CN115006327B - Hair dye without hair care after dyeing and preparation method thereof - Google Patents
Hair dye without hair care after dyeing and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a hair dye without hair washing and hair care after hair dyeing and a preparation method thereof, wherein the hair dye comprises an agent A and an agent B; the agent A comprises: sodium laureth sulfate, cocamidopropyl betaine, oleic acid, propylene glycol, p-phenylenediamine, sodium laurosulfate, ammonium hydroxide, hydrolyzed wheat protein, polydimethylsiloxane, ascorbic acid, sodium chloride, sodium sulfite, resorcinol, m-aminophenol, disodium EDTA, guar hydroxypropyl trimethylammonium chloride, and the balance water; the agent B comprises: hydrogen peroxide, stearic acid, propylene glycol, glyceryl stearate, cetostearyl alcohol polyether-20, stearyl alcohol, hydroxyethyldiphosphate, disodium hydrogen phosphate, disodium EDTA, and the balance water. The invention can finish the hair washing, dyeing and caring in one step, the duration time of the whole process is shortened, and the efficiency is higher.
Description
Technical Field
The present invention relates to the field of cosmetics. More particularly, the present invention relates to a method for preparing a hair dye without the need for shampooing and caring hair after dyeing.
Background
Hair dyes are a type of cosmetic that stains hair. The existing hair dye generally needs to be used for washing hair and protecting hair after dyeing hair, and the whole process lasts for a long time.
Disclosure of Invention
An object of the present invention is to provide a hair dye which does not require hair washing and hair care after dyeing, and which can shorten the duration of the whole process of hair washing, hair dyeing and hair care in one step and has higher efficiency.
The invention also aims to provide a preparation method of the hair dye without hair washing and hair care after hair dyeing, and the cyclodextrin inclusion compound of the curcumin derivative, the cyclodextrin inclusion compound of the plant essential oil and the mixed liquid are introduced, so that the components embedded by the cyclodextrin in the curcumin derivative, the plant essential oil and the bamboo vinegar liquid can be slowly released, and the effects of bacteriostasis, itching relieving, scalp moistening, fragrance lasting, scalp water-oil balance and free radical damage reduction are achieved.
To achieve these objects and other advantages and in accordance with the purpose of the invention, there is provided a hair dye which does not require hair washing and hair care after dyeing, comprising an agent A and an agent B in a mass ratio of 1:1;
the agent A comprises: 10-15% of sodium laureth sulfate, 3-8% of cocoamidopropyl betaine, 3-5% of oleic acid, 2-4% of propylene glycol, 1.5-2.5% of p-phenylenediamine, 0.2-0.5% of sodium laurylsulfate, 2-7% of ammonium hydroxide, 0.1-0.5% of hydrolyzed wheat protein, 0.1-0.5% of polydimethylsiloxane, 0.2-1.0% of ascorbic acid, 0.1-1.0% of sodium chloride, 0.2-0.5% of sodium sulfite, 0.2-0.8% of resorcinol, 0.1-0.5% of m-aminophenol, 0.1-0.2% of EDTA disodium, 0.1-0.2% of guar hydroxypropyl trimethylammonium chloride and the balance of water;
the agent B comprises: 3-6% of hydrogen peroxide, 4-8% of stearic acid, 2-4% of propylene glycol, 1-2% of glyceryl stearate, 2-4% of cetostearyl alcohol polyether, 1-2% of stearyl alcohol, 0.5-3% of hydroxyethyldiphosphate, 0.1-0.5% of disodium hydrogen phosphate, 0.1-0.2% of EDTA disodium and the balance of water.
Preferably, in the hair dye without hair washing and hair care after hair dyeing, the agent A further comprises: cyclodextrin 0.6-1.2%, curcumin derivative 0.3-0.5%, refined bamboo vinegar 0.1-0.5% and plant essential oil 0.01-0.1%.
Preferably, in the hair dye without hair washing and hair care after hair dyeing, the agent A further comprises: cyclodextrin 0.9%, curcumin derivative 0.4%, refined bamboo vinegar 0.3% and plant essential oil 0.05%.
Preferably, in the hair dye which does not require hair washing and hair care after the hair dyeing, the curcumin derivative is 1, 7-bis (p- (4-phenylbenzyloxy) phenyl) -1, 6-heptadiene-3, 5-dione.
Preferably, in the hair dye without hair washing and hair care after hair dyeing, the plant essential oil is one or more of chamomile essential oil, tea tree essential oil, dendrobium essential oil, bamboo leaf essential oil, pine needle essential oil, benzoin essential oil and rose essential oil.
Preferably, in the hair dye which does not need to be washed and hair care after dyeing, the cyclodextrin is gamma-cyclodextrin.
Preferably, in the hair dye without hair washing and hair care after hair dyeing, the preparation method of the agent A comprises the following steps:
adding sodium laureth sulfate, cocamidopropyl betaine, sodium laurylsulfate, EDTA disodium, ascorbic acid, sodium sulfite and propylene glycol into water at 70-85 ℃, stirring until the sodium laurylsulfate, the EDTA disodium, the ascorbic acid, the sodium sulfite and the propylene glycol are completely dissolved, cooling to 50-60 ℃, adding p-phenylenediamine, resorcinol, m-aminophenol, oleic acid, hydrolyzed wheat protein, polydimethylsiloxane and guar gum hydroxypropyl trimethyl ammonium chloride, stirring uniformly, cooling to below 45 ℃, adding ammonium hydroxide to adjust the pH value to 8.5-10.5, and adjusting the viscosity of the sodium chloride to 5000-15000cps to obtain an A agent;
the preparation method of the agent B comprises the following steps:
heating water, propylene glycol, EDTA disodium, stearic acid, stearyl alcohol, cetostearyl alcohol polyether and glyceryl stearate to 70-85deg.C, emulsifying in an emulsifying pot, cooling to below 45deg.C, and adding hydroxyethyldiphosphate, disodium hydrogen phosphate and hydrogen peroxide to obtain agent B.
The preparation method of the hair dye without hair washing and hair care after hair dyeing comprises the following steps:
dissolving 1/3 cyclodextrin in water with the weight being 20-30 times of that of the cyclodextrin, uniformly stirring, then adding the curcumin derivative, and uniformly stirring to obtain a cyclodextrin inclusion compound of the curcumin derivative;
dissolving 1/3 of cyclodextrin in water with the weight being 20-30 times of that of the cyclodextrin, uniformly stirring, adding the plant essential oil, and uniformly stirring to obtain a cyclodextrin inclusion compound of the plant essential oil;
step three, 1/3 cyclodextrin is dissolved in water with the weight being 20-30 times of that of the cyclodextrin, and the mixture is stirred uniformly, then refined bamboo vinegar liquid is added, and the mixture is stirred uniformly to obtain a mixed solution;
adding the mixed solution, the cyclodextrin inclusion compound of the curcumin derivative, the cyclodextrin inclusion compound of the plant essential oil, sodium laureth sulfate, cocamidopropyl betaine, sodium laurylsulfate, disodium EDTA, ascorbic acid, sodium sulfite and propylene glycol into the residual water, stirring until the mixed solution is completely dissolved, cooling to 50-60 ℃, adding p-phenylenediamine, resorcinol, m-aminophenol, oleic acid, hydrolyzed wheat protein, polydimethylsiloxane and guar gum hydroxypropyl trimethyl ammonium chloride, stirring uniformly, cooling to below 45 ℃, adding ammonium hydroxide to adjust the pH value to 8.5-10.5, and adjusting the viscosity of the sodium chloride to 5000-15000cps to obtain the agent A.
The invention at least comprises the following beneficial effects:
according to the invention, the curcumin derivative with poor water solubility is embedded by utilizing the characteristics of outer hydrophilicity and inner hydrophobicity of cyclodextrin, so that the curcumin derivative can be utilized, and the antibacterial effect is more durable, thereby playing a role in long-time bacteriostasis and itching relieving.
The cyclodextrin is used for embedding the plant essential oil, so that the plant essential oil can be slowly released, and the effects of long-acting scalp moistening, long-lasting fragrance retention of hair and water-oil balance of scalp are realized.
The cyclodextrin is used for embedding the active ingredients in the bamboo vinegar, so that the active ingredients in the bamboo vinegar can be slowly released, thereby playing roles in long-time bacteriostasis, itching relieving and oxidation resistance and reducing the damage of free radicals to hair.
After the hair is dyed and cleaned by clear water, substances adsorbed and remained on the hair, such as a hair conditioner, and embedded curcumin derivatives, plant essential oil and bamboo vinegar are used cooperatively to play a role in nourishing and protecting the hair, so that the hair care is not needed.
Additional advantages, objects, and features of the invention will be set forth in part in the description which follows and in part will become apparent to those having ordinary skill in the art upon examination of the following or may be learned from practice of the invention.
Detailed Description
The present invention is described in further detail below with reference to examples to enable those skilled in the art to practice the same by referring to the description.
The experimental methods described in the following embodiments are conventional methods unless otherwise indicated, and the reagents and materials are commercially available.
Example 1
The invention provides a hair dye without hair washing and hair care after hair dyeing, which comprises an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1;
the agent A comprises: 10% of sodium laureth sulfate, 3% of cocoamidopropyl betaine, 3% of oleic acid, 2-4% of propylene glycol, 1.5% of p-phenylenediamine, 0.2% of sodium laurylsulfate, 2% of ammonium hydroxide, 0.1% of hydrolyzed wheat protein, 0.1% of polydimethylsiloxane, 0.2% of ascorbic acid, 0.1% of sodium chloride, 0.2% of sodium sulfite, 0.2% of resorcinol, 0.1% of m-aminophenol, 0.1% of disodium EDTA, 0.1% of guar hydroxypropyl trimethylammonium chloride and the balance of water;
the agent B comprises: 3% of hydrogen peroxide, 4% of stearic acid, 2% of propylene glycol, 1% of glycerol stearate, 2% of cetostearyl alcohol polyether-20%, 1% of stearyl alcohol, 0.5% of hydroxyethyldiphosphate, 0.1% of disodium hydrogen phosphate, 0.1% of EDTA and the balance of water.
The components of the agent A act:
water: solvent(s)
Sodium laureth sulfate, cocamidopropyl betaine: cleaning agent
Sodium lauryl sulfate: foaming agent
Para-phenylenediamine, resorcinol, meta-aminophenol: hair dye (color adjustable, black)
Propylene glycol: humectant type
Ammonium hydroxide: PH regulator
Ascorbic acid (vitamin C), sodium sulfite: antioxidant agent
Disodium EDTA: chelating agent
Sodium chloride: thickening agent
The balance of: a hair conditioner.
The components of the agent B act:
water: solvent(s)
Propylene glycol: humectant type
Cetostearyl alcohol polyether-20, glycerol stearate: emulsifying agent
Stearic acid, stearyl alcohol: grease and oil
Disodium EDTA: chelating agent
Hydroxyethyldiphosphate+disodium hydrogen phosphate: pH adjusting buffer system
Hydrogen peroxide: an oxidizing agent.
The formula contains shampoo raw materials, hair dyeing raw materials and hair care raw materials, and the effects of the shampoo raw materials, the hair dyeing raw materials and the hair care raw materials are coordinated and maximized through the mutual adjustment of the components of each formula, so that the three effects of shampoo, hair dyeing and hair care are simultaneously exerted in one formula.
The using method comprises the following steps: equal amount of A, B agent is directly applied to hair after the palm is uniformly mixed, and the hair is washed clean with clear water after 10-15min of kneading.
In the hair dye without hair washing and hair care after hair dyeing, the preparation method of the agent A comprises the following steps:
adding sodium laureth sulfate, cocamidopropyl betaine, sodium laurylsulfate, EDTA disodium, ascorbic acid, sodium sulfite and propylene glycol into water at 70 ℃, stirring until the mixture is completely dissolved, cooling to 50 ℃, adding p-phenylenediamine, resorcinol, m-aminophenol, oleic acid, hydrolyzed wheat protein, polydimethylsiloxane and guar gum hydroxypropyl trimethyl ammonium chloride, stirring uniformly, cooling to below 45 ℃, adding ammonium hydroxide to adjust the pH value to 8.5, and adjusting the viscosity of the mixture to 5000cps by sodium chloride to obtain the agent A.
The preparation method of the agent B comprises the following steps:
heating water, propylene glycol, EDTA disodium, stearic acid, stearyl alcohol, cetostearyl alcohol polyether and glyceryl stearate to 70 ℃, emulsifying in an emulsifying pot, cooling to below 45 ℃, and adding hydroxyethyldiphosphate, disodium hydrogen phosphate and hydrogen peroxide to obtain the agent B.
Example 2
The invention provides a hair dye without hair washing and hair care after hair dyeing, which comprises an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1;
the agent A comprises: 12% of sodium laureth sulfate, 5% of cocoamidopropyl betaine, 4% of oleic acid, 3% of propylene glycol, 2% of p-phenylenediamine, 0.4% of sodium laurylsulfate, 5% of ammonium hydroxide, 0.3% of hydrolyzed wheat protein, 0.3% of polydimethylsiloxane, 0.6% of ascorbic acid, 0.5% of sodium chloride, 0.4% of sodium sulfite, 0.5% of resorcinol, 0.3% of m-aminophenol, 0.15% of disodium EDTA, 0.15% of guar hydroxypropyl trimethylammonium chloride and the balance of water;
the agent B comprises: 4.5% of hydrogen peroxide, 6% of stearic acid, 3% of propylene glycol, 1.5% of glyceryl stearate, 20% of cetostearyl alcohol polyether, 1.5% of stearyl alcohol, 1.7% of oxyethyl diphosphate, 0.3% of disodium hydrogen phosphate, 0.15% of EDTA disodium and the balance of water.
In the hair dye without hair washing and hair care after hair dyeing, the preparation method of the agent A comprises the following steps:
adding sodium laureth sulfate, cocamidopropyl betaine, sodium laurylsulfate, EDTA disodium, ascorbic acid, sodium sulfite and propylene glycol into water at 78 ℃, stirring until the mixture is completely dissolved, cooling to 55 ℃, adding p-phenylenediamine, resorcinol, m-aminophenol, oleic acid, hydrolyzed wheat protein, polydimethylsiloxane and guar gum hydroxypropyl trimethyl ammonium chloride, stirring uniformly, cooling to below 45 ℃, adding ammonium hydroxide to adjust the pH value to 9.5, and adjusting the viscosity of the mixture to 10000cps by sodium chloride to obtain the agent A.
The preparation method of the agent B comprises the following steps:
heating water, propylene glycol, EDTA disodium, stearic acid, stearyl alcohol, cetostearyl alcohol polyether and glyceryl stearate to 78 ℃, emulsifying in an emulsifying pot, cooling to below 45 ℃, and adding hydroxyethyldiphosphate, disodium hydrogen phosphate and hydrogen peroxide to obtain the agent B.
Example 3
The invention provides a hair dye without hair washing and hair care after hair dyeing, which comprises an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1;
the agent A comprises: 15% of sodium laureth sulfate, 8% of cocoamidopropyl betaine, 5% of oleic acid, 4% of propylene glycol, 2.5% of p-phenylenediamine, 0.5% of sodium laurylsulfate, 7% of ammonium hydroxide, 0.5% of hydrolyzed wheat protein, 0.5% of polydimethylsiloxane, 1.0% of ascorbic acid, 1.0% of sodium chloride, 0.5% of sodium sulfite, 0.8% of resorcinol, 0.5% of m-aminophenol, 0.2% of disodium EDTA, 0.2% of guar hydroxypropyl trimethylammonium chloride and the balance of water;
the agent B comprises: 6% of hydrogen peroxide, 8% of stearic acid, 4% of propylene glycol, 2% of glycerol stearate, 20% of cetostearyl alcohol polyether, 2% of stearyl alcohol, 3% of hydroxyethyldiphosphate, 0.5% of disodium hydrogen phosphate, 0.2% of EDTA disodium and the balance of water.
In the hair dye without hair washing and hair care after hair dyeing, the preparation method of the agent A comprises the following steps:
adding sodium laureth sulfate, cocamidopropyl betaine, sodium laurylsulfate, EDTA disodium, ascorbic acid, sodium sulfite and propylene glycol into water at 85 ℃, stirring until the mixture is completely dissolved, cooling to 60 ℃, adding p-phenylenediamine, resorcinol, m-aminophenol, oleic acid, hydrolyzed wheat protein, polydimethylsiloxane and guar gum hydroxypropyl trimethyl ammonium chloride, stirring uniformly, cooling to below 45 ℃, adding ammonium hydroxide to adjust the pH value to 10.5, and adjusting the viscosity of the mixture to 15000cps by sodium chloride to obtain the agent A.
The preparation method of the agent B comprises the following steps:
heating water, propylene glycol, EDTA disodium, stearic acid, stearyl alcohol, cetostearyl alcohol polyether and glyceryl stearate to 85 ℃, emulsifying in an emulsifying pot, cooling to below 45 ℃, and adding hydroxyethyldiphosphate, disodium hydrogen phosphate and hydrogen peroxide to obtain the agent B.
Example 4
The invention provides a hair dye without hair washing and hair care after hair dyeing, which comprises an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1, a step of;
the agent A comprises: 12% of sodium laureth sulfate, 5% of cocoamidopropyl betaine, 4% of oleic acid, 3% of propylene glycol, 2% of p-phenylenediamine, 0.4% of sodium laurylsulfate, 5% of ammonium hydroxide, 0.3% of hydrolyzed wheat protein, 0.3% of polydimethylsiloxane, 0.6% of ascorbic acid, 0.5% of sodium chloride, 0.4% of sodium sulfite, 0.5% of resorcinol, 0.3% of m-aminophenol, 0.15% of disodium EDTA, 0.15% of guar hydroxypropyl trimethylammonium chloride and the balance of water;
the agent B comprises: 4.5% of hydrogen peroxide, 6% of stearic acid, 3% of propylene glycol, 1.5% of glyceryl stearate, 20% of cetostearyl alcohol polyether, 1.5% of stearyl alcohol, 1.7% of oxyethyl diphosphate, 0.3% of disodium hydrogen phosphate, 0.15% of EDTA disodium and the balance of water.
In the hair dye without hair washing and hair care after hair dyeing, the agent A further comprises: cyclodextrin 0.9%, curcumin derivative 0.4%, refined bamboo vinegar 0.3% and plant essential oil 0.05%.
In the hair dye which does not need to be washed and hair care after hair dyeing, the curcumin derivative is 1, 7-bis (p- (4-phenylbenzyloxy) phenyl) -1, 6-heptadiene-3, 5-dione.
In the hair dye without hair washing and hair care after hair dyeing, the plant essential oil is formed by mixing chamomile essential oil, tea tree essential oil, dendrobium essential oil, bamboo leaf essential oil, pine needle essential oil, benzoin essential oil and rose essential oil according to the mass ratio of 1:1:1:1:1:1:1.
In the hair dye without hair washing and hair care after hair dyeing, the cyclodextrin is gamma-cyclodextrin.
The preparation method of the hair dye without hair washing and hair care after hair dyeing comprises the following steps:
step one, dissolving 1/3 cyclodextrin in water with the weight being 25 times of that of the cyclodextrin, uniformly stirring, then adding the curcumin derivative, and uniformly stirring to obtain a cyclodextrin inclusion compound of the curcumin derivative; according to the invention, the curcumin derivative with poor water solubility is embedded by utilizing the characteristics of outer hydrophilicity and inner hydrophobicity of cyclodextrin, so that the curcumin derivative can be utilized, and the antibacterial effect is more durable, thereby playing a role in long-time bacteriostasis and itching relieving.
Dissolving 1/3 of cyclodextrin in water with the weight being 25 times of that of the cyclodextrin, uniformly stirring, adding the plant essential oil, and uniformly stirring to obtain a cyclodextrin inclusion compound of the plant essential oil; the cyclodextrin is used for embedding the plant essential oil, so that the taste of the plant essential oil can be reduced, and the plant essential oil can be slowly released, so that the effects of long-acting scalp moistening, long-lasting fragrance of hair and water-oil balance of scalp are realized.
Step three, 1/3 cyclodextrin is dissolved in water with the weight being 25 times of that of the cyclodextrin, and the mixture is stirred uniformly, then refined bamboo vinegar liquid is added, and the mixture is stirred uniformly to obtain a mixed solution; the cyclodextrin is used for embedding the active ingredients in the bamboo vinegar, so that the taste of the bamboo vinegar can be reduced, and the active ingredients in the bamboo vinegar can be slowly released, so that the effects of long-time bacteriostasis, itching relieving and oxidization resistance are achieved, and the damage of free radicals to hair is reduced.
And fourthly, adding the mixed solution, the cyclodextrin inclusion compound of the curcumin derivative, the cyclodextrin inclusion compound of the plant essential oil, sodium laureth sulfate, cocamidopropyl betaine, sodium laurylsulfate, disodium EDTA, ascorbic acid, sodium sulfite and propylene glycol into the residual water, stirring until the mixed solution is completely dissolved, cooling to 55 ℃, adding p-phenylenediamine, resorcinol, m-aminophenol, oleic acid, hydrolyzed wheat protein, polydimethylsiloxane and guar gum hydroxypropyl trimethyl ammonium chloride, stirring uniformly, cooling to below 45 ℃, adding ammonium hydroxide to adjust the pH value to 9.5, and adjusting the viscosity of the sodium chloride to 10000cps to obtain the agent A.
The preparation method of the agent B comprises the following steps:
heating water, propylene glycol, EDTA disodium, stearic acid, stearyl alcohol, cetostearyl alcohol polyether and glyceryl stearate to 78 ℃, emulsifying in an emulsifying pot, cooling to below 45 ℃, and adding hydroxyethyldiphosphate, disodium hydrogen phosphate and hydrogen peroxide to obtain the agent B.
The formula contains shampoo raw materials, hair dyeing raw materials and hair care raw materials, and the effects of the shampoo raw materials, the hair dyeing raw materials and the hair care raw materials are coordinated and maximized through the mutual adjustment of the components of each formula, so that the three effects of shampoo, hair dyeing and hair care are simultaneously exerted in one formula.
The using method comprises the following steps: equal amount of A, B agent is directly applied to hair after the palm is uniformly mixed, and the hair is washed clean with clear water after 10-15min of kneading.
After the hair is dyed and cleaned by clear water, substances adsorbed and remained on the hair, such as a hair conditioner, and embedded curcumin derivatives, plant essential oil and bamboo vinegar are used cooperatively to play a role in nourishing and protecting the hair, so that the hair care is not needed.
Comparative example 1
Unlike example 4, in the hair dye without shampoo and hair care after dyeing, the agent a further comprises: cyclodextrin 0.9%, curcumin derivative 0.3%, refined bamboo vinegar 0.2% and plant essential oil 0.05%.
Comparative example 2
Unlike example 4, in the hair dye without shampoo and hair care after dyeing, the agent a further comprises: cyclodextrin 0.9%, curcumin derivative 0.3%, refined bamboo vinegar 0.3% and plant essential oil 0.05%.
Comparative example 3
Unlike example 4, in the hair dye without shampoo and hair care after dyeing, the agent a further comprises: cyclodextrin 0.9%, curcumin derivative 0.4%, refined bamboo vinegar 0.2% and plant essential oil 0.05%.
Comparative example 4
Different from example 4, the method comprises the steps of adding cyclodextrin, curcumin derivative, refined bamboo vinegar, plant essential oil, sodium laureth sulfate, cocamidopropyl betaine, sodium laurylsulfate, disodium EDTA, ascorbic acid, sodium sulfite and propylene glycol into water in the fourth step, stirring until the mixture is completely dissolved, cooling to 55 ℃, adding p-phenylenediamine, resorcinol, m-aminophenol, oleic acid, hydrolyzed wheat protein, polydimethylsiloxane and guar gum hydroxypropyl trimethyl ammonium chloride, stirring uniformly, cooling to below 45 ℃, adding ammonium hydroxide to adjust the pH value to 9.5, and adjusting the viscosity of the sodium chloride to 10000cps, thereby obtaining the agent A. Otherwise, the same as in example 4 was used.
Experiment 1
Preparing a DPPH solution with the concentration of 0.1mmol/L by absolute ethyl alcohol, and preserving the solution in a dark place; 2mL of the test sample solution and 2mL of the 0.1mmol/L DPPH solution were added to the same test tube, the mixture was shaken well, allowed to stand in the dark at room temperature for 30 minutes, the absorbance An thereof was measured at a wavelength of 540nm by An ultraviolet spectrophotometer, and 2mL of the 0.1mmol/L DPPH solution+2 mL of deionized water was used as a reference reagent A0. The absorbance change was measured and ESC= [1-An/A0 ]. Times.100% (N. Gtoreq.1, N. Epsilon. N+), and the results are shown in Table 1. Wherein the test samples were respectively a mixture prepared in the same manner as in example 4 and comparative examples 1 to 3, a cyclodextrin inclusion compound of a curcumin derivative, a composition of a cyclodextrin inclusion compound of a plant essential oil, and a composition of cyclodextrin, a curcumin derivative, a refined bamboo vinegar, and a plant essential oil in the same amounts as in example 4.
Experiment 2
The test was performed with 100 persons, 50 women, 50 men, and ages between 20 and 40, the persons were randomly divided into five groups of 20 persons each, and 10 persons each were dyed once using the products prepared in example 4, comparative examples 1 to 4, repeated eight months later, and three times total dyed, and the itching conditions on the day, the next day, and the third day were scored after each dyeing, and the scores of each group were averaged to obtain the average value of the itching relieving scores of the above five application examples, and the results are shown in table 1. Wherein, no itching is 5 minutes, local itching is sometimes 4 minutes, local itching is often 3 minutes, head itching is full of 2 minutes, and head itching is seriously full of 1 minute.
Experiment 3
The wash fastness and rinse fastness were tested.
Fastness to washing: and (3) cleaning/drying the white hair after complete blackening by using commercially available cleaning silicone oil-free shampoo, and observing the chromaticity of the hair bundle after cleaning after circulation for 20 times, wherein the higher the level is, the darker the color is and the higher the color fastness is after dyeing.
Fastness to rinsing: common commercial Yumei bleaching powder and 6-degree dioxygen milk are adopted, and the volume ratio of the Yumei bleaching powder to the 6-degree dioxygen milk is 1:1, uniformly smearing the mixture on the hair bundles dyed in the same period, cleaning and drying after 5 minutes, observing the chromaticity of the hair bundles after rinsing, dividing the chromaticity into 1-5 grades, wherein the darker the grade is, the higher the color is.
TABLE 1 free radical scavenging ability, antipruritic score and fastness results
As is clear from table 1, in comparative example 1, the free radical scavenging ability of the composition was reduced and the antipruritic score was reduced after the hair dye was applied by reducing the amounts of the curcumin derivative and the purified bamboo vinegar as compared with example 4. Compared with example 2 and example 4, the composition has less change in radical scavenging ability by reducing the amount of curcumin derivative, and the antipruritic score after application of hair dye is reduced. Compared with the example 3 and the example 4, the free radical scavenging ability of the composition is reduced more after only reducing the dosage of the refined bamboo vinegar, and the itching relieving score after the hair dye is used is still higher. Compared with the example 4, the effective components in the curcumin derivative, the plant essential oil and the bamboo vinegar are not embedded, the free radical scavenging capability of the composition is higher, but the itching relieving score after the hair dye is used is lower, which indicates that the cyclodextrin is used for embedding, so that the effective components can be slowly released, and the long-acting antibacterial and itching relieving effects are achieved. In conclusion, the method of the embodiment 4 can ensure that partial components are slowly released after dyeing, and simultaneously ensure that the capability of removing scalp free radicals is strong, and the antibacterial and antipruritic effects are good.
Although embodiments of the present invention have been disclosed above, it is not limited to the details and embodiments shown, it is well suited to various fields of use for which the invention is suited, and further modifications may be readily made by one skilled in the art, and the invention is therefore not to be limited to the particular details and examples shown and described herein, without departing from the general concepts defined by the claims and the equivalents thereof.
Claims (5)
1. The hair dye without hair care after hair dyeing is characterized by comprising an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1;
the agent A comprises: 10-15% of sodium laureth sulfate, 3-8% of cocoamidopropyl betaine, 3-5% of oleic acid, 2-4% of propylene glycol, 1.5-2.5% of p-phenylenediamine, 0.2-0.5% of sodium laurylsulfate, 2-7% of ammonium hydroxide, 0.1-0.5% of hydrolyzed wheat protein, 0.1-0.5% of polydimethylsiloxane, 0.2-1.0% of ascorbic acid, 0.1-1.0% of sodium chloride, 0.2-0.5% of sodium sulfite, 0.2-0.8% of resorcinol, 0.1-0.5% of m-aminophenol, 0.1-0.2% of EDTA disodium, 0.1-0.2% of guar hydroxypropyltrimethyl ammonium chloride, 0.9% of cyclodextrin, 0.4% of curcumin derivative, 0.3% of refined bamboo vinegar, 0.05% of plant essential oil and the balance of water;
the agent B comprises: 3-6% of hydrogen peroxide, 4-8% of stearic acid, 2-4% of propylene glycol, 1-2% of glyceryl stearate, 2-4% of cetostearyl alcohol polyether, 1-2% of stearyl alcohol, 0.5-3% of hydroxyethyldiphosphate, 0.1-0.5% of disodium hydrogen phosphate, 0.1-0.2% of EDTA disodium and the balance of water.
2. The hair dye without hair care after dyeing according to claim 1, wherein the curcumin derivative is 1, 7-bis (p- (4-phenylbenzyloxy) phenyl) -1, 6-heptadiene-3, 5-dione.
3. The hair dye without hair care after hair dyeing according to claim 1, wherein the plant essential oil is one or more of chamomile essential oil, tea tree essential oil, dendrobium essential oil, bamboo leaf essential oil, pine needle essential oil, benzoin essential oil and rose essential oil.
4. The post-hair dye hair care-free hair dye according to claim 1, wherein the cyclodextrin is gamma-cyclodextrin.
5. The hair dye without hair care after dyeing according to claim 1, wherein the preparation method of the agent A is as follows:
dissolving 1/3 cyclodextrin in water with the weight being 20-30 times of that of the cyclodextrin, uniformly stirring, then adding the curcumin derivative, and uniformly stirring to obtain a cyclodextrin inclusion compound of the curcumin derivative;
dissolving 1/3 of cyclodextrin in water with the weight being 20-30 times of that of the cyclodextrin, uniformly stirring, adding the plant essential oil, and uniformly stirring to obtain a cyclodextrin inclusion compound of the plant essential oil;
step three, 1/3 cyclodextrin is dissolved in water with the weight being 20-30 times of that of the cyclodextrin, and the mixture is stirred uniformly, then refined bamboo vinegar liquid is added, and the mixture is stirred uniformly to obtain a mixed solution;
adding the mixed solution, the cyclodextrin inclusion compound of the curcumin derivative, the cyclodextrin inclusion compound of the plant essential oil, sodium laureth sulfate, cocamidopropyl betaine, sodium laurylsulfate, disodium EDTA, ascorbic acid, sodium sulfite and propylene glycol into the residual water at 70-85 ℃, stirring until the mixed solution is completely dissolved, cooling to 50-60 ℃, adding p-phenylenediamine, resorcinol, m-aminophenol, oleic acid, hydrolyzed wheat protein, polydimethylsiloxane and guar gum hydroxypropyl trimethyl ammonium chloride, stirring uniformly, cooling to 45 ℃ or below, adding ammonium hydroxide to adjust the pH value to 8.5-10.5, and adjusting the viscosity of sodium chloride to 5000-15000cps to obtain an agent A;
the preparation method of the agent B comprises the following steps:
heating water, propylene glycol, EDTA disodium, stearic acid, stearyl alcohol, cetostearyl alcohol polyether and glyceryl stearate to 70-85deg.C, emulsifying in an emulsifying pot, cooling to below 45deg.C, and adding hydroxyethyldiphosphate, disodium hydrogen phosphate and hydrogen peroxide to obtain agent B.
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| CN114425027A (en) * | 2022-01-17 | 2022-05-03 | 广州市芊彩化妆品有限公司 | Hair dye and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113730274A (en) * | 2021-09-09 | 2021-12-03 | 上海章华保健化妆品有限公司 | Multifunctional fast black dyeing gel and preparation method thereof |
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| EP0469232A1 (en) * | 1990-08-03 | 1992-02-05 | Kabushiki Kaisha Japan Happy | Materials for hair cosmetics and hair cosmetics |
| CN1089135A (en) * | 1992-09-29 | 1994-07-13 | 亨克尔两合股份公司 | Agent for treatment of hair |
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