CN102796574A - Methanol gasoline - Google Patents

Methanol gasoline Download PDF

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Publication number
CN102796574A
CN102796574A CN2012103048484A CN201210304848A CN102796574A CN 102796574 A CN102796574 A CN 102796574A CN 2012103048484 A CN2012103048484 A CN 2012103048484A CN 201210304848 A CN201210304848 A CN 201210304848A CN 102796574 A CN102796574 A CN 102796574A
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China
Prior art keywords
parts
gasoline
weight
methanol
methanol gasoline
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CN2012103048484A
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张伯义
俞立军
龚谊龙
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Gong Yilong
Yu Lijun
Zhang Boyi
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Individual
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Abstract

Provided is methanol gasoline. The invention relates to the technical field of energy, and specifically relates to a methanol gasoline formula. The methanol gasoline formula includes adding a methanol gasoline compound additive to methanol by weight ratio of 0.05% for denaturation, and mixing 15-65 parts of methanol, 20-30 parts of 90 # gasoline, 10-30 parts of light aromatic hydrocarbons, and 10 parts of naphtha by weight after denaturation. The methanol gasoline is good in corrosion resistance, and generates chemical and physical adsorption to resist corrosion by inhibiting basic groups of molecules. The methanol gasoline is powerful in dynamic property, high in octane value, good in antiknock property, low in fuel consumption, and safe and reliable in use. The method makes alcohol and gasoline dissolve organically, and helps to enhance the stability without delamination and emulsification. The methanol gasoline can be used with ordinary gasoline by mixing or crossing. By using the methanol gasoline, motors are easy to start under the low temperature condition of -35 DEG C, and have no air resistance at high temperature, thereby being started normally. The methanol gasoline is suitable for gasoline and liquid fuels, and can help to save 10-25% of the fuel oil, to reduce the amount of smoke and exhaust gases, and to reduce pollution.

Description

Methanol gasoline
Technical field
The present invention relates to energy technology field, be specifically related to a kind of prescription of methanol gasoline.
Background technology
Under natural situation, methyl alcohol is a kind of compound of high phasic property, is insoluble in hydrocarbon matter, will cause after chance low temperature or the chance water to be separated, and form two layers up and down, the upper strata is that rich oil phase, lower floor are rich pure phase.The following low-temp methanol gasoline of 0 degree Celsius has tangible laminarity.Gasoline in the production process formula, for boosting of octane rating suitably adds aromatic hydrocarbons and alkene, the easiest generation oxidizing reaction of these hydro carbons and polyreaction, and produce colloid.Based on the problems referred to above, existing methanol gasoline all can not make methyl alcohol reach a higher contents level when producing, indexs such as its oil consumption and exhaust emissions also do not reach further control.
Summary of the invention
Technical problem to be solved by this invention is: a kind of methanol gasoline that improves methanol content, reduction oil consumption, reduces pollution is provided.
Technical solution of the present invention is: it is that compound additive for methanol gasoline is added sex change in the methyl alcohol by weight 0.5 ‰, by weight 15~65 parts of methyl alcohol, 20~30 parts in 90# gasoline, 10~30 parts in light aromatic hydrocarbons, petroleum naphtha is mixed and made into for 5~10 parts after the sex change; Said composite additive is 3~7 parts of 5~9 parts of ZPOs of Methylal(dimethoxymethane), 28~32 parts of promoting agents, 16~20 parts of octane promoters, 38~42 parts of solubilizing agent by weight; Said promoting agent is 9~13 parts of sherwood oils, 13~17 parts of isomery alcohol, 27~31 parts of isomeric alkanes, 5~9 parts of Ns, 6~10 parts in acetone, 5~9 parts of 21~25 parts of aniline of sec-butyl alcohol by weight; Said octane promoter is 33~37 parts in heavy oil, 8~12 parts of tert.-butylbenzenes, 23~27 parts of toluene, 3~7 parts in sodium hydroxide, 13~17 parts of trimethyl phosphite 99s, 8~12 parts of methyl cyclopentadienyl tricarbonyl manganeses by weight; Said solubilizing agent is 8~12 parts of isopropylcarbinols, 5~9 parts of ferrocene, 12~16 parts of trotyls, 2.5~6.5 parts in oil of mirbane, 0.5~3.5 part of zinc acetate, 14.5~18.5 parts of the trimethyl carbinols, 8~12 parts of n-propyl alcohols, 5 28~32 parts in carbon, 4.5~8.5 parts of MTBEs by weight.
Technique effect of the present invention is: it has good preservative property, through suppressing molecule neutral and alkali group, produces chemistry and physisorption and suppresses corrosion.Its dynamic property is strong, and octane value is high, and anti-knocking property are good, and oil consumption is low, and is safe and reliable.Can make alcohol and organic the mixing of oil, enhanced stability, not stratified not emulsification can mix or intersect use arbitrarily with regular gasoline.-35 coldcondition are prone to down start, high temperature does not have vapour lock, but the mover normal starting.Be applicable to gasoline, liquid fuel oil, can practice thrift 10-25% oil fuel, and can reduce smog, exhausted air quantity, reduce and pollute.The methyl alcohol interpolation reaches as high as 65%, and meets national gasoline products standard fully.
Embodiment
It is that compound additive for methanol gasoline is added sex change in the methyl alcohol by weight 0.5 ‰, by weight 15~65 parts of methyl alcohol, 20~30 parts in 90# gasoline, 10~30 parts in light aromatic hydrocarbons, petroleum naphtha is mixed and made into for 5~10 parts after the sex change.
Said composite additive is 7 parts of Methylal(dimethoxymethane), 5 parts of ZPOs, 30 parts of promoting agents, 18 parts of octane promoters, 40 parts of solubilizing agent by weight.
Said promoting agent is 11 parts of sherwood oils, 15 parts of isomery alcohol, 29 parts of isomeric alkanes, 7 parts of Ns, 8 parts in acetone, sec-butyl alcohol 23,7 parts of aniline by weight.Improved the gasoline over-all properties, and cost is low, the mover hold tank is had no side effect.Said octane promoter is 35 parts in heavy oil, 10 parts of tert.-butylbenzenes, 25 parts of toluene, 5 parts in sodium hydroxide, 15 parts of trimethyl phosphite 99s, 10 parts of Organic Manganese (methyl cyclopentadienyl tricarbonyl manganese) by weight; Can carry octane value 5~15 units.
Said solubilizing agent is 10 parts of isopropylcarbinols, 7 parts of ferrocene, 14 parts of trotyls, 4.5 parts in oil of mirbane, 1.5 parts of zinc acetates, the trimethyl carbinol 16.5,10 parts of n-propyl alcohols, 5 30 parts in carbon, 6.5 parts of MTBEs by weight.
Methanol gasoline of the present invention is made up of base gasoline, methyl alcohol and related compound additive.After in methyl alcohol, adding composite additive methyl alcohol is carried out denaturing treatment; Ratio and regular gasoline mix the back as vehicle fuel according to the rules again; Make its modification; Make the methanol fuel of aspects such as its combustionvelocity, gasification calorific value, mutual solubility, explosive power acceleration characteristics, need not mover and device be transformed, can directly use near conventional gasoline.
Composite additive is multiple organic cpds, under engine operating temperature, has violent decomposition katalysis.High-proportion methanol oil fuel is under the additive effect, and explosion becomes small mist of oil before burning, makes the methanol fuel contact area moment increase of air and atomizing, is easy to light.Through with the variable central metallic ions of state the transmission of electronics being provided, the key of activation methanol molecules generates H so that decompose part methyl alcohol 2And CO, help lean burn and the thermo-efficiency of methanol gasoline in engine cylinder and improve, make fuel combustion complete, rating of engine rises.Compoundly add agent and also have multiple efficacies such as hydrotropy, anticorrosion, cleaning, be dissolved in easily in the methanol fuel oil, chemical property is stable, and concentration is low, and is safe in utilization, burning back environmentally safe.
The mutual solubility of methyl alcohol and gasoline can improve 40~80% behind the use additive.Because of composite additive adopts a certain amount of high pure material, can increase the stability of mixing oil after the adding, below-35 degree Celsius, still can keep methyl alcohol and gasoline stable phase dissolubility, can layering, guarantee that vehicle is in safe operation in the winter of cold.Composite additive can react with the peroxide radical of hydro carbons, makes radical obtain a Wasserstoffatoms, becomes a kind of comparatively stable radical to additive; Chain reaction is interrupted; The oxidizing reaction that can effectively suppress hydro carbons suitably extends to 500 with inductive phase by 480, has also reduced the gelationus generation simultaneously; Reduce to 3mg/100ml by 5mg/100ml, reduced by 40% than pure gasoline.
The present invention is economical, the renewable green vehicle fuel that replaces conventional general gasoline.This project implementation has wide use prospect.

Claims (2)

1. methanol gasoline; It is characterized in that; It is that compound additive for methanol gasoline is added sex change in the methyl alcohol by weight 0.5 ‰, by weight 15~65 parts of methyl alcohol, 20~30 parts in 90# gasoline, 10~30 parts in light aromatic hydrocarbons, petroleum naphtha is mixed and made into for 5~10 parts after the sex change; Said composite additive is 3~7 parts of 5~9 parts of ZPOs of Methylal(dimethoxymethane), 28~32 parts of promoting agents, 16~20 parts of octane promoters, 38~42 parts of solubilizing agent by weight; Said promoting agent is 9~13 parts of sherwood oils, 13~17 parts of isomery alcohol, 27~31 parts of isomeric alkanes, 5~9 parts of Ns, 6~10 parts in acetone, 5~9 parts of 21~25 parts of aniline of sec-butyl alcohol by weight; Said octane promoter is 33~37 parts in heavy oil, 8~12 parts of tert.-butylbenzenes, 23~27 parts of toluene, 3~7 parts in sodium hydroxide, 13~17 parts of trimethyl phosphite 99s, 8~12 parts of methyl cyclopentadienyl tricarbonyl manganeses by weight; Said solubilizing agent is 8~12 parts of isopropylcarbinols, 5~9 parts of ferrocene, 12~16 parts of trotyls, 2.5~6.5 parts in oil of mirbane, 0.5~3.5 part of zinc acetate, 14.5~18.5 parts of the trimethyl carbinols, 8~12 parts of n-propyl alcohols, 5 28~32 parts in carbon, 4.5~8.5 parts of MTBEs by weight.
2. methanol gasoline as claimed in claim 1 is characterized in that, said composite additive is 5 parts of 7 parts of ZPOs of Methylal(dimethoxymethane), 30 parts of promoting agents, 18 parts of octane promoters, 40 parts of solubilizing agent by weight; Said promoting agent is 11 parts of sherwood oils, 15 parts of isomery alcohol, 29 parts of isomeric alkanes, 7 parts of Ns, 8 parts in acetone, 7 parts of 23 parts of aniline of sec-butyl alcohol by weight; Said octane promoter is 35 parts in heavy oil, 10 parts of tert.-butylbenzenes, 25 parts of toluene, 5 parts in sodium hydroxide, 15 parts of trimethyl phosphite 99s, 10 parts of methyl cyclopentadienyl tricarbonyl manganeses by weight; Said solubilizing agent is 10 parts of isopropylcarbinols, 7 parts of ferrocene, 14 parts of trotyls, 4.5 parts in oil of mirbane, 1.5 parts of zinc acetates, 16.5 parts of the trimethyl carbinols, 10 parts of n-propyl alcohols, 5 30 parts in carbon, 6.5 parts of MTBEs by weight.
CN2012103048484A 2012-08-25 2012-08-25 Methanol gasoline Pending CN102796574A (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013588A (en) * 2012-12-12 2013-04-03 张亚东 Low-gasoline-consumption methanol gasoline
CN103525487A (en) * 2013-10-30 2014-01-22 贵州华宏能源开发有限责任公司 Alcohol group fuel for cleaning vehicle
CN103695047A (en) * 2013-12-20 2014-04-02 山西华顿实业有限公司 Methanol gasoline with low gas resistance
CN103865592A (en) * 2014-03-19 2014-06-18 常胜 Methanol gasoline
CN103911185A (en) * 2014-01-28 2014-07-09 四川华信能源集团有限公司 Methyl gasoline and production method thereof
CN104479768A (en) * 2014-12-01 2015-04-01 四川帝标新能源科技有限公司 Novel high-energy clean fuel additive for automobiles and preparation method thereof
CN104877716A (en) * 2015-06-02 2015-09-02 武夷山天能新能源科技有限公司 High-cleanness navigation alcohol hydrocarbon compound vehicle fuel additive, preparation method and fuel
CN108949261A (en) * 2018-08-03 2018-12-07 湖南中油国通新能源股份有限公司 It is a kind of to hold up dynamic detergent of increasing and preparation method thereof only
CN110016371A (en) * 2019-05-05 2019-07-16 中易华恒石油化工有限责任公司 A kind of methanol gasoline and preparation method thereof
CN110745016A (en) * 2018-07-20 2020-02-04 瑞莱国际开发股份有限公司 Environment-friendly high-efficiency oil-electricity hybrid vehicle
CN110747016A (en) * 2019-08-14 2020-02-04 哈尔滨易安行新能源科技有限公司 Novel efficient environment-friendly fuel capable of replacing gasoline and manufacturing method
CN114479964A (en) * 2022-03-14 2022-05-13 上海援鸣新能源科技集团有限公司 Low-temperature start tail gas cleaning agent
CN114656995A (en) * 2022-05-07 2022-06-24 油源美华(北京)新能源技术研究院有限公司 Hydrogen energy environment-friendly composite fuel and preparation method thereof
WO2023209016A1 (en) * 2022-04-29 2023-11-02 Wrt B.V. Fuel additive
NL2031739B1 (en) * 2022-04-29 2023-11-13 Wrt B V Fuel additive
BE1030486B1 (en) * 2022-04-29 2023-12-05 Wrt B V FUEL ADDITIVE

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1487060A (en) * 2003-05-08 2004-04-07 季子善 Methanol gasoline and its compounding process
CN101024788A (en) * 2006-02-20 2007-08-29 北京福众金源环保科技有限公司 Methanol gasoline modified alcohol additive
CN100462423C (en) * 2006-09-19 2009-02-18 鲁希诺 Composite catalyzing alcohol ether gasoline with no lead, and method of preparation
CN101724474A (en) * 2008-10-14 2010-06-09 陈若歆 Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1487060A (en) * 2003-05-08 2004-04-07 季子善 Methanol gasoline and its compounding process
CN101024788A (en) * 2006-02-20 2007-08-29 北京福众金源环保科技有限公司 Methanol gasoline modified alcohol additive
CN100462423C (en) * 2006-09-19 2009-02-18 鲁希诺 Composite catalyzing alcohol ether gasoline with no lead, and method of preparation
CN101724474A (en) * 2008-10-14 2010-06-09 陈若歆 Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013588A (en) * 2012-12-12 2013-04-03 张亚东 Low-gasoline-consumption methanol gasoline
CN103525487A (en) * 2013-10-30 2014-01-22 贵州华宏能源开发有限责任公司 Alcohol group fuel for cleaning vehicle
CN103695047A (en) * 2013-12-20 2014-04-02 山西华顿实业有限公司 Methanol gasoline with low gas resistance
CN103911185B (en) * 2014-01-28 2015-08-26 四川华信能源集团有限公司 A kind of methyl gasoline and production method thereof
CN103911185A (en) * 2014-01-28 2014-07-09 四川华信能源集团有限公司 Methyl gasoline and production method thereof
CN103865592B (en) * 2014-03-19 2015-12-30 常胜 Methanol gasoline
CN103865592A (en) * 2014-03-19 2014-06-18 常胜 Methanol gasoline
CN104479768A (en) * 2014-12-01 2015-04-01 四川帝标新能源科技有限公司 Novel high-energy clean fuel additive for automobiles and preparation method thereof
CN104877716A (en) * 2015-06-02 2015-09-02 武夷山天能新能源科技有限公司 High-cleanness navigation alcohol hydrocarbon compound vehicle fuel additive, preparation method and fuel
CN110745016A (en) * 2018-07-20 2020-02-04 瑞莱国际开发股份有限公司 Environment-friendly high-efficiency oil-electricity hybrid vehicle
CN108949261A (en) * 2018-08-03 2018-12-07 湖南中油国通新能源股份有限公司 It is a kind of to hold up dynamic detergent of increasing and preparation method thereof only
CN110016371A (en) * 2019-05-05 2019-07-16 中易华恒石油化工有限责任公司 A kind of methanol gasoline and preparation method thereof
CN110747016A (en) * 2019-08-14 2020-02-04 哈尔滨易安行新能源科技有限公司 Novel efficient environment-friendly fuel capable of replacing gasoline and manufacturing method
CN114479964A (en) * 2022-03-14 2022-05-13 上海援鸣新能源科技集团有限公司 Low-temperature start tail gas cleaning agent
WO2023209016A1 (en) * 2022-04-29 2023-11-02 Wrt B.V. Fuel additive
NL2031739B1 (en) * 2022-04-29 2023-11-13 Wrt B V Fuel additive
BE1030486B1 (en) * 2022-04-29 2023-12-05 Wrt B V FUEL ADDITIVE
CN114656995A (en) * 2022-05-07 2022-06-24 油源美华(北京)新能源技术研究院有限公司 Hydrogen energy environment-friendly composite fuel and preparation method thereof

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C06 Publication
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Owner name: YU LIJUN GONG YILONG

Effective date: 20131113

C41 Transfer of patent application or patent right or utility model
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Effective date of registration: 20131113

Address after: Mudanjiang City, Heilongjiang Province, 157000 spinning Market District 8 unit 201

Applicant after: Zhang Boyi

Applicant after: Yu Lijun

Applicant after: Gong Yilong

Address before: Mudanjiang City, Heilongjiang Province, 157000 spinning Market District 8 unit 201

Applicant before: Zhang Boyi

C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20121128