Wherein said mucolyticum acid derivative, homologue and salt thereof can be selected for use: N-acetylcystein, carbamyl cysteine, homocysteine, cysteamine, cysteine hydrochloride monohydrate or cysteine hydrochloride anhydride.
Described food coloring can be selected Gardenia Yellow, brilliant black, carmine, sunset yellow, light green, light blue, caramel color, safflower yellow, radish red pigment, purple sweet potato haematochrome, purple cabbage pigment, phylloxanthin, cacao color, chlorophyll or plant carbon melanocyte for use.
Described thickening agent can be selected sodium carboxymethyl cellulose (CMC), xanthan gum, gelatin or guar gum for use.
Described surfactant can be selected sodium lauryl sulphate (K for use 12), polyoxyethylenated alcohol sodium sulfate (AES) or betanin.
The metal ion that described metal ion can select for use iron salt, aluminum salt, magnesium salt or mantoquita to produce.
Wherein, described inorganic agent also claims softening agent, and its effect is the hair scale sheet of hair to be opened make hair dye be easy to enter in the pipe; The effect of described dying agent has been the colour developing effect; Described metal-chelate mixture mainly is to make metal ion and dye molecule sequestration generate bigger molecule, changes dyestuff, Show Color, and simultaneously, because that molecular change gets is bigger, it is difficult for the hair dyeing back oozing out outside the hair, makes color development lasting.
The preparation method of described hair dye is as follows: with described inorganic agent following weight percentages
Mucolyticum acid derivative, homologue and its esters 2.0-10%
Sodium sulfite 0.1-2.0%
Sodium carboxymethyl cellulose 1.0-10%
Disodiumedetate 0.1-0.5%
Monoethanolamine 1.0-20%
The deionized water surplus
Slowly add in the deionized water in regular turn, and be aided with stirring, up to all dissolvings fully of various components, it is even to continue to be stirred to solution, promptly obtains inorganic agent;
With described dying agent following weight percentages
Food coloring 1.0-20%
Thickening agent 1.0-30%
Surfactant 1.0-3.0%
The deionized water surplus
Slowly add in the deionized water in regular turn, and be aided with stirring, up to all dissolvings fully of various components, it is even to continue to be stirred to solution, promptly obtains dying agent;
With described metal ion intercalating agent following weight percentages
Metal cation salt 0.5-10%
Thickening agent 1.0-30%
The deionized water surplus
Slowly add in the deionized water in regular turn, and be aided with stirring, up to all dissolvings fully of various components, it is even to continue to be stirred to solution, promptly obtains metal ion chelation agent;
The using method of hair dye of the present invention is as follows:
At first hair is washed, towel off the moisture on the clean hair, then inorganic agent is evenly spread upon on the hair, be heated to 35 ℃-45 ℃, kept 15-20 minute, dying agent is evenly spread upon on the hair, reheat to 35 ℃-45 ℃ kept 5-10 minute again, evenly spread upon the metal ion intercalating agent on the hair at last, still be heated to 35 ℃-45 ℃, kept 4-8 minute, totally get final product with warm water washing.If do not heat in the hair dyeing process, should the proper extension time.
Product of the present invention has no side effect to human body, can not cause damage to scalp, sends out light, submissive nature damp with the back.
The specific embodiment:
Embodiment 1:
Take by weighing N-acetylcystein 2.0g, sodium sulfite 0.5g, sodium carboxymethyl cellulose 2.0g, disodiumedetate 0.1g, monoethanolamine 10.0g, add successively in the 85.4g deionized water, stir fully, obtain inorganic agent until dissolving.
Take by weighing Gardenia Yellow 2.0g, sodium carboxymethyl cellulose 5.0g, sodium lauryl sulphate 1.0g, add successively in the 92g deionized water, stir fully, obtain dying agent until dissolving.
Take by weighing iron chloride 3g, xanthan gum 3g, add successively in the 94g deionized water, stir fully, obtain metal ion chelation agent until dissolving.
Use according to using method, poliosis can be dyed black.
Embodiment 2:
Take by weighing amino methyl cysteine 4.0g, sodium sulfite 1.0g, sodium carboxymethyl cellulose 4.0g, disodiumedetate 0.2g, monoethanolamine 15.0g, add successively in the 75.8g deionized water, stir fully, obtain inorganic agent until dissolving.
Take by weighing carmine pigment 3.0g, gelatin 3.0g, sodium lauryl sulphate 1.0g, add successively in the 93g deionized water, stir fully, obtain dying agent until dissolving.
Take by weighing copper sulfate 2.5g, Guar gum 3.0g, add successively in the 94g deionized water, stir fully, obtain metal ion chelation agent until dissolving.
Use according to using method, poliosis can be dyed black.
Embodiment 3:
Take by weighing N-acetylcystein hydrochloride monohydrate 5.0g, sodium sulfite 0.8g, sodium carboxymethyl cellulose 4.0g, disodiumedetate 0.4g, monoethanolamine 8.0g, add successively in the 81.8g deionized water, stirring obtains inorganic agent until dissolving fully.
Take by weighing light blue pigment 8.0g, xanthan gum 3.0g, AES 2.0g, add successively in the 87.0g deionized water, stir fully, obtain dying agent until dissolving.
Take by weighing magnesium sulfate 5.0g, sodium carboxymethyl cellulose 6.0g, add successively in the 89.0g deionized water, stir fully, obtain metal ion chelation agent until dissolving.
Use according to using method, poliosis can be dyed black.

Claims (7)

1, a kind of hair dyeing, agent for permanent hair waving is characterized in that: it is made up of inorganic agent, dying agent and metal-chelate mixture three parts, and the prescription and the percentage by weight thereof of described three parts are as follows,
Described inorganic agent is made by following weight percentages:
Mucolyticum acid derivative, homologue and its esters 2.0-10%
Sodium sulfite 0.1-2.0%
Sodium carboxymethyl cellulose 1.0-10%
Disodiumedetate 0.1-0.5%
Monoethanolamine 1.0-20%
The deionized water surplus
Described dying agent is made by following weight percentages:
Food coloring 1.0-20%
Thickening agent 1.0-30%
Surfactant 1.0-3.0%
The deionized water surplus
Described metal ion intercalating agent is made by following weight percentages:
Metal cation salt 0.5-10%
Thickening agent 1.0-30%
The deionized water surplus.
2, a kind of hair dyeing according to claim 1, agent for permanent hair waving is characterized in that: wherein said mucolyticum acid derivative, homologue and salt thereof can be selected N-acetylcystein, carbamyl cysteine, homocysteine, cysteamine, cysteine hydrochloride monohydrate or cysteine hydrochloride anhydride for use.
3, a kind of hair dyeing according to claim 1, agent for permanent hair waving is characterized in that: described food coloring can be selected Gardenia Yellow, brilliant black, carmine, sunset yellow, light green, light blue, caramel color, safflower yellow, radish red pigment, purple sweet potato haematochrome, purple cabbage pigment, phylloxanthin, cacao color, chlorophyll or plant carbon melanocyte for use.
4, a kind of hair dyeing according to claim 1, agent for permanent hair waving is characterized in that: described thickening agent can be selected sodium carboxymethyl cellulose (CMC), xanthan gum, gelatin or guar gum for use.
5, a kind of hair dyeing according to claim 1, agent for permanent hair waving, it is characterized in that: described surfactant can be selected sodium lauryl sulphate (K for use 12), polyoxyethylenated alcohol sodium sulfate (AES) or betanin.
6, a kind of hair dye according to claim 1 is characterized in that: the metal ion that described metal ion can select for use iron salt, aluminum salt, magnesium salt or mantoquita to produce.
7, the preparation method of a kind of hair dyeing as claimed in claim 1, agent for permanent hair waving is characterized in that, the preparation method of described hair dye is as follows:
With described inorganic agent following weight percentages
Mucolyticum acid derivative, homologue and its esters 2.0-10%
Sodium sulfite 0.1-2.0%
Sodium carboxymethyl cellulose 1.0-10%
Disodiumedetate 0.1-0.5%
Monoethanolamine 1.0-20%
The deionized water surplus
Slowly add in the deionized water in regular turn, and be aided with stirring, up to all dissolvings fully of various components, it is even to continue to be stirred to solution, promptly obtains inorganic agent;
With described dying agent following weight percentages
Food coloring 1.0-20%
Thickening agent 1.0-30%
Surfactant 1.0-3.0%
The deionized water surplus
Slowly add in the deionized water in regular turn, and be aided with stirring, up to all dissolvings fully of various components, it is even to continue to be stirred to solution, promptly obtains dying agent;
With described metal ion intercalating agent following weight percentages
Metal cation salt 0.5-10%
Thickening agent 1.0-30%
The deionized water surplus
Slowly add in the deionized water in regular turn, and be aided with stirring, up to all dissolvings fully of various components, it is even to continue to be stirred to solution, promptly obtains metal ion chelation agent.
CN 200410009258 2004-06-25 2004-06-25 Hair dyeing, hairdressing agent and its making method Expired - Fee Related CN1242737C (en)

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Application Number Priority Date Filing Date Title
CN 200410009258 CN1242737C (en) 2004-06-25 2004-06-25 Hair dyeing, hairdressing agent and its making method

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Application Number Priority Date Filing Date Title
CN 200410009258 CN1242737C (en) 2004-06-25 2004-06-25 Hair dyeing, hairdressing agent and its making method

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CN1593375A true CN1593375A (en) 2005-03-16
CN1242737C CN1242737C (en) 2006-02-22

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010094207A1 (en) 2009-02-20 2010-08-26 浙江养生堂天然药物研究所有限公司 A mordant and a hair dyeing composition comprising the said mordant
CN102485201A (en) * 2010-12-01 2012-06-06 庄国昇 Hair dye containing one or more food pigments or cosmetic pigments and hair dyeing method thereof
CN102781412A (en) * 2009-12-23 2012-11-14 莱雅公司 Composition for dyeing keratin fibres including at least one ortho-diphenol derivative, and oxidising agent, a clay and an alkalising agent
CN103497535A (en) * 2013-10-10 2014-01-08 西南科技大学 Animal melanin extraction method and application of extraction product thereof
CN101812246B (en) * 2009-02-20 2014-10-01 浙江养生堂天然药物研究所有限公司 Mordant and hair dyeing product containing same
CN104083307A (en) * 2014-07-28 2014-10-08 江南大学 Natural hair dye prepared by adopting plant pigment safflower pigment and hair dyeing method using natural hair dye
CN105748325A (en) * 2016-03-10 2016-07-13 蚌埠团结日用化学有限公司 Auxiliaries for hair perming and hair dyeing and preparation method thereof
CN104398441B (en) * 2014-12-08 2017-05-10 上海海洋大学 Seaweed pigment hair dye and application method thereof
KR20210003404A (en) 2019-07-02 2021-01-12 한국과학기술원 Cosmetic composition for dyeing hair and method of dyeing using the same

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010094207A1 (en) 2009-02-20 2010-08-26 浙江养生堂天然药物研究所有限公司 A mordant and a hair dyeing composition comprising the said mordant
US8313537B2 (en) 2009-02-20 2012-11-20 Natural Medicine Institute Of Zhejiang Yangshengtang Co. Ltd. Mordant and hair coloring products containing the same
CN101812246B (en) * 2009-02-20 2014-10-01 浙江养生堂天然药物研究所有限公司 Mordant and hair dyeing product containing same
CN102781412A (en) * 2009-12-23 2012-11-14 莱雅公司 Composition for dyeing keratin fibres including at least one ortho-diphenol derivative, and oxidising agent, a clay and an alkalising agent
CN102485201A (en) * 2010-12-01 2012-06-06 庄国昇 Hair dye containing one or more food pigments or cosmetic pigments and hair dyeing method thereof
CN103497535A (en) * 2013-10-10 2014-01-08 西南科技大学 Animal melanin extraction method and application of extraction product thereof
CN103497535B (en) * 2013-10-10 2016-03-30 西南科技大学 A kind of extracting method of Animal melanin and the application of extraction product thereof
CN104083307A (en) * 2014-07-28 2014-10-08 江南大学 Natural hair dye prepared by adopting plant pigment safflower pigment and hair dyeing method using natural hair dye
CN104083307B (en) * 2014-07-28 2016-08-17 江南大学 Use a kind of natural hair dye of preparing of plant pigment carthamin and hair colouring methods thereof
CN104398441B (en) * 2014-12-08 2017-05-10 上海海洋大学 Seaweed pigment hair dye and application method thereof
CN105748325A (en) * 2016-03-10 2016-07-13 蚌埠团结日用化学有限公司 Auxiliaries for hair perming and hair dyeing and preparation method thereof
KR20210003404A (en) 2019-07-02 2021-01-12 한국과학기술원 Cosmetic composition for dyeing hair and method of dyeing using the same

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