CN105380817B - Three component hair dyes and hair colouring methods - Google Patents
Three component hair dyes and hair colouring methods Download PDFInfo
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- CN105380817B CN105380817B CN201510937947.XA CN201510937947A CN105380817B CN 105380817 B CN105380817 B CN 105380817B CN 201510937947 A CN201510937947 A CN 201510937947A CN 105380817 B CN105380817 B CN 105380817B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
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- A61K8/00—Cosmetics or similar toiletry preparations
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/411—Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/415—Aminophenols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/893—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
- A61K2800/4324—Direct dyes in preparations for permanently dyeing the hair
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Abstract
The present invention relates to a kind of three component hair dyes and hair colouring methods.Three component hair dye is formed by three doses, the coloring agent respectively containing oxidation dye and alkaline agent, color developing agent and care agent containing strong oxidizer, wherein, the care agent, by weight percentage, including following component:The derivative of protein hydrolysate and/or protein hydrolysate derivative 5 35%, auxiliary agent 0 1.0%, balance of solvent, the protein hydrolysate and/or protein hydrolysate accounts for the 0.2 2% of the coloring agent, color developing agent and care agent total weight.Three component hair dye, break the recipe configuration pattern of traditional hair dyeing product, the breakthrough three component hair dye formulas for proposing protein hydrolysate and individually packing, the protein hydrolysate of specified weight percentage and/or the care agent of its derivative are included by reasonable preparation, it solves the problems, such as that albumen is vulnerable in the prior art, achievees the effect that protein is made to play repair in hair dye.
Description
Technical field
The present invention relates to hair dye, more particularly to a kind of three component hair dyes and hair colouring methods.
Background technology
Due to there are a large amount of alkaline matters to enter in hair in hair dye, original protein and amino acid are destroyed,
It can hardly be avoided to the damage of hair, therefore the hair after contaminating would generally become to dry up, tarnish and elasticity.
And the Asian color development overwhelming majority is pitch-black or dark brown, because the cuticula of hair has accumulated a large amount of melanin
The factor, and comparatively Asia human hair is more thicker, and hair quality is thicker, is consequently belonging to more chromophobe hair form.From dye
It is said in hair principle, on the one hand the intrinsic pigment of a part of hair will be taken off by changing hair primary colors, it is new on the other hand to increase some
Pigment, the two processes simultaneously act on and obtain final effect.Hair dye can contaminate somber hair, usually all contain hydrogen peroxide and ammonia
Water, concentration is higher, and the ability for taking off melanin is stronger, and hair is with regard to that can contaminate more shallow, while the damage that hair is subject to is more strict
Evil.Some hair care ingredients can generally be added in hair dyeing, hair care dye --- hair care and hair dyeing are carried out at the same time here it is popular at present.
Containing a large amount of protein, that is, keratin in hair, account for about the 65%~95% of hair, many natural activity angles egg
Its derivative of bletilla has hair very high compatibility, is easily absorbed for hair, has moist, film forming, moisture-keeping function.And hydrolyze angle
Albumen has more repair to damaged hair, this is because the hair cuticle of damaged hair, which damages, so that protein is exposed, hair
Hydrophily increase is easily combined with protein hydrolysate, forms one layer of albuminous membranae, can improve the hydrophobicity of damaged hair, reduces hair damage
Wound is so as to become to be more easy to comb and have certain gloss.Therefore, in current hair dye, some meeting addition protein hydrolysate, which is used as, to be repaiied
Protect ingredient.
But high temperature, peracid or alkali and strong oxidizer, heavy metal, high concentration ion etc. excessively can all destroy protein
Stability.Hair dye containing dyestuff one (coloring agent) for high ph-values containing more ionic raw material;And hair dye contains hydrogen peroxide
One (color developing agent) in then contain for low ph value compared with strong oxidizer, although present technological development go out it is many to high temperature, peracid or
Metastable aminosal under the conditions of alkali and strong oxidizer, heavy metal, high concentration ion etc. is crossed, if in this two doses dyes
It sends out and aminosal or derivatives thereof is added in agent, then during long-term storage, still suffer from part active ingredient and occur
Variation causes the repairing effect of hair is reduced or failed.
Invention content
Based on this, it is necessary to provide a kind of three component hair dyes for having effects that well to nurse, repair.
A kind of three component hair dyes, are formed, the coloring agent respectively containing oxidation dye and alkaline agent, containing Strong oxdiative by three doses
The color developing agent and care agent of agent, wherein,
The care agent, by weight percentage, including following component:
Protein hydrolysate and/or protein hydrolysate derivative 5-35%
Auxiliary agent 0-1.0%
Balance of solvent,
The derivative of the protein hydrolysate and/or protein hydrolysate accounts for the coloring agent, color developing agent and care agent total weight
0.2-2%.
The derivative of the protein hydrolysate and/or protein hydrolysate accounts for the coloring agent, colour developing in one of the embodiments,
Agent and the 0.4-1.5% of care agent total weight.
The protein hydrolysate is the protein hydrolysate containing cystine in one of the embodiments,.Cystine is hair
The chief component of cuticula and cortex handles hair using the protein derivatives being chemically similar during hair dyeing, can protect
Hair keratin, while provide opsonic action for hair.
In one of the embodiments, the protein hydrolysate for Lauryldimonium Hydroxypropyl base hydrolysis of keratin and/or
Hydrolysis of keratin.
The solvent is one or more combinations in water, propylene glycol, ethyl alcohol, glycerine in one of the embodiments,.
The solvent is water and/or propylene glycol in one of the embodiments,.
The coloring agent in one of the embodiments, by weight percentage, including following component:
The color developing agent in one of the embodiments, by weight percentage, including following component:
Oxidation dye of the present invention is preferably meta-aminophenol, resorcinol, 2,4- diamino ethoxybenzenes sulfate, 2,
It is one or more in 5- bis aminomethyls sulfate, p-phenylenediamine, 4- amino -2- hydroxy-methylbenzenes, 4-aminophenol;
The emulsifier is preferably one or more in oleyl alcohol ether -5, ceteareth -20;
The alkaline agent is preferably ethanol amine and/or ammonium hydroxide;
The conditioner is preferably PEG-12 dimethyl silicone polymers;
The moisturizer is preferably propylene glycol;
The thickener is preferably -20 methacrylate copolymer of acrylic acid (ester) class/stereth, cetearyl alcohol
It is one or more in alcohol;
The antioxidant is preferably sodium sulfite and/or arabo-ascorbic acid;
The metal-chelator is preferably EDTA-2Na;
The strong oxidizer is preferably hydrogen peroxide.
The present invention also provides a kind of hair colouring methods, include the following steps:
The coloring agent and color developing agent are mixed, the care agent is added, is applied on hair after mixing, 25 DEG C-
It is kept for 10-40 minutes, cleaned under the conditions of 50 DEG C, you can.
Compared with prior art, the invention has the advantages that:
Three component hair dye of the present invention breaks the recipe configuration pattern of traditional hair dyeing product, breakthrough proposition
Three component hair dye formulas that protein hydrolysate is individually packed include the protein hydrolysate of specified weight percentage by reasonable preparation
And/or the care agent of its derivative, solve the problems, such as that albumen is vulnerable in the prior art, reach makes albumen in hair dye
Matter plays the effect of repair.
Further, due to using protein hydrolysate as independent one use, when mixing, makees coloring agent and color developing agent dyeing
Performance be easy to cause influence, through experimental study, need to the derivative of the protein hydrolysate and/or protein hydrolysate be accounted for the dye
The 0.2-2% of toner, color developing agent and care agent total weight thus while being repaired to hair, reaches good colouring
Effect.
In addition, the solvent that the type and care agent to protein hydrolysate use screens, it can be in hair dye effectively
Optimize restoration care effect, reduce the damage of coloring agent and color developing agent to hair.
Specific embodiment
Three component hair dyes and hair colouring methods of the present invention are described in further detail below in conjunction with specific embodiment.
Embodiment 1
The present embodiment three component hair dyes of one kind, by weight percentage, including forming as shown in table 1.
Table 1
By the coloring agent, color developing agent and care agent with weight ratio 5:5:1 (Lauryldimonium Hydroxypropyl base hydrolysis angle
About 0.5%), applied to hair dyeing, specific hair colouring methods are protein content:
First by color developing agent described in coloring agent described in 30g and 30g, adding in hybrid bottle and tighten lid, concussion is rocked under 5-8,
Material is made in bottle to be substantially uniformly mixed, then turns on bottle cap, adds in 6g care agents, tightens to shake after lid and rock under 5-8, make
Material substantially after mixing, mixing hair dye from bottle neck is squeezed out, is coated on hair, 20- is stopped on hair in bottle
30min if temperature is relatively low or the thick and stiff hardly possible of hair is painted, can be heated suitably, controlled at 25 DEG C -50 DEG C, hair be waited for reach
It is rinsed well after color effects with clear water, dries up hair, you can.
Embodiment 2
The present embodiment three component hair dyes of one kind, by weight percentage, including forming as shown in table 2.
Table 2
By the coloring agent, color developing agent and care agent with weight ratio 10:10:1 (Lauryldimonium Hydroxypropyl base hydrolysis
About 1.0%) applied to hair dyeing, specific hair colouring methods are keratin content:
First by color developing agent described in coloring agent described in 30g and 30g, adding in hybrid bottle and tighten lid, concussion is rocked under 5-8,
Material is made in bottle to be substantially uniformly mixed, then turns on bottle cap, adds in 3g care agents, tightens to shake after lid and rock under 5-8, make
Material substantially after mixing, mixing hair dye from bottle neck is squeezed out, is coated on hair, 20- is stopped on hair in bottle
30min if temperature is relatively low or the thick and stiff hardly possible of hair is painted, can be heated suitably, controlled at 25 DEG C -50 DEG C, hair be waited for reach
It is rinsed well after color effects with clear water, dries up hair, you can.
Embodiment 3
The present embodiment three component hair dyes of one kind, by weight percentage, including forming as shown in table 3.
Table 3
By the coloring agent, color developing agent and care agent with weight ratio 3:3:1 (hydrolysis of keratin content about 1.5%) is applied
In hair dyeing, specific hair colouring methods are:
Color developing agent described in coloring agent described in 30g and 30g first is squeezed into tune to mix in bowl, 10g institutes are added in after being uniformly mixed
Care agent is stated, is stirred for uniformly, mixing hair dye being coated on hair, 20-30min is stopped on hair, if temperature is relatively low
Or the thick and stiff difficult colouring of hair, it can suitably heat, hair is waited for be rinsed well after reaching color effects with clear water, dries up hair, i.e.,
It can.
Comparative example
This comparative example three component hair dyes of one kind, by weight percentage, including forming as shown in table 4.
Table 4
By the coloring agent, color developing agent and care agent with weight ratio 3:3:1 (hydrolysis of keratin content about 3%) is applied to
Hair dyeing, specific hair colouring methods are:
Color developing agent described in coloring agent described in 30g and 30g first is squeezed into tune to mix in bowl, 10g institutes are added in after being uniformly mixed
Care agent is stated, is stirred for uniformly, mixing hair dye being coated on hair, 20-30min is stopped on hair, if temperature is relatively low
Or the thick and stiff difficult colouring of hair, it can suitably heat, hair is waited for be rinsed well after reaching color effects with clear water, dries up hair, i.e.,
It can.
The using effect of three component hair dyes described in embodiment 1-3:
Above test is scored by 10 trained evaluation personnels, is averaged, and full marks are 10 points.
To dye when can be seen that the hydrolysis of keratin of embodiment 1-3 additions or the hair dyeing of its derivative from more than test result
Hair color effects does not influence substantially, and the wet comb performance of hair after dye is done to comb performance, hair gloss, hair feel and have and significantly carried
Height, and additive amount is bigger, and raising is more apparent, illustrates that it is correct can to reduce hair dyeing for addition hydrolysis of keratin or derivatives thereof during hair dyeing
The damage of hair has protection and opsonic action to hair.And it is more than 2% to work as additive amount, has abated effect to hair dyeing effect, Er Qiehu
Reason effect does not significantly improve.
In addition, in example 2, care agent is directly added into coloring agent, after room temperature is stored 3 months, hair dyeing survey is carried out
It tries, the effect having hair dyed in the hair dyeing agent composition for mixing care agent addition with ability during hair dyeing compare as follows:
Above test is scored by 10 trained evaluation personnels, is averaged, and full marks are 10 points.
More than test result shows that hydrolysis of keratin is added in hair dye has hair nursing role, but hydrolyzes angle
Albumen is mixed with hair dye to be stored for a long time, can reduce nursing role of the hydrolysis of keratin to hair.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, it is all considered to be the range of this specification record.
Embodiment described above only expresses the several embodiments of the present invention, and description is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that those of ordinary skill in the art are come
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (9)
1. a kind of three component hair dyes, which is characterized in that it is formed by three doses, the dyeing respectively containing oxidation dye and alkaline agent
Agent, color developing agent and care agent containing strong oxidizer, wherein,
The care agent, by weight percentage, including following component:
The derivative 5-35% of protein hydrolysate and/or protein hydrolysate
Auxiliary agent 0-1.0%
Balance of solvent,
The derivative of the protein hydrolysate and/or protein hydrolysate accounts for the 0.2- of the coloring agent, color developing agent and care agent total weight
2%.
2. three component hair dye according to claim 1, which is characterized in that the protein hydrolysate and/or protein hydrolysate
Derivative accounts for the 0.4-1.5% of the coloring agent, color developing agent and care agent total weight.
3. three component hair dye according to claim 1 or 2, which is characterized in that the protein hydrolysate is contains cystine
Protein hydrolysate.
4. three component hair dye according to claim 3, which is characterized in that the protein hydrolysate is lauryl dimethyl ammonium
Hydroxypropyl hydrolysis of keratin and/or hydrolysis of keratin.
5. three component hair dye according to claim 1 or 2, which is characterized in that the solvent for water, propylene glycol, ethyl alcohol,
One or more combinations in glycerine.
6. three component hair dye according to claim 5, which is characterized in that the solvent is water and/or propylene glycol.
7. three component hair dye according to claim 1 or 2, which is characterized in that the coloring agent, with weight percent
Meter, including following component:
8. three component hair dye according to claim 1 or 2, which is characterized in that the color developing agent, with weight percent
Meter, including following component:
And adding in acid makes the pH of the color developing agent be 2-4.
9. a kind of hair colouring methods, which is characterized in that include the following steps:
Any one of the claim 1-8 coloring agents and color developing agent are mixed, the care agent is added, head is applied to after mixing
It on hair, is kept for 10-40 minutes, cleaned under the conditions of 25 DEG C -50 DEG C, you can.
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CN1108521A (en) * | 1994-03-15 | 1995-09-20 | 陈寿生 | Hair-dyeing shampoo |
CN102824283A (en) * | 2012-09-17 | 2012-12-19 | 山西大学 | Environment-friendly hair-care hair dye and preparation method thereof |
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CN1108521A (en) * | 1994-03-15 | 1995-09-20 | 陈寿生 | Hair-dyeing shampoo |
CN102824283A (en) * | 2012-09-17 | 2012-12-19 | 山西大学 | Environment-friendly hair-care hair dye and preparation method thereof |
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