CN102643685A - High-energy organic fuel capable of being mixed with diesel oil at will - Google Patents

High-energy organic fuel capable of being mixed with diesel oil at will Download PDF

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Publication number
CN102643685A
CN102643685A CN2012101195296A CN201210119529A CN102643685A CN 102643685 A CN102643685 A CN 102643685A CN 2012101195296 A CN2012101195296 A CN 2012101195296A CN 201210119529 A CN201210119529 A CN 201210119529A CN 102643685 A CN102643685 A CN 102643685A
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fuel
diesel oil
high energy
energy organic
miscible
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CN102643685B (en
Inventor
秦建荣
戴君惕
秦红霞
秦思佳
黄湘华
钟根强
朱自高
罗争鸣
庞菊红
张君
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HUNAN CHUNYI NEW ENERGY TECHNOLOGY DEVELOPMENT CO LTD
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HUNAN CHUNYI NEW ENERGY TECHNOLOGY DEVELOPMENT CO LTD
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Abstract

The invention relates to a high-energy organic fuel capable of being mixed with diesel oil at will. As everyone knows, the shortage of energy sources and the environmental pollution are major issues concerned by people all over the world in nowadays and each country all over the world pay more attention to developing a novel source which can be used for replacing the existing fuels such as diesel oil and gasoline and the like. The invention aims to develop a high-energy organic fuel capable of being mixed with diesel oil at will. The organic fuel is prepared by the following main steps: adding cosolvent combination of acetone and 120# solvent oil into a mixed high-energy organic fuel composed by low carbon, methyl tertiary butyl ether, heavy aromatics, naphtha, dimethylbenzene, ethanolamine and an anti-swelling agent; and finely mixing by a reaction device to obtain the high-energy organic fuel. The high-energy organic fuel is safe and reliable and benefits to human beings; and with adoption of the high-energy organic fuel, the environmental pollution can be reduced and a large amount of petroleum resources can be saved.

Description

Can with any miscible high energy organic-fuel of diesel oil
Technical field
The invention belongs to technical field of new energies, be specifically related to a kind of can with any miscible high energy organic-fuel of diesel oil.
Background technology
As everyone knows, the petroleum resources and the environmental issue of the world today are on the rise, and pay attention to more to substitute wholly or in part gasoline with new forms of energy, and in all solutions of Research in China, methyl alcohol substitutes gasoline becomes first-selection.This is because the methyl alcohol octane value is high, is prone to fully burning, and is cheap, can utilize the coal resources mass production of China's abundant.But the trial of adopting methyl alcohol to substitute diesel oil is fully never succeedd, its subject matter, and the one, the low heat value of methyl alcohol has only 21000KJ/KG, and low-calorie half the less than diesel oil, dynamic property is relatively poor during use, and has the problem of cold start-up difficulty; The 2nd, thus methyl alcohol is prone to make rubber and plastics swelling on the automobile component to cause the swelling thing to stop up oil circuit; The 3rd, methyl alcohol produces formaldehyde and formic acid when imperfect combustion, and the latter possibly cause corrosion to automobile component.The 4th, though the toxicity of methyl alcohol is high unlike diesel oil, people is lost one's sight for it even lethal toxicity is bound to arouse fear.
In order in promoting the use of the process of methyl alcohol, to avoid the generation of the problems referred to above, the solution of taking both at home and abroad is to use the emulsification or the microemulsified fuel of the diesel oil that contains part methyl alcohol, but this scheme does not reach a standard as yet.The 2nd, on diesel vehicle, add fuel tank and sparging unit, repack what is called " methanol diesel-oil car " into, allocate methyl alcohol and diesel oil ratio, the purpose of minimizing diesel oil consumption and pollutant emission when reaching running car as required.But will be transformed into diesel vehicle " methanol diesel-oil car ", not only increased the use achievement, and on various diesel oil car and boat, generally to use methyl alcohol to bring difficulty.
The content of invention
The objective of the invention is problem according to above-mentioned existence provide a kind of can with diesel oil miscible high energy organic-fuel arbitrarily.It solves this fuel and diesel oil effectively with the instant miscible problem of arbitrary proportion.
Technology of the present invention is achieved in that
(1) the present invention a kind of can with any miscible high energy organic-fuel of diesel oil; The solubility promoter that in the organic-fuel of the miscible combination of the low-carbon alcohol of the high energy organic-fuel that substitutes diesel oil fully, MTBE, heavy aromatics, petroleum naphtha, YLENE, thanomin, anti-swelling agent, adds by acetone and 120# solvent oil makes up; Mix through conversion unit is meticulous; The solubility promoter combination is made up of in 1: 2 ratio acetone, 120# solvent oil; Add-on is 40-60% (weight ratio), correspondingly turns down the per-cent of methyl alcohol simultaneously.
(2) a kind of method of making system of disposition row methanol diesel-oil of the present invention; Organic-fuel with the miscible combination of the low-carbon alcohol of high energy organic-fuel of the present invention, MTBE, heavy aromatics, petroleum naphtha, YLENE, ethanol, amine, anti-swelling agent; Pressing different ratios mixes with diesel oil; With high-shear emulsifying pump circulating emulsion, just can obtain the fuel that the various parts different with diesel oil content substitute diesel oil.
The effect or the characteristics of invention
(1) product of the present invention and diesel oil are can arbitrary proportion miscible immediately, not only can be used for " methanol diesel-oil car ", also can directly inject fuel tank on without hot-rod and use.
(2) utilize product of the present invention and diesel oil to develop to contain respectively " the new methanol diesel-oil " of various ratios such as this product 15%, 30%, 40%, 50%, 60%, 70%, 80%, 90%, its low heat value, leave standstill stability and anti swelling all will be equivalent to or be higher than methanol diesel-oil emulsion of the same type.
The comparison of new methanol diesel-oil of table 1.15% and 15% methanol diesel-oil emulsion
Figure BSA00000705295500021
The comparison of new methanol diesel-oil of table 2.50% and 15% methanol diesel-oil emulsion
Figure BSA00000705295500022
Embodiment
Embodiment 1.
The present invention can with the production preparation of the arbitrarily miscible high energy organic-fuel of diesel oil
In methyl alcohol, add methanol modified dose in 60: 1 ratios; Add hydrocarbon mixture, high energy fuels and calorific value blender after mixing respectively, the ratio of three and methyl alcohol was followed successively by 18: 10: 5: 60, behind the thorough mixing; In mixture, add solubility promoter combination acetone 1 again: 120# solvent oil, corrosion inhibitor and anti-swelling agent; The ratio of 3 kinds of compounds and methyl alcohol is 5: 0.5: 0.5: 60, fully miscible after, all system component are added after reaction kettles mix; Start the high-shear emulsifying pump mixed solution carried out circulation shear, can obtain can with diesel oil miscible high energy organic-fuel arbitrarily.
Embodiment 2. configurations contain organic diesel oil of 15% high energy organic-fuel
The high energy organic-fuel of the present invention of 15% weight ratio and 85% diesel oil are injected container mix, carry out circulation shear emulsification half a hour with the high-shear emulsifying pump then, can obtain to contain organic diesel oil of 15% high energy organic-fuel.
Embodiment 3. configurations contain organic diesel oil of 50% high energy organic-fuel
The high energy organic-fuel of the present invention of 50% weight ratio and 50% diesel oil are injected container mix, carry out circulation shear emulsification half a hour with the high-shear emulsifying pump then, can obtain to contain organic diesel oil of 50% high energy organic-fuel.

Claims (4)

  1. One kind can with any miscible high energy organic-fuel of diesel oil; It is characterized in that low-carbon alcohol at the high energy organic-fuel that substitutes diesel oil; Add solubility promoter combination in the high energy organic-fuel of MTBE, heavy aromatics, petroleum naphtha, YLENE, thanomin, the miscible combination of anti-swelling agent by acetone and 120# solvent oil; Mix through conversion unit is meticulous; The solubility promoter combination is made up of in 1: 2 ratio acetone, 120# solvent oil, and add-on is 40-60% (weight ratio), correspondingly turns down the per-cent of methyl alcohol simultaneously.
  2. 2. according to claim 1 can with any miscible high energy organic-fuel of diesel oil; It is characterized in that high energy organic-fuel with the low-carbon alcohol of high energy organic-fuel of the present invention, MTBE, heavy aromatics, petroleum naphtha, YLENE, thanomin, the miscible combination of anti-swelling agent; Pressing different ratios mixes together with bavin; With high-shear emulsifying pump circulating emulsion, obtain the fuel that the various parts different with diesel oil content substitute diesel oil.
  3. 3. according to claim 1 can with any miscible high energy organic-fuel of diesel oil; It is characterized in that the ratio in 60: 1 adds methanol modified dose in methyl alcohol; Add hydrocarbon mixture, high energy fuels and calorific value blender after mixing respectively, the ratio of three and methyl alcohol was followed successively by 18: 10: 5: 60, behind the thorough mixing; In mixture, add solubility promoter combination acetone 1 again: the 120# solvent oil; The ratio that corrosion inhibitor and anti-swelling agent, 3 kinds of chemical combination are herded with methyl alcohol is 5: 0.5: 0.5: 60 fully miscible after, all system component are added after reaction kettles mix; Start the high-shear emulsifying pump mixed solution carried out circulation shear, obtain can with diesel oil miscible high energy organic-fuel arbitrarily.
  4. 4. according to claim 1 can with any miscible high energy organic-fuel of diesel oil; It is characterized in that the high energy organic-fuel of the present invention of 15% weight ratio and 85% diesel oil injected and dissolve device and mix; Cut emulsification pump with height then and carry out circulation shear emulsification half a hour, can obtain to contain organic diesel oil of 15% high energy organic-fuel; The high energy organic-fuel of the present invention of 50% weight ratio and 50% diesel oil are injected container mix, carry out circulation shear emulsification half a hour with the high-shear emulsifying pump then, can obtain to contain organic diesel oil of 50% high energy organic-fuel.
CN201210119529.6A 2012-04-23 2012-04-23 High-energy organic fuel capable of being mixed with diesel oil at will Expired - Fee Related CN102643685B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104531235A (en) * 2014-12-09 2015-04-22 河南派尔生物技术有限公司 Methanol gasoline
CN104789281A (en) * 2015-03-23 2015-07-22 李彦静 Marine diesel oil and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1746271A (en) * 2004-09-09 2006-03-15 马春宇 Energy-saving clean fuel substituting diesel oil and production thereof
CN1931970A (en) * 2006-09-29 2007-03-21 刘连强 Additive for gasoline and diesel oil and its prepn process
CN101987981A (en) * 2009-08-06 2011-03-23 漆建宁 Environmentally-friendly high-energy alcohol group liquid fuel formula model and product preparation method
CN102161920A (en) * 2011-03-16 2011-08-24 平煤蓝天化工股份有限公司 Composite diesel oil
CN102391897A (en) * 2011-10-09 2012-03-28 谢虎 Methanol gasoline for vehicles
CN102399599A (en) * 2010-09-16 2012-04-04 陈若歆 Methanol diesel oil manufacturing mode

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1746271A (en) * 2004-09-09 2006-03-15 马春宇 Energy-saving clean fuel substituting diesel oil and production thereof
CN1931970A (en) * 2006-09-29 2007-03-21 刘连强 Additive for gasoline and diesel oil and its prepn process
CN101987981A (en) * 2009-08-06 2011-03-23 漆建宁 Environmentally-friendly high-energy alcohol group liquid fuel formula model and product preparation method
CN102399599A (en) * 2010-09-16 2012-04-04 陈若歆 Methanol diesel oil manufacturing mode
CN102161920A (en) * 2011-03-16 2011-08-24 平煤蓝天化工股份有限公司 Composite diesel oil
CN102391897A (en) * 2011-10-09 2012-03-28 谢虎 Methanol gasoline for vehicles

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104531235A (en) * 2014-12-09 2015-04-22 河南派尔生物技术有限公司 Methanol gasoline
CN104789281A (en) * 2015-03-23 2015-07-22 李彦静 Marine diesel oil and preparation method thereof
CN104789281B (en) * 2015-03-23 2016-08-10 舟山冉升能源科技有限公司 marine diesel oil and preparation method thereof

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