CN1633965A - Hair dye composition using henna pollen as dye - Google Patents

Hair dye composition using henna pollen as dye Download PDF

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Publication number
CN1633965A
CN1633965A CN 200410096854 CN200410096854A CN1633965A CN 1633965 A CN1633965 A CN 1633965A CN 200410096854 CN200410096854 CN 200410096854 CN 200410096854 A CN200410096854 A CN 200410096854A CN 1633965 A CN1633965 A CN 1633965A
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Prior art keywords
hair
henna
pollen
composition
sodium
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CN 200410096854
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闫征
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SANJING CHINESE MEDICINE DAILY CHEMISTRY CO Ltd BEIJING
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SANJING CHINESE MEDICINE DAILY CHEMISTRY CO Ltd BEIJING
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Priority to CN 200410096854 priority Critical patent/CN1633965A/en
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Abstract

According to the present invention, new colors are produced from Egyptian henna pollen, other pigments and metallic ions, thus obtaining wider color system. The hair dyeing agent comprises hair softening additive and dyestuff preparation, wherein the hair softening additive mainly comprises sodium mercaptoacetate, sodium carboxymethylcellulose, monoethanol-amine, sodium thiosulphate, disodium ethylene diamine tetraacetate and water, and the dyestuff preparation mainly comprises Egyptian henna pollen, sodium carboxymethylcellulose, sodium dodecanesulphonate and color blending constituent, which is selected from cape jasmine cyanine, alizarine red pigment, and copper sulfate.

Description

With the henna pollen is the hair coloring preparation composition of dyestuff
Technical field
The invention belongs to the daily-use chemical industry cosmetic field, being specifically related to the henna pollen is the hair coloring preparation composition of dyestuff.
Technical background
At present, most hair dyes of selling on the market, all adopt p-phenylenediamine (PPD) and other band benzene ring type compounds of organic synthesis to make, a large amount of research and report proof, this class hair dye has certain toxicity to skin, can cause skin allergy, life-time service can cause poisoning, and can bring out various cancers.Therefore, the safety issue of hair dye product more and more causes people's attention, and it is imperative to seek nontoxic hair dye.
The mignonettetree dyestuff is exactly the unique natural dye that is applied to the hair dye industry before the nineties in 20th century, belongs to permeability hair dyeing pigment, is the pigment that U.S. FDA is permitted use.China has minority cosmetics producer to begin this type of plant type dyestuff hair dye Products Development and use at present, but on result of use, because the colour system that henna pollen produces is not a hair nature color, colour system is narrower, removes black, and it is only limited to blush and russet, and be easy to form bead when using, form bulk, be difficult to evenly be coated on the hair, make very difficulty of colouring.
Summary of the invention:
The purpose of this invention is to provide a kind of having no side effect, color and luster is stablized and be easy-operating is the hair coloring preparation composition of dyestuff with the henna pollen.
Technical scheme of the present invention be a kind of be the hair coloring preparation composition of dyestuff with the henna pollen, it is made up of softening inorganic agent of hair and dye formulations, it is characterized in that,
Hair softens inorganic agent: the part by weight of dye formulations is 100: (10-20);
The softening inorganic agent of hair is that benchmark contains following ingredients with himself weight:
Composition weight %
Sodium thioglycolate 2.0-8.0%
Sodium carboxymethyl cellulose 1.0-2.0%
Monoethanolamine 5.0-10%
Sodium thiosulfate 0.1-2.0%
Disodiumedetate 0.1-0.5%
The Purified Water surplus
Dye formulations is a benchmark with himself weight, contains following ingredients:
Composition weight %
Henna pollen 2.0-20%
Sodium carboxymethyl cellulose 1.0-2.0%
Sodium lauryl sulphate (K12) 1.0-3.0%
Color matching composition 1.5-5.0%
The Purified Water surplus
Wherein, the color matching composition is to be selected from gardenia blue pigment, alizarin red pigment, the copper sulfate any.
As above-mentioned technical scheme described a kind of be the hair coloring preparation composition of dyestuff with the henna pollen, color matching composition wherein is a gardenia blue pigment, its percentage by weight is 1.5-3.0%.At this moment the hair color that dyes is a nature black.
As above-mentioned technical scheme described a kind of be the hair coloring preparation composition of dyestuff with the henna pollen, the color matching composition be the alizarin red pigment, its percentage by weight is 1.5-4.5%.At this moment the hair color that dyes is that nature is brown.
As above-mentioned technical scheme described a kind of be the hair coloring preparation composition of dyestuff with the henna pollen, the color matching composition is a copper sulfate, its percentage by weight is 2.5-5.0%.At this moment the hair color that dyes is the nature redness.
The characteristic of henna pollen as dye formulations at first is described.
The outward appearance of henna pollen is a red powder, be a kind of leaf with mignonettetree pulverize, through extraction and dry and the dried plant powder.Belong to the permeability pigment, can firmly be deposited in the horny layer of hair, it can make hair blush or russet.Mignonettetree (Lawsonia inermis) is the plant that a kind of Lythraceae (Lythtaceae) mignonettetree belongs to, shrub, high 3-6 rice, originate in the torrid zone, subtropical zone, extensively be present in the Middle East, north African, extensive cultivation is all arranged in provinces such as China Guangdong, Guangxi, Fujian, Taiwan.As other natural products, the complicated component of henna pollen contains number of chemical compositions such as Coumarins, quinones and flavonoid, and its main active is a 2-hydroxyl-1, the 4-naphthoquinone.
Structural formula is:
Figure A20041009685400061
2-hydroxyl-1, the 4-naphthoquinone
Because henna pollen colouring speed is slower, and easily form piece, be difficult to be applied in equably on the hair, so we have taked hair is carried out remollescent method, the hair scale sheet of hair is opened, and dye molecule is easy to enter in the hair, makes henna pollen be easy to disperse simultaneously, be convenient to smear, thereby shorten the hair dyeing time.
Making the open chemical compound of hair scale is sodium thioglycolate, sodium thiosulfate, cysteine and derivant thereof etc., and the disulfide bond effect of their energy and hair inside is opened the hair scale sheet of hair, softening hair.Because the colour system that henna pollen produces is narrower, pure henna pollen is confined to blush and russet, we have been by having produced new color with henna pollen and other pigments (as indigo, curcumin, Gardenia Yellow, monascorubin etc.) and metal ion (as copper ion, iron ion, magnesium ion etc.) effect, thereby have obtained wideer colour system.As using simultaneously, just can obtain black with bipseudoindoxyl dye or gardenia blue; As dye red promptly wash again and dye with the iron ion preparation, just can obtain dark-brown.
This hair dye is two dosage forms, can make powder or mastic.Softening inorganic agent of hair and dye formulations will be packed respectively and deposit, and mix during use, spread upon jointly on the hair, and hair can be dyed the corresponding color of this kind dye formulations.The softening inorganic agent of hair wherein can adopt 1 dose of popular two dosage form cold wave lotions on the market; Dye formulations is that henna pollen is equipped with common thickening agent and surfactant gets final product, and the two consumption is controlled with the viscosity of preparation, and mastic does not drip when needing only hair dyeing.
Obtain color except that blush and russet as need, can in dye formulations, add other pigments or metal ion and henna pollen and be used.
Compare with the state of the art, the present invention has following useful effect:
1) this hair dye nontoxic, have no side effect, do not have irritated phenomenon.
2) color and luster natural stability, similar to natural color development, it is many with powdery to have overcome plant hair dye, not easy-operating shortcoming.
3) can supply with hair nutrition, make hair have gloss.
The specific embodiment:
Enumerate embodiment below and further describe the present invention.
1, embodiment one:
Take by weighing sodium thioglycolate 4.0 grams, sodium thiosulfate 1.0 grams, sodium carboxymethyl cellulose 1.5 grams, disodium salt disodium 0.3 gram, an ethanol ammonia 5.5 grams, join successively in the Purified Water of 87.7 grams, stir fully, promptly obtain softening inorganic agent until dissolving.
Take by weighing henna pollen 6.0 grams, gardenia blue pigment 2.0 grams, sodium carboxymethyl cellulose 1.5 grams, sodium lauryl sulphate 1.5 grams, join successively in the Purified Water of 89.0 grams, stir fully, can obtain dye formulations until dissolving.
During use the softening inorganic agent of hair and dye formulations mixed according to 100: 15 part by weight that (the two concrete consumption is controlled with the viscosity of preparation, as long as mastic does not drip during hair dyeing) evenly spread upon on the hair jointly, put on and wash down natural air drying with clear water after the medicated cap of preserving moisture is waited for 25-30 minute.Promptly dye nature black.
2, embodiment two:
Take by weighing sodium thioglycolate 5.0 grams, sodium thiosulfate 1.5 grams, sodium carboxymethyl cellulose 1.0 grams, disodium salt disodium 0.4 gram, an ethanol ammonia 6.0 grams, join successively in the Purified Water of 86.1 grams, stir fully, promptly obtain softening inorganic agent until dissolving.
Take by weighing henna pollen 6.5 grams, alizarin red pigment 3.0 grams, sodium carboxymethyl cellulose 1.5 grams, sodium lauryl sulphate 1.7 grams, join successively in the Purified Water of 87.3 grams, stir fully, can obtain dye formulations until dissolving.
With the softening inorganic agent of hair and dye formulations part by weight according to 100: 17, as the operational approach of embodiment 1, same operation.It is brown that hair is dyed nature.
3, embodiment three:
Take by weighing sodium thioglycolate 6.0 grams, sodium thiosulfate 1.4 grams, sodium carboxymethyl cellulose 1.7 grams, disodium salt disodium 0.35 gram, an ethanol ammonia 7.5 grams, join successively in the Purified Water of 83.05 grams, stirring promptly obtains softening inorganic agent until dissolving fully.
Take by weighing henna pollen 18 grams, copper sulfate 3.75 grams, sodium carboxymethyl cellulose 1.15 grams, sodium lauryl sulphate 2.62 grams, join successively in the Purified Water of 74.48 grams, stir fully, can obtain dye formulations until dissolving.
With the softening inorganic agent of hair and dye formulations part by weight according to 100: 13, as the operational approach of embodiment 1, same operation.Hair is dyed the nature redness.
4, embodiment four:
Take by weighing sodium thioglycolate 2.5 grams, sodium thiosulfate 0.15 gram, sodium carboxymethyl cellulose 1.17 grams, disodium salt disodium 0.18 gram, an ethanol ammonia 8.5 grams, join successively in the Purified Water of 87.5 grams, stirring promptly obtains softening inorganic agent until dissolving fully.
Take by weighing henna pollen 2.5 grams, alizarin red pigment 3.0 grams, sodium carboxymethyl cellulose 1.7 grams, sodium lauryl sulphate 2.5 grams, join successively in the Purified Water of 90.3 grams, stir fully, can obtain dye formulations until dissolving.
With the softening inorganic agent of hair and dye formulations part by weight according to 100: 18.5, as the operational approach of embodiment 1, same operation.It is brown that hair is dyed nature.
5, embodiment five:
Take by weighing sodium thioglycolate 7.75 grams, sodium thiosulfate 0.18 gram, sodium carboxymethyl cellulose 1.3 grams, disodium salt disodium 0.25 gram, an ethanol ammonia 7.75 grams, join successively in the Purified Water of 82.77 grams, stirring promptly obtains softening inorganic agent until dissolving fully.
Take by weighing henna pollen 10 grams, copper sulfate 4.0 grams, sodium carboxymethyl cellulose 1.6 grams, sodium lauryl sulphate 2.0 grams, join successively in the Purified Water of 82.4 grams, stir fully, can obtain dye formulations until dissolving.
With the softening inorganic agent of hair and dye formulations part by weight according to 100: 15, as the operational approach of embodiment 1, same operation.Hair is dyed the nature redness.
Produce respectively for two doses during production, pack respectively and deposit.
Using method: with the softening inorganic agent of hair and dye formulations by weight 100: ratio (10-20) is added in the nonmetallic vessel, fully be in harmonious proportion evenly, with hairbrush mixed mastic is coated on the hair uniformly then, waits for that 30-40 minute afterwash hair gets final product.
Need to prove,, then need correct loss of hairs color if hair color dyes colored hair, utilize commercially available depigmenting agent or decolouring milk all can, earlier hair color is decoloured to appropriate color, implement dyeing operation again.
Add up with market like product effect controlled trial result:
Number on probation Irritated situation statistics The colour stable situation
Numbness Minimal irritation Causalgia Can't stand 7 days 60 days 120 days
The market like product ????375 ????357 ????15 ????0 ???3 ????375 ????355 ????332
This product ????375 ????370 ????4 ????1 ???0 ????375 ????369 ????365
Annotate: should be that natural black compares according to same color 1) with contrast test.
2) the colour stable situation is followed the tracks of, and is according to the standard of comparison of first hair dyeing back hair color as later stage contrast color.
3) 375 people of this contrast test were same fixedly crowds, with different product hair dyeing interval 2 months.

Claims (4)

1, a kind of is the hair coloring preparation composition of dyestuff with the henna pollen, is made up of softening inorganic agent of hair and dye formulations, it is characterized in that,
Hair softens inorganic agent: the part by weight of dye formulations is 100: (10-20);
The softening inorganic agent of hair is that benchmark contains following ingredients with himself weight:
Composition weight %
Sodium thioglycolate 2.0-8.0%
Sodium carboxymethyl cellulose 1.0-2.0%
Monoethanolamine 5.0-10.0%
Sodium thiosulfate 0.1-2.0%
Disodiumedetate 0.1-0.5%
The Purified Water surplus
Dye formulations is a benchmark with himself weight, contains following ingredients:
Composition weight %
Henna pollen 5.0-8.0%
Sodium carboxymethyl cellulose 1.0-2.0%
Sodium lauryl sulphate (K12) 1.0-3.0%
Color matching composition 1.5-5.0%
The Purified Water surplus
Wherein, the color matching composition is to be selected from gardenia blue pigment, alizarin red pigment, the copper sulfate any.
2, as claimed in claim 1 is the hair coloring preparation composition of dyestuff with the henna pollen, it is characterized in that, the color matching composition in its dye formulations is a gardenia blue pigment, and its percentage by weight is 1.5-3.0%.
3, as claimed in claim 1 is the hair coloring preparation composition of dyestuff with the henna pollen, it is characterized in that, the color matching composition in its dye formulations is the alizarin red pigment, and its percentage by weight is 1.5-4.5%.
4, as claimed in claim 1 is the hair coloring preparation composition of dyestuff with the henna pollen, it is characterized in that, the color matching composition in its dye formulations is a copper sulfate, and its percentage by weight is 2.5-5.0%.
CN 200410096854 2004-12-08 2004-12-08 Hair dye composition using henna pollen as dye Pending CN1633965A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102058503A (en) * 2009-11-12 2011-05-18 北京世纪博康医药科技有限公司 Henna natural plant hair dye
CN103919705A (en) * 2014-04-29 2014-07-16 张显文 Composite hair dyeing powder prepared from indigofera tinctoria plant

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102058503A (en) * 2009-11-12 2011-05-18 北京世纪博康医药科技有限公司 Henna natural plant hair dye
CN103919705A (en) * 2014-04-29 2014-07-16 张显文 Composite hair dyeing powder prepared from indigofera tinctoria plant

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