CN102399599A - Methanol diesel oil manufacturing mode - Google Patents

Methanol diesel oil manufacturing mode Download PDF

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CN102399599A
CN102399599A CN2010102914184A CN201010291418A CN102399599A CN 102399599 A CN102399599 A CN 102399599A CN 2010102914184 A CN2010102914184 A CN 2010102914184A CN 201010291418 A CN201010291418 A CN 201010291418A CN 102399599 A CN102399599 A CN 102399599A
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fat
acid
alcohol
oil
nitric acid
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陈若歆
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Abstract

The invention relates to a manufacturing mode of environment-friendly and energy-saving M15_M85 methanol diesel oil. The methanol diesel oil is composed of diesel oil, methanol, and additives. The methanol diesel oil is prepared with operations under normal temperatures and normal pressures. The invention discloses a plurality of common additives used for preparing methanol diesel oil in modern times. If explosives and aviation fuels are appropriately utilized, methanol defalcated heat value can be well compensated. The theory is tentatively considered as a gaseous detonation theory. The additives can be selected from nitric acid esters, nitrates, nitro compounds, non-aromatic compounds, peroxides, and the like.

Description

A kind of methanol diesel-oil manufacturing mode
Technical field
M15_M85 methanol diesel-oil technology manufacturing mode according to the invention belongs to chemical industry cleaning new energy alternative fuel field.Mean by methyl alcohol and be major ingredient and must do not transform explosive motor that the phase is to benefit society to substitute exhausted day by day petrifaction diesel.The oil of diesel internal combustion engine for combusting is that fuel is hydrocarbon fuel, and alcohols is the compound that alkyl and hydroxyl-OH form, and this is just from having determined alcohols to can be used as the fuel substitute of oil engine in essence; Suitably allocate, not only on salient features, can match in excellence or beauty, and burning fully with diesel oil; Efficiency of utilization is high; CO in the exhaust emissions and CH amount significantly reduce, and have alleviated environmental pollution, are the most promising in the recent period spatter property fuel substitutes.Methyl alcohol begins one's study so far from the twenties in 20th century as the diesel oil alternative fuel, has obtained internationally recognized and is able to extensive popularization.
Background technology
Known; Though methyl alcohol has a series of advantages as the alternative fuel of petrifaction diesel; Himself tangible unfavorable factor is arranged also; Overcome with the advanced theory in modern times and science and technology in the time of must waiting to modulate methanol diesel-oil and remedy, inferior make synthetic methanol diesel-oil near the physicochemical property of petrifaction diesel and surmount it, this just at present pendulum in the world the big problem in face of the scientist.The methyl alcohol characteristic has determined it to participate in the methanol diesel-oil of preparation, the several problems that must study, such as:
1. miscible problem.
It is strong polar material that methyl alcohol contains hydroxyl, and the hydroxyl of methyl alcohol can be infinitely water-soluble, possess hydrophilic property, and diesel oil is the oil base mixture of complicated hydro carbons.The alcohol hydrocarbon phase is contrary to, and two thing ratio of mixture are difficulty.
2. cetane value problem.
Diesel motor is compression-ignited igniting, and cetane value is to embody the important indicator of diesel combustion performance.Diesel oil is 45-55 unit's (slow speed diesel engine can be 35 with diesel oil), and methyl alcohol is merely 3 units.And the methyl alcohol burning-point exceeds 250-270 ℃ than petrifaction diesel, so methyl alcohol is difficult for by compression ignite.Cross low cetane value and too high kindling temperature, make many inventors abandon the research of methyl alcohol on diesel motor, then be absorbed in the major cause that substitutes on the petrochemical industry gasoline.
3. calorific value problem.
The low heat value of diesel oil is 42.7MJ/Kg, and the methyl alcohol low heat value is 19.7MJ/Kg, is merely 46% of diesel oil, and obviously the engine power performance curve can plummet.To account for the calorific value additive of fuel overall weight 1%-5%, be used to compensate because of interpolation methyl alcohol makes nearly half the heat and lose, show non-easy thing.
4. latent heat of vaporization problem.
The latent heat of vaporization of methyl alcohol is high, the engine cold-start poor performance.Alkyl alcohol is compared with corresponding alkane, and molecular weight, density, boiling point, atmospheric boiling point and heat of gasification etc. are all high than alkane.To be alkyl alcohol Duo a Sauerstoffatom than corresponding alkane to the reason that molecular weight and density are high; And the high reason of boiling point and heat of gasification is because liquid pure intermolecular through the hydrogen bond complexing, and with the form appearance of complex molecule.Complexing action is exactly dipolar interaction between hydrogen bond or polar molecule, and this effect makes molecule of the same race have reversible bonded effect, and does not cause the change of molecular chemistry character.Therefore, need to provide a heat when heating makes it become steam to alcohols more, to destroy its hydrogen bond, the big reason of alcohols gasification latent heat that Here it is.Therefore, have only small amount of methanol evaporation during engine cold-start, if the inflammable mixture concentration that evaporation forms does not reach when catching fire concentration limit, then gas mixture can not fire burns, this methanol content in methanol fuel surpass 60% o'clock particularly outstanding.
5. lamination problem.
Mixed fuel stability is relatively poor, to moisture-sensitive.(OH), hydroxyl and water can associate mutually with the hydrogen bond form, so methyl alcohol has very strong wetting ability to contain alkyl and hydroxyl in the methanol molecules.The wetting ability of methyl alcohol and oleophilicity are mutually exclusive, and methyl alcohol absorbs water the more, and the mutual solubility of it and gasoline is poorer, more easily and the oil content layer.Even during with the contact with moisture that from damp atmosphere, absorbs, also usually can cause the layering again of miscible methyl alcohol-gasoline.Methyl alcohol and fuel tank ponding meet and separate out, and possibly become turbid, and oxidation stain also is prone to layering at short notice.After putting into fuel tank to made methanol diesel-oil, garage is just auto extinguishing soon, or back overnight beats missing of ignitionly, and many contrivers have ignored this problem.
6. etching problem.
Methyl alcohol is a solvent, has stronger chemically reactive.Methanol fuel can generate acidic substance such as a small amount of formaldehyde, formic acid in combustion processes, give the various hardwares (fuel tank, oil circuit, float chamber, oil pump etc.) that contact on the mover that uses Aalcohols fuel, causes corrosion.Sulphur and sulfide have direct or indirect corrosive nature to multiple metal and alloy in the fuel oil, and the engine air carbon-deposits the cylinder is increased, and the corrodibility of methanol gasoline mixed fuel increases with the increase of methanol content.
7. swelling problem.
Methanol gasoline can produce certain burn into swelling action to the non-metallic material in the automobile oil supply system.Swelling, hardening can take place in rubber parts (like the oil sealing of oil pump, packing ring etc.) in methanol fuel, become fragile or phenomenon such as softening, loses use value.Also can produce similar effect to plastics, the fiber mat sector-meeting is softening gradually and cause leakage of oil.For improving in the employed additive of methanol fuel performance, some composition also can produce detrimentally affect to rubber and plastic components.The rubber volume swelling is the result of methyl alcohol and gasoline compound action, and having corrosive material is sulphur and undesirable componentss such as sulfide, organic acid and water-soluble acid and alkali.See that from the angle of intermolecular interaction force methanol molecules at first is immersed in the rubber molecular chain, have an effect, thereby weakened the reactive force between the polymer polar group that oil molecule is to expand again to wherein diffusion then with the polarity gene on the chain.
8. vapour locking problem.
Pure methyl alcohol is (no range of boiling) boiling when 64 ℃ of fixed boiling points, and boiling point is low, is easy to generate vapour lock, forces the fuel oil road of mover to interrupt and stop working.
…
Summary of the invention
Only know it, can be with it.The present invention is directed to the methyl alcohol natural characteristics, several times dangerous experiment and vehicle operating, a kind of large-proportion methanol diesel oil prepares successfully under inventor's " air detonation " theoretical direction finally, is published in inferior now with regard to its preparing mode:
GB diesel oil 20-40
Methyl alcohol 30-85
Additive 0.1-5
: solubility promoter
Cetane number improver
Heat value agent
Anticorrosive agent
Anti-swelling agent
The seasonal adjustment agent
Other
About additive
1. solubility promoter
For obtaining stable methanol diesel-oil, just must add one or more can reduce capillary additive between methyl alcohol and the diesel oil, and this is a kind of physical mixed for Bi Jing, i.e. O/W and W/O relation.Experiment proof: 1.. similar molecular then mixes; 2., proportion is close then mixes.Density is physical parameter, and size is adjustable, can adopt the weighted-average method adjustment.3., intermiscibility is formed relevant with temperature, methanol gasoline.When methanol content was lower or higher, methyl alcohol and gasoline also can dissolve each other under lower temperature, can not produce demixing phenomenon.With adding of methanol content in methyl alcohol-gasoline mixture, the intermiscibility variation, phase separation temperature rises very fast.When methanol content reached 40%, phase separation temperature reached peak, and the methanol fuel under this ratio is least stable; When quantity of methyl alcohol continuation increase, the performance that mixes improves, and phase separation temperature descends rapidly.When temperature more than-18 ℃ the time, methanol content is less than 4% or need not add solubility promoter greater than 73% o'clock methyl alcohol and gasoline and just can dissolve each other fully with any ratio, the methanol fuel under this ratio is relatively stable.At methanol content is 30%～40% o'clock, and the critical consumption of solubility promoter is maximum, and both are layering very easily.At methanol content is 4%～30% o'clock, and the critical consumption of solubility promoter increases along with the increase of methanol content.At methanol content is 40%～73% o'clock, and the critical consumption of solubility promoter reduces along with the increase of methyl alcohol.By being proportioning in the middle of M15 and M85 are superior to.4., the homology alcohols of methyl alcohol is good solubility promoter, isomery alcohol analogy n-alkanol class is effective, along with increasing of carbonatoms, its hydrotropy performance increases.5.. the benzene class also can be used as solubility promoter, and normal paraffin does not have the hydrotropy effect basically.
Materials are preferably: the secondary octanol Virahol trimethyl carbinol isopropylcarbinol sec-butyl alcohol primary isoamyl alcohol octanol isooctyl alcohol iso-heptanol C5-C8 n-alkanol of ethanol propyl carbinol amylalcohol octanol certain herbaceous plants with big flowers alcohol (isomery alcohol) lauryl alcohol stearyl alcohol 1; 4 butyleneglycol polyoxyethylene glycol fusel acetone butanone ring ethyl ketone methyl ethyl diketone dimethyl ketone PVP K120 isobutylamine dme diisobutyl ether MTBE TAME sherwood oil ethylene glycol monobutyl ether EGME ether sec.-butyl methyl ethers narrow positive heptan the stupid formaldehyde dibutyl phthalate (DBP) of Methylal(dimethoxymethane) Nitromethane 99Min. 2-methylpent (suffering) alkane octane-iso pentamethylene 2,6 di t butyl phenol S-80 T-80 OP---7 dodecyl phenol polyethenoxy ether AEO polyoxyethylene nonylphenol (TX-10) peregal naphthenic acid oleic acid epoxy soybean oil Viscotrol C turps silk floss oil (acid) silicone oil hexahydroaniline quadrol triethylamine dibutylamine trolamine NA (K.CA) OH phthalic acid di-allyl ester phthalic acid Diisooctyl nitric acid fat (different suffering. penta) type different propylene of methyl formate acetate second (fourth) fat isopropylformic acid second fat acetate Zhong Ding fat acetate uncle's fourth fat dimethyl carbonate carbonic acid diethyl ester glycerine nitrilotriacetic fat tetraethoxysilance boric acid three (two) formicesters ... Etc. a kind of or mixture.
2. cetane number improver
Cetane value is exactly the pyrophoricity index of expression diesel oil when in oil motor, burn, and it is big or small relevant with the character of diesel component.The cetane value height of fuel means that its pyrophoricity is good, starts easily when being used for oil motor, and it is soft to work.Too high like cetane value, because the too short fuel of delay period also has little time perfect combustion, cause the diesel exhaust gas over-emitting black exhaust, economy descends; If cross low, starting difficulty then, running roughly.The cetane value of general diesel fuel is within 40～60 scopes.Should select high-cetane fuel for use in cold or high altitude localities, the large-sized low-speed oil motor can be 30 fuel with cetane value.The adoptable cetane value 40-45 of most oil motor can.
Materials are preferably: generally speaking, the cetane value of alkane is maximum, the minimum of aromatic hydrocarbon, and naphthenic hydrocarbon and alkene then fall between.The composition of cetane value is generally nitric acid ether, amyl group nitric ether and superoxide.Effect manifests and commonly used is mostly positive hot fat triphosphoric acid glyceryl ester two many alkyl of the tertiary alkyl peroxide tert-butyl peroxide ditertiary butyl peroxide base superoxide of the positive fourth fat of the also own fat nitro-thinner of nitric acid second fat propyl nitrate nitric acid isopropyl ester nitric acid isooctyl pental nitrate nitric acid isoamyl fat 2-ethylhexyl nitric acid fat (2-EHN) nitric acid dodecyl nitric acid fat nitric acid nitric acid
3. heat value agent
Be the calorific value of a methanol gasoline addition below, so as to saying methanol diesel-oil.
Figure BSA00000282812700031
Before address, desire with the calorific value additive that accounts for fuel overall weight 1%-5% (be mostly the high price industrial chemicals, amount can not be excessive, otherwise lose more than gain), be used to compensate that nearly half the heat is lost is easier said than done because of adding methyl alcohol.
At present, the guiding theory that diesel oil heat value agent commonly used uses is: hydrocarbon close person's calorific value is high, and many persons of carbon number calorific value is high.Mostly be: hydrogen peroxide anhydrous hydrazine THF 1,4-dioxane thing methylethyl ketone peroxide PVP K120 acetone butanone positive propyl ether isopropyl ether Ethyl Tertisry Butyl Ether ether water-soluble metal salt nitro-paraffin compound sulfonated petro-leum (amine) zn phosphate trimethylpentane propane butane pentane ethyl acetate nitric acid lipid phosphoric acid fat (tricresyl phosphite formicester) ethanol Virahol enanthol aviation kerosene toluene YLENE o-Xylol MTBE methyl cyclopentadienyl tricarbonyl manganese (MMT) dicyclopentadieny iron methylal ethyl acetate cerous nitrate acetone sherwood oil Di Iso Propyl Ether ether MTBE USP Kosher propane butane pentane ... Etc. a kind of or its mixture.
Noteworthyly in the above-mentioned raw materials be; Hydrogen peroxide. anhydrous hydrazine. methylethyl ketone peroxide. the nitro-paraffin compound, what raw material is this? I provide again: trotyl. pannonit .1,3; The 5-trinitrobenzene. the dark fund rope, what raw material is this again? Be explosive and aerospace fuel! How it feels? I have used an ammonium nitrate and oil of mirbane to obtain surprising effect at an accidental test run, repeatedly various raw materials difference compatibility test runs later on, firm my research direction.I propose at this point, and am just right if explosive and aerospace fuel use, and will be a desirable behave that remedies methyl alcohol calorific value in debt, worn-out this am said that tentative is that " air detonation " discussed.Theoretical basis is: though the reaction heat of 1 kilogram of TNT has only 1000 kilocalories; But because it accomplishes second one of time only about 100,000 of blast; So the moment in that blast is accomplished just is not heated to 2000～3000 ℃ by reaction heat when gas has enough time to expand as yet, this moment, high-temperature gas had very big pressure at little volume; About 10～400,000 normal atmosphere, thereby produced great compression ability.Instant of detonation is converted into gas the explosive constant volume, and its density arrives several thousand times than the big hundred times of density of gas under the normal condition.That is to say; So many gas is compressed in the volume occupied before the explosive charge strongly under the normal condition; Thereby cause several ten thousand to the atmospheric high pressure of hundreds of thousands of, simultaneously owing to the exothermicity of reaction, the gas that is in HTHP like this must expand sharp.With several ten thousand/hundreds of thousands of of this merit (Working environment that is just meeting mover)/once making the mover full-speed operation; And explosive additive also can fall sharply than the conventional additives addition; Its additive (being mostly high price) cost descends thereupon significantly, and methanol fuel has just had fine development prospect.Notice, the methanol fuel success or not, calorific value (power) is an important indicator.
The explosive useful raw materials has: nitrate esters Nitrates nitro-compound non-aromatic compounds superoxide ...
The shallow knowledge of the said sheerly inventor of this calorific value item.Liquor-saturated mistake knows that wine is dense! My once liquor-saturated mistake, having half knowledge is the most dangerous thing, we once heard about the thing that countless development explosive persons and its device are perished together, more than said having seen be.
4. anticorrosive agent
Impose lubricated, anticorrosion, anti-wear additive.Experience: 1., conscientiously clean fuel tank one time, put things right once and for all by regulation; 2., according to external research, methanol content 20% etching problem is very slight, can ignore.Normal temperature adds inhibiter; In the time of gasoline combustion, strict control oxygen excess, and make burning situation be in weakly alkaline. avoid the generation of acidic substance. 3., some raw material can form etch-proof protective membrane in the metallic surface; Experiment is known: HD05 and HDg05 are better in certain connection metal effect of inhibition; This be since its molecule neutral and alkali group can with the metallic surface strong effect, form protective membrane, and hydroxyl can mix with methyl alcohol; Thereby isolated contacting of methyl alcohol and metal to a certain extent, reduced methyl alcohol corrosion of metal.Add essential wear-resistant anticorrosion auxiliary agent, prevent that corrosion and premature wear from can appear in the motor oil parts.
Materials are preferably: phenylpropyl alcohol triazole three (two) thanomin whiteruss AEO fatty acid ester fatty amide Fatty Alcohol(C12-C14 and C12-C18) CI-1046 NS-Q3 BR-7064 (BJ phenyl ring) methylcarbonate nitric acid isooctyl Ortho Toluidine phosphine methyl nitrosoureas 2; 6-ditertbutylparacresol (BHT) is to methoxyl group phenol xylenol 2,6 di tert butyl 4 methyl phenol two field phenol urotropine benzoic acid methyl vinylformic acid dodecyl fat barium sulfonate Vinylpyrrolidone polymer paraffin ... Etc. a kind of or its mixture.Still: inhibition stabilizer T 1401 N, the inferior bigcatkin willow tn of N '-two polyoxyethylene nonylphenol AEO (AEO-3) urotropine carbonyl salt sulphonate TMBEA silica gel si molecular sieves aluminium silicophosphate SODIUM PHOSPHATE, MONOBASIC ... Etc. a kind of or its mixture.
5. anti-swelling agent
Reduce with curing rubber in activated molecule, prevent the methyl alcohol etch, with prolongation rubber duration of service.Select the FPM of high fluorine content, the acrylic copolymer that contains a certain amount of high polarity gene, saturated NBR, trifluoropropyl siloxane etc., can satisfy request for utilization.Materials are preferably: phenylformic acid hexahydroaniline (inhibiter) quadrol hexahydroaniline amylamine hexylamine N, N '-two salicylidene-1,2-tn.
6. seasonal adjustment agent
Anti-vapour lock
Select for use boiling point resistance to release the additive of function, like acetone, can hydrotropy, anti-layering can be prevented vapour lock again; PVP, this thing molecule contains hydrophilic radical and lipophilic group simultaneously, and water soluble and multiple organic solvent are good miscible agents.Can make the preparation thickening, can hinder the release of methyl alcohol vaporization again, prevent that air-resistance phenomenon from taking place.In addition: trimethyl carbinol vinyl pyrrolidone (NVP) Vinylpyrrolidone polymer etc. also is.
Cold start-up
Add volatile and can improve the additive of thermo-efficiency, can protect-42 ℃ and still can normally start.
Facts have proved: 1, add low-boiling point gas winter and can obviously improve engine cold-start performance (for example propane, dme), can prevent that the liquid phase of subzero 40 ℃ of temperature is not stratified; 2, winter, methanol content should not should be implemented adjustment according to temperature greater than 60%.
Materials are preferably: methylal ethyl acetate cerous nitrate acetone sherwood oil dme Di Iso Propyl Ether ether MTBE USP Kosher propane butane pentane ... Etc. a kind of or its mixture.
Still have: deicing agent. inhibitor ..., belong to conventional materials, do not give unnecessary details.
The invention instance
In sum; A successful methanol diesel-oil must be successful solution by methyl alcohol mix in and the pure hydrocarbon that causes is insoluble, power descends, the cold starting difficulty, meet seven big problems such as water stratification, corroding metal, swollen rubber, generation vapour lock; The additive that must add; That is: classes such as detergent-dispersant additive, antioxidant preservative, inhibiter, metal passivator, anti-wear agent, water-resisting agent, frostproofer, octane promoter, anti-swelling agent, stablizer, catalyst, ignition dope, solubility promoter, static inhibitor, cold starting additive are must follow pattern for the methanol diesel-oil prescription.
Pattern utilization principle is:
1, must satisfy of the requirement of various movers, promptly suitable vapo(u)rability, good incendivity, the stability of height to the general character of the quality of liquid fuel; Good low temperature properties, good cleanliness, non-corrosiveness, the economy of fuel; Energy-conservation and environmental requirement, except that above-mentioned each item main quality, it is little that liquid fuel also should toxicity own; Products of combustion is environmentally safe, and the source is sufficient simultaneously, is convenient to mass production.
2, select for use the methyl alcohol of much ratios to mix burning, should be according to many factor careful selection such as surrounding area material supply situation, supply of fuel scope, self economic technology strength, successful product forges out.
3, select additive flexibly for use by the different proportionings of methanol gasoline, a material uses to being more.Example, Di Iso Propyl Ether, have freeze proof, heat-resisting, reduce six functionses such as vapour pressure, dehydration, solution vapour lock in summer and cold start-up in winter.MTBE, in the recent period, EU Committee has been its rectification of name, does not have the carcinogenic and pollution of saying like the U.S., can relievedly use to the greatest extent.It can hydrotropy, and cold-starting improves saturated vapor pressure, can increase power by boosting of octane rating again, can also reduce discharge index.
4, additive types is as far as possible to lack for wanting.Notice at will is added a kind of raw material on the desk menu, that is just meaned must hold up an oil tank in field, oil district on the ground! The patent of Ceng Jianyou is numerous draws up 37 kinds more than, sighs!
5, avoid selecting for use uncommon raw material as far as possible.Example, known Methylal(dimethoxymethane) can improve calorific value by homogeneous phase, but market is short, is difficult to form mass production capabilities.6, avoid " reverse " to produce as far as possible.The additive price is far longer than major ingredient, and consumption is excessive to be equaled to remove to make mixture with valuable simple substance is reverse, has no feasibility economically.7, methanol gasoline must have double dissolubility, can with the miscible use of the arbitrary ratio of marketable gasolines.
The preparation of methanol diesel-oil of the present invention:
With this pattern, from above-mentioned corresponding entry raw material, choose it wantonly.

Claims (3)

  1. M15_M85 methanol diesel-oil manufacturing mode
    1. M15_M85 methanol diesel-oil manufacturing mode:
    GB diesel oil 20-40
    Methyl alcohol 30-85
    Additive 0.1-5
    : solubility promoter
    Cetane number improver
    Heat value agent
    Anticorrosive agent
    Anti-swelling agent
    The seasonal adjustment agent
    Other
  2. 2. according to claim 1, actual effect additive in a collection of modern age is disclosed:
    1. solubility promoter: the secondary octanol Virahol trimethyl carbinol isopropylcarbinol sec-butyl alcohol primary isoamyl alcohol octanol isooctyl alcohol iso-heptanol C5-C8 n-alkanol of ethanol propyl carbinol amylalcohol octanol certain herbaceous plants with big flowers alcohol (isomery alcohol) lauryl alcohol stearyl alcohol 1; 4 butyleneglycol polyoxyethylene glycol fusel acetone butanone ring ethyl ketone methyl ethyl diketone dimethyl ketone PVP K120 isobutylamine dme diisobutyl ether MTBE TAME sherwood oil ethylene glycol monobutyl ether EGME ether sec.-butyl methyl ethers narrow positive heptan the stupid formaldehyde dibutyl phthalate (DBP) of Methylal(dimethoxymethane) Nitromethane 99Min. 2-methylpent (suffering) alkane octane-iso pentamethylene 2,6 di t butyl phenol S-80 T-80 OP---7 dodecyl phenol polyethenoxy ether AEO polyoxyethylene nonylphenol (TX-10) peregal naphthenic acid oleic acid epoxy soybean oil Viscotrol C turps silk floss oil (acid) silicone oil hexahydroaniline quadrol triethylamine dibutylamine trolamine NA (K.CA) OH phthalic acid di-allyl ester phthalic acid Diisooctyl nitric acid fat (different suffering. penta) type different propylene of methyl formate acetate second (fourth) fat isopropylformic acid second fat acetate Zhong Ding fat acetate uncle's fourth fat dimethyl carbonate carbonic acid diethyl ester glycerine nitrilotriacetic fat tetraethoxysilance boric acid three (two) formicesters ... Etc. a kind of or mixture.
    2. cetane number improver: be mostly positive hot fat two many alkyl of the tertiary alkyl peroxide tert-butyl peroxide ditertiary butyl peroxide base superoxide of the positive fourth fat of the also own fat nitro-thinner of nitric acid second fat propyl nitrate nitric acid isopropyl ester nitric acid isooctyl pental nitrate nitric acid isoamyl fat 2-ethylhexyl nitric acid fat (2-EHN) nitric acid dodecyl nitric acid fat nitric acid nitric acid
    3. heat value agent: hydrogen peroxide anhydrous hydrazine THF 1,4-dioxane methylethyl ketone peroxide PVP K120 acetone butanone hydrogen peroxide positive propyl ether isopropyl ether Ethyl Tertisry Butyl Ether ether water-soluble metal salt nitro-paraffin compound sulfonated petro-leum (amine) zn phosphate trimethylpentane propane butane pentane ethyl acetate nitric acid lipid phosphoric acid fat (tricresyl phosphite formicester) ethanol Virahol enanthol aviation kerosene toluene YLENE o-Xylol MTBE methyl cyclopentadienyl tricarbonyl manganese (MMT) dicyclopentadieny iron ... Deng a kind of or its compsn.Methylal ethyl acetate cerous nitrate acetone sherwood oil Di Iso Propyl Ether ether MTBE USP Kosher propane butane pentane ... Etc. a kind of or its mixture.
    4. anticorrosive agent: phenylpropyl alcohol triazole three (two) thanomin whiteruss fatty acid ester fatty amide Fatty Alcohol(C12-C14 and C12-C18) CI-1046 NS-Q3 BR-7064 (BJ phenyl ring) methylcarbonate nitric acid isooctyl Ortho Toluidine phosphine methyl nitrosoureas 2; 6-ditertbutylparacresol (BHT) is to methoxyl group phenol xylenol 2,6 di tert butyl 4 methyl phenol two field phenol urotropine benzoic acid methyl vinylformic acid dodecyl fat barium sulfonate Vinylpyrrolidone polymer paraffin ... Etc. a kind of or its mixture.Still: inhibition stabilization additives T1401 N, the inferior bigcatkin willow tn of N '-two polyoxyethylene nonylphenol AEO (AEO-3) urotropine carbonyl salt sulphonate TMBEA silica gel si molecular sieves aluminium silicophosphate SODIUM PHOSPHATE, MONOBASIC ... Etc. a kind of or its mixture.
    5. anti-swelling agent: select the FPM of high fluorine content, the acrylic copolymer that contains a certain amount of high polarity gene, saturated NBR, trifluoropropyl siloxane etc., can satisfy request for utilization.Materials are preferably: phenylformic acid hexahydroaniline (inhibiter) quadrol hexahydroaniline amylamine hexylamine N, N '-two salicylidene-1,2-tn.
    6. seasonal adjustment agent:
    Anti-vapour lock: select for use the boiling point resistance to release the additive of function, like acetone, can hydrotropy, anti-layering can be prevented vapour lock again; PVP, this thing molecule contains hydrophilic radical and lipophilic group simultaneously, and water soluble and multiple organic solvent are good miscible agents.Can make the preparation thickening, can hinder the release of methyl alcohol vaporization again, prevent that air-resistance phenomenon from taking place.In addition: trimethyl carbinol vinyl pyrrolidone (NVP) Vinylpyrrolidone polymer etc. also is.
    Cold start-up: methylal ethyl acetate cerous nitrate acetone sherwood oil dme Di Iso Propyl Ether ether MTBE USP Kosher propane butane pentane ... Etc. a kind of or its mixture.
  3. 3. having proposed " air detonation " says.If it is just right that explosive and aerospace fuel use, will be a desirable behave that remedies methyl alcohol calorific value in debt.Useful raw materials has nitrate esters Nitrates nitro-compound non-aromatic compounds superoxide ...
CN2010102914184A 2010-09-16 2010-09-16 Methanol diesel oil manufacturing mode Pending CN102399599A (en)

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CN102643691A (en) * 2012-04-19 2012-08-22 山东京博控股股份有限公司 Gasoline compound additive
CN102660337A (en) * 2012-05-10 2012-09-12 河南煤业化工集团研究院有限责任公司 Method for preparing novel clean synthetic diesel oil
CN102732336A (en) * 2012-06-19 2012-10-17 庞英才 Multi-component vehicle fuel composition and preparation method thereof
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Publication number Priority date Publication date Assignee Title
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CN107011953B (en) * 2017-04-14 2018-04-20 北京天下通衢技术股份有限公司 Multi-function gasoline additives and preparation method thereof and the fuel combination containing the multi-function gasoline additives
CN107523365A (en) * 2017-09-10 2017-12-29 曹平 A kind of stable type fuel oil additive
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CN109749790A (en) * 2017-11-02 2019-05-14 苏日强 Pure diesel oil in alcohol group additive and clean and effective produce pure diesel oil in alcohol group method
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CN108130143A (en) * 2017-11-26 2018-06-08 杨勇 A kind of high performance fuel additive
CN109054913A (en) * 2018-03-31 2018-12-21 黄晓磊 The methanol diesel-oil of methanol diesel fuel additive and its preparation based on yeast grease
CN109054913B (en) * 2018-03-31 2020-08-28 桂林茂兴新能源科技有限公司 Methanol diesel oil additive based on yeast grease and methanol diesel oil prepared by same
CN108456563A (en) * 2018-05-04 2018-08-28 北京天下上乘科技有限公司 A kind of environment-friendly type diesel fuel and its preparation method and application
CN108841421A (en) * 2018-06-25 2018-11-20 车亿达河北新能源科技有限公司 Diesel vehicle dynamic combustion detergent
CN109294687A (en) * 2018-10-24 2019-02-01 定远县碧蓝山新能源有限公司 A kind of promotion biomass fuel forming additive
CN109337722A (en) * 2018-11-26 2019-02-15 苑瀚文 A kind of methanol diesel-oil and preparation method thereof
CN109576019A (en) * 2019-01-04 2019-04-05 华南理工大学 A kind of reduction vehicle exhaust fine particulates additive and preparation method thereof added in diesel oil
CN109666519A (en) * 2019-02-27 2019-04-23 中宁县中创气业有限公司 A kind of automobile exhaust detergent composition
CN110240954A (en) * 2019-06-30 2019-09-17 中库金创有限公司 A kind of cleaning compound diesel and preparation method thereof
CN110437895A (en) * 2019-08-17 2019-11-12 夏丹 A kind of diesel oil oxygenation agent and its preparation, application method
CN111196939A (en) * 2020-01-21 2020-05-26 张晋忠 Diesel oil additive and preparation method thereof
CN111635790A (en) * 2020-06-12 2020-09-08 大容新能源科技(深圳)有限公司 Agricultural alcohol ether diesel fuel
CN111979001A (en) * 2020-08-20 2020-11-24 高家彬 Diesel oil additive and preparation method thereof
CN112159689A (en) * 2020-09-09 2021-01-01 重庆耐燃新能源科技有限公司 Synthetic environment-friendly clean liquid fuel and preparation method thereof
CN112521990A (en) * 2020-11-16 2021-03-19 四川金尚环保科技有限公司 Method for producing high-flash-point pure oil fuel by modifying methanol with waste cooking oil
CN112592744A (en) * 2020-11-23 2021-04-02 邵占林 Ashless diesel oil cleaning synergist and preparation method thereof
CN113186005A (en) * 2021-03-29 2021-07-30 叁久国际新能源科技有限公司 Civil energy-saving environment-friendly fuel and preparation method thereof
CN113174276A (en) * 2021-04-27 2021-07-27 重庆邑丰新能源有限公司 Compression ignition type modified methanol fuel and preparation process thereof

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Application publication date: 20120404