CN101879135A - Curcuma plant hair dye - Google Patents
Curcuma plant hair dye Download PDFInfo
- Publication number
- CN101879135A CN101879135A CN 201010225971 CN201010225971A CN101879135A CN 101879135 A CN101879135 A CN 101879135A CN 201010225971 CN201010225971 CN 201010225971 CN 201010225971 A CN201010225971 A CN 201010225971A CN 101879135 A CN101879135 A CN 101879135A
- Authority
- CN
- China
- Prior art keywords
- hair
- hair dye
- tannic acid
- water
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000118 hair dye Substances 0.000 title claims abstract description 98
- 244000164439 Curcuma angustifolia Species 0.000 title 1
- 210000004209 hair Anatomy 0.000 claims abstract description 160
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims abstract description 108
- 229920002258 tannic acid Polymers 0.000 claims abstract description 54
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000001263 FEMA 3042 Substances 0.000 claims abstract description 47
- 235000015523 tannic acid Nutrition 0.000 claims abstract description 47
- 229940033123 tannic acid Drugs 0.000 claims abstract description 47
- 238000000034 method Methods 0.000 claims abstract description 34
- VFLDPWHFBUODDF-FCXRPNKRSA-N curcumin Chemical compound C1=C(O)C(OC)=CC(\C=C\C(=O)CC(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-FCXRPNKRSA-N 0.000 claims abstract description 33
- 238000004043 dyeing Methods 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 64
- 239000000284 extract Substances 0.000 claims description 47
- 239000003795 chemical substances by application Substances 0.000 claims description 43
- 239000000463 material Substances 0.000 claims description 41
- 241000628997 Flos Species 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 18
- 241000196324 Embryophyta Species 0.000 claims description 16
- 238000012856 packing Methods 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- 239000004148 curcumin Substances 0.000 claims description 15
- 235000012754 curcumin Nutrition 0.000 claims description 15
- 229940109262 curcumin Drugs 0.000 claims description 15
- VFLDPWHFBUODDF-UHFFFAOYSA-N diferuloylmethane Natural products C1=C(O)C(OC)=CC(C=CC(=O)CC(=O)C=CC=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-UHFFFAOYSA-N 0.000 claims description 15
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 14
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 13
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 9
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 claims description 9
- 235000018417 cysteine Nutrition 0.000 claims description 9
- 229940074391 gallic acid Drugs 0.000 claims description 9
- 235000004515 gallic acid Nutrition 0.000 claims description 9
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 8
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 8
- PWKSKIMOESPYIA-BYPYZUCNSA-N L-N-acetyl-Cysteine Chemical compound CC(=O)N[C@@H](CS)C(O)=O PWKSKIMOESPYIA-BYPYZUCNSA-N 0.000 claims description 8
- 229960002089 ferrous chloride Drugs 0.000 claims description 8
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 8
- 150000007530 organic bases Chemical class 0.000 claims description 7
- 229960004308 acetylcysteine Drugs 0.000 claims description 6
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 6
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 6
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 claims description 5
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 5
- 239000011790 ferrous sulphate Substances 0.000 claims description 5
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 5
- XXMBEHIWODXDTR-UHFFFAOYSA-N 1,2-diaminoethanol Chemical compound NCC(N)O XXMBEHIWODXDTR-UHFFFAOYSA-N 0.000 claims description 4
- FFFHZYDWPBMWHY-VKHMYHEASA-N L-homocysteine Chemical compound OC(=O)[C@@H](N)CCS FFFHZYDWPBMWHY-VKHMYHEASA-N 0.000 claims description 4
- 240000003152 Rhus chinensis Species 0.000 claims description 4
- 235000014220 Rhus chinensis Nutrition 0.000 claims description 4
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 claims description 4
- 229910000358 iron sulfate Inorganic materials 0.000 claims description 4
- ZOLPMMWNCLHKPX-UHFFFAOYSA-N ligustrin Natural products CC1=CCC2C1C3OC(=C)C(=O)C3C(O)CC2=C ZOLPMMWNCLHKPX-UHFFFAOYSA-N 0.000 claims description 4
- QJVXKWHHAMZTBY-GCPOEHJPSA-N syringin Chemical compound COC1=CC(\C=C\CO)=CC(OC)=C1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 QJVXKWHHAMZTBY-GCPOEHJPSA-N 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims description 3
- 235000013312 flour Nutrition 0.000 claims description 3
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 claims description 2
- 150000001945 cysteines Chemical class 0.000 claims 2
- 238000002360 preparation method Methods 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 7
- 244000164480 Curcuma aromatica Species 0.000 abstract description 2
- 235000014375 Curcuma Nutrition 0.000 abstract 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 26
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 18
- 239000001768 carboxy methyl cellulose Substances 0.000 description 18
- 239000000975 dye Substances 0.000 description 18
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- 230000000052 comparative effect Effects 0.000 description 16
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- 239000000243 solution Substances 0.000 description 11
- 206010049865 Achromotrichia acquired Diseases 0.000 description 10
- 239000002671 adjuvant Substances 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 10
- 229910021641 deionized water Inorganic materials 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 229920001864 tannin Polymers 0.000 description 10
- 235000018553 tannin Nutrition 0.000 description 10
- 239000001648 tannin Substances 0.000 description 10
- 108010010803 Gelatin Proteins 0.000 description 9
- 229920000159 gelatin Polymers 0.000 description 9
- 239000008273 gelatin Substances 0.000 description 9
- 235000019322 gelatine Nutrition 0.000 description 9
- 235000011852 gelatine desserts Nutrition 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 8
- -1 iron ion Chemical class 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- 150000001944 cysteine derivatives Chemical class 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 229920002907 Guar gum Polymers 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 229910001448 ferrous ion Inorganic materials 0.000 description 5
- 239000000665 guar gum Substances 0.000 description 5
- 235000010417 guar gum Nutrition 0.000 description 5
- 229960002154 guar gum Drugs 0.000 description 5
- 238000010298 pulverizing process Methods 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 4
- 229930003268 Vitamin C Natural products 0.000 description 4
- 239000000469 ethanolic extract Substances 0.000 description 4
- 150000002505 iron Chemical class 0.000 description 4
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 4
- 235000019345 sodium thiosulphate Nutrition 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- 235000019154 vitamin C Nutrition 0.000 description 4
- 239000011718 vitamin C Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000000230 xanthan gum Substances 0.000 description 4
- 229920001285 xanthan gum Polymers 0.000 description 4
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- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 239000004141 Sodium laurylsulphate Substances 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
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- 239000012567 medical material Substances 0.000 description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 150000008442 polyphenolic compounds Chemical class 0.000 description 3
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- 238000001556 precipitation Methods 0.000 description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 3
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- 239000006228 supernatant Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
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- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 2
- 230000003696 hair cross section Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
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- YRWWOAFMPXPHEJ-OFBPEYICSA-K sodium L-ascorbic acid 2-phosphate Chemical compound [Na+].[Na+].[Na+].OC[C@H](O)[C@H]1OC(=O)C(OP([O-])([O-])=O)=C1[O-] YRWWOAFMPXPHEJ-OFBPEYICSA-K 0.000 description 2
- GNBVPFITFYNRCN-UHFFFAOYSA-M sodium thioglycolate Chemical compound [Na+].[O-]C(=O)CS GNBVPFITFYNRCN-UHFFFAOYSA-M 0.000 description 2
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- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 1
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 description 1
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- 150000001557 benzodiazepines Chemical class 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
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- NLDDIKRKFXEWBK-AWEZNQCLSA-N gingerol Chemical compound CCCCC[C@H](O)CC(=O)CCC1=CC=C(O)C(OC)=C1 NLDDIKRKFXEWBK-AWEZNQCLSA-N 0.000 description 1
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- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
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- Cosmetics (AREA)
Abstract
The invention discloses hair dye, which comprises curcuma and tannic acid substances. Further, the invention discloses a commercial package product of the hair dye. At the same time, the invention discloses a preparation method and a use method of the hair dye. The hair dye of the invention is used for dyeing white hair into black hair, and has excellent effect.
Description
Technical field
The invention discloses a kind of hair dye, comprise Rhizoma Curcumae Longae and tannic acid material, belong to cosmetic field.
Background technology
At present, existing hair dyeing product mostly is oxidized form on the market, thereby adopts p-phenylenediamine (PPD) or Benzodiazepines compounds to show black through hydrogen peroxide oxidation.The skin test that the hair dye that contains this type of chemical constituent mostly needs to be 1-2 days before use is used for determining whether consumer can use.The multinomial infringement that studies confirm that the oxidized form dyestuff hair dye is certain to scalp simultaneously, toxicity is big, causes skin to produce sense of discomfort, life-time service even cause cancers such as redness, twinge easily.
In order to overcome the problems referred to above, plant hair dye has been subjected to extensive attention.Tannic acid, claim tannin, tannin, tannin again, it is the polyhydric phenols that is present in the intravital a kind of structure more complicated of plant, it is found that in actual applications tannic acid is applied in and to make hair colouring on the hair, constant color under the chelation of metal ion, thus in existing botanical hair dye, have extensive use.
But adopt the hair dye of tannic acid merely, as Chinese patent 200810037717.8 disclosed a kind of hair dyes, comprise compositions such as tannin (gallotannic acid), green vitriol, glacial acetic acid, diethanolamine, surfactant, the problem that this technical scheme exists is independent tannin (tannic acid) hair dyeing effect instability, long-time fading easily later.
Chinese patent 01127328 discloses a kind of hair dye that adopts inorganic agent, hair dye, chelating agen, thus iron ion wherein and the colouring of gallic acid generation chelatropic reaction.It is brown to purple that but the material that ferric ion and gallic acid are combined into is, and with black apparent in view difference arranged equally.The used ferrum sulfuricum oxydatum solutum of its chelating agen is easy to generate precipitation, need get its supernatant during actual preparation and add thickening agent etc. then and make the solid state powder packing, is mixed with solution or thickness unguentum during use temporarily, is not suitable for ordinary consumer and uses in the family.
It is the hair dye of staining components with the Rhizoma Zingiberis Recens that Chinese patent application 200810093657 discloses a kind of, and the multiple staining components of can arranging in pairs or groups uses, but the main component of Rhizoma Zingiberis Recens is a gingerol, can produce acid after it is water-soluble, is not suitable for human body and uses.
Make a general survey of prior art, remaining in the color that dyes is not problems such as ater, Color instability, product stability be not good, and hair dye provided by the invention makes significant progress on addressing these problems.
Summary of the invention
In lot of experiments, the applicant finds to adopt the hair dye of Rhizoma Curcumae Longae and the preparation of tannic acid material to be used to have hair dyed to have excellent effect, and wherein, described tannic acid material is preferably Galla Chinensis.Be embodied in following several aspect:
1. use Rhizoma Curcumae Longae, tannic acid material not contain as the hair dye of dyestuff preparation that oxidized form stain such as p-phenylenediamine (PPD) contains
Benzene class material has been avoided its side effect.
2. adopt tannic acid (the particularly tannic acid that extracts in Galla Chinensis or the Galla Chinensis) to compare as the hair dye of staining components with existing, adopt the hair color that hair dye dyes of Rhizoma Curcumae Longae and tannic acid material better, near ater, and effect is colour-fast lastingly.
3. in hair dyeing cosmetics, adopt iron ion or ferrous ion as the metal-chelating composition usually, Rhizoma Curcumae Longae, tannic acid material and ferrous ion or iron ion chelate stability obviously are better than independent tannic acid material and iron ion, ferrous ion chelating.
Based on above-mentioned discovery, the applicant has finished the present invention.
The invention provides a kind of hair dye, comprise Rhizoma Curcumae Longae and tannic acid material, the ratio of the two is 50: 1-1: 50, and preferred, 20: 1-1: 20, preferred 10: 1-1: 10, by weight.
In the present invention, Rhizoma Curcumae Longae be positions such as zingiberaceous plant Rhizoma Curcumae Longae (claiming Radix Curcumae again) root, stem be used as medicine after pulverizing powder or powder extracted after extract or the effective ingredient curcumin (CAS:458-37-7 of Rhizoma Curcumae Longae, chemical name: 1, two (the 4-hydroxy 3-methoxybenzene bases)-1 of 7-, 6-heptadiene-3, the 5-diketone).The preferred used Rhizoma Curcumae Longae of the present invention is Rhizoma Curcumae Longae extract or curcumin.Powder after Rhizoma Curcumae Longae extract can adopt extracting method commonly used with Rhizoma Curcumae Longae plant or specific part pulverizing extracts acquisition, and water or alcohol are extracted, and preferred use 30-95% ethanol extracts.
Tannic acid described in the present invention, claim tannin, tannin, tannin again, be the wider polyhydric phenols of molecule weight range, be divided into condensed tannins and hydrolyzable tannic acid, adopt suitable condition to be hydrolyzed the hydrolyzable tannic acid and can obtain micromolecule tannic acid and gallic acid monomer.Tannic acid material of the present invention comprises macromolecular tannic acid, also comprises micromolecule tannic acid and gallic acid.Industrial, above-mentioned tannic acid material all can adopt the synthetic method of chemical industry to obtain, and also can be that the fine powder that the plant of extracting from the plant that contains this type of material or will contain this type of material grinds to form obtains.These plants include but not limited to Galla Chinensis, Herba Ecliptae, Fructus rhois chinensis, Pericarpium Granati, Chinese gall Beihua, Fructus Musae neck etc., and are preferred, and tannic acid material of the present invention is a Galla Chinensis, Galla Chinensis extract preferably, and the tannic acid material is a gallotannic acid among preferred the present invention.
Being used for from the method for above-mentioned plant extraction tannic acid material can be this area extracting method commonly used, and water or alcohol are extracted, and preferred use 30-95% ethanol extracts.
On basis of the present invention, can also add Flos Caryophylli in the hair dye further increases dyeing kinetics, and the poliosis color is deepened rapidly.
Used Flos Caryophylli can be powder, the water of Flos Caryophylli or the extract of alcohol that the Flos Caryophylli medical material grinds, and can also be the effective ingredient ligustrin in the Flos Caryophylli.Flos Caryophylli preferred of the present invention is adopted water or the alcohol extract of Flos Caryophylli, the ethanol extraction of most preferred its 30-95% of employing.
On the mentioned component basis, can also add an amount of hair dye adjuvant in the hair dye, include but not limited to that thickening agent, surfactant and water etc. make final products.These hair dye adjuvants are that the hair dye industry is generally used, and are not subjected to special restriction.
In actual use,, improve and infiltrate and hair dyeing effect, can also before using hair dye of the present invention, adopt softening inorganic agent handle hair in order better to improve Rhizoma Curcumae Longae, tannic acid material permeability to hair.Hair dyeing industry softening processing class material commonly used all can use in the present invention, as sodium thioglycolate, sodium thiosulfate, cysteine class material etc., preferably adopts the softening inorganic agent before cysteine class material is had hair dyed as hair dye of the present invention in conjunction with organic base.
Cysteine class material of the present invention can be one or more the mixture in cysteine, homocysteine, carbamyl cysteine, the N-acetylcysteine, also can be the hydrochlorate of these materials.
Organic base of the present invention is the small molecule alkaline organic, its carbochain is short, comprise ethanolamine, ethylenediamine, diethylamine, triethylamine, dimethylamine, hydroxyethylethylene diamine, aminoethanolamine, sodium ethylene diamine tetracetate etc., preferably adopt ethanolamine, ethylenediamine or its mixture.
On the mentioned component basis, can also add an amount of hair dye adjuvant in the softening inorganic agent, include but not limited to that thickening agent, surfactant and water etc. make final products.These hair dye adjuvants are that the hair dye industry is generally used, and are not subjected to special restriction.
In actual use, hair dye of the present invention can adopt chelating agen that hair is handled before hair dye of the present invention uses in order further to strengthen the effect of fixation, to those skilled in the art, and the method that this is commonly used when being the hair dye hair dyeing.Described chelating agen is water solublity iron salt or ferrous salt, can be one or more the mixture in ferrous sulfate, ferrous chloride, iron sulfate, iron chloride, ferric nitrate, the ferrous nitrate.In order to improve the stability of iron ion or ferrous ion, can also in chelating agen, add stabilizing agent.Used stabilizing agent can be one or more the mixture in vitamin C, curcumin, sodium thiosulfate, iron powder, tea polyphenols, the sodium L-ascorbate-2-phosphate, a kind of or its mixture in preferred vitamin C, the curcumin.
Above-mentioned hair dye adjuvant commonly used is the adjuvant that a class is widely used in hair dye to those skilled in the art, as thickening agent, surfactant etc.
Used thickening agent can be one or more the mixture in sodium carboxymethyl cellulose, xanthan gum, gelatin, Guar gum, Radix Acaciae senegalis, methylcellulose, hydroxy methocel, hydroxyethyl-cellulose, the strong propyl cellulose.
Used surfactant can be cation, anion, both sexes or a nonionic surfactant commonly used in the hair dye, includes but not limited to a kind of in polyoxyethylenated alcohol sodium sulfate, glyceryl monostearate, alkyl sulfate salt, the sorbitol monostearate etc. or more than one mixture.
The invention provides the using method of above-mentioned hair dye, comprise hair dye is dissolved in evenly back and spread upon step on the hair of stirring and dissolving in water or the aqueous solution.Described aqueous solution can be the solution of dissolving hair dye adjuvant, especially can be the solution that contains surfactant, thickening agent.
The invention provides a kind of hair dyeing commercial packing, comprise the 1. part: hair dye, contain Rhizoma Curcumae Longae and tannic acid material; The 2. part: softening inorganic agent; The 3. part: chelating agen.This packing can further include the description of how to have hair dyed.
In commercial packing of the present invention, the two ratio of Rhizoma Curcumae Longae and tannic acid material is 50 in the described hair dye: 1-1: 50, and preferred, 20: 1-1: 20, preferred 10: 1-1: 10, by weight.
Rhizoma Curcumae Longae be positions such as zingiberaceous plant Rhizoma Curcumae Longae (claiming Radix Curcumae again) root, stem be used as medicine after pulverizing powder or powder extracted after extract or the effective ingredient curcumin (CAS:458-37-7 of Rhizoma Curcumae Longae, chemical name: 1, two (the 4-hydroxy 3-methoxybenzene bases)-1 of 7-, 6-heptadiene-3, the 5-diketone).The preferred used Rhizoma Curcumae Longae of the present invention is Rhizoma Curcumae Longae extract or curcumin.Powder after Rhizoma Curcumae Longae extract can adopt extracting method commonly used with Rhizoma Curcumae Longae plant or specific part pulverizing extracts acquisition, and water or alcohol are extracted, and preferred use 30-95% ethanol extracts.
Tannic acid claims tannin, tannin, tannin again, is the wider polyhydric phenols of molecule weight range, is divided into condensed tannins and hydrolyzable tannic acid, adopts suitable condition to be hydrolyzed the hydrolyzable tannic acid and can obtain micromolecule tannic acid and gallic acid monomer.Tannic acid material of the present invention comprises macromolecular tannic acid, also comprises micromolecule tannic acid and gallic acid.Industrial, above-mentioned tannic acid material all can adopt the synthetic method of chemical industry to obtain, and also can be that the fine powder that the plant of extracting from the plant that contains this type of material or will contain this type of material grinds to form obtains.These plants include but not limited to Galla Chinensis, Herba Ecliptae, Fructus rhois chinensis, Pericarpium Granati, Chinese gall Beihua, Fructus Musae neck etc., and preferred, tannic acid material of the present invention is a Galla Chinensis, preferred Galla Chinensis extract, and the tannic acid material is a gallotannic acid among preferred the present invention.
Being used for from the method for above-mentioned plant extraction tannic acid material can be this area extracting method commonly used, and water or alcohol are extracted, and preferred use 30-95% ethanol extracts.
In the hair dye of commercial packing of the present invention, can also add Flos Caryophylli further increases dyeing kinetics.Used Flos Caryophylli can be powder, the water of Flos Caryophylli or the extract of alcohol that the Flos Caryophylli medical material grinds, it can also be the effective ingredient ligustrin in the Flos Caryophylli, Flos Caryophylli preferred of the present invention is adopted water or the alcohol extract of Flos Caryophylli, and the Flos Caryophylli of adopting among preferred the present invention is the ethanol extraction of its 30-95%.
In the commercial packing of the present invention; the softening inorganic agent of described hair can comprise this area conventional substances; as sodium thioglycolate; sodium thiosulfate; cysteine class material etc.; the preferred inorganic agent that adopts before cysteine class material is had hair dyed as hair dye of the present invention in conjunction with organic base; described cysteine class material can be a cysteine; homocysteine; the carbamyl cysteine; the mixture of one or more in the N-acetylcysteine; it also can be the hydrochlorate of these materials; described organic base is the small molecule alkaline organic; its carbochain is short; comprise ethanolamine; ethylenediamine; diethylamine; triethylamine; dimethylamine; hydroxyethylethylene diamine; aminoethanolamine; sodium ethylene diamine tetracetates etc. preferably adopt ethanolamine; ethylenediamine or its mixture.
In the commercial packing of the present invention, described chelating agen is water solublity iron salt or ferrous salt, can be one or more the mixture in ferrous sulfate, ferrous chloride, iron sulfate, iron chloride, ferric nitrate, the ferrous nitrate.In order to improve the stability of iron ion or ferrous ion, can also in chelating agen, add stabilizing agent.Used stabilizing agent can be one or more the mixture in vitamin C, curcumin, sodium thiosulfate, iron powder, tea polyphenols, the sodium L-ascorbate-2-phosphate, a kind of or its mixture in preferred vitamin C, the curcumin.
In the commercial packing of the present invention, can also further add an amount of hair dye adjuvant in hair dye or the softening inorganic agent, these adjuvants are that the hair dye industry is generally used, and include but not limited to thickening agent, surfactant and water.Described thickening agent can be one or more the mixture in sodium carboxymethyl cellulose, xanthan gum, gelatin, Guar gum, Radix Acaciae senegalis, methylcellulose, hydroxy methocel, hydroxyethyl-cellulose, the hydroxypropyl cellulose, described surfactant can be cation, anion, both sexes or a nonionic surfactant commonly used in the hair dye, includes but not limited to a kind of in polyoxyethylenated alcohol sodium sulfate, glyceryl monostearate, alkyl sulfate salt, the sorbitol monostearate etc. or more than one mixture.
In the actual production, the chelating agen in the above-mentioned commercial packing can also be joined in the hair dye, be used for reducing the complexity of product, improve and produce use convenient.
At last, the invention provides the using method of above hair dye, comprise the following step:
A) behind the hair wash clean inorganic agent is evenly coated on the hair, keeps in touch 15-40min;
B) behind the hair wash clean of a step chelating agen is evenly coated on the hair, keeps in touch 15-40min;
C) behind the hair wash clean of b step hair dye is evenly spread upon on the hair, keep in touch 15-60min.
On the basis of above-mentioned steps, can reduce the operating time of each step by the method for hair being carried out preheating, accelerate hair dyeing speed, this is well-known to those skilled in the art.
At last, the invention provides the preparation method of above-mentioned hair dye:
Join Rhizoma Curcumae Longae, tannic acid material in the suitable quantity of water solution and be aided with stirring, it is even to continue to be stirred to solution after various components are dissolved fully, promptly gets hair dye.
Ferrous salt and/or iron salt are joined in the aqueous solution, and be aided with stirring, it is even to continue to be stirred to solution after various components are dissolved fully, promptly gets chelating agen.
Cysteine and derivant thereof and/or its salt and organic base are joined in the aqueous solution, and be aided with stirring, it is even to continue to be stirred to solution after various components are dissolved fully, promptly gets inorganic agent.
In above-mentioned preparation method, described aqueous solution can be a water, also can be the solution of dissolving hair dye adjuvant, especially can be the solution that contains surfactant, thickening agent.Chelating agen can also add stabilizing agent to increase the stability of ferrous salt and/or iron salt.
In above-mentioned preparation method, for the needs of producing, can be with chelating agen and inorganic agent encapsulation admixed together.
Description of drawings
Fig. 1 comparative example 2 hair dyes hair dyeing cross-sectional view
Fig. 2 embodiment of the invention 7 hair dyes hair dyeing cross-sectional view
The specific embodiment
Following embodiment is intended to illustrate specific embodiments of the present invention.
It is pointed out that the Galla Chinensis extract described in the following preparation embodiment, Rhizoma Curcumae Longae extract, Flos Caryophylli extract etc. can adopt extracting method provided by the invention to prepare, also can adopt any attainable extracting method acquisition in the prior art.Extracting method provided by the present invention only is used for illustrating a kind of implementation that obtains these extracts.
Rhizoma Curcumae Longae in the following example (Radix Curcumae) extract can adopt following method preparation:
Get 10g Radix Curcumae root or stem and be ground into powder, join in the 100ml water and stir 20min, sucking filtration.The ethanol that adds 100ml95% behind the gained filtrate transpiring moisture fully dissolves, and stirs 10min.Be condensed into extractum after the method for employing distilling under reduced pressure is removed ethanol, drying and crushing gets final product.
Galla Chinensis extract among the following embodiment can adopt following method preparation:
Get the 10g Galla Chinensis, join in the 50ml acetone and soaked 4 hours, be heated to 50 ℃ of hot refluxs 2 hours, behind the concentrated filtrate distillation acetone, the pulverizing of gained extract dry is got final product.
Used Flos Caryophylli extract can adopt following method preparation in the following example:
Folium Caryophylli is ground into powder, decocts three times each two hours with 5 times of water gagings.To cross macroporous resin treatment behind the gained filtrate hybrid filtering, water cleans after colourless and discards washing liquid, uses 80% ethanol elution.Behind the distilling under reduced pressure ethanol its concentrate drying is obtained Flos Caryophylli extract.
Curcumin in the following example is available from Nanjing Zelang Pharmaceutical Technology Inc., and gallotannic acid is purchased in the Xi'an amount thing Science and Technology Ltd. that supports one's family, and gallic acid is purchased in WuFeng ChiCheng Biology Science Co., Ltd.
Getting N-acetylcystein 2g, ethanolamine 10g, sodium carboxymethyl cellulose 3g joins 85g deionized water for stirring to dissolving fully and evenly promptly gets inorganic agent of the present invention;
Getting curcumin 3g, Galla Chinensis extract 2g, sodium carboxymethyl cellulose 5g joins 90g deionized water for stirring to dissolving fully and evenly promptly gets hair dye of the present invention;
Get ferrous chloride 4g, gelatin 3g and join the 93g deionized water for stirring, promptly get chelating agen of the present invention to dissolving is even fully.
According to the using method hair dyeing, with the hair wash clean, after drying inorganic agent is evenly spread upon on the hair, keep 10min; With the hair wash clean, after drying chelating agen is evenly spread upon on the hair again, keep 15min; Clean hair again, after drying hair dye evenly spread upon keep 15min on the hair after the wash clean hair can make the poliosis blackening.
Embodiment 2
Get cysteine 1g, ethylenediamine 5g, hydroxyethylethylene diamine 1g, sodium ethylene diamine tetracetate 1g, gelatin 5g and join in the 37g water, being stirred to fully, dissolving evenly promptly gets inorganic agent of the present invention;
Getting Galla Chinensis extract 5g, Rhizoma Curcumae Longae extract 5g, sodium carboxymethyl cellulose 10g joins and is stirred in the 30g water fully that dissolving evenly promptly gets hair dye of the present invention;
Get iron sulfate 2g, xanthan gum 1g and join and be stirred to fully dissolving in the 45g water evenly, promptly get chelating agen of the present invention.
According to the using method hair dyeing, with the hair wash clean, after drying inorganic agent is evenly spread upon on the hair, keep 10min; With the hair wash clean, after drying chelating agen is evenly spread upon on the hair again, keep 20min; Clean hair again, after drying hair dye evenly spread upon keep 30min on the hair after the wash clean hair can make the poliosis blackening.
Embodiment 3
Get homocysteine 5g, dimethylamine 4g, aminoethanolamine 5g and join and be stirred to dissolving fully in the 76g water, add the 10g sodium carboxymethyl cellulose again and continue to be stirred to fully that dissolving evenly promptly gets inorganic agent of the present invention;
Get Galla Chinensis abrasive flour 5g, Rhizoma Curcumae Longae extract 10g, Flos Caryophylli extract 2g, gelatin 10g join in the 73g water and stir, elimination precipitation.Continuing to be stirred to the gained supernatant fully, dissolving evenly promptly gets hair dye of the present invention;
Get ferrous sulfate 4g, sodium ascorbate 1g, polyoxyethylenated alcohol sodium sulfate 1g, xanthan gum 5g join in the 89g water, are stirred to fully dissolving in the water evenly, promptly get chelating agen of the present invention.
According to the using method hair dyeing, with the hair wash clean, after drying inorganic agent is evenly spread upon on the hair, keep 10min; Again with the hair wash clean, wipe in after chelating agen is evenly spread upon on the hair, keep 20min; Clean hair again, after drying hair dye evenly spread upon keep 20min on the hair after the wash clean hair can make the poliosis blackening.
Embodiment 4
Getting N-acetylcysteine hydrochlorate two hydrate 10g, ethylenediamine 7g, sodium carboxymethyl cellulose 10g, glyceryl monostearate 1g joins and is stirred in the 22g water fully that dissolving evenly promptly gets inorganic agent of the present invention;
Get gallotannic acid 2g, Rhizoma Curcumae Longae medical material abrasive flour 6g, sodium lauryl sulphate 1g, gelatin 5g join in the 36g water and stir, elimination medicinal powder residue.The gained supernatant is continued to be stirred to dissolving fully, promptly get hair dye of the present invention;
Getting iron chloride 3g, tea polyphenols 0.5g, Guar gum 3g joins and is stirred in the 43.5g water fully that dissolving evenly promptly gets chelating agen of the present invention.
According to the using method hair dyeing, with the hair wash clean, after drying inorganic agent is evenly spread upon on the hair, keep 10min; With the hair wash clean, after drying chelating agen is evenly spread upon on the hair again, keep 20min; Clean hair again, after drying hair dye evenly spread upon keep 30min on the hair after the wash clean hair can make the poliosis blackening.
Embodiment 5
Getting gallotannic acid 7g, curcumin 5g, ligustrin 0.1g, sodium carboxymethyl cellulose 15g joins and is stirred in the 73g water fully that dissolving evenly promptly gets hair dye of the present invention;
Getting ferrous chloride 5g, Catergen g, sodium carboxymethyl cellulose 7g joins and is stirred in the 86g water fully that dissolving evenly promptly gets chelating agen of the present invention.
According to using method hair dyeing, with the hair wash clean, after drying just chelating agen evenly spread upon on the hair, keep 20min; Clean hair again, after drying hair dye evenly spread upon keep 40min on the hair after the wash clean hair can make the poliosis blackening.
Embodiment 6
Getting N-acetylcysteine 10g, ethylenediamine 8g, sodium carboxymethyl cellulose 10g joins and is stirred in the 22g water fully that dissolving evenly promptly gets inorganic agent of the present invention;
Get gallic acid 3g, curcumin 5g, sodium lauryl sulphate 1g, gelatin 5g and join and be stirred to dissolving fully in the 36g water, promptly get hair dye of the present invention;
Getting ferrous chloride 3g, curcumin 0.5g, iron powder 0.01g, Guar gum 3g joins and is stirred in the 43.4g water fully that dissolving evenly promptly gets chelating agen of the present invention.
According to the using method hair dyeing, with the hair wash clean, after drying inorganic agent is evenly spread upon on the hair, keep 15min; With the hair wash clean, after drying chelating agen is evenly spread upon on the hair again, keep 10min; Clean hair again, after drying hair dye evenly spread upon keep 50min on the hair after the wash clean hair can make the poliosis blackening.
Embodiment 7
Getting black Herba Ecliptae extract 5g, curcumin 5g, sodium carboxymethyl cellulose 15g joins and is stirred in the 73g water fully that dissolving evenly promptly gets hair dye of the present invention;
Get iron chloride 5g, sodium carboxymethyl cellulose 7g and join and be stirred to fully dissolving in the 86g water evenly, promptly get chelating agen of the present invention.
Getting N-acetylcysteine 10g, ethylenediamine 8g, sodium carboxymethyl cellulose 10g joins and is stirred in the 72g water fully that dissolving evenly promptly gets inorganic agent of the present invention;
According to the using method hair dyeing, with the hair wash clean, just softening inorganic agent evenly spreads upon on the hair after drying, and keeps 20min; Clean hair again, after drying chelating agen evenly spread upon and keep wash clean hair behind the 40min on the hair; Hair dye evenly spread upon on the hair keep 60min can make the poliosis blackening.
Embodiment 8
Getting carbamyl cysteine 10g, hydroxyethylethylene diamine 8g, sodium carboxymethyl cellulose 10g joins and is stirred in the 22g water fully that dissolving evenly promptly gets inorganic agent of the present invention;
Get Chinese gall Beihua extract 3g, Rhizoma Curcumae Longae extract 10g, sodium lauryl sulphate 1g, gelatin 5g and join and be stirred to dissolving fully in the 31g water, promptly get hair dye of the present invention;
Get ferrous chloride 3g, Guar gum 3g and join and be stirred to fully dissolving in the 44g water evenly, promptly get chelating agen of the present invention.
According to the using method hair dyeing, with the hair wash clean, after drying inorganic agent is evenly spread upon on the hair, keep 15min; With the hair wash clean, after drying chelating agen is evenly spread upon on the hair again, keep 20min; Clean hair again, after drying hair dye evenly spread upon keep 60min on the hair after the wash clean hair can make the poliosis blackening.
The comparative example 1
According to the composition of the embodiment of the invention 1, get N-acetylcystein 2g, ethanolamine 10g, sodium carboxymethyl cellulose 3g join the 85g deionized water for stirring to dissolving fully evenly, as inorganic agent;
Get Galla Chinensis extract 5g, sodium carboxymethyl cellulose 5g and join the 90g deionized water for stirring to dissolving is even fully, as hair dye;
Get ferrous chloride 4g, gelatin 3g and join the 93g deionized water for stirring to dissolving is even fully, as chelating agen.
Use according to using method of the present invention.
The comparative example 2
Be prepared as follows hair dye according to China's application 2005101123796 technical schemes that provide:
Ferrous sulfate 15g, azone 12g, hydroxyethyl-cellulose 0.5g join in the 72.5g deionized water as the A agent;
Galla Chinensis extract 15g, silicone oil 8g, Lignum Sappan extract 1g join in the 76g deionized water as the B agent.
Using method: the A agent is brushed on hair with small brushes, at room temperature left standstill 8-10 minute; The B agent in kind being brushed on hair room temperature leaves standstill and got final product in 8-10 minute again.
The comparative example 3
Take by weighing Melanteritum 2.5g, Rhizoma Zingiberis Recens extract 3.0g, sodium carboxymethyl cellulose 3.0g, join the 91.5g deionized water for stirring successively to dissolving fully, as No. 1 agent;
Take by weighing sodium carboxymethyl cellulose 2.0g, Rhizoma Zingiberis Recens extract 3.0g, Pericarpium Granati 3.5g, join successively in the 91.5g deionized water, be stirred to dissolving fully, as No. 2 agent;
Hair washed No. 1 agent is evenly spread upon on the hair after drying, be heated to 40 ℃, keep 20min; Wash then, again No. 2 agent are evenly spread upon on the hair, be heated to 40 ℃, keep 20min.
Experimental example 1
Get a branch of hair, wash the back towel to there not being the globule.The inorganic agent of the invention process 1 evenly is applied on the hair, and water is cleaned hair behind the maintenance 20min.After toweling one's hair dry chelating agen evenly is applied in and keeps 15min on the hair, water is with the hair wash clean and dry.With hair dye evenly smear with hair on keep 30min after, water is dried the hair wash clean and is observed.
Get a branch of hair, wash the back towel to there not being the globule.The chelating agen of the invention process 5 evenly is applied on the hair, keep 20min after water hair is cleaned, with hair dye evenly smear with hair on keep 30min after, water is dried the hair wash clean and is observed.
Get a branch of hair, wash the back towel to there not being the globule.The inorganic agent of the embodiment of the invention 8 is evenly spread upon on the hair, keep 15min; With the hair wash clean, after drying chelating agen is evenly spread upon on the hair again, keep 20min; Clean hair again, after drying hair dye evenly spread upon keep 35min on the hair after the wash clean hair can make the poliosis blackening.
Get a branch of hair, wash the back towel to there not being the globule.Comparative example's 1 of the present invention inorganic agent evenly is applied on the hair, and water is cleaned hair behind the maintenance 20min.After toweling one's hair dry chelating agen evenly is applied in and keeps 15min on the hair, water is with the hair wash clean and dry.With hair dye evenly smear with hair on keep 30min after, water is dried the hair wash clean and is observed.
Get a branch of hair, wash the back towel to there not being the globule.Adopt comparative example's 2 of the present invention product, according to observing after its using method hair dyeing.
Get a branch of hair, wash the back towel, adopt comparative example's 3 of the present invention product, according to observing after its using method hair dyeing to there not being the globule.
The hair that under room temperature, daylight above-mentioned three embodiment is dyed is observed, and adopts contrast color to stick into row evaluation.The hair that embodiment 1,5,8 dyes is an ater, bias colour, variegated; The hair that comparative example 1 dyes is a rufous, and direct-view shows brown partially under daylight; The hair that comparative example 2 dyes is a dark-brown.The hair that comparative example 3 dyes is a brownish black, and pungent abnormal flavour is arranged.
With the hair washing frequency of above-mentioned three hairs that embodiment dyed according to the normal person, per two days with the warm water washing once.Continued to wash four months.The result shows that hair black that embodiment 1,8 dyes does not have and weakens not have the decolouring phenomenon., the hair that embodiment 5 dyes slight decolouring phenomenon occurs after two months at eluting.Phenomenon promptly appearred significantly fading in comparative example's 1,2 hairs that dyed at about 30 days, the hair that comparative example 3 dyes occurred fading significantly at 40 days, and acid is all arranged during eluting.
Can confirm that by above-mentioned experiment hair dye of the present invention can dye the hair of pure black, and use softening inorganic agent that hair is handled to make the black of hair more stable.Comparative example 1 and 2 only uses Galla Chinensis as staining components, and the color that dyes is bad, and stability is not good.Comparative example 3 adopts Pericarpium Granati extract (effective ingredient is a tannic acid) and Rhizoma Zingiberis Recens extract as hair dye ingredient, color that dyes and stability all are worse than tannic acid and Rhizoma Curcumae Longae extract, be zingiberaceous plant although show Rhizoma Zingiberis Recens and Rhizoma Curcumae Longae, but the character of its extract has very big difference, and Rhizoma Zingiberis Recens extract can not play the effect of Rhizoma Curcumae Longae extract.
Experimental example 2
Three doses of the hair dyes of the embodiment of the invention 2 preparation are all placed under 40 ℃, 75% relative humidity deposited six months, not seeing has precipitation or three agent solution layerings or three agent solution muddinesses.Dye a branch of hair according to using method then.And compare with hair that the hair dye of freshly prepd embodiment 2 dyes.The visualization indistinction illustrates that hair dye of the present invention has good stability.
Experimental example 3
The hair that hair dye embodiment 7 of the present invention is dyed is got one as specimen, and black part area is weighed the effect of the present invention's hair dyeing in the observation hair cross section.Comparative example's 2 hair dye cross section microexaminations as shown in Figure 1, it is bad that on the one hand effect is infiltrated in its hair dyeing, hair cross-section center part still is a white; Often it dyes black part and also becomes white along with time duration on the other hand.
Per two days frequencies according to the normal person with a hair of warm water washing, the embodiment of the invention 7 is dyed cross section of good hair observation in per two days, find that black part area is 100% in continuous two months cross sections, do not have white section and occur that microexamination figure as shown in Figure 2.
Above-mentioned microexamination figure as can be seen, hair dye better effects if of the present invention, it is more thorough to dye.
Experimental example 4
With the hair dyeing product of the embodiment of the invention 4 and comparative example's 1,2,3 preparations, carry out Color, painted stability relatively.The sampling number is 100 people, all tests on same crowd, and the interval is two months each other.Result of the test shows that hair dye of the present invention relative prior art on Color and painted stability all has tangible progress.Its statistical result such as following table:
Claims (15)
1. a hair dye comprises Rhizoma Curcumae Longae and tannic acid material.
2. according to the hair dye of claim 1, described Rhizoma Curcumae Longae is a kind of in the extract, curcumin of zingiberaceous plant Rhizoma Curcumae Longae or the mixture of the two.
3. according to the hair dye of claim 1, described tannic acid material comprises gallic acid.
4. according to the hair dye of claim 1, described tannic acid material is one or more alcohol extract and/or the water extract in Galla Chinensis, Herba Ecliptae, Fructus rhois chinensis, Pericarpium Granati, Chinese gall Beihua, the Fructus Musae neck.
5. according to the hair dye of claim 1, described tannic acid is a gallotannic acid.
6. according to the hair dye of claim 1, also further comprise Flos Caryophylli.
7. according to the hair dye of claim 6, described Flos Caryophylli is Flos Caryophylli abrasive flour, Flos Caryophylli water or alcohol extract, ligustrin or its mixture.
8. hair dyeing commercial packing comprises the hair dye of each claim among the 1. claim 1-7; 2. hair softens inorganic agent; 3. chelating agen.
9. commercial packing according to Claim 8, softening inorganic agent wherein contains cysteine compounds, organic base.
10. according to the commercial packing of claim 9, described cysteine compounds is one or more the mixture in cysteine, homocysteine, carbamyl cysteine, the N acetylcysteine.
11. according to the commercial packing of claim 9, described organic base is a kind of in ethanolamine, ethylenediamine, diethylamine, triethylamine, dimethylamine, hydroxyethylethylene diamine, aminoethanolamine, the sodium ethylene diamine tetracetate and/or more than one mixture.
12. commercial packing according to Claim 8, described chelating agen are one or more the mixture in ferrous sulfate, ferrous chloride, iron sulfate, iron chloride, ferric nitrate, the ferrous nitrate.
13. commercial packing according to Claim 8 also comprises operation instructions.
14. the using method of the hair dye of the arbitrary claim of claim 1-7 comprises Rhizoma Curcumae Longae, tannic acid material are joined water or water
In the solution and be aided with stirring, smear to the step of hair.
15. the using method of the hair dyeing commercial packing of each claim of claim 8-13 comprises the steps:
A) behind the hair wash clean inorganic agent is evenly coated on the hair, keeps in touch 15-40min;
B) behind the hair wash clean of a step chelating agen is evenly coated on the hair, keeps in touch 15-40min;
C) behind the hair wash clean of b step hair dye is evenly spread upon on the hair, keep in touch 15-60min.
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| CN 201010225971 CN101879135B (en) | 2009-11-12 | 2010-07-14 | Curcuma plant hair dye |
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| CN 201010225971 CN101879135B (en) | 2009-11-12 | 2010-07-14 | Curcuma plant hair dye |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102166173A (en) * | 2011-03-08 | 2011-08-31 | 贵州阿斯科科技开发有限公司 | Ecological plant hair dye and preparation method thereof |
| CN102423286A (en) * | 2011-11-24 | 2012-04-25 | 江南大学 | Natural hair dye prepared by using phytochrome curcumin and hair dyeing method of natural hair dye |
| CN102657585A (en) * | 2012-05-30 | 2012-09-12 | 江南大学 | Hair dye for enhancing color fastness of natural pigment curcumin |
| CN103237540A (en) * | 2010-12-24 | 2013-08-07 | 东星制药株式会社 | Mixed metal-plant-based hair dye composition including cysteine, and method for dyeing hair using same |
| WO2014139163A1 (en) * | 2013-03-15 | 2014-09-18 | 北京世纪博康医药科技有限公司 | Composition for hair dyeing and hair dye prepared thereby |
| WO2014139153A1 (en) * | 2013-03-15 | 2014-09-18 | 北京世纪博康医药科技有限公司 | Composition for hair dyeing and application thereof |
| CN105687085A (en) * | 2016-03-10 | 2016-06-22 | 蚌埠团结日用化学有限公司 | Natural plant hair dye and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103237540A (en) * | 2010-12-24 | 2013-08-07 | 东星制药株式会社 | Mixed metal-plant-based hair dye composition including cysteine, and method for dyeing hair using same |
| CN102166173A (en) * | 2011-03-08 | 2011-08-31 | 贵州阿斯科科技开发有限公司 | Ecological plant hair dye and preparation method thereof |
| CN102166173B (en) * | 2011-03-08 | 2012-11-28 | 贵州阿斯科科技开发有限公司 | Ecological plant hair dye and preparation method thereof |
| CN102423286A (en) * | 2011-11-24 | 2012-04-25 | 江南大学 | Natural hair dye prepared by using phytochrome curcumin and hair dyeing method of natural hair dye |
| CN102657585A (en) * | 2012-05-30 | 2012-09-12 | 江南大学 | Hair dye for enhancing color fastness of natural pigment curcumin |
| WO2014139163A1 (en) * | 2013-03-15 | 2014-09-18 | 北京世纪博康医药科技有限公司 | Composition for hair dyeing and hair dye prepared thereby |
| WO2014139153A1 (en) * | 2013-03-15 | 2014-09-18 | 北京世纪博康医药科技有限公司 | Composition for hair dyeing and application thereof |
| CN105687085A (en) * | 2016-03-10 | 2016-06-22 | 蚌埠团结日用化学有限公司 | Natural plant hair dye and preparation method thereof |
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| CN101879135B (en) | 2013-03-06 |
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