CN108743481B - Walnut green husk black hair dye and preparation method thereof - Google Patents
Walnut green husk black hair dye and preparation method thereof Download PDFInfo
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- CN108743481B CN108743481B CN201810804198.7A CN201810804198A CN108743481B CN 108743481 B CN108743481 B CN 108743481B CN 201810804198 A CN201810804198 A CN 201810804198A CN 108743481 B CN108743481 B CN 108743481B
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- hair
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- green husk
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- 235000020234 walnut Nutrition 0.000 title claims abstract description 84
- 235000009496 Juglans regia Nutrition 0.000 title claims abstract description 80
- 239000010903 husk Substances 0.000 title claims abstract description 68
- 239000000118 hair dye Substances 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims description 31
- 240000007049 Juglans regia Species 0.000 title 1
- 210000004209 hair Anatomy 0.000 claims abstract description 148
- 241000758789 Juglans Species 0.000 claims abstract description 79
- 239000000975 dye Substances 0.000 claims abstract description 77
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 27
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 27
- 239000008367 deionised water Substances 0.000 claims description 27
- 229910021641 deionized water Inorganic materials 0.000 claims description 27
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 27
- 229940071826 hydroxyethyl cellulose Drugs 0.000 claims description 27
- 239000000284 extract Substances 0.000 claims description 25
- 239000002562 thickening agent Substances 0.000 claims description 23
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 22
- 239000003086 colorant Substances 0.000 claims description 22
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- 235000013824 polyphenols Nutrition 0.000 claims description 21
- 238000000605 extraction Methods 0.000 claims description 20
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 18
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 13
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 13
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 13
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 13
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 12
- 229920000053 polysorbate 80 Polymers 0.000 claims description 12
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Natural products SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 claims description 11
- 244000269722 Thea sinensis Species 0.000 claims description 11
- 239000011668 ascorbic acid Substances 0.000 claims description 11
- 235000010323 ascorbic acid Nutrition 0.000 claims description 11
- 229960005070 ascorbic acid Drugs 0.000 claims description 11
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 11
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 11
- 239000012670 alkaline solution Substances 0.000 claims description 10
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000008139 complexing agent Substances 0.000 claims description 7
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical group [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 7
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 235000010493 xanthan gum Nutrition 0.000 claims description 7
- 239000000230 xanthan gum Substances 0.000 claims description 7
- 229920001285 xanthan gum Polymers 0.000 claims description 7
- 229940082509 xanthan gum Drugs 0.000 claims description 7
- 239000004201 L-cysteine Substances 0.000 claims description 6
- 235000013878 L-cysteine Nutrition 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000011790 ferrous sulphate Substances 0.000 claims description 5
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 5
- 230000000149 penetrating effect Effects 0.000 claims description 4
- 235000010489 acacia gum Nutrition 0.000 claims description 3
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 229910021577 Iron(II) chloride Inorganic materials 0.000 claims description 2
- 239000006286 aqueous extract Substances 0.000 claims description 2
- 235000010418 carrageenan Nutrition 0.000 claims description 2
- 239000000679 carrageenan Substances 0.000 claims description 2
- 229920001525 carrageenan Polymers 0.000 claims description 2
- 229940113118 carrageenan Drugs 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
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- 229960002154 guar gum Drugs 0.000 claims description 2
- 235000010413 sodium alginate Nutrition 0.000 claims description 2
- 239000000661 sodium alginate Substances 0.000 claims description 2
- 229940005550 sodium alginate Drugs 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims 3
- 125000000415 L-cysteinyl group Chemical group O=C([*])[C@@](N([H])[H])([H])C([H])([H])S[H] 0.000 claims 1
- 238000011161 development Methods 0.000 abstract description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract description 4
- 230000006378 damage Effects 0.000 abstract description 4
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 abstract description 3
- 230000000711 cancerogenic effect Effects 0.000 abstract description 3
- 231100000315 carcinogenic Toxicity 0.000 abstract description 3
- 229940018564 m-phenylenediamine Drugs 0.000 abstract description 3
- 238000004043 dyeing Methods 0.000 description 46
- 230000000052 comparative effect Effects 0.000 description 31
- 239000000243 solution Substances 0.000 description 26
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 238000010438 heat treatment Methods 0.000 description 14
- 230000000694 effects Effects 0.000 description 9
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical group [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 230000002829 reductive effect Effects 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 238000004090 dissolution Methods 0.000 description 6
- 229910021645 metal ion Inorganic materials 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 235000011121 sodium hydroxide Nutrition 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- PWKSKIMOESPYIA-UHFFFAOYSA-N 2-acetamido-3-sulfanylpropanoic acid Chemical compound CC(=O)NC(CS)C(O)=O PWKSKIMOESPYIA-UHFFFAOYSA-N 0.000 description 4
- 241000758791 Juglandaceae Species 0.000 description 4
- 108010076876 Keratins Proteins 0.000 description 4
- 102000011782 Keratins Human genes 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 229960002433 cysteine Drugs 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
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- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 241000283973 Oryctolagus cuniculus Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000003648 hair appearance Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- IYRMWMYZSQPJKC-UHFFFAOYSA-N kaempferol Chemical compound C1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 IYRMWMYZSQPJKC-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000008354 sodium chloride injection Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- 238000002137 ultrasound extraction Methods 0.000 description 2
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 2
- QIJRTFXNRTXDIP-UHFFFAOYSA-N (1-carboxy-2-sulfanylethyl)azanium;chloride;hydrate Chemical compound O.Cl.SCC(N)C(O)=O QIJRTFXNRTXDIP-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- OFQCQIGMURIECL-UHFFFAOYSA-N 2-[2-(diethylamino)ethyl]-2',6'-dimethylspiro[isoquinoline-4,4'-oxane]-1,3-dione;phosphoric acid Chemical compound OP(O)(O)=O.O=C1N(CCN(CC)CC)C(=O)C2=CC=CC=C2C21CC(C)OC(C)C2 OFQCQIGMURIECL-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- UBSCDKPKWHYZNX-UHFFFAOYSA-N Demethoxycapillarisin Natural products C1=CC(O)=CC=C1OC1=CC(=O)C2=C(O)C=C(O)C=C2O1 UBSCDKPKWHYZNX-UHFFFAOYSA-N 0.000 description 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
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- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229960001631 carbomer Drugs 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 229960001305 cysteine hydrochloride Drugs 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000008777 kaempferol Nutrition 0.000 description 1
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 description 1
- -1 nitryl p-phenylenediamine Chemical compound 0.000 description 1
- 235000014571 nuts Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
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- 230000001235 sensitizing effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 229940001474 sodium thiosulfate Drugs 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention provides a walnut green husk black hair dye. The hair dye comprises a hair dyeing agent I and a hair dyeing agent II, and the hair is dyed into black by combining the hair dyeing agent I and the hair dyeing agent II. The walnut green husk black hair dye can quickly dye white hair black; the hair conditioner does not contain carcinogenic components such as m-phenylenediamine and the like, does not contain components such as hydrogen peroxide and the like which damage hair, and has high use safety; the invention fully utilizes the walnut green husk, realizes the value development of the walnut green husk and provides technical support for the development of the black hair dye.
Description
Technical Field
The invention relates to a black hair dye, in particular to a black hair dye containing natural hair dyeing components in walnut green husks.
Background
The walnut is one of common nuts, and has rich yield and wide planting area in China. The walnut cultivation area in 2013 in China is reported to be 253.3 million hectares, and the annual yield is reported to be 232.5 million tons. In recent years, the walnut cultivation area in China is increased by 10% every year, 267 ten thousand hectares can be expected in 2020, and the annual output at that time can reach 300 ten thousand tons.
The walnut green husks are wrapped outside the walnuts, and the walnut green husks removed after the walnuts are harvested are usually abandoned at will and are not fully utilized, so that resource waste and environmental pollution are caused. If the green husks of the walnuts are utilized, not only can the resource waste and the environmental pollution be reduced, but also the comprehensive value of the deeply processed walnuts can be increased, and the economic income of fruit growers can be improved.
In the prior art, hair dye often contains chemical substances which are harmful or sensitive to human bodies, such as m-phenylenediamine and the like, and serious health risks can be caused to the human bodies after long-term use.
Therefore, the inventor researches a walnut green husk black hair dye and a preparation method thereof on the basis of the prior art aiming at the technical problems.
Disclosure of Invention
In order to solve the above problems, the present inventors have conducted intensive studies and, as a result, have found that: the walnut green husk extract has a dyeing effect, and can realize a better hair dyeing effect through the compatible use of a penetrating agent, a color developing agent, a complexing agent and a dyeing agent, thereby completing the invention.
The object of the present invention is to provide the following:
in a first aspect, the invention provides a walnut green husk black hair dye, which is prepared from the following components in parts by weight:
50-60 parts of a hair dyeing agent I;
40-70 parts of hair dyeing II agent.
The hair dyeing agent I comprises the following components in parts by weight:
the hair dyeing agent II comprises the following components in parts by weight:
in a second aspect, the invention provides a preparation method of a walnut green husk black hair dye, which comprises the following steps:
(1) preparing a hair dyeing agent I;
(2) preparing a hair dyeing agent II.
The walnut green husk black hair dye and the preparation method thereof provided by the invention have the following beneficial effects:
(1) the walnut green husk black hair dye can quickly dye white hair black; the hair conditioner does not contain carcinogenic components such as m-phenylenediamine and the like, does not contain components such as hydrogen peroxide and the like which damage hair, and has high use safety;
(2) the walnut green husk black hair dye provided by the invention can fully utilize the walnut green husks, realizes the value development of the walnut green husks, and provides technical support for the development of the black hair dye.
(3) In the walnut green husk black hair dye provided by the invention, the metal dye and the walnut green husk extract have good permeation efficiency, and the hair dyeing time is shortened under the condition of no need of heating, so that the hair dye is more convenient and quicker to use.
(4) The preparation method of the walnut green husk black hair dye provided by the invention has the advantages of few steps, simple preparation, high reproducibility and small difficulty in industrial quantitative production.
Detailed Description
The features and advantages of the present invention will become more apparent and appreciated from the following detailed description of the invention.
The word "exemplary" is used exclusively herein to mean "serving as an example, embodiment, or illustration. Any embodiment described herein as "exemplary" is not necessarily to be construed as preferred or advantageous over other embodiments.
In the description of the present invention, it should be noted that the terms "first", "second", "third" and "fourth" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
The present invention is described in detail below.
The inventor researches and discovers that the walnut green husk contains natural dyeing components and can be used for preparing the hair dye, so that chemical substances harmful or sensitizing to human bodies are avoided. However, since keratin is a majority of hair components, it is difficult for the dyeing components to adhere for a long time; furthermore, as consumers pay attention to hair quality, the hair quality of dyed hair is also becoming more important.
Based on the above, the invention provides a walnut green husk black hair dye, which is prepared from the following components in parts by weight:
40-70 parts of a hair dyeing agent I;
40-70 parts of hair dyeing II agent.
Preferably, the hair dye is prepared from the following components in parts by weight:
50-60 parts of a hair dyeing agent I;
40-70 parts of hair dyeing II agent.
The hair dyeing agent I comprises the following components in parts by weight:
the walnut green husk extract is a multi-component mixture containing natural dyeing components and extracted from walnut green husks, contains a plurality of phenolic hydroxyl groups, and is easy to complex with metal ions to change color.
Preferably, the walnut green husk extract is an aqueous extract, and more preferably, the extraction solvent is an alkaline solution during extraction, because phenolic hydroxyl has weak acidity, the solubility of polyphenol in the walnut green husk can be increased under alkaline conditions, and the extraction rate and the extraction efficiency are improved.
Preferably, the alkaline solution can be prepared from one or more of sodium hydroxide, potassium hydroxide, ammonia water, sodium carbonate, sodium bicarbonate, sodium oxide, calcium hydroxide, potassium carbonate and triethylamine; preferably, a non-volatile inorganic base is used, and more preferably, a more basic sodium hydroxide or potassium hydroxide is used. In view of the cost of industrial development, it is better to extract the walnut green husk by using sodium hydroxide with lower cost.
Further, the mass concentration of the alkaline component in the alkaline solution is 1 to 5% (or 1 to 5g/100ml), preferably 1 to 4%, more preferably 1.5 to 3%, for example 2%. At the moment, the alkaline solution can well dissolve and extract polyphenol components in the walnut green husks, and the dyeing capability is improved. When the alkaline component in the alkaline solution is excessive, the structure of some components in the walnut green husk can be damaged during extraction, especially under the heating condition, and the dyeing ability is reduced.
In the invention, the walnut green peel refers to a green peel wrapping the woody hard skin of the walnut before the walnut is ripe, in particular to a fresh walnut green peel which is not dried. The cells of the walnut green husk contain more water, so that the effective components can be extracted more easily, and the processing treatment of the walnut green husk is not needed, so that the extraction steps are less, and the process flow is short.
In order to improve the extraction efficiency and the extraction rate, the walnut green husk is preferably subjected to crushing treatment before extraction so as to increase the specific surface area. The walnut green husk can be subjected to one or more of shearing crushing, grinding crushing and collision crushing, and the crushed particle size is not higher than 2 cm.
In a preferred embodiment, the particle size of the crushed walnut green husk is 1.5-2 cm.
Extracting with pulverized exocarpium Juglandis Immaturus. When the walnut green husk is extracted by using an alkaline solution, the material-liquid ratio of the walnut green husk to the alkaline solution is 1: 1-5, preferably 1: 1-4, more preferably 1: 2-3. The feed-liquid ratio can fully extract polyphenol substances in the polyphenol substances, reduces the extraction volume, reduces the workload of concentration after extraction, reduces the concentration time and energy consumption waste, and provides feasible parameters and references for industrialization.
The extraction method of the walnut green husk can be a decoction method or an ultrasonic method.
In the decocting method, boiling and extracting for 2-4 hr to dissolve out effective components; in a preferred embodiment, the filtrates are combined by further extraction.
In the ultrasonic extraction method, when the ultrasonic frequency is 40-80KHz and the power is 500-1000W, the wall breaking rate of the walnut green seedcase can be improved, and the extraction efficiency is improved.
Preferably, the frequency of the ultrasonic wave is 60-80KHz, and the power is 500-800W.
Preferably, the ultrasonic extraction is performed for 0.5-2h, more preferably 0.5-1h, and the extraction time is short and the extraction efficiency is high.
More preferably, the extract is concentrated after the extraction is completed, so as to increase the concentration of the effective components, and facilitate the subsequent preparation of the hair dye.
Preferably, the extract is concentrated to 1/10-3/10 of the original volume, more preferably to 1/10-1/5 of the original volume, so that the preparation requirement of the hair dye can be met. The concentrated solution is the walnut green husk extract.
In the present invention, the penetrant is selected from one or more of L-cysteine, sodium thiosulfate and cysteine hydrochloride, preferably L-cysteine and sodium thiosulfate, because L-cysteine and sodium thiosulfate can destroy disulfide bonds in hair keratin, promote the combination and/or complexation of keratin and coloring agent, make coloring agent enter hair pores, and enhance hair dyeing effect and duration.
In a preferred embodiment, the mass ratio of L-cysteine to sodium thiosulfate is 4-8:1, preferably 4-7:1, e.g. 6: 1. On the premise of meeting hair permeability, the usage amount of sodium thiosulfate can be reduced, and the sulfur content of the hair dye can be reduced.
The synergist is selected from one or more of tea polyphenol, kaempferol, grape polyphenol and apple polyphenol, preferably tea polyphenol, and has structure containing more phenolic hydroxyl groups, and can be complexed with metal coloring agent to change color. Particularly, the color converted after the tea polyphenol is complexed with the metal coloring agent is the same as the color converted after the walnut green husk extract is complexed with the metal coloring agent, so that the dyeing effect of the walnut green husk extract can be enhanced.
The color developing agent is selected from one or more of ascorbic acid, 2-mercaptoethanol, urea and thioglycolic acid, preferably ascorbic acid is used, the ascorbic acid can decompose disulfide bonds of hair keratin and form sulfydryl, and in the hair dye, hydrogen bonds, ionic bonds and covalent bonds can be formed among active methyl, carboxyl and hydroxyl functional groups in various components, so that the dyeing effect of the hair dye is enhanced, and therefore, the ascorbic acid is a good color developing agent and can improve the blackness of hair dyed; meanwhile, the ascorbic acid is safe to use and has small harm to human bodies.
The thickening agent is selected from one or more of sodium carboxymethylcellulose, hydroxyethyl cellulose, xanthan gum, guar gum, carrageenan, Arabic gum, sodium alginate and gelatin, and the sodium carboxymethylcellulose and the hydroxyethyl cellulose are preferably used as the thickening agent.
In a preferred embodiment, the mass ratio of the sodium carboxymethyl cellulose to the hydroxyethyl cellulose is 1:0.5-4, preferably 1: 1-3. The hair dye prepared by the combination has good consistency, and meanwhile, the hair dye has good dispersion and film-forming properties and is not easy to lose moisture.
The complexing agent is EDTA-2Na (disodium ethylene diamine tetraacetate). EDTA-2Na has strong complexing ability, and when the hair dyeing agent I containing EDTA-2Na is used, the penetrant further opens the pores (or scales) of the hair, so that the components in the hair dyeing agent I enter the hair cortex. EDTA-2Na can capture metal ions in the hair dyeing agent II when the hair dyeing agent II is used to form a metal ion-EDTA complex; meanwhile, the metal ions can be complexed with the tea polyphenol/walnut green husk extract to form a metal ion-EDTA-tea polyphenol/walnut green husk extract complex, the molecular structure of the substance is large, the substance is difficult to flow out through pores of hair, the blackness of dyed hair is provided, and the hair washing and fading after hair dyeing are reduced.
The deionized water is water containing no ions, and optionally, may be subjected to distillation, osmosis or ion adsorption treatment, without limitation.
In a preferred embodiment, the hair dyeing agent I comprises the following components in parts by weight:
more preferably, the hair dyeing agent I comprises the following components in parts by weight:
the hair dyeing agent II comprises the following components in parts by weight:
wherein the metal coloring agent contains Fe2+Or Cu2+Preferably, the use is harmless or dangerous to human healthFe with minimal harm2+. Preferably, the metal coloring agent is FeSO4、FeCl2Or Fe (NO3)2The metal coloring agent is safe and easy to obtain and convenient to use.
In the hair dyeing agent II, the thickening agent plays a role of dispersing the metal coloring agent, so that the metal coloring agent is prevented from being polymerized into large particles, and the dyeing effect is reduced. The thickening agent is selected from one or more of hydroxyethyl cellulose, xanthan gum, polyethylene oxide, polyvinylpyrrolidone, carbomer resin and Arabic gum, preferably hydroxyethyl cellulose or xanthan gum with proper viscosity is used, the water solubility of the hydroxyethyl cellulose or the xanthan gum is good, a film can be well formed, water is prevented from being lost, and the use and long-term storage are facilitated.
In addition, the hydroxyethyl cellulose has better stability, and even if the hydroxyethyl cellulose does not generate precipitation in a saturated salt solution, the thickening effect is not influenced. The hair dyeing II agent containing metal ion components prepared from hydroxyethyl cellulose also does not generate precipitation and influence the emulsion form.
And the sodium carboxymethyl cellulose can not be used as a hair dyeing agent II, and the sodium carboxymethyl cellulose can form precipitates with metal ions to influence the thickening effect.
The emulsifier is one or more selected from tween-80, sodium dodecyl sulfate, lauric acid monoglyceride, fatty acid monoglyceride and lanolin, and tween-80 is preferably used as the emulsifier. Tween-80 has wetting and penetrating capability, can reduce friction on hair surface, and can penetrate components in hair dyeing agent II, especially metal ion components into hair cortex layer through hair scales, increase complexing probability of metal coloring agent and EDTA, tea polyphenols, and Juglandis pericarpium Citri Reticulatae viride extract, thereby enhancing dyeing effect and prolonging dyeing time.
The Tween-80 has emulsifying capacity, and the components in the hair dyeing agent II can be uniform and not separated by using the Tween-80 as an emulsifier, so that the hair dyeing agent II is beneficial to long-term storage and use and improves the sensory experience of users.
In a preferred embodiment, the hair dyeing II agent comprises the following components in parts by weight:
in another preferred embodiment, the hair dyeing agent II comprises the following components in parts by weight:
more preferably, the hair dyeing agent II comprises the following components in parts by weight:
in the walnut green seedcase black hair dye, the hair dye I is uniformly coated on hair during hair dyeing, the hair dye I is washed off by clear water after 15-30min, the hair dye II is uniformly coated on the hair, and the hair dye II is washed off after 3-5min, so that the black hair can be dyed, and the dyeing time is very short.
In the walnut green husk black hair dye provided by the invention, the metal dye and the walnut green husk extract have good permeation efficiency, and the hair dyeing time is shortened under the condition of no need of heating, so that the hair dye is more convenient and quicker to use.
The hair dye provided by the invention does not contain carcinogenic substances such as phenylenediamine, nitryl p-phenylenediamine and the like, does not contain an oxidant, has high use safety performance, and can reduce the harm of the hair dye to human bodies.
Meanwhile, the hair dye provided by the invention contains the walnut green husk extract, so that the waste is recycled, the resource is saved, the added value of agricultural products is improved, the deep development is carried out, and the economic benefit is improved.
The invention also provides a preparation method of the walnut green husk black hair dye, which comprises the following steps:
(1) preparing a hair dyeing agent I;
(2) preparing a hair dyeing agent II.
Wherein, in the step (1), the penetrating agent, the complexing agent and part of the thickening agent are dissolved in deionized water; dissolving the walnut green husk extract, the synergist, the color developing agent and the rest of the thickener in the deionized water, and uniformly stirring to obtain the hair dyeing agent I.
Preferably, when a plurality of thickeners are used, the thickener having a slow dissolution rate is dissolved preferentially, and the thickener having a fast dissolution rate is dissolved again. For example, when sodium carboxymethylcellulose and hydroxyethylcellulose are used as thickeners, the sodium carboxymethylcellulose can be dissolved first and the hydroxyethylcellulose can be dissolved.
More preferably, when the penetrant, the complexing agent and the thickener having a slow dissolution rate are dissolved in deionized water, the solution is heated with stirring to accelerate the dissolution of the solute. Preferably, the heating temperature is not more than 90 deg.C, so as to avoid the oxidative degradation of some components.
After heating, the solution is preferably cooled to room temperature, and then walnut green husk extract, synergist, developer and thickener with high dissolution rate are added to prevent the reductive substance from degrading or oxidizing under heating.
In step (2), the metal stain is dissolved in 1/5-1/3 deionized water. The remaining deionized water is dissolved with the thickener and emulsifier, preferably by heating, to increase the rate of dissolution.
Because the metal coloring agent, especially the ferrous coloring agent, is easily oxidized and converted into the trivalent under the heating condition, the color of the complex of the trivalent iron and the coloring agent in the coloring agent I is not black. Therefore, the hair dyeing agent II is preferably prepared by adding the solution dissolved with the metal coloring agent after the solution dissolved with the thickening agent and the emulsifying agent is cooled to room temperature so as to avoid the oxidation of the metal coloring agent and stirring the solution uniformly.
The room temperature in the invention means that the indoor temperature is 20-35 ℃.
In the step (2), the metal coloring agent is separately dissolved and then added into the solution in which the thickening agent and the emulsifying agent are dissolved, so that the metal coloring agent can be fully dispersed without aggregation.
The preparation method of the walnut green husk black hair dye provided by the invention has the advantages of few steps, simple preparation, high reproducibility and small difficulty in industrial quantitative production.
Examples
Example 1
Walnut green husk black hair dye formula 1
A hair dyeing agent I:
hair dyeing agent II:
the preparation method of the walnut green husk extracting solution comprises the following steps:
cutting fresh walnut green peel into small pieces with the particle size of about 2cm, and ultrasonically extracting for 0.5h in 2% sodium hydroxide solution according to the feed liquid mass ratio of 1:2.5, wherein the ultrasonic frequency is 80KHz, and the power is 600W.
The preparation method comprises the following steps:
adding L-cysteine, EDTA-2Na, sodium thiosulfate and sodium carboxymethylcellulose into 50mL of deionized water, heating at 85 deg.C for 5min, and stirring to dissolve. And (3) cooling the solution to room temperature, adding the walnut green husk extracting solution, tea polyphenol, ascorbic acid and hydroxyethyl cellulose into the solution, stirring to dissolve, and uniformly mixing to obtain the hair dyeing agent I.
Ferrous sulfate heptahydrate was added to 10mL of deionized water and stirred to dissolve it. And adding hydroxyethyl cellulose and tween-80 into the rest 40mL of deionized water, heating at 85 ℃ to completely dissolve the hydroxyethyl cellulose and tween-80, cooling to room temperature, adding a ferrous sulfate solution, and mixing the two agents uniformly to obtain the agent II.
Example 2
Walnut green husk black hair dye formula 2
A hair dyeing agent I:
hair dyeing agent II:
the preparation method of the walnut green husk extracting solution comprises the following steps:
cutting fresh walnut green peel into small blocks with the particle size of about 1.5cm, and ultrasonically extracting for 0.5h in 4% sodium hydroxide solution according to the feed liquid mass ratio of 1:1.5, wherein the ultrasonic frequency is 80KHz, and the power is 800W.
The preparation method comprises the following steps:
adding L-cysteine, EDTA-2Na, sodium thiosulfate and sodium carboxymethylcellulose into deionized water, heating at 60 deg.C for 8min, and stirring to dissolve. And (3) cooling the solution to room temperature, adding the walnut green husk extracting solution, tea polyphenol, ascorbic acid and hydroxyethyl cellulose into the solution, stirring to dissolve, and uniformly mixing to obtain the hair dyeing agent I.
Ferrous sulfate heptahydrate was added to 15mL of deionized water and stirred to dissolve it. And adding hydroxyethyl cellulose and tween-80 into the residual 45mL of deionized water, heating at 90 ℃ to completely dissolve the hydroxyethyl cellulose and tween-80, cooling to room temperature, adding a ferrous sulfate solution, and uniformly mixing the two to obtain the preparation II.
Example 3
Walnut green husk black hair dye formula 3
A hair dyeing agent I:
hair dyeing agent II:
the preparation method of the walnut green husk extracting solution comprises the following steps:
cutting fresh walnut green peel into small pieces with the particle size of about 2cm, and ultrasonically extracting for 1h in 1% sodium hydroxide solution according to the feed liquid mass ratio of 1:4, wherein the ultrasonic frequency is 80KHz, and the power is 600W.
The preparation method comprises the following steps:
adding L-cysteine, EDTA-2Na, sodium thiosulfate and sodium carboxymethylcellulose into deionized water, heating at 70 deg.C for 6min, and stirring to dissolve. And (3) cooling the solution to room temperature, adding the walnut green husk extracting solution, tea polyphenol, ascorbic acid and hydroxyethyl cellulose into the solution, stirring to dissolve, and uniformly mixing to obtain the hair dyeing agent I.
Ferrous sulfate heptahydrate was added to 10mL of deionized water and stirred to dissolve it. And adding hydroxyethyl cellulose and tween-80 into the rest 30mL of deionized water, heating at 60 ℃ to completely dissolve the hydroxyethyl cellulose and tween-80, cooling to room temperature, adding a ferrous sulfate solution, and mixing the two agents uniformly to obtain the agent II.
Comparative example
Comparative example 1
Comparative prescription 1
A hair dyeing agent I:
hair dyeing II agent the same as example 1.
The preparation method is the same as example 1.
Comparative example 2
Comparative prescription 2
A hair dyeing agent I:
hair dyeing II agent the same as example 1.
The preparation method is the same as example 1.
Comparative example 3
Comparative prescription 3
A hair dyeing agent I:
hair dyeing II agent the same as example 1.
The preparation method is the same as example 1.
Comparative example 4
Comparative prescription 4
A hair dyeing agent I:
hair dyeing II agent the same as example 1.
The preparation method is the same as example 1.
Comparative example 5
Comparative prescription 5
Hair dyeing II agent the same as example 1.
The preparation method is the same as example 1.
Comparative example 6
Comparative prescription 6
Hair dyeing agent I was the same as in example 1.
Hair dyeing agent II:
hydroxyethyl cellulose 1.5g
Tween-801 ml
50ml of deionized water
The preparation method is the same as example 1.
Comparative example 7
Comparative prescription 7
A hair dyeing agent I:
hair dyeing II agent the same as example 1.
The preparation method is the same as example 1.
The obtained hair dye I has low thickness and high fluidity, and is not easy to stay on hair.
Comparative example 8
Comparative prescription 8
A hair dyeing agent I:
hair dyeing II agent the same as example 1.
The preparation method is the same as example 1.
The obtained hair dye I has low thickness and high fluidity, and is not easy to stay on hair.
Comparative example 9
Comparative prescription 9
Hair dyeing agent I was the same as in example 1.
Hair dyeing agent II:
ferrous sulfate heptahydrate 1.5g
Tween-801 ml
50ml of deionized water
The preparation method is the same as example 1.
The obtained hair dyeing agent II has low thickness and high fluidity, and is not easy to stay on hair.
Comparative example 10
Comparison prescription 10
Hair dyeing agent I was the same as in example 1.
Hair dyeing agent II:
the preparation method is the same as example 1.
The obtained hair dyeing agent II has precipitation, and has low viscosity, and is not suitable for hair retention and development.
Examples of the experiments
Experimental example 1
Skin irritation test
1 laboratory animal
Four healthy primary adult rabbits (two in each of male and female) with the body weight of not less than 2kg are selected.
One day before experiment 2, the experimental rabbits were fixed manually, and the hairs (about 10 × 15cm) on both sides of the spine were cut off as the experimental and observation sites (one side of the observation site was kept healthy and undamaged, and one side of the experimental site was cut with a small knife with a # shape).
3 on the day of experiment, the hair dye I and the hair dye II are uniformly mixed according to the ratio of 1:1, 0.5g of the uniformly mixed hair dye is taken and directly smeared on the shaved part. The part for smearing the hair dye is applied with a dressing with good air permeability of 25 multiplied by 25mm, the outer layer of the dressing is wrapped with gauze, and the dressing and the gauze are fixed by a bandage for 4 hours. And (4) after the contact period is finished, sequentially taking down the bandage, the gauze and the dressing, marking the contact position, cleaning with warm water and wiping to dry.
A gauze piece dropping 0.5g of 0.9% sodium chloride injection is applied to the control part by taking the 0.9% sodium chloride injection as a control sample, and the application time and the observation time are the same as those of the experimental group.
4 Observation of results
The contact site condition was recorded at 1h, 24h, 48h and 72h after removal of the application.
Scoring according to the GB7919 scoring standard, the results are given in the table below
Experimental example 2
Dyeing test
Uniformly applying the hair dyeing agent I on white hair, and washing with clear water after 25 min; and then uniformly applying the hair dyeing agent II on the hair, and washing after 3 min. The amount of the hair dye is based on the amount of the hair dye which can be uniformly coated on the hair.
If the hair is not dyed successfully, taking untreated white hair, repeating the steps, prolonging the retention time of the hair dyeing agent I to 50min, and prolonging the retention time of the hair dyeing agent II in the hair to 10 min.
The test samples were the hair dyes prepared in examples 1 to 3 and comparative examples 1 to 10.
After the dyeing treatment, the following results were found:
example 1: after dyeing the hair for 28min, the hair is black;
example 2: after dyeing the hair for 28min, the hair is black;
example 3: after dyeing the hair for 28min, the hair is black;
comparative example 1: after 1 hour of dyeing, the hair was brown;
comparative example 2: after 1 hour of dyeing, the hair was dark brown;
comparative example 3: after 1 hour of dyeing, the hair was light brown;
comparative example 4: after dyeing for 1 hour, the hair is dark brown and is easy to break;
comparative example 5: after dyeing for 1 hour, the hair is dark brown and has little odor;
comparative example 6: after 1 hour of dyeing, the hair was dark brown;
comparative example 7: after dyeing the hair for 28min, the hair is black, but the prepared hair dyeing agent I has small consistency and high fluidity, and is not beneficial to staying on the hair;
comparative example 8: after dyeing the hair for 28min, the hair is black, but the prepared hair dyeing agent I has small consistency and high fluidity, and is not beneficial to staying on the hair;
comparative example 9: after dyeing for 28min, the hair is black, but the prepared hair dyeing agent II has small consistency and high fluidity and is not beneficial to staying on the hair;
comparative example 10: after 1 hour of dyeing, the hair is dark brown, but the prepared hair dyeing agent II has precipitation, so that the thickness of the agent II is small, the agent II is not easy to stay on the hair, and the color development is not easy.
The invention has been described in detail with reference to specific embodiments and illustrative examples, but the description is not intended to be construed in a limiting sense. Those skilled in the art will appreciate that various equivalent substitutions, modifications or improvements may be made to the technical solution of the present invention and its embodiments without departing from the spirit and scope of the present invention, which fall within the scope of the present invention. The scope of the invention is defined by the appended claims.
Claims (7)
1. The walnut green husk black hair dye is prepared from the following components in parts by weight:
50-60 parts of a hair dyeing agent I;
40-70 parts of hair dyeing agent II;
the hair dyeing agent I comprises the following components in parts by weight:
2-6 parts of a penetrating agent;
30-60 parts of walnut green husk extract;
0.3-4 parts of a synergist;
0.1-3 parts of a color developing agent;
1-5 parts of a thickening agent;
0.1-0.5 part of complexing agent;
35-70 parts of deionized water;
in the hair dyeing agent I, the walnut green husk extract is an aqueous extract;
during extraction, the extraction solvent is alkaline solution, and the mass concentration of alkaline components in the alkaline solution is 1-5%;
during extraction, the material-liquid ratio of the walnut green husk to the alkaline solution is 1: 1-5;
ultrasonically extracting a walnut green seedcase extract, and concentrating the extract to 1/10-3/10 of the original volume;
in the hair dyeing agent I, the penetrant is L-cysteine and sodium thiosulfate;
the synergist is tea polyphenol;
the color developing agent is ascorbic acid;
the thickening agent is selected from one or more of sodium carboxymethylcellulose, hydroxyethyl cellulose, xanthan gum, guar gum, carrageenan, Arabic gum, sodium alginate and gelatin;
the complexing agent is EDTA-2 Na;
the hair dyeing agent II comprises the following components in parts by weight:
0.5-5 parts of a metal coloring agent;
0.5-4 parts of a thickening agent;
0.5-3 parts of an emulsifier;
35-70 parts of deionized water;
in the hair dyeing agent II, the metal coloring agent is FeSO4、FeCl2Or Fe (NO3)2；
The thickening agent is hydroxyethyl cellulose or xanthan gum;
tween-80 is used as the emulsifier.
2. The hair dye according to claim 1, wherein the hair dye I comprises the following components in parts by weight:
1.0-4 parts of L-cysteine;
0.5-2 parts of sodium thiosulfate
30-55 parts of walnut green husk extract;
0.3-3 parts of tea polyphenol;
0.5-3 parts of ascorbic acid;
0.5-2 parts of sodium carboxymethylcellulose;
0.5-3 parts of hydroxyethyl cellulose;
0.1-0.5 part of EDTA-2 Na;
35-70 parts of deionized water.
3. The hair dye according to claim 2, wherein the hair dye I comprises the following components in parts by weight:
2-4 parts of L-cysteine;
0.5 to 1.5 portions of sodium thiosulfate
35-50 parts of walnut green husk extract;
0.5-2 parts of tea polyphenol;
0.5-2 parts of ascorbic acid;
0.5-1.5 parts of sodium carboxymethylcellulose;
0.5-2.5 parts of hydroxyethyl cellulose;
0.1-0.5 part of EDTA-2 Na;
45-60 parts of deionized water.
4. The hair dye of claim 1, wherein the hair dye II comprises the following components in parts by weight:
0.5-5 parts of ferrous sulfate;
0.5-4 parts of hydroxyethyl cellulose or xanthan gum;
tween-800.5-3 parts;
35-70 parts of deionized water.
5. The hair dye of claim 4, wherein the hair dye II comprises the following components in parts by weight:
0.5-3 parts of ferrous sulfate;
1-3 parts of hydroxyethyl cellulose;
tween-800.5-2 parts;
40-60 parts of deionized water.
6. A preparation method of the walnut green husk black hair dye as set forth in one of claims 1 to 5, characterized in that the preparation method comprises the following steps:
(1) preparing a hair dyeing agent I;
(2) preparing a hair dyeing agent II.
7. The preparation method according to claim 6, wherein in the step (1), the penetrant, the complexing agent and a part of the thickener are dissolved in deionized water; dissolving the walnut green husk extract, the synergist, the color developing agent and the rest of the thickener in the deionized water, and uniformly stirring to obtain a hair dyeing agent I;
in the step (2), dissolving the metal coloring agent in 1/5-1/3 deionized water; dissolving the thickening agent and the emulsifying agent in the rest deionized water, and uniformly mixing the thickening agent and the emulsifying agent to obtain the hair dyeing agent II.
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| CN115581648A (en) * | 2022-10-21 | 2023-01-10 | 浙江章华保健美发实业有限公司 | Dry fruit hair dye and using method thereof |
| CN115501152A (en) * | 2022-11-08 | 2022-12-23 | 苏州中纺学面料产业研究院 | Preparation method of natural hair dye and natural hair dye |
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| JP2003212728A (en) * | 2002-01-17 | 2003-07-30 | Hoyu Co Ltd | Hair cosmetic composition |
| CN101559029A (en) * | 2008-04-18 | 2009-10-21 | 闫征 | Natural hair dye by taking coptis extract as dye |
| CN101812246A (en) * | 2009-02-20 | 2010-08-25 | 浙江养生堂天然药物研究所有限公司 | Mordant and hair dyeing product containing same |
| CN101810549A (en) * | 2010-04-16 | 2010-08-25 | 范黎明 | Black hair dye and hair dyeing method |
| CN104800108A (en) * | 2014-11-20 | 2015-07-29 | 折改梅 | Preparation of constituents of cortex juglandis mandshuricae and manufacturing method of different-colored hair dyes |
| CN107412133A (en) * | 2017-08-13 | 2017-12-01 | 新疆农业科学院海南三亚农作物育种试验中心 | A kind of pure natural hair dye and its compound method, hair colouring methods |
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2018
- 2018-07-20 CN CN201810804198.7A patent/CN108743481B/en active Active
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003212728A (en) * | 2002-01-17 | 2003-07-30 | Hoyu Co Ltd | Hair cosmetic composition |
| CN101559029A (en) * | 2008-04-18 | 2009-10-21 | 闫征 | Natural hair dye by taking coptis extract as dye |
| CN101812246A (en) * | 2009-02-20 | 2010-08-25 | 浙江养生堂天然药物研究所有限公司 | Mordant and hair dyeing product containing same |
| CN101810549A (en) * | 2010-04-16 | 2010-08-25 | 范黎明 | Black hair dye and hair dyeing method |
| CN104800108A (en) * | 2014-11-20 | 2015-07-29 | 折改梅 | Preparation of constituents of cortex juglandis mandshuricae and manufacturing method of different-colored hair dyes |
| CN107412133A (en) * | 2017-08-13 | 2017-12-01 | 新疆农业科学院海南三亚农作物育种试验中心 | A kind of pure natural hair dye and its compound method, hair colouring methods |
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