CN103271844A - Hair dye taking 2,5-diaminophenylethanol sulfate as intermediate - Google Patents
Hair dye taking 2,5-diaminophenylethanol sulfate as intermediate Download PDFInfo
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- CN103271844A CN103271844A CN2013102103756A CN201310210375A CN103271844A CN 103271844 A CN103271844 A CN 103271844A CN 2013102103756 A CN2013102103756 A CN 2013102103756A CN 201310210375 A CN201310210375 A CN 201310210375A CN 103271844 A CN103271844 A CN 103271844A
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Abstract
The invention relate to a formula of a two-form permanent hair dye taking 2,5-diaminophenylethanol sulfate as an intermediate. The hair dye provided by the invention is composed of an agent A and an agent B, wherein the agent A comprises hexadecanol, oleic acid, wool fat, monostearin, propylene glycol, ethanol amine, 2,5-diaminophenylethanol sulfate, hydroxypropyl methyl cellulose, sodium sulfite, ascorbic acid, EDTA (ethylene diamine tetraacetic acid) disodium, 4-amino-m-cresol or 5-amino-o-cresol or 6-amino-m-cresol and water; and the agent B comprises hydrogen peroxide, propylene glycol, stearic acid, stearyl alcohol, monostearin, cetostearyl alcohol polyether-20, dimethicone, phosphoric acid, EDTA disodium, phenacetin and water. According to the hair dye provided by the invention, the intermediate 2,5-diaminophenylethanol sulfate has low toxicity, and white hair can be dyed to a fashionable hair color purple or light brown by adding a small amount of the hair dye.
Description
Technical field
The present invention relates to a kind of prescription of two-form Permanent Hair Dyeing Agent, belong to cosmetics hair product technical field.
Background technology
Paste two-form Permanent Hair Dyeing Agent because of its Color is good, tone range is wide, longer duration, be easy to carry, advantage such as easy to use is the main flow of commercially available hair dye always, yet contain p-phenylenediamine (PPD) mostly in the Permanent Hair Dyeing Agent that existing market is sold, studies show that p-phenylenediamine (PPD) has side effect such as acute toxicity, sensitization and potential carcinogenecity.
Summary of the invention
The objective of the invention is with 2 of low toxicity, 5-diamino benzene ethanol sulfate substitutes the p-phenylenediamine (PPD) of traditional acute toxicity, thereby makes safer effective oxide hair dye.
Concrete technical scheme of the present invention:
2,5-diamino benzene ethanol sulfate is that the hair dye of intermediate is the two-form oxide hair dye, constitutes by dying cream base matter (A agent) and oxidized color developing agent (B agent).The A agent comprises mastic substrate and dyestuff substrate, the prescription of mastic substrate is: following content of material is mass fraction, hexadecanol 8-12%, oleic acid 5-10%, lanoline 2-4%, monoglyceride 2-4%, propylene glycol 8-12%, ethanolamine 0.5-2%, hydroxypropyl emthylcellulose 0.5-1%, sodium sulfite 0.5-1%, ascorbic acid 0.1-0.5%, EDTA disodium 0.05-0.1%, water to 100%.
Dyestuff substrate is made up of dyestuff intermediate and coupling agent in the A agent, its prescription is: following content of material is mass fraction, dyestuff intermediate 2, the amino metacresol 0.03125-0.5% of 5-diamino benzene ethanol sulfate 0.5-2%, coupling agent 4-or the amino orthoresol 0.03125-0.5% of 5-or the amino metacresol 0.03125-0.5% of 6-.
B agent oxidative color-developing prescription: following content of material is mass fraction, and hydrogen peroxide 4-6%, propylene glycol 8-12%, stearic acid 5-8%, stearyl alcohol 8-12%, monoglyceride 2-4%, ceteareth-202-4%, dimethicone 0.5-2%, phosphoric acid are regulated PH2-5, EDTA disodium 0.05-0.1%, an amount of, the water to 100% of Phenacetin.
The compare advantage of prior art and product of the present invention is:
Among the present invention, substitute the pH value that ammonia is regulated substrate with ethanolamine, thereby reduced stimulation and corrosiveness to eyes, mucosa, skin and hair.
Among the present invention, substitute the p-phenylenediamine (PPD) of traditional acute toxicity with 2,5-diamino benzene ethanol sulfate.Studies show that in the construction unit of p-phenylenediamine (PPD) alkyl or the alkoxyl of introducing large volume, the anil that obtains can make its mutagenic activity weaken or disappears, and the principle of having hair dyed is constant.Therefore 2,5-diamino benzene ethanol sulfate has been improved hair dye on the basis that does not change Color as dyestuff intermediate safety.
The specific embodiment
With specific embodiment the present invention is further described below:
2,5-diamino benzene ethanol sulfate is that the hair dye of intermediate is the two-form oxide hair dye, constitutes by dying cream base matter (A agent) and oxidized color developing agent (B agent).The A agent comprises mastic substrate and dyestuff substrate, the prescription of mastic substrate is: following content of material is mass fraction, hexadecanol 8-12%, oleic acid 5-10%, lanoline 2-4%, monoglyceride 2-4%, propylene glycol 8-12%, ethanolamine 0.5-2%, hydroxypropyl emthylcellulose 0.5-1%, sodium sulfite 0.5-1%, ascorbic acid 0.1-0.5%, EDTA disodium 0.05-0.1%, water to 100%.
Dyestuff substrate is made up of dyestuff intermediate and coupling agent in the A agent, and its prescription is: following content of material is mass fraction,
Dyestuff intermediate 2, the amino metacresol 0.03125-0.5% of 5-diamino benzene ethanol sulfate 0.5-2%, coupling agent 4-or the amino orthoresol 0.03125-0.5% of 5-or the amino metacresol 0.03125-0.5% of 6-.
B agent oxidative color-developing prescription: following content of material is mass fraction, and hydrogen peroxide 15-20% (30% hydrogen peroxide), propylene glycol 8-12%, stearic acid 5-8%, stearyl alcohol 8-12%, monoglyceride 2-4%, ceteareth-202-4%, dimethicone 0.5-2%, phosphoric acid are regulated PH2-5, EDTA disodium 0.05-0.1%, an amount of, the water to 100% of Phenacetin.
Using method of the present invention:
Be with glove, after A agent and B agent mixed in equal amounts, evenly spread upon on the hair, dye 30 minutes under the room temperature after, water cleans up hair and gets final product.
Claims (1)
1. one kind 2,5-diamino benzene ethanol sulfate is that the hair dye of intermediate is the two-form oxide hair dye, and adding small amount of intermediate can be with poliosis purple, beige fashion color development; This hair dye claims A agent and oxidized color developing agent again by dying cream base matter, claims the B agent to constitute again; The mass fraction of each material of A agent is respectively: hexadecanol 8-12%, oleic acid 5-10%, lanoline 2-4%, monoglyceride 2-4%, propylene glycol 8-12%, ethanolamine 0.5-2%, 2,5-diamino benzene ethanol sulfate 0.5-2%, hydroxypropyl emthylcellulose 0.5-1%, sodium sulfite 0.5-1%, ascorbic acid 0.1-0.5%, the amino metacresol 0.03125-0.5% of EDTA disodium 0.05-0.1%, 4-or the amino orthoresol 0.03125-0.5% of 5-or the amino metacresol 0.03125-0.5% of 6-, water to 100%; The mass fraction of each material of B agent is hydrogen peroxide 4-6%, propylene glycol 8-12%, stearic acid 5-8%, stearyl alcohol 8-12%, monoglyceride 2-4%, ceteareth-202-4%, dimethicone 0.5-2%, phosphoric acid adjusting PH2-5, EDTA disodium 0.05-0.1%, an amount of, the water to 100% of Phenacetin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102103756A CN103271844A (en) | 2013-05-31 | 2013-05-31 | Hair dye taking 2,5-diaminophenylethanol sulfate as intermediate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2013102103756A CN103271844A (en) | 2013-05-31 | 2013-05-31 | Hair dye taking 2,5-diaminophenylethanol sulfate as intermediate |
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| CN103271844A true CN103271844A (en) | 2013-09-04 |
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| CN2013102103756A Pending CN103271844A (en) | 2013-05-31 | 2013-05-31 | Hair dye taking 2,5-diaminophenylethanol sulfate as intermediate |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103726347A (en) * | 2013-12-05 | 2014-04-16 | 安徽三喜针织有限公司 | Textile dye and preparation method thereof |
| US10588837B2 (en) * | 2016-02-29 | 2020-03-17 | Conopco, Inc. | Oxidative coloration of hair with reduced hair damage |
| CN111440077A (en) * | 2020-05-15 | 2020-07-24 | 上海舒尔发化妆品科技有限公司 | Synthesis method of 2, 5-diaminophenylethanol sulfate and application thereof in anti-allergic hair dye |
| CN115006327A (en) * | 2022-06-27 | 2022-09-06 | 浙江章华保健美发实业有限公司 | Hair dye without washing and caring hair after dyeing hair and preparation method thereof |
| CN117017809A (en) * | 2023-07-07 | 2023-11-10 | 珠海横琴一果投资合伙企业(有限合伙) | Dioxygen-free hair dye paste and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1171246A (en) * | 1997-08-26 | 1999-03-16 | Kao Corp | Hair-dyeing agent composition |
| CN101966138A (en) * | 2010-09-29 | 2011-02-09 | 广州温雅日用化妆品有限公司 | Method for curling and dyeing hair |
-
2013
- 2013-05-31 CN CN2013102103756A patent/CN103271844A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1171246A (en) * | 1997-08-26 | 1999-03-16 | Kao Corp | Hair-dyeing agent composition |
| CN101966138A (en) * | 2010-09-29 | 2011-02-09 | 广州温雅日用化妆品有限公司 | Method for curling and dyeing hair |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103726347A (en) * | 2013-12-05 | 2014-04-16 | 安徽三喜针织有限公司 | Textile dye and preparation method thereof |
| US10588837B2 (en) * | 2016-02-29 | 2020-03-17 | Conopco, Inc. | Oxidative coloration of hair with reduced hair damage |
| CN111440077A (en) * | 2020-05-15 | 2020-07-24 | 上海舒尔发化妆品科技有限公司 | Synthesis method of 2, 5-diaminophenylethanol sulfate and application thereof in anti-allergic hair dye |
| CN115006327A (en) * | 2022-06-27 | 2022-09-06 | 浙江章华保健美发实业有限公司 | Hair dye without washing and caring hair after dyeing hair and preparation method thereof |
| CN115006327B (en) * | 2022-06-27 | 2023-08-01 | 浙江章华保健美发实业有限公司 | Hair dye without hair care after dyeing and preparation method thereof |
| CN117017809A (en) * | 2023-07-07 | 2023-11-10 | 珠海横琴一果投资合伙企业(有限合伙) | Dioxygen-free hair dye paste and preparation method thereof |
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Application publication date: 20130904 |