CN106309248A - Natural hair dye prepared from plant pigment geranium haematochrome and hair dyeing method of natural hair dye - Google Patents

Natural hair dye prepared from plant pigment geranium haematochrome and hair dyeing method of natural hair dye Download PDF

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Publication number
CN106309248A
CN106309248A CN201610894415.7A CN201610894415A CN106309248A CN 106309248 A CN106309248 A CN 106309248A CN 201610894415 A CN201610894415 A CN 201610894415A CN 106309248 A CN106309248 A CN 106309248A
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China
Prior art keywords
agent
hair
hair dye
natural
dye
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CN201610894415.7A
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Chinese (zh)
Inventor
高海燕
訾慧敏
史宏艺
王建国
侯秀良
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Jiangnan University
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Jiangnan University
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/20—Halogens; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27—Zinc; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/82—Preparation or application process involves sonication or ultrasonication

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Cosmetics (AREA)

Abstract

The invention relates to a hair dye and particularly relates to a natural hair dye prepared from plant pigment geranium haematochrome and a hair dyeing method of the natural hair dye. The hair dye comprises an agent A and an agent B. The hair dye is characterized in that the agent A comprises the following components in percentage by weight: 0.1%-10% of a geranium pigment, 1%-5% of a thickening agent, 1%-10% of a surfactant and the balance of water, and the pH value is regulated to 3-7; and the agent B comprises the following components in percentage by weight: 1%-10% of a metal ion dye mordant, 1%-5% of the thickening agent, 1%-10% of the surfactant, 0.1%-0.3% of a natural essence and the balance of water, and the pH value is regulated to 3-7. The hair dyeing method comprises the following steps: uniformly smearing hair with the agent A, and dyeing the hair at a temperature interval of the room temperature to 60 DEG C for 10-40 minutes; and uniformly smearing the hair with the agent B, carrying out mordant dyeing for 10-20 minutes, and cleaning and airing the hair. The geranium pigment has a good hair dyeing effect, is suitable for various skin conditions, is capable of balancing sebum secretion of the scalp so as to brighten the hair and further has a hypnotic effect, so that the natural hair dye has dual effects of dyeing the hair and protecting the scalp.

Description

Use a kind of natural hair dye of preparing of plant pigment Flos Pelargonii red pigment and hair dyeing thereof Method
Technical field
The invention discloses a kind of natural botanical hair dye, with Flos Pelargonii red pigment and metal ion as active component, belong to In cosmetic field.
Background technology
Along with the raising of people's living standard, people increasingly notice that the image problem of self, hair dyeing also become increasingly Come into vogue.Since reform and opening-up, having been affected by international popular color development, China has also released one after another the hair dye of various tone, Yield unusually brilliant results in the hair-color market making China.Hair dye conventional on market mostly is oxidative hair dyes, and it does not contains general institute The dyestuff said, but containing dyestuff intermediate and coupling agent, this dyestuff intermediate and coupling agent penetrate into the cortex of hair After, occur oxidation reaction, coupling and condensation reaction to form bigger dye molecule, be closed in hair fiber.Multinomial research Confirming that this oxidative hair dyes has certain infringement to hair, toxicity is big, easily causes skin allergy, and life-time service may result in Poisoning, and induce various cancer.And why hair dye can cause the multiple disease such as skin allergy, leukemia, one of reason to be Because containing this chemical substance of p-phenylenediamine in hair dye.Expert claims, and p-phenylenediamine is the one must used in hair dye Coloring agent, is internationally recognized a kind of carcinogen.Along with stepping up of health of people consciousness and constantly entering of science of improving looks Step, natural plant pigment hair dye is increasingly becoming the development trend in following hair dye market.But, existing botanical hair dye exists Problem be that the hair color that can dye is less, it is impossible to meeting the individual demand of people, the most various botanical hair dyes are in succession Occur.
In the botanical hair dye of red colour system, Chinese patent application 201110008881.8 discloses a kind of with Stigma Croci extraction Thing is the main effect component of colored hair dyeing, the colored hair dyeing frost combined with plant coloured silk dye color matching composition.Stigma Croci belongs to unifacial leaf Plant guiding principle Liliales Iridaceae class plant, the main component of Stigma Croci extract contains crocetin, crocin, Stigma Croci Aldehyde, aminoacid, vitamin B1, vitamin B2, oils and fats and quintessence oil etc..But Stigma Croci is expensive so that prepared hair dye Expensive.Flos Carthami belongs to Dicotyledoneae chrysanthemum mesh Compositae class plant, and the main component of Flos Carthami extract contains Safflor Yellow A, carthamin, 6-hydroxyl kaempferol, kaempferol, Palmic acid, myristic acid, lauric acid, oleic acid, linoleic acid and sweet Oleate etc..
Although Flos Pelargonii is different from croceous composition, but it has the highest its cosmetic values.Flos Pelargonii can promote blood Circulation, can make pale skin become the most ruddy after using.And Geranium Essential has preferable syngignoscism.Flos Pelargonii is Niu Er Seedling section storksbill, pattern has redness, pink, rose-colored, orange red, white or secondary colour.In the sunflower of India Containing a large amount of anthocyanin, it it is a kind of important natural pigment resource.Anthocyanin is a kind of water miscible pigment, is anthocyanidin and sugar The compounds formed after being combined by glucosides, has a strongest colorability, but its poor stability.
The present invention uses acidic alcohol to extract the red pigment in Flos Pelargonii, and by pillar layer separation by colloid therein Thing separates, and the Flos Pelargonii red pigment after purification can make hair paint as main constituent.
Summary of the invention
The present invention uses the hydrochloric acid 50 of 0.3mol/L～80% ethanol (V/V) solution as solvent, the solution extracted Separating through silica gel column chromatography, coloured moiety, as flowing phase, is merged distillation, institute by the dichloromethane aqueous solution of 10～30wt% The Flos Pelargonii red pigment obtained, as the hair dye formulas of hair dye main constituent, finds individually to have hair dyed or by Flos Pelargonii Flos Pelargonii It is applied in combination as upper colour content with mordant, hair can be dyed different colors.
The technical scheme provided according to the present invention, uses lyochromes Flos Pelargonii red pigment to prepare a kind of novel Natural hair dye includes agent A and agent B, it is characterised in that agent A includes plant pigment 0.1%-10%, polyhydric alcohol 20-50%, table Face activating agent 1-10%, thickening agent 1-5%, remaining is water, regulates pH to 5-7；Agent B includes comprising metal salt mordant 1-5%, increases Thick dose of 1-5%, surfactant 1-10%, natural essence 0.1-0.3%, remaining is water, regulates pH to 5-7.Unit is weight Percent.
Polyhydric alcohol in agent A is one or more in wetting agent glycerol, butanediol, isopropanol.
In agent B, metal salt mordant is the salt of any metal ion allowing use in cosmetics, includes but not limited to Ferrous sulfate, ferrous chloride, iron chloride, zinc sulfate, aluminum chloride, copper nitrate.Natural essence can use Flos Rosae Rugosae essence, Flos Jasmini Sambac One in essence, lavandula angustifolia essence.
The pH of agent A mediating recipe B regulates with phosphoric acid, acetic acid, lactic acid, tartaric acid or citric acid.
Described thickening agent include but not limited to Radix Acaciae senegalis, carboxymethyl cellulose, hydroxyethyl cellulose, guar gum, One or more combination in propylene glycol stearate.
Surfactant include stearyl alcohol, glyceryl stearate, sodium lauryl sulfate, OPEO etc. cloudy from Son, cation, both sexes or nonionic surfactant.
Agent A and agent B is solution or any degree thickening or adds the liquid of glue, Emulsion or cream form.
Generally, colored hair dyeing is youngster mostly, before coloured silk contaminates, use inorganic agent to hair at Reason.The sofening treatment agent that hair dyeing industry is commonly used all can use, in the present invention such as sodium thiosulfate, cysteine class material, sulfur Guanidine-acetic acid sodium etc., preferential employing cysteine class material combines the inorganic agent before organic base is had hair dyed as hair dye of the present invention.
Cysteine class material of the present invention can be cysteine, homocysteine, amino A-wire cysteine, N- The mixture of one or more in acetylcysteine.
Organic base of the present invention is small molecule, short carbon chain, alkaline organic, including ethanolamine, ethylenediamine, two Ethamine, dimethylamine, hydroxyethylethylene diamine, aminoethanolamine, sodium ethylene diamine tetracetate etc..
Preservative used can be one or more in KF88, parabens, Glydant series etc. Mixture.
On the basis of the above, soft agent can include but not limited to thickening agent, surfactant with appropriate amount of auxiliary materials, prevent Rotten agent and water etc. make final products.These hair dye adjuvants are to commonly use in hair dye industry, are limited the most especially System.
In a preferred embodiment, the invention discloses a kind of hair dye, including
Flos Pelargonii Hortori 5wt% 80wt%
Mordant 0.1wt% 10wt%
Soft inorganic agent of hair containing following component:
Cysteine and derivant thereof and salt 1wt% 10wt%
Organic base 1wt% 10wt%
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is described further, but protection scope of the present invention does not limit In this.
Embodiment one
Take 1000 Flos Pelargonii petals to join water bath with thermostatic control 40 DEG C in 0.3mol/L hydrochloric acid 80% ethanol of 5000ml and carry Taking 30min, sucking filtration obtains extracting solution.By filtrate chromatography on a silica gel column, 20wt% dichloromethane is flowing phase, is associated with face The component of color, concentrates distillation and is dried.
Hair dye
Oil phase
Aqueous phase
1,3 butylene glycol 2
Glycerol 2
Deionized water 75
Oil phase and aqueous phase are heated separately to 100 DEG C, under agitation aqueous phase is joined oil phase mixing and emulsifying, homogenizing 3min, continues stirring, until about 45 DEG C add essence 0.2, continues stirring 30min, obtains stain mastic.
Soft inorganic agent
Above-mentioned raw materials is mixed under agitation to being completely dissolved uniformly, obtain inorganic agent of the present invention.
By hair wash clean, after drying by hair sofening treatment agent uniform application on hair, keep 20min；Again by head Send out wash clean, by hair dye uniform application on hair, keep 1 hour-3 hours, wash clean hair.The hair dyed Color is red.
Embodiment two
Take 1000 Flos Pelargonii petals and join supersound extraction 30min in 0.3mol/L hydrochloric acid 60% ethanol of 5000ml, Sucking filtration obtains extracting solution.By filtrate chromatography on a silica gel column, 10wt% dichloromethane is flowing phase, merges coloured group Point, concentrate distillation and be dried.
Hair dye
Oil phase
Aqueous phase
Oil phase and aqueous phase are heated separately to 100 DEG C, under agitation aqueous phase is joined oil phase mixing and emulsifying, homogenizing 3min, continues stirring, until about 45 DEG C add essence 0.2, continues stirring 30min, obtains stain mastic.
Soft inorganic agent
Above-mentioned raw materials is mixed under agitation to being completely dissolved uniformly, obtain inorganic agent of the present invention.
By hair wash clean, after drying by hair sofening treatment agent uniform application on hair, keep 20min；Again by head Sending out wash clean, by hair dye uniform application on hair, keep 1 hour-3 hours, wash clean hair, hair presents yellowish-brown Color.

Claims (1)

1. one kind uses natural hair dye prepared by Flos Pelargonii red pigment, it is characterised in that use 0.3mol/LHCl 50～ Ethanol (V/V) the solution ethanol solution of 80%, as solvent, carries out supersound extraction 20～60min, extracts Flos Pelargonii petal Solution through silica gel column chromatography separate, the dichloromethane aqueous solution with 10～30wt% as flowing phase, by coloured moiety conjunction And distill, obtained Flos Pelargonii red pigment is as hair dye main constituent；
Described natural hair dye includes that agent A and agent B, agent A comprise Flos Pelargonii red pigment 0.1%-10%, thickening agent 1-5%, surface Activating agent 1-10%, regulates pH to 3-7, and surplus is water；Agent B comprises metal ion mordant 1-10%, thickening agent 1-5%, table Face activating agent 1-10%, natural essence 0.1-0.3%, regulate pH to 3-7, and surplus is water；Unit is percetage by weight；
In agent B, metal ion mordant is the salt of the metal ion allowing use in cosmetics, and it is selected from ferrous sulfate, chlorine Change ferrous iron, zinc sulfate, aluminum chloride or copper nitrate；
Natural essence in agent B uses the one in Flos Rosae Rugosae essence, jasmine flower essence, lavandula angustifolia essence；
The pH of agent A mediating recipe B regulates with phosphoric acid, acetic acid, lactic acid, tartaric acid or citric acid；
Thickening agent in agent A mediating recipe B is selected from Radix Acaciae senegalis, carboxymethyl cellulose, hydroxyethyl cellulose, guar gum, propylene glycol One or more combination in stearate；
The surfactant of agent A mediating recipe B is selected from stearyl alcohol, glyceryl stearate, sodium lauryl sulfate or octyl phenol polyoxyethylene Ether.
CN201610894415.7A 2016-10-13 2016-10-13 Natural hair dye prepared from plant pigment geranium haematochrome and hair dyeing method of natural hair dye Pending CN106309248A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116617101A (en) * 2023-07-25 2023-08-22 北京立仁堂医药科技开发有限公司 Pigment composition for dyeing hair, blackening hair and nourishing hair and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102423286A (en) * 2011-11-24 2012-04-25 江南大学 Natural hair dye prepared by using phytochrome curcumin and hair dyeing method of natural hair dye
CN104083307A (en) * 2014-07-28 2014-10-08 江南大学 Natural hair dye prepared by adopting plant pigment safflower pigment and hair dyeing method using natural hair dye

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102423286A (en) * 2011-11-24 2012-04-25 江南大学 Natural hair dye prepared by using phytochrome curcumin and hair dyeing method of natural hair dye
CN104083307A (en) * 2014-07-28 2014-10-08 江南大学 Natural hair dye prepared by adopting plant pigment safflower pigment and hair dyeing method using natural hair dye

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
闫颖: "《天竺葵红色素提取及在压花保色中应用的研究》", 《天竺葵红色素提取及在压花保色中应用的研究》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116617101A (en) * 2023-07-25 2023-08-22 北京立仁堂医药科技开发有限公司 Pigment composition for dyeing hair, blackening hair and nourishing hair and application thereof
CN116617101B (en) * 2023-07-25 2023-10-13 北京立仁堂医药科技开发有限公司 Pigment composition for dyeing hair, blackening hair and nourishing hair and application thereof

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