TWI713829B - Plant-based black hair dye and hair dyeing method - Google Patents

Plant-based black hair dye and hair dyeing method Download PDF

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TWI713829B
TWI713829B TW107109917A TW107109917A TWI713829B TW I713829 B TWI713829 B TW I713829B TW 107109917 A TW107109917 A TW 107109917A TW 107109917 A TW107109917 A TW 107109917A TW I713829 B TWI713829 B TW I713829B
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hair dye
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black hair
eucalyptus
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TW201940153A (en
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彭瓊玲
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田錦衡
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Abstract

一種植物性黑色染髮劑及染髮方法,是採用桉樹葉及柚木葉之植物萃取物為主要原料,此植物性黑色染髮劑分為第一劑和第二劑,先利用第一劑中的植物萃取物於溫熱環境下滲入頭髮纖維中,再與第二劑中的亞鐵離子絡合形成大分子不溶性黑色物質而固著於頭髮上;其中,第一劑進一步可搭配印地科植物或茶葉植物萃取物共同使用,而染得深黑色之髮色。本發明並未使用化學溶劑、滲透劑及表面活性劑等對人體有害之物質,配方簡單、安全,且染色效果佳。A botanical black hair dye and a method for dyeing hair. It uses plant extracts of eucalyptus leaves and teak leaves as the main raw materials. This botanical black hair dye is divided into the first agent and the second agent. The plant extracts in the first agent are used first The substance penetrates into the hair fibers in a warm environment, and then complexes with the ferrous ions in the second agent to form a macromolecular insoluble black substance which is fixed on the hair; wherein the first agent can be further matched with Indian plants or tea leaves Plant extracts are used together, and the hair is dyed dark black. The invention does not use chemical solvents, penetrants, surfactants and other substances harmful to the human body, and the formula is simple and safe, and the dyeing effect is good.

Description

植物性黑色染髮劑及染髮方法Plant-based black hair dye and hair dyeing method

本發明係有關於一種植物性染髮劑,特別是有關於一種提取桉樹葉萃取物或柚木葉萃取物作為主要原料之植物性黑色染髮劑及染髮方法。The present invention relates to a botanical hair dye, and particularly relates to a botanical black hair dye and a hair dyeing method using eucalyptus leaf extract or teak leaf extract as the main raw material.

目前市場上銷售的各種染髮劑,其成分大都含有對人體有害的化學物質,例如,對苯二胺、雙氧水、氨水、滲透劑、防腐劑及有害重金屬等,容易引起皮膚刺激、過敏,嚴重者可能誘發癌症。因此,近年來安全性較高的植物性染髮劑越來越受消費者重視。如富含多酚類或鞣酸成分之植物,例如,兒茶素、蘇木精、五倍子、柿子皮、檳榔子……等,均有被研究應用於染髮劑。The various hair dyes currently on the market mostly contain chemical substances harmful to the human body, such as p-phenylenediamine, hydrogen peroxide, ammonia, penetrants, preservatives, and harmful heavy metals, which can easily cause skin irritation, allergies, and severe cases. May induce cancer. Therefore, in recent years, more and more safe plant-based hair dyes have attracted more and more attention from consumers. For example, plants rich in polyphenols or tannic acids, such as catechins, hematoxylin, gallnut, persimmon peel, betel nut, etc., have all been studied for use in hair dyes.

舉例來說,中國專利第101164528A號揭示一種天然染髮劑,其包括A、B兩劑,A劑含有兒茶素、有機溶劑,B劑含有亞鐵鹽、還原鐵粉、表面活性劑、增稠劑、天然香精等。中國專利第106265333A號揭示一種中藥染髮劑,以柿子皮為主要原料,利用柿子皮富含的酚類及鞣酸活性物質作為染髮劑的染料,並含有五倍子、生薑、半胱氨酸、尿素、抗氧化劑、防腐劑等。另外,中國專利第102397170A號揭示一種植物染髮劑,其包括A、B兩劑,A劑含有水溶性鐵鹽與賦形劑,B劑含有含單寧酸或蘇木素,並含有半胱氨酸、烷醇胺、鹼性無機物。上述專利雖然使用植物性成分作為原料,但為了提昇染色效果仍需添加有機溶劑、氨水、抗氧化劑等化學物質,這些物質對人體仍有危害之疑慮。For example, Chinese Patent No. 101164528A discloses a natural hair dye, which includes two agents A and B. Agent A contains catechins and organic solvents, and agent B contains ferrous salts, reduced iron powder, surfactants, and thickening agents. Agents, natural flavors, etc. Chinese Patent No. 106265333A discloses a traditional Chinese medicine hair dye, which uses persimmon skin as the main raw material, uses the phenols and tannic acid active substances rich in persimmon skin as the dye for hair dye, and contains gall, ginger, cysteine, and urea , Antioxidants, preservatives, etc. In addition, Chinese Patent No. 102397170A discloses a plant hair dye, which includes two agents A and B. Agent A contains water-soluble iron salts and excipients, and agent B contains tannic acid or hematoxylin, and contains cysteine, Alkanolamine, alkaline inorganic substance. Although the above-mentioned patent uses plant-based ingredients as raw materials, in order to improve the dyeing effect, organic solvents, ammonia, antioxidants and other chemical substances are still added. These substances are still harmful to the human body.

因此,便有需要尋求一種植物性染髮劑及染髮方法,不用添加任何化學物質,以對人體具有更高之安全性。Therefore, there is a need to find a plant-based hair dye and a method for dyeing hair without adding any chemical substances, so as to have higher safety to the human body.

有鑑於此,本發明的主要目的在於提供一種植物性黑色染髮劑及染髮方法,利用桉樹葉或柚木葉之植物萃取物作為主要原料,其先於溫熱環境下滲入頭髮纖維,再與亞鐵離子形成絡合鍵結,能獲得自然黑髮之染色效果,不僅配方簡單、安全,無須添加任何化學物質,且其染色具有更佳的耐久性。In view of this, the main purpose of the present invention is to provide a botanical black hair dye and a hair dyeing method, using plant extracts of eucalyptus leaves or teak leaves as the main raw material, which penetrates into the hair fibers in a warm environment, and then interacts with ferrous iron The ions form a complex bond to obtain the dyeing effect of natural black hair. Not only the formula is simple and safe, no chemical substances are added, and the dyeing has better durability.

本發明的另一目的在於提供一種植物性黑色染髮劑及染髮方法,進一步可將桉樹葉或柚木葉之植物萃取物搭配印地科植物或茶葉植物,而可將髮色染成深黑色,以滿足較高強度顏色的染髮需求。Another object of the present invention is to provide a botanical black hair dye and a method for dyeing hair. Furthermore, plant extracts of eucalyptus leaves or teak leaves can be combined with Indian plants or tea plants, and the hair color can be dyed dark black. Meet the needs of hair dyeing with higher intensity colors.

為了達到上述目的,本發明提供了一種植物性黑色染髮劑,此植物性黑色染髮劑為第一劑與第二劑所配套組合而成,其中第一劑包含植物萃取物與第一增稠劑,植物萃取物包含桉樹葉萃取物或柚木葉萃取物,而第二劑包含亞鐵鹽與第二增稠劑。In order to achieve the above objective, the present invention provides a botanical black hair dye. The botanical black hair dye is a combination of a first agent and a second agent, wherein the first agent contains a plant extract and a first thickener , The plant extract contains eucalyptus leaf extract or teak leaf extract, and the second agent contains ferrous salt and a second thickener.

前述植物性黑色染髮劑中,植物萃取物可由桉樹葉或柚木葉萃取之液體或直接由桉樹葉或柚木葉乾燥磨碎之粉體;具體而言,植物萃取物佔第一劑的重量百分比為5~50%,較佳為15~50%。In the aforementioned botanical black hair dye, the plant extract can be a liquid extracted from eucalyptus leaves or teak leaves or directly dried and ground powder from eucalyptus leaves or teak leaves; specifically, the weight percentage of the plant extracts in the first agent is 5-50%, preferably 15-50%.

前述植物性黑色染髮劑中,桉樹葉萃取物可為任何桉樹屬植物之樹葉,例如檸檬桉、大葉桉、蘋果桉或薄荷桉之樹葉。柚木葉萃取物可為任何柚木屬植物之樹葉。In the aforementioned botanical black hair dye, the eucalyptus leaf extract can be leaves of any plant of the genus Eucalyptus, such as leaves of Eucalyptus lemon, Eucalyptus grandis, Eucalyptus apple, or Eucalyptus mint. The teak leaf extract can be the leaves of any teak plant.

前述植物性黑色染髮劑中,植物萃取物更可包含印地科(indigo)植物萃取物或茶葉萃取物;其中,印地科植物萃取物可為任何含印地科之植物,例如,可取自木藍或大青;茶葉植物可為任何茶樹品種之植物,例如,可取自台茶12號;具體而言,印地科植物萃取物或茶葉萃取物與桉樹葉萃取物或柚木葉萃取物的重量比可為0.1~1:1,較佳為0.5~1:1。Among the aforementioned botanical black hair dyes, the plant extract may further include an indigo plant extract or a tea extract; wherein the indigo plant extract may be any plant containing the indigo family, for example, it is desirable From Mulan or Daqing; the tea plant can be any tea plant species, for example, it can be taken from Taicha No. 12; specifically, Hindi family plant extract or tea extract and eucalyptus leaf extract or teak leaf extract The weight ratio of the substance can be 0.1-1:1, preferably 0.5-1:1.

前述植物性黑色染髮劑中,亞鐵鹽可選自硫酸亞鐵、醋酸亞鐵、氯化亞鐵或氧化鐵;具體而言,亞鐵鹽佔第二劑的重量百分比為0.1~6%。In the aforementioned botanical black hair dye, the ferrous salt can be selected from ferrous sulfate, ferrous acetate, ferrous chloride or ferric oxide; specifically, the ferrous salt accounts for 0.1 to 6% by weight of the second agent.

前述植物性黑色染髮劑中,第一增稠劑與第二增稠劑可為任何增加濃稠度之增稠劑,如羧甲基纖維素、甲基纖維素、乙基纖維素、阿拉伯膠或玉米糖膠;具體而言,第一增稠劑佔第一劑的重量百分比為1~30%,第二增稠劑佔該第二劑的重量百分比為1~30%。In the aforementioned botanical black hair dye, the first thickener and the second thickener can be any thickener that increases the consistency, such as carboxymethyl cellulose, methyl cellulose, ethyl cellulose, gum arabic or Corn gum; specifically, the first thickener accounts for 1-30% by weight of the first agent, and the second thickener accounts for 1-30% by weight of the second agent.

此外,本發明也提供一種染髮方法,使用前述植物性黑色染髮劑,此染髮方法是先將前述第一劑均勻塗抹於頭髮上,於40~50℃的溫度下加熱30分鐘,以清水沖洗,然後,將第二劑均勻塗抹於頭髮上,於室溫下停留20~40分鐘,再以清水沖洗、吹乾,可得到近似自然黑色之髮色。In addition, the present invention also provides a hair dyeing method using the aforementioned botanical black hair dye. The method of dyeing hair is to first apply the first agent evenly on the hair, heat it at a temperature of 40-50°C for 30 minutes, and rinse with water. Then, apply the second agent evenly on the hair, leave it at room temperature for 20-40 minutes, rinse with water, and blow dry to obtain a hair color similar to natural black.

前述染髮方法中,於將第一劑塗抹於頭髮並加熱30分鐘的步驟之後,更包含於室溫下停留2~3小時,再進行清水沖洗。In the aforementioned hair dyeing method, after the step of applying the first agent to the hair and heating for 30 minutes, it further includes staying at room temperature for 2 to 3 hours, and then rinsing with water.

根據本發明所揭露之植物性黑色染髮劑及染髮方法,其中第一劑所使用之桉樹葉或柚木葉及印地科或茶葉植物萃取物均為植物性成分,無添加其他溶劑或化學物質,對人體具有更高之安全性,而第二劑所使用之亞鐵鹽,對人體同樣無害,且為化妝品及食品所允許使用之成分。再者,藉由本發明所揭露之植物性黑色染髮劑,由於桉樹葉或柚木葉萃取物可滲入頭髮纖維並透過亞鐵離子形成絡合鍵結,相較於一般僅為表面附著之植物染髮劑,係具有更佳之耐久性。According to the botanical black hair dye and hair dyeing method disclosed in the present invention, the eucalyptus leaves or teak leaves and the extracts of Indysaceae or tea plants used in the first agent are all botanical ingredients, and no other solvents or chemical substances are added. It has higher safety to the human body, and the ferrous salt used in the second dose is also harmless to the human body, and it is an allowed ingredient in cosmetics and food. Furthermore, with the botanical black hair dye disclosed in the present invention, since the eucalyptus leaf or teak leaf extract can penetrate into the hair fiber and form complex bonds through ferrous ions, it is compared with the general plant hair dye that is only attached to the surface. It has better durability.

底下藉由具體實施例詳加說明,當更容易瞭解本發明之目的、技術內容、特點及其所達成之功效。Detailed descriptions are given below by specific embodiments, so that it is easier to understand the purpose, technical content, features, and effects of the present invention.

本發明揭露一種植物性黑色染髮劑,乃是由第一劑與第二劑所配套組合而成,且第一劑與第二劑的形式可為粉體或黏稠液體,它們是由以下重量百分比的原料配置而成。The present invention discloses a plant-based black hair dye, which is formed by a combination of the first agent and the second agent, and the first agent and the second agent can be in the form of powder or viscous liquid, and they are composed of the following weight percentages The raw materials are configured.

用於本發明植物性黑色染髮劑之第一劑,包含有5~50%且較佳為15~50%的植物萃取物與1~30%的第一增稠劑,其餘為水,且各成份加總的重量百分比為100%。其中,植物萃取物包含桉樹(Eucalyptus)葉萃取物或柚木(Teak;Tectona grandis)葉萃取物,且可由桉樹葉或柚木葉萃取之液體或直接由桉樹葉或柚木葉乾燥磨碎之粉體。具體而言,桉樹葉萃取物的來源可為任何桉樹屬植物之樹葉,例如檸檬桉、大葉桉、蘋果桉或薄荷桉之樹葉。柚木葉萃取物的來源可為任何柚木屬植物之樹葉;柚木又名胭脂樹,英文名稱為Tectona grandis,屬馬鞭草科,相較於中文名稱同樣稱為胭脂樹、但英文名稱為bixa Orleans,則屬胭脂科,兩者並不相同。具體而言,第一增稠劑可為羧甲基纖維素、甲基纖維素、乙基纖維素、阿拉伯膠或玉米糖膠。The first agent used in the plant-based black hair dye of the present invention contains 5-50% and preferably 15-50% of plant extracts and 1-30% of the first thickener, the rest being water, and each The total weight percentage of the ingredients is 100%. Among them, the plant extracts include Eucalyptus leaf extract or Teak (Teak; Tectona grandis) leaf extract, and can be extracted from eucalyptus leaves or teak leaves or directly dried and ground powders from eucalyptus leaves or teak leaves. Specifically, the source of the eucalyptus leaf extract can be the leaves of any plant of the genus Eucalyptus, such as the leaves of lemon eucalyptus, eucalyptus grandis, apple eucalyptus, or mint eucalyptus. The source of teak leaf extract can be the leaves of any teak genus; teak is also known as annatto, and the English name is Tectona grandis, belonging to the Verbena family. Compared with the Chinese name, it is also called annatto, but the English name is bixa Orleans. They belong to the cochineal family, and the two are not the same. Specifically, the first thickener may be carboxymethyl cellulose, methyl cellulose, ethyl cellulose, gum arabic or corn sugar gum.

用於本發明植物性黑色染髮劑之第二劑,包含有0.1~6%的亞鐵鹽與1~30%的第二增稠劑,其餘為水,且各成份加總的重量百分比為100%。具體而言,亞鐵鹽可選自硫酸亞鐵、醋酸亞鐵、氯化亞鐵或氧化鐵。具體而言,第二增稠劑可為任何增加濃稠度之增稠劑,如羧甲基纖維素、甲基纖維素、乙基纖維素、阿拉伯膠或玉米糖膠。The second agent used in the plant-based black hair dye of the present invention contains 0.1 to 6% of ferrous salt and 1 to 30% of the second thickener, the rest is water, and the total weight percentage of each component is 100 %. Specifically, the ferrous salt may be selected from ferrous sulfate, ferrous acetate, ferrous chloride, or iron oxide. Specifically, the second thickening agent can be any thickening agent that increases the consistency, such as carboxymethyl cellulose, methyl cellulose, ethyl cellulose, gum arabic or corn gum.

進一步地,用於本發明植物性黑色染髮劑之植物萃取物中,更可包含有印地科(indigo)植物萃取物或茶葉萃取物,印地科植物萃取物或茶葉萃取物與桉樹葉萃取物或柚木葉萃取物的重量比可為任何比例,例如為0.1~1:1,較佳為0.5~1:1。具體而言,印地科植物萃取物可為任何含印地科之植物,例如,可取自木藍或大青;茶葉萃取物可為任何茶樹,例如,可取自台茶12號。Further, the plant extracts used in the botanical black hair dye of the present invention may further include indigo plant extracts or tea extracts, indigo plant extracts or tea extracts and eucalyptus leaf extracts. The weight ratio of the extract or the teak leaf extract can be any ratio, for example, 0.1-1:1, preferably 0.5-1:1. Specifically, the extract of the Indian family plant may be any plant containing the Indian family, for example, it may be taken from Mulan or Daqing; the tea extract may be any tea tree, for example, it may be taken from No. 12 Taicha.

在實際應用上,本發明之植物性黑色染髮劑能夠被用於對於頭髮進行染色,透過這種植物性黑色染髮劑將可得到近似自然黑色之髮色,同時,由於桉樹葉或柚木葉之植物萃取物可滲入頭髮纖維,並透過亞鐵離子來形成絡合鍵結,請參見第2圖和第3圖,其分別為桉樹葉萃取物、柚木葉萃取物與亞鐵離子絡合反應之示意圖。藉此,相較於一般僅為表面附著之植物染髮劑,本發明之植物性黑色染髮劑係具有更佳之耐久性。In practical applications, the plant-based black hair dye of the present invention can be used to dye hair. Through this plant-based black hair dye, a hair color that is similar to natural black can be obtained. At the same time, due to the plants of eucalyptus or teak leaves The extract can penetrate hair fibers and form complex bonds through ferrous ions. Please refer to Figures 2 and 3, which are schematic diagrams of the complex reaction between eucalyptus leaf extract, teak leaf extract and ferrous ions. As a result, the plant-based black hair dye of the present invention has better durability than the general plant hair dye that is only attached to the surface.

請參照第1圖,說明本發明所提供之染髮方法的流程圖。此染髮方法,使用了前述植物性黑色染髮劑,並包括如下步驟:Please refer to Figure 1 to illustrate the flow chart of the hair dyeing method provided by the present invention. This hair dyeing method uses the aforementioned plant-based black hair dye and includes the following steps:

首先,見步驟S101,將前述植物性黑色染髮劑之第一劑均勻塗抹於頭髮上,於40~50℃的溫度下加熱30分鐘,以清水沖洗;此步驟中,在將第一劑塗抹於頭髮上並加熱30分鐘之後,可先於室溫下停留2~3小時,再進行清水沖洗。First, see step S101, apply the first agent of the aforementioned botanical black hair dye evenly on the hair, heat it at a temperature of 40-50°C for 30 minutes, and rinse with water; in this step, apply the first agent to the hair After heating the hair for 30 minutes, it can be left at room temperature for 2 to 3 hours, and then rinsed with water.

然後,見步驟S102,將前述植物性黑色染髮劑之第二劑均勻塗抹於頭髮上,於室溫下停留20~40分鐘,再以清水沖洗、吹乾,以得到近似自然黑色之髮色。Then, referring to step S102, the second agent of the aforementioned botanical black hair dye is evenly applied to the hair, and left at room temperature for 20-40 minutes, and then rinsed with water and blow-dried to obtain a hair color that is approximately natural black.

接著,以下藉由提出複數具體實施例,將進一步詳細說明本發明如何製備植物性黑色染髮劑,以及使用此些植物性黑色染髮劑所進行的染髮方法,最後再比較所得到的染髮效果。Next, by presenting a plurality of specific examples, how to prepare the plant-based black hair dye and the method of dyeing using these plant-based black hair dyes according to the present invention will be further explained in detail, and finally the obtained hair dyeing effects will be compared.

實施例一 第一劑:取檸檬桉葉萃取液2克、羧甲基纖維素0.6克、水10克,於室溫下溶解。 第二劑:取硫酸亞鐵0.5克、羧甲基纖維素0.6克、水10克,於室溫下溶解。 染髮方法:將第一劑均勻塗抹於頭髮上,於45℃的溫度下加熱30分鐘,以清水沖洗。再將第二劑均勻塗抹於頭髮上,於室溫下停留30分鐘,再以清水沖洗、吹乾。 Example 1 The first dose: Take 2 grams of lemon eucalyptus leaf extract, 0.6 grams of carboxymethyl cellulose, and 10 grams of water, and dissolve at room temperature. The second dose: Take 0.5 g of ferrous sulfate, 0.6 g of carboxymethyl cellulose, and 10 g of water, and dissolve at room temperature. Hair dyeing method: apply the first dose evenly on the hair, heat it at 45℃ for 30 minutes, and rinse with water. Then apply the second agent evenly on the hair, leave it at room temperature for 30 minutes, rinse with water and blow dry.

實施例二 第一劑:取檸檬桉葉萃取液2克、木藍粉2克、羧甲基纖維素0.6克,於10克的80℃熱水中溶解。 第二劑:取硫酸亞鐵0.5克、羧甲基纖維素0.6克、水10克,於室溫下溶解。 染髮方法:將第一劑均勻塗抹於頭髮上,於45℃的溫度下加熱30分鐘,然後於室溫下停留3小時,以清水沖洗。再將第二劑均勻塗抹於頭髮上,於室溫下停留30分鐘,再以清水沖洗、吹乾。 Example 2 The first agent: Take 2 grams of lemon eucalyptus leaf extract, 2 grams of wood blue powder, and 0.6 grams of carboxymethyl cellulose, and dissolve them in 10 grams of hot water at 80°C. The second dose: Take 0.5 g of ferrous sulfate, 0.6 g of carboxymethyl cellulose, and 10 g of water, and dissolve at room temperature. Hair dyeing method: apply the first dose evenly on the hair, heat it at 45°C for 30 minutes, then leave it at room temperature for 3 hours, and rinse with water. Then apply the second agent evenly on the hair, leave it at room temperature for 30 minutes, rinse with water and blow dry.

實施例三 第一劑:取大葉桉葉萃取液2克、羧甲基纖維素0.6克、水10克,於室溫下溶解。 第二劑:取硫酸亞鐵0.5克、羧甲基纖維素0.6克、水10克,於室溫下溶解。 染髮方法:將第一劑均勻塗抹於頭髮上,於45℃的溫度下加熱30分鐘,以清水沖洗。再將第二劑均勻塗抹於頭髮上,於室溫下停留30分鐘,再以清水沖洗、吹乾。 Example 3 First agent: Take 2 grams of Eucalyptus leaf extract, 0.6 grams of carboxymethyl cellulose, and 10 grams of water, and dissolve at room temperature. The second dose: Take 0.5 g of ferrous sulfate, 0.6 g of carboxymethyl cellulose, and 10 g of water, and dissolve at room temperature. Hair dyeing method: apply the first dose evenly on the hair, heat it at 45℃ for 30 minutes, and rinse with water. Then apply the second agent evenly on the hair, leave it at room temperature for 30 minutes, rinse with water and blow dry.

實施例四 第一劑:取大葉桉葉萃取液2克、木藍粉2克、羧甲基纖維素0.6克,於10克的80℃熱水中溶解。 第二劑:取硫酸亞鐵0.5克、羧甲基纖維素0.6克、水10克,於室溫下溶解。 染髮方法:將第一劑均勻塗抹於頭髮上,於45℃的溫度下加熱30分鐘,然後於室溫下停留3小時,以清水沖洗。再將第二劑均勻塗抹於頭髮上,於室溫下停留30分鐘,再以清水沖洗、吹乾。 Example 4 First agent: Take 2 grams of Eucalyptus grandis leaf extract, 2 grams of wood blue powder, and 0.6 grams of carboxymethyl cellulose, and dissolve them in 10 grams of hot water at 80°C. The second dose: Take 0.5 g of ferrous sulfate, 0.6 g of carboxymethyl cellulose, and 10 g of water, and dissolve at room temperature. Hair dyeing method: apply the first dose evenly on the hair, heat it at 45°C for 30 minutes, then leave it at room temperature for 3 hours, and rinse with water. Then apply the second agent evenly on the hair, leave it at room temperature for 30 minutes, rinse with water and blow dry.

實施例五 第一劑:取柚木葉粉2克、玉米糖漿0.2克,於10克的80℃熱水中溶解。 第二劑:取硫酸亞鐵0.5克、玉米糖漿0.2克、水10克,於室溫下溶解。 染髮方法:將第一劑均勻塗抹於頭髮上,於45℃的溫度下加熱30分鐘,然後以清水沖洗。再將第二劑均勻塗抹於頭髮上,於室溫下停留30分鐘,再以清水沖洗、吹乾。 Example 5 First dose: Take 2 grams of teak leaf powder and 0.2 grams of corn syrup, and dissolve them in 10 grams of hot water at 80°C. The second dose: take 0.5 g of ferrous sulfate, 0.2 g of corn syrup, and 10 g of water, and dissolve at room temperature. Hair dyeing method: Apply the first dose evenly on the hair, heat it at 45°C for 30 minutes, and then rinse with water. Then apply the second agent evenly on the hair, leave it at room temperature for 30 minutes, rinse with water and blow dry.

實施例六 第一劑:取柚木葉粉2克、木藍粉2克、玉米糖漿0.2克,於10克的80℃熱水中溶解。 第二劑:取硫酸亞鐵0.5克、玉米糖漿0.2克、水10克,於室溫下溶解。 染髮方法:將第一劑均勻塗抹於頭髮上,於45℃的溫度下加熱30分鐘,然後於室溫下停留3小時,以清水沖洗。再將第二劑均勻塗抹於頭髮上,於室溫下停留30分鐘,再以清水沖洗、吹乾。 Example 6 The first dose: Take 2 grams of teak leaf powder, 2 grams of wood blue powder, and 0.2 grams of corn syrup, and dissolve them in 10 grams of hot water at 80°C. The second dose: take 0.5 g of ferrous sulfate, 0.2 g of corn syrup, and 10 g of water, and dissolve at room temperature. Hair dyeing method: apply the first dose evenly on the hair, heat it at 45°C for 30 minutes, then leave it at room temperature for 3 hours, and rinse with water. Then apply the second agent evenly on the hair, leave it at room temperature for 30 minutes, rinse with water and blow dry.

實施例七 第一劑:取柚木葉粉2克、茶葉粉2克、玉米糖漿0.2克,於10克的80℃熱水中溶解。 第二劑:取硫酸亞鐵0.5克、玉米糖漿0.2克、水10克,於室溫下溶解。 染髮方法:將第一劑均勻塗抹於頭髮上,於45℃的溫度下加熱30分鐘,然後以清水沖洗。再將第二劑均勻塗抹於頭髮上,於室溫下停留30分鐘,再以清水沖洗、吹乾。 Example 7 The first dose: Take 2 grams of teak leaf powder, 2 grams of tea powder, and 0.2 grams of corn syrup, and dissolve them in 10 grams of hot water at 80°C. The second dose: take 0.5 g of ferrous sulfate, 0.2 g of corn syrup, and 10 g of water, and dissolve at room temperature. Hair dyeing method: Apply the first dose evenly on the hair, heat it at 45°C for 30 minutes, and then rinse with water. Then apply the second agent evenly on the hair, leave it at room temperature for 30 minutes, rinse with water and blow dry.

比較例一 第一劑:取木藍粉2克、羧甲基纖維素0.6克,於10克的80℃熱水中溶解。 第二劑:取硫酸亞鐵0.5克、羧甲基纖維素0.6克、水10克,於室溫下溶解。 染髮方法:將第一劑均勻塗抹於頭髮上,於45℃的溫度下加熱30分鐘,然後於室溫下停留3小時,以清水沖洗。再將第二劑均勻塗抹於頭髮上,於室溫下停留30分鐘,再以清水沖洗、吹乾。 Comparative Example 1 The first agent: Take 2 grams of wood blue powder and 0.6 grams of carboxymethyl cellulose and dissolve them in 10 grams of hot water at 80°C. The second dose: Take 0.5 g of ferrous sulfate, 0.6 g of carboxymethyl cellulose, and 10 g of water, and dissolve at room temperature. Hair dyeing method: apply the first dose evenly on the hair, heat it at 45°C for 30 minutes, then leave it at room temperature for 3 hours, and rinse with water. Then apply the second agent evenly on the hair, leave it at room temperature for 30 minutes, rinse with water and blow dry.

比較例二 第一劑:取檸檬桉葉萃取液2克、木藍粉2克、羧甲基纖維素0.6克,於10克的80℃熱水中溶解。 第二劑:取硫酸亞鐵0.5克、羧甲基纖維素0.6克、水10克,於室溫下溶解。 染髮方法:將第一劑均勻塗抹於頭髮上,於室溫(約28℃)下停留3小時,以清水沖洗。再將第二劑均勻塗抹於頭髮上,於室溫下停留30分鐘,再以清水沖洗、吹乾。 Comparative Example 2 The first agent: Take 2 grams of lemon eucalyptus leaf extract, 2 grams of wood blue powder, and 0.6 grams of carboxymethyl cellulose, and dissolve them in 10 grams of hot water at 80°C. The second dose: Take 0.5 g of ferrous sulfate, 0.6 g of carboxymethyl cellulose, and 10 g of water, and dissolve at room temperature. Hair dyeing method: Apply the first dose evenly on the hair, leave it at room temperature (about 28°C) for 3 hours, and rinse with water. Then apply the second agent evenly on the hair, leave it at room temperature for 30 minutes, rinse with water and blow dry.

比較例三 第一劑:取茶葉粉2克、玉米糖漿0.1克,於10克的80℃熱水中溶解。 第二劑:取硫酸亞鐵0.5克、玉米糖漿0.1克、水10克,於室溫下溶解。 染髮方法:將第一劑均勻塗抹於頭髮上,於45℃的溫度下加熱30分鐘,然後以清水沖洗。再將第二劑均勻塗抹於頭髮上,於室溫下停留30分鐘,再以清水沖洗、吹乾。 Comparative Example 3 The first dose: Take 2 grams of tea powder and 0.1 grams of corn syrup, and dissolve them in 10 grams of hot water at 80°C. The second dose: Take 0.5 g of ferrous sulfate, 0.1 g of corn syrup, and 10 g of water, and dissolve at room temperature. Hair dyeing method: Apply the first dose evenly on the hair, heat it at 45°C for 30 minutes, and then rinse with water. Then apply the second agent evenly on the hair, leave it at room temperature for 30 minutes, rinse with water and blow dry.

上述實施例及比較例所製備的植物性黑色染髮劑之植物性成分及染色條件和染色結果,請參見下列表一。 表一

Figure 107109917-A0304-0001
For the botanical ingredients, dyeing conditions and dyeing results of the botanical black hair dyes prepared in the above examples and comparative examples, please refer to Table 1 below. Table I
Figure 107109917-A0304-0001

由表一可明顯得知,本發明實施例一~實施例七所揭露的植物性黑色染髮劑及染髮方法,利用桉樹葉及柚木葉之植物萃取物為主要原料,或再搭配印地科植物或茶葉植物共同使用,於溫熱環境下進行染色,確實可得到黑色或深黑色之染髮效果。相較於比較例一,其單純使用印地科植物萃取物為染髮原料,以及比較例二,其於常溫下進行染色,僅能得到藍色或藍黑色之髮色,以及比較例三,其單純使用茶葉植物萃取物為染髮原料,僅能得到灰色之髮色。It can be clearly seen from Table 1 that the botanical black hair dyes and hair dyeing methods disclosed in Examples 1 to 7 of the present invention use plant extracts of eucalyptus leaves and teak leaves as the main raw materials, or combined with Indian plants Or it can be used together with tea plants and dyed in a warm environment to get black or deep black hair dyeing effect. Compared with Comparative Example 1, which simply uses the extract of the Indian family plant as the hair dyeing material, and Comparative Example 2, which dyes at room temperature, only blue or blue-black hair color can be obtained, and Comparative Example 3, which Using only tea plant extracts as raw materials for hair dyeing, only gray hair color can be obtained.

綜合上述,根據本發明所揭露的植物性黑色染髮劑及染髮方法,乃利用桉樹葉或柚木葉的植物萃取物於溫熱環境下滲入頭髮纖維中,再與亞鐵離子絡合形成大分子不溶性黑色物質而固著於頭髮上,即可得到近似自然黑色之染髮效果。同時,亦可搭配印地科植物或茶葉植物共同使用來得到深黑色之髮色。本發明沒有使用化學溶劑、滲透劑及表面活性劑等對人體有害之物質,配方安全、簡單,且染色效果佳,可滿足人們對於自然黑髮或深黑色髮的染髮需求。In summary, the botanical black hair dye and hair dyeing method disclosed in the present invention utilize plant extracts of eucalyptus leaves or teak leaves to penetrate into hair fibers under warm conditions, and then complex with ferrous ions to form macromolecular insolubility The black substance is fixed on the hair to get a hair dyeing effect similar to natural black. At the same time, it can also be used together with Indian plants or tea plants to get dark black hair color. The invention does not use chemical solvents, penetrants, surfactants and other harmful substances to the human body. The formula is safe and simple, and the dyeing effect is good, which can meet people's hair dyeing needs for natural black or deep black hair.

唯以上所述者,僅為本發明之較佳實施例而已,並非用來限定本發明實施之範圍。故即凡依本發明申請範圍所述之特徵及精神所為之均等變化或修飾,均應包括於本發明之申請專利範圍內。Only the above are merely preferred embodiments of the present invention, and are not used to limit the scope of the present invention. Therefore, all equivalent changes or modifications made in accordance with the characteristics and spirit of the application scope of the present invention shall be included in the patent application scope of the present invention.

no

第1圖為本發明所提供的使用植物性黑色染髮劑之染髮方法的流程圖。 第2圖為桉樹葉萃取物與亞鐵離子絡合之示意圖。 第3圖為柚木葉萃取物與亞鐵離子絡合之示意圖。Figure 1 is a flowchart of the hair dyeing method using plant-based black hair dye provided by the present invention. Figure 2 is a schematic diagram of the complexation of eucalyptus leaf extract with ferrous ions. Figure 3 is a schematic diagram of the complexation of teak leaf extract with ferrous ions.

Claims (18)

一種植物性黑色染髮劑,其由下列的成分所組成:一第一劑,該第一劑包含一植物萃取物、一第一增稠劑以及其餘為水,該植物萃取物包含桉樹葉萃取物或柚木葉萃取物,該柚木葉萃取物係取自柚木屬植物之樹葉;及一第二劑,該第二劑包含一亞鐵鹽、一第二增稠劑以及其餘為水。 A botanical black hair dye, which is composed of the following ingredients: a first agent, the first agent contains a plant extract, a first thickener and the rest is water, the plant extract contains eucalyptus leaf extract Or teak leaf extract, the teak leaf extract is taken from the leaves of a teak plant; and a second agent, the second agent contains a ferrous salt, a second thickener, and the rest is water. 如請求項第1項所述的植物性黑色染髮劑,其中該植物萃取物係由一桉樹葉或一柚木葉萃取之液體或直接由該桉樹葉或該柚木葉乾燥磨碎之粉體。 The botanical black hair dye according to claim 1, wherein the plant extract is a liquid extracted from a eucalyptus leaf or a teak leaf or a powder directly dried and ground from the eucalyptus leaf or the teak leaf. 如請求項第1項所述的植物性黑色染髮劑,其中該桉樹葉萃取物係取自檸檬桉、大葉桉、蘋果桉或薄荷桉之樹葉。 The botanical black hair dye according to claim 1, wherein the eucalyptus leaf extract is derived from the leaves of eucalyptus lemon, eucalyptus grandis, eucalyptus apple, or eucalyptus mint. 如請求項第1項所述的植物性黑色染髮劑,其中該植物萃取物更包含一印地科(indigo)植物萃取物。 The botanical black hair dye according to claim 1, wherein the plant extract further comprises an indigo plant extract. 如請求項第4項所述的植物性黑色染髮劑,其中該印地科植物萃取物係取自木藍或大青。 The botanical black hair dye according to claim 4, wherein the Hindi family plant extract is taken from Mulan or Daqing. 如請求項第4項所述的植物性黑色染髮劑,其中該印地科植物萃取物與該桉樹葉萃取物或該柚木葉萃取物的重量比係為0.1~1:1。 The botanical black hair dye according to claim 4, wherein the weight ratio of the Indian plant extract to the eucalyptus leaf extract or the teak leaf extract is 0.1-1:1. 如請求項第6項所述的植物性黑色染髮劑,其中該印地科植物萃取物與該桉樹葉萃取物或該柚木葉萃取物的重量比係為0.5~1:1。 The botanical black hair dye according to claim 6, wherein the weight ratio of the Indian plant extract to the eucalyptus leaf extract or the teak leaf extract is 0.5-1:1. 如請求項第1項所述的植物性黑色染髮劑,其中該植物萃取物更包含一茶葉植物萃取物。 The botanical black hair dye according to claim 1, wherein the plant extract further comprises a tea plant extract. 如請求項第8項所述的植物性黑色染髮劑,其中該茶葉植物萃取物係取自台茶12號。 The botanical black hair dye according to claim 8, wherein the tea plant extract is taken from Taicha No. 12. 如請求項第8項所述的植物性黑色染髮劑,其中該茶葉植物萃取物與 該桉樹葉萃取物或該柚木葉萃取物的重量比係為0.1~1:1。 The botanical black hair dye according to claim 8, wherein the tea plant extract and The weight ratio of the eucalyptus leaf extract or the teak leaf extract is 0.1-1:1. 如請求項第10項所述的植物性黑色染髮劑,其中該茶葉植物萃取物與該桉樹葉萃取物或該柚木葉萃取物的重量比係為0.5-1:1。 The botanical black hair dye according to claim 10, wherein the weight ratio of the tea plant extract to the eucalyptus leaf extract or the teak leaf extract is 0.5-1:1. 如請求項第1項所述的植物性黑色染髮劑,其中該亞鐵鹽係選自硫酸亞鐵、醋酸亞鐵、氯化亞鐵或氧化鐵。 The botanical black hair dye according to claim 1, wherein the ferrous salt is selected from ferrous sulfate, ferrous acetate, ferrous chloride or ferric oxide. 如請求項第1項所述的植物性黑色染髮劑,其中該第一增稠劑與該第二增稠劑係分別選自羧甲基纖維素、甲基纖維素、乙基纖維素、阿拉伯膠或玉米糖膠。 The plant-based black hair dye according to claim 1, wherein the first thickener and the second thickener are selected from the group consisting of carboxymethyl cellulose, methyl cellulose, ethyl cellulose, and Arabica. Gum or corn sugar gum. 如請求項第1項所述的植物性黑色染髮劑,其中該第一劑的組成中,該植物萃取物佔該第一劑的重量百分比為5~50%,該第一增稠劑佔該第一劑的重量百分比為1~30%,其餘為水。 The botanical black hair dye according to claim 1, wherein in the composition of the first agent, the plant extract accounts for 5-50% of the weight of the first agent, and the first thickener accounts for The weight percentage of the first agent is 1-30%, and the rest is water. 如請求項第14項所述的植物性黑色染髮劑,其中該第一劑的組成中,該植物萃取物佔該第一劑的重量百分比為15~50%。 The botanical black hair dye according to claim 14, wherein in the composition of the first agent, the plant extract accounts for 15-50% of the weight of the first agent. 如請求項第1項所述的植物性黑色染髮劑,其中該第二劑的組成中,該亞鐵鹽佔該第二劑的重量百分比為0.1~6%,該第二增稠劑佔該第二劑的重量百分比為1~30%,其餘為水。 The plant-based black hair dye according to claim 1, wherein in the composition of the second agent, the ferrous salt accounts for 0.1 to 6% of the weight of the second agent, and the second thickener accounts for the The weight percentage of the second agent is 1-30%, and the rest is water. 一種染髮方法,使用如請求項第1項所述的植物性黑色染髮劑,該染髮方法包含下列步驟:將該第一劑均勻塗抹於一頭髮上,於40~50℃的溫度下加熱30分鐘,以清水沖洗;及將該第二劑均勻塗抹於該頭髮上,於室溫下停留20~40分鐘,以清水沖洗、吹乾。 A hair dyeing method using the botanical black hair dye as described in claim 1, the hair dyeing method comprising the following steps: apply the first agent evenly on a hair, and heat it at a temperature of 40-50°C for 30 minutes , Rinse with clean water; and evenly spread the second agent on the hair, leave it at room temperature for 20-40 minutes, rinse with clean water, and blow dry. 如請求項第17項所述的染髮方法,其中於將該第一劑塗抹於該頭髮並加熱30分鐘的步驟之後,更包含於室溫下停留2~3小時,再進行 清水沖洗。The hair dyeing method according to claim 17, wherein after the step of applying the first agent to the hair and heating for 30 minutes, it further comprises staying at room temperature for 2 to 3 hours before proceeding Rinse with clean water.
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CN101283959A (en) * 2008-05-20 2008-10-15 上海大学 Black hair dye of natural-like plant active component
TW201223552A (en) * 2010-11-19 2012-06-16 Natural Medicine Inst Ofzhejiang Yangshengtang Co Ltd Use of tea polyphenols and/or tea pigments as dyes and products thereof
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