CN103627448B - A kind of liquid cleaning environmental protection diesel oil and preparation method thereof - Google Patents
A kind of liquid cleaning environmental protection diesel oil and preparation method thereof Download PDFInfo
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- CN103627448B CN103627448B CN201210309816.3A CN201210309816A CN103627448B CN 103627448 B CN103627448 B CN 103627448B CN 201210309816 A CN201210309816 A CN 201210309816A CN 103627448 B CN103627448 B CN 103627448B
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Abstract
The present invention relates to a kind of high-efficiency environment friendly liquid ring fuel, particularly relate to <b> mono-</b> kind liquid cleaning environmental protection diesel oil and preparation method thereof, it is formed by the preparation of raw material of following weight proportion, its optimum proportioning is as follows: oleic acid 40%, methyl alcohol 20%, methylal 10%, water 8%, ammoniacal liquor 8%, propyl carbinol 6.5%, its preparation process of methylcarbonate 7.5% are: select methyl alcohol, methylal and water to pour in oleic acid and mix, then add ammoniacal liquor; After fully being mixed by composition in above-mentioned steps, static reaction 5 minutes is for subsequent use; Select propyl carbinol, methylcarbonate hybrid reaction for subsequent use; Above-mentioned two kinds of reacted mixtures are added together gentle agitation 10-20 minute, get the solution for standby of 50%; By 0# ,-10#, the international diesel oil of-20# any one mix with above-mentioned solution, gentle agitation 10-20 minute, namely becomes a kind of liquid cleaning environmental protection diesel oil, dynamic property of the present invention is strong, quantity discharged is few, applied widely, long quality-guarantee period.
Description
Technical field
The present invention relates to a kind of environment-friendly liquid fuel, be specifically related to a kind of liquid cleaning environmental protection diesel oil and preparation method thereof.
Background technology
Because worldwide energy day is becoming tight, and the continuous reinforcement of environmental consciousness, in conjunction with energy situation and the national energy strategy considering China in the world, promote the present situation that ethanol petrol can improve current China's oil resource scarcity, gasoline is from non-renewable petroleum resources, ethanol then derives from the renewable resources of plant, and using and promoting of ethanol petrol can alleviate China energy situation in short supply, more can continue the history of petroleum times.With existing resource and utilization power analysis, oil only remains the life of about 40 years in the world.Energy expert thinks, the way that China promotes the use of ethanol petrol is the strategic choice of carrying that an energy expenditure big country implements energy structure diversification.World many countries begins one's study oil alternate energy source particularly methyl alcohol, the extensive internal combustion engine use research of the Aalcohols fuels such as ethanol, methyl alcohol is directly burning or enter the practical stage with the technology that burning mixed by gasoline on petrol motor, by transforming the method single fire methyl alcohol technology on a diesel engine of engine, abroad also grasp, do not changing the structure of diesel engine, and in diesel oil, mix burning methyl alcohol, in the method for ethanol, by methyl alcohol, the method that ethanol and diesel oil dissolve each other generally has emulsion process, add flux method etc., the method that the many employings of emulsion process add water, make methyl alcohol, ethanol, diesel oil, water forms Ternary Emulsified Fuel, add flux method mainly by isopropylcarbinol, primary isoamyl alcohol, aromatic series nitrogenous compounds etc. and composition thereof are re-dubbed solubility promoter, make methyl alcohol, ethanol and diesel oil dissolve each other, allocation ratio is methyl alcohol, ethanol content is (weight percent) 15%, 20%, 25% etc.But soldier not can solve the problem of diesel oil and methyl alcohol, ethanol mutual solubility difference add these solubility promoters in diesel oil after, but also product price can be produced increase, increase the weight of containing N waste discharge so that the problem such as weighting ring environment pollution.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art and a kind of liquid cleaning environmental protection diesel oil provided and preparation method thereof,
The present invention is formed by the preparation of raw material of following weight proportioning:
A kind of liquid cleaning environmental protection diesel oil, it is characterized in that: it is by taking diesel oil as major ingredient, with oleic acid, methyl alcohol, methylal, water, ammoniacal liquor, propyl carbinol, methylcarbonate is the liquid cleaning environmental protection diesel oil of auxiliary material composition, the preparation of raw material of its following weight proportioning forms: oleic acid 15--25%, methyl alcohol 5-15%, methylal 3-7%, water 2-6%, ammoniacal liquor 2-6%, propyl carbinol 1-5%, methylcarbonate 2-6%, diesel oil 40-60%, its high-quality proportioning is as follows: oleic acid 18-22%, methyl alcohol 8-12%, methylal 4-6%, water 3-4%, ammoniacal liquor 3-4%, propyl carbinol 2-4%, methylcarbonate 3-5%, diesel oil 45-55%, its optimum proportioning is as follows: oleic acid 20%, methyl alcohol 10%, methylal 5%, water 4%, ammoniacal liquor 4%, propyl carbinol 3.25%, methylcarbonate 3.75%, diesel oil 50%.
A kind of liquid cleaning environmental protection diesel oil, its preparation process is as follows:
Step one, selects methyl alcohol, methylal and water to pour in oleic acid and mixes, then add ammoniacal liquor;
Step 2, after fully being mixed by the composition in above-mentioned steps, static reaction 5 minutes is for subsequent use;
Step 3, selects propyl carbinol, methylcarbonate hybrid reaction for subsequent use;
Step 4, mixture reacted in step 2 and step 3 is added together gentle agitation or plays circulation, and static reaction is after 10 minutes, for subsequent use;
Step 5, the diesel oil getting weight same with step 4 mix with solution reacted in step 4, and gentle agitation 10-20 minute, namely becomes a kind of liquid cleaning environmental protection diesel oil.
In described step 4, mixture reacted in step 2 and step 3 being added together gentle agitation or beating the time of circulating is 10-20 minute.
Described diesel oil is 0# ,-10# in GB diesel oil, any one in-20#.
The present invention has the following advantages:
First, contain ignition dope, oxygenation agent in formula, be more conducive to burning, make burning more complete, stable, improve combustion efficacy, secondly, dynamic property is strong: in allotment clean environmental-protective diesel solubility promoter process for preparation, composite improves calorific value, strengthens the component of power, being aided with new compounding process, is that this fuel compares dynamic property and strengthens with like product; 3rd, quantity discharged is few: use noxious emission CO, HC and NO of clean environmental-protective diesel obviously to reduce, emission smoke intensity declines more than 70%, solve vehicle emission pollution, one of effective way of environmental protect quality, meet completely Copenhagen World Climate Conference to subtracting carbon, subtract sulphur, the emission request of denitration; 4th, filter point reduces: the condensation point of this product and the comparable same label diesel oil of cold filter clogging temperature reduce by 5-7 units, expand the scope of application under cold condition, 5th, versatility is good: this product, when without the need to changing diesel motor structure and parameters, can directly use, and can meet power demand and the steady running of engine, and there is the equal scope of application and effect with same label finished diesel fuel, can be used alone, also arbitrary proportion and finished diesel fuel can exchange and use; 6th, applied widely: this product is mainly applicable to the diesel motor, Industrial Boiler, power plant boiler etc. of various uses.All places using ordinary diesel oil, can use clean environmental-protective diesel; 7th, long quality-guarantee period: clean environmental-protective diesel does not exceed standard in moisture content or in normal temperature range, Absorbable organic halogens more than 6 months phase of maintenance, can meet storage, transport, sell and use the time needed for each link.
Embodiment
Embodiment 1: the present invention is formed by the preparation of raw material of following weight proportioning: it is by taking diesel oil as major ingredient, with oleic acid, methyl alcohol, methylal, water, ammoniacal liquor, propyl carbinol, methylcarbonate is the liquid cleaning environmental protection diesel oil of auxiliary material composition, the preparation of raw material of its following weight proportioning forms: oleic acid 15--25%, methyl alcohol 5-15%, methylal 3-7%, water 2-6%, ammoniacal liquor 2-6%, propyl carbinol 1-5%, methylcarbonate 2-6%, diesel oil 40-60%, its high-quality proportioning is as follows: oleic acid 18-22%, methyl alcohol 8-12%, methylal 4-6%, water 3-4%, ammoniacal liquor 3-4%, propyl carbinol 2-4%, methylcarbonate 3-5%, diesel oil 45-55%, its optimum proportioning is as follows: oleic acid 20%, methyl alcohol 10%, methylal 5%, water 4%, ammoniacal liquor 4%, propyl carbinol 3.25%, methylcarbonate 3.75%, diesel oil 50%.Preparation process of the present invention is as follows:
Step one, selects methyl alcohol 5kg, methylal 3kg and water 2kg to pour in 15kg oleic acid and mixes, then add 3kg ammoniacal liquor;
Step 2, after fully being mixed by the composition in above-mentioned steps, static reaction 5 minutes is for subsequent use;
Step 3, selects propyl carbinol 1kg, methylcarbonate 2kg hybrid reaction for subsequent use;
Step 4, mixture reacted in step 2 and step 3 is added together gentle agitation or plays circulation, and static reaction is after 10 minutes, for subsequent use;
Step 5, get 40kg diesel oil and mix with mixture solution reacted in step 4, gentle agitation 10-20 minute, namely becomes a kind of liquid cleaning environmental protection diesel oil.
In step 4, mixture reacted in step 2 and step 3 being added together gentle agitation or beating the time of circulating is 10 minutes.
Described diesel oil is 0# GB diesel oil.
Embodiment 2: raw material weight proportioning of the present invention is with embodiment 1, and preparation technology of the present invention is as follows:
Step one, selects methyl alcohol 8kg, methylal 4kg and water 3kg to pour in 18kg oleic acid and mixes, then add 3kg ammoniacal liquor;
Step 2, after fully being mixed by the composition in above-mentioned steps, static reaction 5 minutes is for subsequent use;
Step 3, selects propyl carbinol 2kg, methylcarbonate 3kg hybrid reaction for subsequent use;
Step 4, mixture reacted in step 2 and step 3 is added together gentle agitation or plays circulation, and static reaction is after 10 minutes, for subsequent use;
Step 5, get 45kg diesel oil and mix with mixture solution reacted in step 4, gentle agitation 15 minutes, namely becomes a kind of liquid cleaning environmental protection diesel oil.
In described step 4, mixture reacted in step 2 and step 3 being added together gentle agitation or beating the time of circulating is 15 minutes.
Described diesel oil is in-10# GB diesel oil.
Embodiment 3: raw material weight proportioning of the present invention is with embodiment 1, and preparation technology of the present invention is as follows:
Step one, selects methyl alcohol 10kg, methylal 5kg and water 4kg to pour in 20kg oleic acid and mixes, then add 4kg ammoniacal liquor;
Step 2, after fully being mixed by the composition in above-mentioned steps, static reaction 5 minutes is for subsequent use;
Step 3, selects propyl carbinol 3.25kg, methylcarbonate 3.75kg hybrid reaction for subsequent use;
Step 4, mixture reacted in step 2 and step 3 is added together gentle agitation or plays circulation, and static reaction is after 10 minutes, for subsequent use;
Step 5, get the international diesel of 50kg-20# and mix with mixture solution reacted in step 4, gentle agitation 15 minutes, namely becomes a kind of liquid cleaning environmental protection diesel oil.
In described step 4, mixture reacted in step 2 and step 3 being added together gentle agitation or beating the time of circulating is 20 minutes.
Embodiment 4: raw material weight proportioning of the present invention is with embodiment 1, and preparation technology of the present invention is as follows:
Step one, selects methyl alcohol 50kg, methylal 30kg and water 20kg to pour in 150kg oleic acid and mixes, then add 30kg ammoniacal liquor;
Step 2, after fully being mixed by the composition in above-mentioned steps, static reaction 5 minutes is for subsequent use;
Step 3, selects propyl carbinol 10kg, methylcarbonate 20kg hybrid reaction for subsequent use;
Step 4, mixture reacted in step 2 and step 3 is added together gentle agitation or plays circulation, and static reaction is after 10 minutes, for subsequent use;
Step 5, get 400kg diesel oil and mix with mixture solution reacted in step 4, gentle agitation 10 minutes, namely becomes a kind of liquid cleaning environmental protection diesel oil.
In step 4, mixture reacted in step 2 and step 3 being added together gentle agitation or beating the time of circulating is 10 minutes.
Described diesel oil is 0# GB diesel oil.
Embodiment 5: raw material weight proportioning of the present invention is with embodiment 1, and preparation technology of the present invention is as follows:
Step one, selects methyl alcohol 80kg, methylal 40kg and water 30kg to pour in 180kg oleic acid and mixes, then add 30kg ammoniacal liquor;
Step 2, after fully being mixed by the composition in above-mentioned steps, static reaction 5 minutes is for subsequent use;
Step 3, selects propyl carbinol 20kg, methylcarbonate 30kg hybrid reaction for subsequent use;
Step 4, mixture reacted in step 2 and step 3 is added together gentle agitation or plays circulation, and static reaction is after 10 minutes, for subsequent use;
Step 5, get 450kg diesel oil and mix with mixture solution reacted in step 4, gentle agitation 15 minutes, namely becomes a kind of liquid cleaning environmental protection diesel oil.
In described step 4, mixture reacted in step 2 and step 3 being added together gentle agitation or beating the time of circulating is 15 minutes.
Described diesel oil is in-20# GB diesel oil.
Embodiment 6: raw material weight proportioning of the present invention is with embodiment 1, and preparation technology of the present invention is as follows:
Step one, selects methyl alcohol 100kg, methylal 50kg and water 40kg to pour in 200kg oleic acid and mixes, then add 40kg ammoniacal liquor;
Step 2, after fully being mixed by the composition in above-mentioned steps, static reaction 5 minutes is for subsequent use;
Step 3, selects propyl carbinol 32.5kg, methylcarbonate 37.5kg hybrid reaction for subsequent use;
Step 4, mixture reacted in step 2 and step 3 is added together gentle agitation or plays circulation, and static reaction is after 15 minutes, for subsequent use;
Step 5, get the international diesel of 500kg-20# and mix with mixture solution reacted in step 4, gentle agitation 15 minutes, namely becomes a kind of liquid cleaning environmental protection diesel oil.
In described step 4, mixture reacted in step 2 and step 3 being added together gentle agitation or beating the time of circulating is 20 minutes.
Embodiment 7: raw material weight proportioning of the present invention is with embodiment 1, and preparation technology of the present invention is as follows:
Step one, selects methyl alcohol 49kg, methylal 28kg and water 18kg to pour in 148kg oleic acid and mixes, then add 29kg ammoniacal liquor;
Step 2, after fully being mixed by the composition in above-mentioned steps, static reaction 5 minutes is for subsequent use;
Step 3, selects propyl carbinol 9kg, methylcarbonate 18kg hybrid reaction for subsequent use;
Step 4, mixture reacted in step 2 and step 3 is added together gentle agitation or plays circulation, and static reaction is after 10 minutes, for subsequent use;
Step 5, get 398kg diesel oil and mix with mixture solution reacted in step 4, gentle agitation 10 minutes, namely becomes a kind of liquid cleaning environmental protection diesel oil.
In step 4, mixture reacted in step 2 and step 3 being added together gentle agitation or beating the time of circulating is 20 minutes.
Described diesel oil is-20# GB diesel oil.
Although disclose embodiments of the invention for the purpose of illustration, its object is to help to understand content of the present invention tool to implement, but person skilled in the art, without departing from the spirit and scope of the invention and the appended claims, can do various replacement, change and retouching.Therefore, the present invention should not be limited to the content disclosed in embodiment, and the scope that protection scope of the present invention defines with appending claims is as the criterion.
Claims (1)
1. a liquid cleaning environmental protection diesel oil, it is characterized in that: it is by taking diesel oil as major ingredient, with the liquid cleaning environmental protection diesel oil that oleic acid, methyl alcohol, methylal, water, ammoniacal liquor, propyl carbinol, methylcarbonate form for auxiliary material, formed by the preparation of raw material of following weight proportioning: oleic acid 20%, methyl alcohol 10%, methylal 5%, water 4%, ammoniacal liquor 4%, propyl carbinol 3.25%, methylcarbonate 3.75%, diesel oil 50%, its preparation process is as follows:
Step one, selects methyl alcohol, methylal and water to pour in oleic acid and mixes, then add ammoniacal liquor;
Step 2, after fully being mixed by the composition in above-mentioned steps, static reaction 5 minutes is for subsequent use;
Step 3, selects propyl carbinol, methylcarbonate hybrid reaction for subsequent use;
Step 4, mixture reacted in step 2 and step 3 is added together gentle agitation or plays circulation, and static reaction is after 10 minutes, for subsequent use;
Step 5, get diesel oil to mix with mixture solution reacted in step 4, gentle agitation 10-20 minute, namely a kind of liquid cleaning environmental protection diesel oil is become, wherein in step 4, mixture reacted in step 2 and step 3 being added together gentle agitation or beating the time of circulating is 10 minutes, and described diesel oil is 0# GB diesel oil.
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| CN201210309816.3A CN103627448B (en) | 2012-08-29 | 2012-08-29 | A kind of liquid cleaning environmental protection diesel oil and preparation method thereof |
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| CN201210309816.3A CN103627448B (en) | 2012-08-29 | 2012-08-29 | A kind of liquid cleaning environmental protection diesel oil and preparation method thereof |
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| CN103627448A CN103627448A (en) | 2014-03-12 |
| CN103627448B true CN103627448B (en) | 2015-11-18 |
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| CN104449889A (en) * | 2014-10-31 | 2015-03-25 | 新疆亿科林新能源科技有限公司 | Modified clean diesel oil and preparation method thereof |
| CN113092405B (en) * | 2021-04-08 | 2023-06-16 | 晨光生物科技集团股份有限公司 | Method for rapidly pre-judging induction period of vegetable oil under normal temperature condition |
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| CN1201065A (en) * | 1997-05-29 | 1998-12-09 | 关恩泽 | Diesel oil |
| CN1563290A (en) * | 2004-04-07 | 2005-01-12 | 宋振中 | Clean fuel |
| CN101434874A (en) * | 2007-11-16 | 2009-05-20 | 上海欧罗福企业（集团）有限公司 | Clean fuel liquid |
| CN101531931A (en) * | 2009-04-10 | 2009-09-16 | 熊道陵 | Clean energy-saving methanol diesel oil and preparation method thereof |
| CN102399599A (en) * | 2010-09-16 | 2012-04-04 | 陈若歆 | Methanol diesel oil manufacturing mode |
-
2012
- 2012-08-29 CN CN201210309816.3A patent/CN103627448B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1201065A (en) * | 1997-05-29 | 1998-12-09 | 关恩泽 | Diesel oil |
| CN1563290A (en) * | 2004-04-07 | 2005-01-12 | 宋振中 | Clean fuel |
| CN101434874A (en) * | 2007-11-16 | 2009-05-20 | 上海欧罗福企业（集团）有限公司 | Clean fuel liquid |
| CN101531931A (en) * | 2009-04-10 | 2009-09-16 | 熊道陵 | Clean energy-saving methanol diesel oil and preparation method thereof |
| CN102399599A (en) * | 2010-09-16 | 2012-04-04 | 陈若歆 | Methanol diesel oil manufacturing mode |
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Inventor after: Yang Geping Inventor after: Chen Minhang Inventor after: Chen Jianshe Inventor before: Chen Minhang Inventor before: Chen Jianshe |
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Effective date of registration: 20200723 Address after: No.277, group 47, Zhongshan street, Chengguan Town, Zhenping county, Nanyang City, Henan Province Patentee after: Yang Geping Address before: 461694, Xuchang City, Henan province Yuzhou Beizhen army Zhang village 5 groups Patentee before: Chen Minhang |