CN109330950A - A kind of pericarpium juglandis hair dye and preparation method thereof and application method - Google Patents
A kind of pericarpium juglandis hair dye and preparation method thereof and application method Download PDFInfo
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- A61K8/00—Cosmetics or similar toiletry preparations
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
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Abstract
The present invention provides a kind of pericarpium juglandis hair dyes, including A agent and B agent, A agent is mainly prepared by green peel of walnut, surfactant, ethanol amine, thickener, L-cysteine and plant penetrant, and B agent is mainly prepared by surfactant, antioxidant, thickener, ferrous salt and green peel of walnut juice.The present invention also provides the preparation method of pericarpium juglandis hair dye and application methods.The present invention is used as primary raw material, appliable plant pigment and plant penetrant using green peel of walnut, safe and non-stimulating, performance is stable, colorability is strong, uniform coloring, to dye retention time long, and various crowds is suitble to have hair dyed for a long time use.
Description
Technical field
The invention belongs to cosmetic technical field more particularly to a kind of pericarpium juglandis hair dye and preparation method thereof and users
Method.
Background technique
Currently, the main product of hair dye is phenyl amines synthetic hair dyes in the market.Phenyl amines hair dye hair dyeing effect
Fruit is good, easy to operate, cheap, but there is also certain security risks.It can not only be damaged using the hair dyeing of phenyl amines hair dye
Hair stimulates skin, causes lesions of liver and kidney, can also cause leukaemia and kinds cancer.This is because must in phenyl amines hair dye
Indispensable phenylenediamine and its derived material can enter human body via pore and respiratory tract in hair dyeing, but need six months
Time can just gradually pass through metabolism and incompletely be discharged.Although these ingredients are harmless when measuring micro-, with hair dyeing
The dosage of the increase of number, accumulation adds continuous action, it is possible to destroy candidate stem cell, and cause organ tissue canceration.And
The main component of natural hair dye is extracted from natural plants, generally will not be generated primary sexual stimulus to hair, is considered
It is safe and non-toxic, without anaphylaxis；From the point of view of environmental angle, natural botanical hair dye environmental pollution it is small and can natural degradation, this
The favor that natural plants hair dyeing is increasingly subject to people is allowed for, more and more cosmetics, pharmaceutical manufacturer turn one's attention to naturally
The exploitation of pigment hair dye.But since natural pigment stability is poor, colorability is weak, coloring is uneven, dyeing retention time
Short equal many reasons, cause that natural pigment hair dye is of less types on market today and hair dyeing effect is unsatisfactory.Therefore with peace
Full natural pigment is that raw material develops strong, coloring stabilized, dyeing retention time length the natural hair dye of colouring power as people
Research and development focus.
Summary of the invention
In order to solve the above technical problem, the present invention provides a kind of pericarpium juglandis hair dyes, including A agent and B agent；
The A agent is mainly prepared by each component of following parts by weight:
Green peel of walnut 2-10 surfactant 4-9 ethanol amine 2-5
Thickener 2-4 L-cysteine 4-10 plant penetrant 3-6；
The pH value of the A agent is 6-12, and the A agent application urea adjusts pH value；
The B agent is mainly prepared by each component of following parts by weight:
Surfactant 4-9 antioxidant 1-2 thickener 2-4
Ferrous salt 3-6 green peel of walnut juice 40-90；
The pH value of the B agent is 3.5-7.5.
Green peel of walnut: also known as pericarpium juglandis, it is the exocarp of the fruit of juglandaceae plant walnut, the function with removing toxicity for detumescence
Effect.
The green peel of walnut that A agent is used to prepare in the present invention is dry green peel of walnut.
Green peel of walnut juice is using the liquid obtained after fresh green peel of walnut squeeze and filter.
The present invention prepares hair dye as primary raw material using green peel of walnut, the polyphenol oxidase (PPO) in green peel of walnut
It is present in the thylakoid of green peel of walnut chloroplaset and the matrix of other plastids, is under normal circumstances inactive state, works as core
When the eucaryotic cell structure of peach green peel is destroyed when external force or Cryogenic burns, polyphenol oxidase is activated, and is present in
Phenolic substances in the Cell vacuoles of green peel of walnut reacts, and generates black and brown material precipitating, to realize to hair
The effect of dyeing；Meanwhile ferrous ion is also added into coloring agent provided by the invention, ferrous ion can with vegetable active at
Distribute raw complex reaction, generates the insoluble pigment of macromolecular being locked in inside hair, deepen hair color, thus further
Reinforce the stability of dyeing effect and dyeing.
Pericarpium juglandis hair dye provided by the invention use phytochrome and plant penetrant, it is safe and non-stimulating, performance is stable,
Colorability is strong, uniform coloring, dyeing retention time are long, and various crowds is suitble to have hair dyed for a long time use.
In coloring agent provided by the invention, surfactant can select anionic surfactant, amphoteric ion table
Any one or a few in face activating agent and nonionic surfactant, including oleyl alcohol ether -5, Plantacare 818, dodecyl
Sodium sulphate, glycine betaine, polyethylene glycol, ceteareth -20 etc..
Ethanol amine includes any one or a few in monoethanolamine, diethanol amine and triethanolamine.
Thickener can select any one or a few in water-soluble polymer, including propylene glycol alginate, hydroxyl second
Base cellulose, sodium carboxymethylcellulose, hydroxylmethyl cellulose sodium, gum arabic, methylcellulose, carboxymethyl cellulose, hydroxypropyl
Base cellulose, xanthan gum, gelatin, guar gum etc..
Plant penetrant includes the ethanol extract of peppermint, Rhizoma Chuanxiong, cortex cinnamomi, cloves, Radix Angelicae Sinensis, folium eucalypti, galangal, Radix Glycyrrhizae
And/or any one or a few in aqueous extract.
The preparation method of plant penetrant includes:
(1) ethanol extract: using 75% ethyl alcohol as extractant, solid-to-liquid ratio 1:20, ultrasonic extraction, when being concentrated into 1/4 from
The heart, filtering, take supernatant；
(2) aqueous extract: using pure water as extractant, solid-to-liquid ratio 1:20, ultrasonic extraction, centrifugation, filtering when being concentrated into 1/4,
Take supernatant.
Antioxidant can choose the common antioxidant of cosmetic industry, including arabo-ascorbic acid, ascorbic acid, sulfurous
Sour sodium etc..
Ferrous salt be allow in cosmetics using it is any containing Fe2+Salt, including frerrous chloride, ferrous sulfate, seven water
Close ferrous sulfate, ferrous nitrate etc..
The pH value of B agent is adjusted using pH adjusting agent, including citric acid, lactic acid, tartaric acid, malic acid, citric acid
Sodium, potassium citrate, hydrochloric acid, any one or a few in sulfuric acid.
Preferably, the green peel of walnut for being used to prepare A agent is first prepared into green peel of walnut extracting solution and adds A agent.
Preferably, the preparation method of green peel of walnut extracting solution includes: after crushing green peel of walnut with 75% alcohol steep, material
Liquor ratio is 1:20, and filtering, concentration obtain green peel of walnut extracting solution.
The preparation method of pericarpium juglandis hair dye includes: that green peel of walnut is prepared into green peel of walnut extracting solution first；Then will
The other components for preparing A agent are added in green peel of walnut extracting solution, stir evenly, reapply urea and be adjusted to pH value between 6-12 i.e.
It can get A agent；By prepare B agent other components be added green peel of walnut juice in, stir evenly, then by pH value be adjusted to 3.5-7.5 it
Between can be obtained B agent.
Preferably, the L-cysteine is 7-10 parts.In the present invention, L-cysteine additive amount is very few, will affect
Hair contaminates black effect；And L-cysteine additive amount is excessive, will not have further improvement to the effect of hair-dyeing.
Further, gallic acid or gallic acid-derivate that the A agent further includes 0.5-2 parts are prepared, and/or, 4-6
The tannic acid of part or tannin acid derivative.In pericarpium juglandis hair dye provided by the invention, gallic acid or tannic acid is added, or
It is to share gallic acid and tannic acid, pericarpium juglandis hair dye can be made to realize the technical effect that hair is dyed to black.
Gallic acid-derivate in the present invention is the compound of gallic acid out of can dissociating by hydrolysis.In the present invention
Tannin acid derivative be the compound of tannic acid out of can dissociating by hydrolysis.
Further, the Chinese gall that the A agent further includes 10-50 parts is prepared.Preparing pericarpium juglandis dye provided by the invention
It is more black than the hair color that green peel of walnut dyes is used alone that Chinese gall and green peel of walnut is added in the raw material of hair agent simultaneously.
Chinese gall: also known as hundred worm storehouses, fermented Chinese gall herb and tea leaves, gall, it is that horned gall aphid or the melaphis peitan Tsai et Tang female adult of Homoptera aphid section are parasitic
In Anacardiaceae plant " Chinese sumac " and its tender leaf or petiole of other plant are belonged to, stabs and generates a kind of cryptomere consor object worm
Goitre, gained after baked drying.
Preferably, Chinese gall Chinese nutgall is prepared into be added in A agent.
Preferably, Chinese nutgall can be Chinese gall aqueous extract, Chinese gall ethanol extract or be Chinese gall
The 1:1 mixture of aqueous extract and Chinese gall ethanol extract.
Wherein, the preparation method of Chinese gall aqueous extract includes: that gallnut extract is broken into powder, is wrapped up with gauze, is impregnated
In pure water, 24-48h is stood, soak, which is boiled concentration, can be obtained Chinese nutgall.
The preparation method of Chinese gall ethanol extract includes: that gallnut extract is broken into powder, is wrapped up with gauze, is soaked in
In 75% ethyl alcohol, 24-48h is stood, soak, which is boiled concentration, can be obtained Chinese nutgall.
Preferably, the Chinese gall that the A agent includes 30-40 parts is prepared.In pericarpium juglandis hair dye provided by the invention, five
Gall nut additive amount is very few, will affect hair and contaminates black effect；And Chinese gall additive amount is excessive, then will increase cost, but it is correct
The effect of hair dyeing does not have further improvement.
Further, preparing the A agent further includes 0.3-0.6 parts of Testa sojae atricolor and 10-50 parts of Chinese gall.Work as the present invention
When gallic acid or tannic acid are not provided in the pericarpium juglandis hair dye of offer, in the raw material for preparing pericarpium juglandis hair dye while adding
Black can also be dyed for hair by entering Chinese gall and Testa sojae atricolor.
Testa sojae atricolor: also known as SEMEN COAT GLYCINES NIGRUM, it is the drying crust of the seed of leguminous plant semen sojae atricolor.Preferably, it prepared by Testa sojae atricolor
It is added in A agent at Testa sojae atricolor extracting solution, Chinese gall is prepared into Chinese nutgall and is added in A agent.
Preferably, the preparation method of Testa sojae atricolor extracting solution includes: that Testa sojae atricolor is ground into powder, is wrapped up with gauze, is impregnated
In 2% sodium hydroxide solution of 10 times of weight, after 3-4 days, the pH of soak, which is adjusted to 7-8, can be obtained semen sojae atricolor extraction
Liquid.
Preferably, Chinese nutgall can be Chinese gall aqueous extract, Chinese gall ethanol extract or be Chinese gall
The 1:1 mixture of aqueous extract and Chinese gall ethanol extract.
Further, in pericarpium juglandis hair dye provided by the invention, the increasing such as lanolin, olive oil, silicone oil can be added
Rouge agent or vitamin, protein hydrolysate isoreactivity ingredient improve the nutrition condition of hair after hair dyeing, keep hair bright, easily comb
Reason.
The present invention also provides a kind of preparation methods of above-mentioned pericarpium juglandis hair dye, comprising: is first prepared into green peel of walnut
Green peel of walnut extracting solution；Then the other components for preparing A agent are added in green peel of walnut extracting solution, stir evenly, reapplies urine
PH value is adjusted to can be obtained A agent between 6-12 by element；The other components for preparing B agent are added in green peel of walnut juice, are stirred evenly,
PH value is adjusted to again to can be obtained B agent between 3.5-7.5.
Preferably, the preparation method of the green peel of walnut extracting solution includes: and is soaked after crushing green peel of walnut with 75% ethyl alcohol
It mentions, solid-liquid ratio 1:20, filtering, concentration obtain green peel of walnut extracting solution.
Further, gallic acid or gallic acid-derivate that the A agent further includes 0.5-2 parts are prepared, and/or, 4-6
The tannic acid of part or tannin acid derivative.
Further, the Chinese gall that the A agent further includes 10-50 parts is prepared, the Chinese gall is prepared into Chinese gall and is mentioned
Liquid is taken to be added in the A agent.
Preferably, Chinese nutgall can be Chinese gall aqueous extract, Chinese gall ethanol extract or be Chinese gall
The 1:1 mixture of aqueous extract and Chinese gall ethanol extract.
Wherein, the preparation method of Chinese gall aqueous extract includes: that gallnut extract is broken into powder, is wrapped up with gauze, is impregnated
In pure water, 24-48h is stood, soak, which is boiled concentration, can be obtained Chinese nutgall.
The preparation method of Chinese gall ethanol extract includes: that gallnut extract is broken into powder, is wrapped up with gauze, is soaked in
In 75% ethyl alcohol, 24-48h is stood, soak, which is boiled concentration, can be obtained Chinese nutgall.
Preferably, gallic additive amount is 30-40 parts.
Further, preparing the A agent further includes 0.3-0.6 parts of Testa sojae atricolor and 10-50 parts of Chinese gall, will be described black
Skin of beancurd is prepared into Testa sojae atricolor extracting solution and is added in the A agent, and Chinese gall is prepared into Chinese nutgall and is added in A agent.
Preferably, the preparation method of Testa sojae atricolor extracting solution includes: that Testa sojae atricolor is ground into powder, is wrapped up with gauze, is impregnated
In 2% sodium hydroxide solution of 10 times of weight, after 3-4 days, the pH of soak, which is adjusted to 7-8, can be obtained semen sojae atricolor extraction
Liquid.
Preferably, Chinese nutgall can be Chinese gall aqueous extract, Chinese gall ethanol extract or be Chinese gall
The 1:1 mixture of aqueous extract and Chinese gall ethanol extract.
The present invention also provides a kind of hair colouring methods using above-mentioned pericarpium juglandis hair dye, comprising: is first uniformly applied to A agent
On hair, hair 25-40min is heated at 25-45 DEG C, the A agent on hair is then cleaned with clear water；It is after hair is dry that B agent is equal
It is even to be applied on hair, hair 25-40min is heated at 25-45 DEG C, then clean the B agent on hair with clear water and dye can be completed
Hair.
Compared with prior art, the beneficial effects of the present invention are:
Pericarpium juglandis hair dye provided by the invention is seeped using green peel of walnut as primary raw material, appliable plant pigment and plant
Saturating agent, it is safe and non-stimulating, performance is stable, colorability is strong, uniform coloring, dyeing retention time it is long, be suitble to various crowds long-term
Hair dyeing uses.
Specific embodiment
Embodiment 1
A kind of pericarpium juglandis hair dye, including A agent and B agent；
The A agent is prepared by each component of following weight:
Green peel of walnut 2g Plantacare 818 4g ethanol amine 2g
Hydroxyethyl cellulose 2g L-cysteine 4g peppermint bleeding agent 3g；
The pH value of A agent is adjusted to 6 using urea；
The B agent is prepared by each component of following weight:
Plantacare 818 4g ascorbic acid 1g hydroxyethyl cellulose 2g
Frerrous chloride 3g green peel of walnut juice 90g；
The pH value of B agent is adjusted to 3.5 using hydrochloric acid.
Embodiment 2
A kind of pericarpium juglandis hair dye, including A agent and B agent；
The A agent is prepared by each component of following weight:
Green peel of walnut 10g glycine betaine 9g ethanol amine 5g
Sodium carboxymethylcellulose 4g L-cysteine 10g cortex cinnamomi bleeding agent 6g；
The pH value of A agent is adjusted to 12 using urea；
The B agent is prepared by each component of following weight:
Glycine betaine 9g sodium sulfite 2g sodium carboxymethylcellulose 4g
Ferrous nitrate 6g green peel of walnut juice 40g；
The pH value of B agent is adjusted to 7.5 using tartaric acid.
Embodiment 3
A kind of pericarpium juglandis hair dye, including A agent and B agent；
The A agent is prepared by each component of following weight:
- 5 5g ethanol amine 4g of green peel of walnut 4g oleyl alcohol ether
Propylene glycol alginate 3g L-cysteine 7g cloves bleeding agent 4g；
The pH value of A agent is adjusted to 9 using urea；
The B agent is prepared by each component of following weight:
- 5 6g arabo-ascorbic acid 1.5g propylene glycol alginate 3g of oleyl alcohol ether
Ferrous sulfate 5g green peel of walnut juice 60g；
The pH value of B agent is adjusted to 4 using citric acid；
The preparation method of pericarpium juglandis hair dye includes: after first crushing green peel of walnut with 75% alcohol steep, solid-liquid ratio
For 1:20, filtering, concentration obtain green peel of walnut extracting solution；Then green peel of walnut extracting solution is added in the other components for preparing A agent
In, it stirs evenly, reapplying urea pH value is adjusted to 9 can be obtained A agent；It is green that walnut is added in the other components for preparing B agent
It in skin juice, stirs evenly, reapplying citric acid pH value is adjusted to 4 can be obtained B agent.
Embodiment 4
A kind of pericarpium juglandis hair dye prepares the gallic acid that A agent further includes 0.5g unlike the first embodiment.
Embodiment 5
A kind of pericarpium juglandis hair dye prepares the gallic acid that A agent further includes 2g as different from Example 2.
Embodiment 6
A kind of pericarpium juglandis hair dye prepares the gallic acid that A agent further includes 1g as different from Example 3.
Embodiment 7
A kind of pericarpium juglandis hair dye prepares the Chinese gall that A agent further includes 10g as different from Example 4.
Embodiment 8
A kind of pericarpium juglandis hair dye prepares the Chinese gall that A agent further includes 50g as different from Example 5.
Embodiment 9
A kind of pericarpium juglandis hair dye prepares the Chinese gall that A agent further includes 30g as different from Example 6；
The preparation method of pericarpium juglandis hair dye includes: after crushing green peel of walnut with 75% alcohol steep, solid-liquid ratio 1:
20, filtering, concentration obtain green peel of walnut extracting solution；Gallnut extract is broken into powder, is wrapped up with gauze, 2 times of weight are soaked in
In pure water, 24-48h is stood, soak is boiled and is concentrated into the 1/5 of original volume and can be obtained Chinese gall aqueous extract；Then will
Chinese gall aqueous extract and the other components for preparing A agent are added in green peel of walnut extracting solution, stir evenly, reapply urea for pH
Value, which is adjusted to 9, can be obtained A agent；The other components for preparing B agent are added in green peel of walnut juice, stirs evenly, reapplies lemon
PH value is adjusted to 9 by acid can be obtained B agent.
Embodiment 10
A kind of pericarpium juglandis hair dye prepares the tannic acid that A agent further includes 4g as different from Example 7.
Embodiment 11
A kind of pericarpium juglandis hair dye prepares the tannic acid that A agent further includes 6g as different from Example 8.
Embodiment 12
A kind of pericarpium juglandis hair dye prepares the tannic acid that A agent further includes 5g as different from Example 9.
Embodiment 13
A kind of pericarpium juglandis hair dye prepares the black of Chinese gall that A agent further includes 10g and 0.3g unlike the first embodiment
Skin of beancurd.
Embodiment 14
A kind of pericarpium juglandis hair dye prepares the black of Chinese gall that A agent further includes 50g and 0.6g as different from Example 2
Skin of beancurd.
Embodiment 15
A kind of pericarpium juglandis hair dye prepares the black of Chinese gall that A agent further includes 30g and 0.5g as different from Example 3
Skin of beancurd；
The preparation method of pericarpium juglandis hair dye includes: after crushing green peel of walnut with 75% alcohol steep, solid-liquid ratio 1:
20, filtering, concentration obtain green peel of walnut extracting solution；Testa sojae atricolor is ground into powder, is wrapped up with gauze, 10 times of weight are soaked in
In 2% sodium hydroxide solution, after 3-4 days, the pH of soak, which is adjusted to 7-8, can be obtained Testa sojae atricolor extracting solution；By Chinese gall
It is ground into powder, is wrapped up with gauze, is soaked in the pure water of 2 times of weight, 24-48h is stood, soak is boiled and is concentrated into substance
Long-pending 1/5 can be obtained Chinese gall aqueous extract；Then by Testa sojae atricolor extracting solution, Chinese gall aqueous extract and prepare A agent its
His component is added in green peel of walnut extracting solution, stirs evenly, and reapplying urea pH value is adjusted to 9 can be obtained A agent；It will preparation
The other components of B agent are added in green peel of walnut juice, stir evenly, and reapplying citric acid pH value is adjusted to 4 can be obtained B agent.
Comparative example 1
A kind of hair dye replaces the 4g cloves bleeding agent in embodiment 3 using 4g azone as different from Example 3.
Comparative example 2
A kind of hair dye prepares the Chinese gall that A agent further includes 10g as different from Example 6.
Comparative example 3
A kind of hair dye prepares the Chinese gall that A agent further includes 50g as different from Example 6.
Comparative example 4
A kind of hair dye, as different from Example 9, the additive amount of L-cysteine is 5g in A agent.
Comparative example 5
A kind of hair dye, as different from Example 9, the additive amount of L-cysteine is 12g in A agent.
Comparative example 6
A kind of hair dye, as different from Example 3, preparing A agent further includes the Chinese gall of 30g and the tannic acid of 5g.
Comparative example 7
A kind of hair dye prepares the Chinese gall that A agent further includes 30g as different from Example 3.
Comparative example 8
A kind of hair dye prepares the Testa sojae atricolor that A agent further includes 0.5g as different from Example 3.
Hair dyeing effect evaluation
1. the pericarpium juglandis hair dye that section Example provides and the hair dye that comparative example provides dye topknot.
Hair colouring methods include: first uniformly to be applied to A agent on topknot, and topknot 30min is heated at 40 DEG C, then uses clear water
The A agent on topknot is cleaned, topknot is dried；B agent is uniformly applied on topknot again, topknot 30min is heated at 40 DEG C, then with clearly
Water cleans the B agent on topknot, dries.
The topknot color after hair dye dyes is observed, the results are shown in Table 1:
1 hair dye hair color contrast table of table
| Test serial number | Using coloring agent | Color after topknot dyeing |
| 1 | Embodiment 3 | Brown |
| 2 | Embodiment 6 | Black -1 |
| 3 | Embodiment 9 | Black -3 |
| 4 | Embodiment 12 | Black -3 |
| 5 | Embodiment 15 | Black -2 |
| 6 | Comparative example 1 | Sundown |
| 7 | Comparative example 2 | Black -2 |
| 8 | Comparative example 3 | Black -3 |
| 9 | Comparative example 4 | Black -2 |
| 10 | Comparative example 5 | Black -3 |
| 11 | Comparative example 6 | Black -3 |
| 12 | Comparative example 7 | Flax green |
| 13 | Comparative example 8 | Dark-brown |
Note: in table 1, black -1, black -2, the three kinds of black of black -3 color successively deepen, and can visually see
It distinguishes out.
From above-mentioned test result:
(1) color that the topknot of the hair dye dyeing provided through embodiment 3 and comparative example 1 is provided, although by above-mentioned two
The topknot of kind of hair dye dyeing is all pale brown colour system, but the tinting strength, tinting power of hair dye that embodiment 3 provides is obviously more preferable, makes to dye
Topknot color is deeper.It can thus be appreciated that coloring agent provided by the invention is not only safe using plant penetrant as cloves bleeding agent
Property it is good, dyeing effect also than using azone it is more preferable as bleeding agent effect.
(2) color for comparing the topknot of the hair dye dyeing provided through embodiment 6 and embodiment 3, provides through embodiment 6
The topknot of hair dye dyeing is black, and the topknot of the hair dye dyeing provided through embodiment 3 is brown.It can thus be appreciated that in this hair
0.5-2 parts of gallic acid is added in the hair dye of bright offer can make hair dye realize that the technology that hair is dyed black is imitated
Fruit.
(3) face of the topknot for the hair dye dyeing that comparison is provided through embodiment 6, embodiment 9, comparative example 2 and comparative example 3
Color, although being all black by the topknot that above-mentioned four kinds of hair dyes dye, there are the deep mixed samples of color.Wherein, real
The topknot black for applying the hair dye dyeing of example 9 and comparative example 3 is most deep, and the two naked eyes can not find out significant difference；Comparative example 2
The black depth of the topknot of hair dye dyeing is taken second place；The black of the topknot of the hair dye dyeing of embodiment 6 is most shallow.It follows that
It is single together as the raw material ratio for preparing A agent that 10-50 parts of Chinese gall and green peel of walnut are added in hair dye provided by the invention
The topknot color solely dyed using green peel of walnut is more black, therefore Chinese gall is added with promotion in hair dye provided by the invention
Hair is contaminated black effect.And gallic additive amount is also with 30-40 parts of better effect, Chinese gall additive amount is very few, can shadow
It rings hair and contaminates black effect；And Chinese gall additive amount is excessive, then will increase cost, but do not have to the effect of hair-dyeing
It is further to improve.
(4) color of the topknot for the hair dye dyeing that comparison is provided through embodiment 9, comparative example 4 and comparative example 5, although through
The topknot for crossing above-mentioned three kinds of hair dyes dyeing is all black, but there are the deep mixed samples of color.Wherein, embodiment 9 and right
The topknot black of the hair dye dyeing of ratio 5 is obviously relatively deep, and the two naked eyes can not find out significant difference；And the dye of comparative example 4
The topknot black for sending out agent dyeing is obviously partially shallow.It follows that in hair dye provided by the invention L-cysteine additive amount
Proper between 7-10 parts, L-cysteine additive amount is very few, will affect hair and contaminates black effect；And L-cysteine adds
There will not be further improvement to the effect of hair-dyeing after dosage is excessive.
(5) color for the topknot that the hair dye that provides through embodiment 9, embodiment 12 and comparative example 6 of comparison dyes, in process
The topknot for stating the dyeing of three kinds of hair dyes is all black, and three's naked eyes can not find out significant difference.It follows that being mentioned in the present invention
For hair dye in can tannic acid or tannin acid derivative replace gallic acid or gallic acid-derivate, or by two
Person is used cooperatively, and can achieve identical hair dyeing effect.
(6) color of the topknot for the hair dye dyeing that comparison is provided through embodiment 15, comparative example 7 and comparative example 8, can obtain
Out: when not including gallic acid or tannic acid in hair dye provided by the invention, individually adding Chinese gall or black in the feed
Hair cannot all be dyed black by skin of beancurd, but black can be dyed for hair by adding Chinese gall and Testa sojae atricolor simultaneously.
2. selecting the white alternate people of four hair blacks as subject, by embodiment 6, embodiment 9, embodiment 12 and implement
The hair dye that example 15 provides is respectively four subject's hair dyeings.
Hair colouring methods include: that first A agent is uniformly applied on subject's hair, and 30min is heated at 40 DEG C, then with clear
Water cleans the A agent on hair, and B agent is uniformly applied on the hair of subject again after drying, 30min is heated at 40 DEG C, then
It cleaned, dried with clear water.The usage amount of A agent and B agent needs the long progress of hair amount and hair according to subject in hair dye
Adjustment, guarantees that all hairs of subject can be applied to by A agent or B agent.
After hair dyeing, all obvious blackening of the hair of four subjects and color is uniform, hair is shiny black and hair quality does not occur obviously
Variation, four subjects do not occur allergy or other malaise symptoms after hair dyeing；After one month, what four subjects contaminated
Hair still can keep pitch-black shinny, but the visible white hair newly born at root of hair.Thus, it can be known that the Green Dragon provided by the invention
Clothing hair dye dyeing ability is strong, and hair dyeing effect is lasting.
Safety evaluatio
1. total plate count detects
(1) preparation of nutrient agar:
1000mL pure water+1g beef extract+5g peptone+5g sodium chloride+15g agar → fusing → adjusting pH (7.2-7.4)
→ boiling on electrothermal furnace twice → is dispensed into culture dish → tying up → and sterilizes (high pressure steam sterilization 15-30min) → check sterilizing
Situation (i.e. 28-30 DEG C culture 2-3d).
(2) sample dilutes:
Each 1mL of pericarpium juglandis hair dye of Example 1-15, is respectively placed in sterilizing test tubes, draws 9mL with sterilized straw
Physiological saline is injected into above-mentioned sample (attention does not make suction pipe contact liquid level), sufficiently shakes up, that is, be made into the dilution of 1:10；
The dilution of 1:100,1:1000 can similarly be obtained.
(3) sample inoculation:
Each 1mL of prepare liquid of each sample 1:10,1:100,1:1000 is taken to be injected separately into sterilizing potato culture, often
A dilution respectively uses 2 culture mediums, sufficiently shakes up, and sets in 28 DEG C of incubators and cultivates.
(4) total plate count in the sample after culture is counted, the total plate count count results of each sample are small
In 1000CFU/mL, meet the requirement of national cosmetic hygienic standard.
2. yeast and mold detects
(1) prepared by potato culture:
Potato (removes the peel, removes bud eye), and → cutting into slices (corn size) → weighs 200g+1000mLH2O → boil 20-
30min → bilayer yarn filters → takes filtrate and supplies 1000mL+20g glucose+20g agar → fusing → adjusting pH (natural pH)
→ boiling on electrothermal furnace twice → is dispensed into culture dish → tying up → and sterilizes (high pressure steam sterilization 15-30min) → check sterilizing
Situation (i.e. 28-30 DEG C culture 2-3d).
(2) sample dilutes:
Each 1mL of pericarpium juglandis hair dye of Example 1-15, is respectively placed in sterilizing test tubes, draws 9mL with sterilized straw
Physiological saline is injected into above-mentioned sample (attention does not make suction pipe contact liquid level), sufficiently shakes up, that is, be made into the dilution of 1:10；
The dilution of 1:100,1:1000 can similarly be obtained.
(3) sample inoculation:
Each 1mL of prepare liquid of each sample 1:10,1:100,1:1000 is taken to be injected separately into sterilizing potato culture, often
A dilution respectively uses 2 culture mediums, sufficiently shakes up, and sets in 28 DEG C of incubators and cultivates.
(4) yeast and mold in the sample after culture is counted, the meter of the yeast and mold of each sample
Number result is respectively less than 100CFU/mL, meets the requirement of national cosmetic hygienic standard.
3. staphylococcus aureus, Escherichia coli and pseudomonas aeruginosa detection
(1) sample dilutes:
Each 4mL of pericarpium juglandis hair dye of Example 1-15 is respectively placed in sterilizing test tubes, draws 36mL with sterilized straw
Physiological saline is injected separately into above-mentioned each sample (attention does not make suction pipe contact liquid level), sufficiently shakes up, that is, be made into the dilute of 1:10
Release liquid.
(2) sample dispenses:
Take above-mentioned each sample 32mL in 4 sterilizes culture dishes, every ware 8mL.
(3) Gram's staining:
It takes piece: taking clean glass slide, the position of bacterium will be applied by 2-3 times above flame；
Smear: first dripping sterile water on glass slide, and then left hand holds bacterium solution test tube, opens in alcolhol burner flame vicinity
Tampon；The right hand holds oese calcination in flame and sterilizes, and the sample after picking ring dilution in test tube, is applied to clean after cooling
On net glass slide, finally by oese, calcination sterilizes on flame；
It dries: spontaneously drying；
It is fixed: to allow and apply bacterium position upward, by 2-3 times above flame, it is made to fix (proper temperature)；
Dyeing: ammonium oxalate crystal violet liquid is dripped applying on piece, keeps 1-2min；
Washing: the dye liquor for applying on piece is slowly rinsed with water；
Mordant dyeing: 1 drop iodine solution is added dropwise, keeps 1-3min, washing；
Decoloration: 95% ethanol decolorization 20-30s of continuous dropwise addition does not have purple to efflux, washes immediately；
It redyes: Huang red is added dropwise and redyes 10-20s, washes, so far Gram's staining terminates.
(4) each sample after microscopy Gram's staining, it can be seen that each sample is all dyed to after Gram's staining
Without red, therefore Gram-negative bacteria, i.e., no Escherichia coli and pseudomonas aeruginosa is not present in purple in sample.Aobvious
Staphylococcus aureus is arranged in thyrsiform under micro mirror, and does not also observe similar bacterium colony in each sample, so sample
In also be not present staphylococcus aureus.Therefore, Staphylococcus aureus is not detected in pericarpium juglandis hair dye provided by the invention
Bacterium, Escherichia coli and pseudomonas aeruginosa meet national health codes and standards.
Finally it should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although reference
Preferred embodiment describes the invention in detail, those skilled in the art should understand that, it can be to of the invention
Technical solution is modified or replaced equivalently, and without departing from the spirit and scope of the technical solution of the present invention, should all be covered
In scope of the presently claimed invention.
Claims (10)
1. a kind of pericarpium juglandis hair dye, which is characterized in that the pericarpium juglandis hair dye includes A agent and B agent；
The A agent is mainly prepared by each component of following parts by weight:
Green peel of walnut 2-10 surfactant 4-9 ethanol amine 2-5
Thickener 2-4 L-cysteine 4-10 plant penetrant 3-6；
The pH value of the A agent is 6-12, and the A agent application urea adjusts pH value；
The B agent is mainly prepared by each component of following parts by weight:
Surfactant 4-9 antioxidant 1-2 thickener 2-4
Ferrous salt 3-6 green peel of walnut juice 40-90；
The pH value of the B agent is 3.5-7.5.
2. pericarpium juglandis hair dye according to claim 1, which is characterized in that the L-cysteine is 7-10 parts.
3. pericarpium juglandis hair dye according to claim 1 or 2, which is characterized in that preparing the A agent further includes 0.5-2 parts
Gallic acid or gallic acid-derivate, and/or, 4-6 parts of tannic acid or tannin acid derivative.
4. pericarpium juglandis hair dye according to claim 3, which is characterized in that prepare the A agent further includes 10-50 parts five
Gall nut.
5. pericarpium juglandis hair dye according to claim 4, which is characterized in that prepare five times that the A agent includes 30-40 parts
Son.
6. pericarpium juglandis hair dye according to claim 1 or 2, which is characterized in that preparing the A agent further includes 0.3-0.6
The Testa sojae atricolor of part and 10-50 parts of Chinese gall.
7. a kind of preparation method of pericarpium juglandis hair dye as claimed in claim 1 or 2, which is characterized in that the preparation method
It include: that green peel of walnut is prepared into green peel of walnut extracting solution first；Then the other components for preparing A agent addition green peel of walnut is mentioned
It takes in liquid, stirs evenly, reapply urea and be adjusted to pH value to can be obtained A agent between 6-12；The other components for preparing B agent are added
Enter in green peel of walnut juice, stir evenly, then pH value is adjusted to can be obtained B agent between 3.5-7.5.
8. preparation method according to claim 7, which is characterized in that prepare the galla turcica that the A agent further includes 0.5-2 parts
Acid or gallic acid-derivate, and/or, 4-6 parts of tannic acid or tannin acid derivative.
9. preparation method according to claim 7, which is characterized in that prepare the semen sojae atricolor that the A agent further includes 0.3-0.6 parts
The Testa sojae atricolor is prepared into Testa sojae atricolor extracting solution and is added in the A agent, is prepared by Chinese gall by skin and 10-50 parts of Chinese gall
The sub- extracting solution of quintupling is added in A agent.
10. a kind of hair colouring methods of pericarpium juglandis hair dye of application as described in claim 1-6 is any, which is characterized in that described
Hair colouring methods include: first uniformly to be applied to A agent on hair, and hair 25-40min is heated at 25-45 DEG C, is then washed with clear water
A agent on net hair；B agent is uniformly applied on hair after hair is dry, hair 25-40min is heated at 25-45 DEG C, then use
Hair dyeing can be completed in the B agent that clear water is cleaned on hair.
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| CN110037965A (en) * | 2019-05-30 | 2019-07-23 | 西藏圣雪生物科技有限公司 | A kind of pericarpium juglandis hair dye and preparation method thereof |
| CN114344182A (en) * | 2022-02-17 | 2022-04-15 | 刘子抄 | Hair dye containing natural plant active ingredients and preparation method thereof |
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| CN114344182A (en) * | 2022-02-17 | 2022-04-15 | 刘子抄 | Hair dye containing natural plant active ingredients and preparation method thereof |
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Application publication date: 20190215 |