CN102260546B - Biological methanol large-proportion alternative diesel and preparation method thereof - Google Patents
Biological methanol large-proportion alternative diesel and preparation method thereof Download PDFInfo
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- CN102260546B CN102260546B CN201110170192.7A CN201110170192A CN102260546B CN 102260546 B CN102260546 B CN 102260546B CN 201110170192 A CN201110170192 A CN 201110170192A CN 102260546 B CN102260546 B CN 102260546B
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- diesel
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 159
- 238000002360 preparation method Methods 0.000 title abstract description 3
- 238000000034 method Methods 0.000 claims abstract description 8
- 239000002283 diesel fuel Substances 0.000 claims description 44
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical group CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000005642 Oleic acid Substances 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 5
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 5
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 abstract description 11
- 239000007788 liquid Substances 0.000 abstract description 5
- 230000009972 noncorrosive effect Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012452 mother liquor Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Fats And Perfumes (AREA)
- Lubricants (AREA)
Abstract
The invention discloses biological methanol large-proportion alternative diesel and a preparation method thereof. The biological methanol large-proportion alternative diesel is prepared by mixing the following raw materials in percentage by weight: 60 to 95 percent of biological methanol, and 5 to 40 percent of national standard diesel or promotor. The methanol synthetic diesel prepared by the process is obtained by adding liquid biological methanol which is cheap, has an extremely high relative reserve volume and is combustible and other liquid combustibles into the traditional diesel in a large proportion, and the substitution rate of oil components is extremely high, so energy sources can be saved; and the biological methanol large-proportion alternative diesel has good social and economic benefits, also has the advantages of environment friendliness, excellent power performance, wide application range, stable quality and the like, is non-corrosive, and is easy to produce. The biological methanol large-proportion alternative diesel can be directly used and mixed to be used under the condition of not changing any device of automobiles, ships, motor vehicles and other diesel engines. General methanol diesel No. 10.0 to 35 can be produced. Performance indexes of the methanol diesel reach the standard of model GB/T20828-2007(BD100).
Description
Technical field
The present invention relates to a kind of biological methanol vast scale diesel oil substitute and compound method thereof;
Technical background
Tellurian petroleum resources are limited, it is predicted; The average life of world oil exploitation is approximately 30 years;
This pessimistic estimation makes oil more become the energy unexpectedly striven in world wide, and automobile emission regulation is more and more harsher in recent years, thus for automobile find a kind of cheap and easy to get, pollute little fuel substitute, be of great immediate significance;
Developing the environmental protection new forms of energy of fuel as an alternative, is the needs of national energy strategy, the needs of the industry of Ye Shi China and even entire society's sustainable development.Methanol diesel-oil is exactly so a kind of new forms of energy, there is certain application in daily life, but existing methanol diesel-oil, in diesel oil, just simply mix certain proportion analyse methanol mixed and form, and along with the increase of methanol ratio, methyl alcohol calorific value is low, be short of power, high oil consumption, cold starting difficulty, high temperature vapour lock, poor stability, corrosion are swelling, and many problems such as to dissolve each other of diesel oil, will come out one by one, has a strong impact on result of use;
The sharp increase of diesel car.Because processed oil price rises suddenly, a large amount of auto vendors is increasing the Motor vehicles of diesel motor, with developing target market, reduces costs, promotion.The listing of massive diesel-fuel Motor vehicles, certainly will cause diesel oil to sell and surge, and other business's domestic fuel oil is universal in addition, and the requirement of diesel oil is more and more larger:
The needs of environment protection.By 2015, China's motor vehicle total amount will reach 1,000 ten thousand." the Chinese human evolution report " of United Nations Development Programme in 2003 is pointed out, in contaminated 20 the most serious cities, the world, 16 in China.The traveling of a large amount of motor vehicle causes the objectionable impurities of exhaust emissions, methanol diesel-oil be applied to the discharge that can reduce tail gas objectionable impurities CO and HC etc.;
Summary of the invention:
The object of this invention is to provide a kind of vast scale diesel oil substitute and there is dynamic property by force, versatility, stability, biological methanol diesel fuel that anti-knocking property are good and preparation method thereof;
Above-mentioned object is realized by following technical scheme;
A kind of biological methanol diesel fuel, its composition comprises; Methyl alcohol, diesel oil, auxiliary agent, the parts by weight of described methyl alcohol are 60-80%; The parts by weight of described diesel oil are 20-40%; The parts by weight of described auxiliary agent are 5%;
Above-mentioned biological methanol diesel fuel, described auxiliary agent comprises: the parts by weight of ring penta ferrocene are 6-17, and the parts by weight of carbon lauryl alcohol are 5-12, the parts by weight of oleic acid are 8-25, the parts by weight of acetone are 1-6, and propyl carbinol parts by weight are 1-1.5, and the parts by weight of isopropylcarbinol are 0.5-1;
Above-mentioned biological methanol vast scale diesel oil substitute compound method, according to the height using season and region temperature, the ratio that methyl alcohol and diesel oil respectively account for is different;
If the Changjiang river areas to the south summer temperature is more than 18 DEG C, the parts by weight of described biological methanol are 75%, and the parts by weight of described diesel oil are 20%, and the parts by weight of described auxiliary agent are 5%;
As North of Yangtze River, the Yellow River areas to the south temperature in spring and autumn is when 5-18 DEG C, and the parts by weight of described methyl alcohol are 65%; The parts by weight of described diesel oil are 30%; The parts by weight of described auxiliary agent are 5%;
. if winter temperature to the north of the Yellow River is below 5 DEG C, the parts by weight of described methyl alcohol are 55%; The parts by weight of described diesel oil are 40%; The parts by weight of described auxiliary agent are 5%.
Technical scheme of the present invention has following beneficial effect; 1. methyl alcohol fuel mixing ratio can reach 60%-80%; 2. use this methanol diesel-oil engine cold starting normal; 3. power strengthens, oil consumption decline 0.7%-3.6%; 4. exhaust emissions carbon monoxide reduces more than 95%, and hydrocarbon reduces more than 85%; 5. can use with ordinary diesel oil cross exchanged, without the need to changing any structure of vehicle and component; 6. the valency of this methanol diesel-oil reduction by 1200 yuan to 1800 yuan more per ton than ordinary diesel oil, reduces diesel oil simultaneously and uses 60%-80%, save energy; 7. the present invention have fabulous versatility, anti-knocking property, stability, save 15%-20%, this product is not stratified, inorganic, without colloid, corrosion-free, octane value is high, 8. product of the present invention, low cost, low price, the present invention can be the petroleum resources that country saves 60%-95% every year, economic benefit and social benefit cannot be estimated, and without three wastes environmental protection, marketing is rapid, is 21st century high and new technology environmental protection new forms of energy; 9. product of the present invention is to automobile, steamer, and motor vehicle and other commercial diesel must not change any device, can directly use and mix, and the wide model of use range has very large development prospect.10. compound method of the present invention fundamentally solves by adding auxiliary agent the difficult problem that methyl alcohol and ordinary diesel oil can not be mixed, methyl alcohol and diesel oil mix the important breakthrough of making a gesture of measuring and having had, methyl alcohol is mixed to make a gesture of measuring and rises to 60%-80% diesel oil from 10% and mix to make a gesture of measuring and be reduced to 20 from 70%, auxiliary agent 5%, after being fully uniformly mixed, 10.0-35 label universal methyl alcohol diesel can be produced.Its performance index reach 94-GB252 model standard.
Embodiment:
Embodiment 1:
This biological methanol diesel fuel, it is that the material combination of following weight proportioning is made: GB diesel oil 20kg, biological methanol 75kg, the parts by weight of ring penta ferrocene are 6kg, the parts by weight of carbon lauryl alcohol are 5kg, and the parts by weight of oleic acid are 8kg, and the parts by weight of acetone are 1kg, propyl carbinol parts by weight are 1kg, and the parts by weight of isopropylcarbinol are 0.5kg;
First above six kinds of auxiliary agents being mixed into mother liquor is that to take weight be 5kg to 21.5kg, join in 75kg biological methanol, mixing and stirring at normal temperatures, leave standstill more than 8 hours, and then by 20kg, GB diesel oil joins in the methyl alcohol blending liquid after leaving standstill, mixing and stirring at normal temperatures, after 50 minutes, namely obtain biological methanol diesel fuel product;
Embodiment 2:
This biological methanol diesel fuel, it is that the material combination of following weight proportioning is made: GB diesel oil 30kg, biological methanol 65kg, the parts by weight of ring penta ferrocene are 10kg, the parts by weight of carbon lauryl alcohol are 8kg, and the parts by weight of oleic acid are 12kg, and the parts by weight of acetone are 1kg, propyl carbinol parts by weight are 1kg, and the parts by weight of isopropylcarbinol are 0.5kg;
Compound method:
First above six kinds of auxiliary agents being mixed into mother liquor is that to take weight be 5kg to 32.5kg, join in 65kg biological methanol, mixing and stirring at normal temperatures, leave standstill more than 8 hours, and then by 30kg, GB diesel oil joins in the methyl alcohol blending liquid after leaving standstill, mixing and stirring at normal temperatures, after 50 minutes, namely obtain biological methanol diesel fuel product;
Embodiment 3:
This biological methanol diesel fuel, it is that the material combination of following weight proportioning is made: GB diesel oil 40kg, biological methanol 55kg, the parts by weight of ring penta ferrocene are 10kg, the parts by weight of carbon lauryl alcohol are 12kg, and the parts by weight of oleic acid are 25kg, and the parts by weight of acetone are 6kg, propyl carbinol parts by weight are 1.5kg, and the parts by weight of isobutyl ferment are 1kg;
Compound method:
First above six kinds of auxiliary agents being mixed into mother liquor is that to take weight be 5kg to 55.5kg, join in 55kg biological methanol, mixing and stirring at normal temperatures, leave standstill more than 8 hours, and then by 40kg, GB diesel oil joins in the methyl alcohol blending liquid after leaving standstill, mixing and stirring at normal temperatures, after 50 minutes, namely obtain biological methanol diesel fuel product.
Claims (1)
1. the compound method of biological methanol vast scale diesel oil substitute, its composition comprises; Biological methanol, diesel oil, auxiliary agent, the Changjiang river areas to the south summer temperature is more than 18 DEG C, and the parts by weight of described biological methanol are 75%, and the parts by weight of described diesel oil are 20%, and the parts by weight of described auxiliary agent are 5%;
Described auxiliary agent comprises: the parts by weight of ring penta ferrocene are 6-17, and the parts by weight of carbon lauryl alcohol are 5-12, and the parts by weight of oleic acid are 8-25, and the parts by weight of acetone are 1-6, and propyl carbinol parts by weight are 1-1.5, and the parts by weight of isopropylcarbinol are 0.5-1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110170192.7A CN102260546B (en) | 2011-06-23 | 2011-06-23 | Biological methanol large-proportion alternative diesel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110170192.7A CN102260546B (en) | 2011-06-23 | 2011-06-23 | Biological methanol large-proportion alternative diesel and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102260546A CN102260546A (en) | 2011-11-30 |
| CN102260546B true CN102260546B (en) | 2015-05-13 |
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| CN201110170192.7A Expired - Fee Related CN102260546B (en) | 2011-06-23 | 2011-06-23 | Biological methanol large-proportion alternative diesel and preparation method thereof |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105273773A (en) * | 2014-06-18 | 2016-01-27 | 雷菊花 | Low-carbon biological methanol high-proportion substitute diesel oil and preparation method thereof |
| CN105273776A (en) * | 2014-07-21 | 2016-01-27 | 雷菊花 | Energy-saving low-carbon diesel oil core agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101235325A (en) * | 2008-03-06 | 2008-08-06 | 浙江赛孚能源科技有限公司 | Methanol diesel oil fuel and preparation method thereof |
| CN101935561A (en) * | 2010-09-09 | 2011-01-05 | 上海化工研究院 | Methanol-diesel and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1745162A (en) * | 2002-12-13 | 2006-03-08 | 生态性能产品有限公司 | Alcohol enhanced alternative fuels |
| CN101475855A (en) * | 2009-01-13 | 2009-07-08 | 中国林业科学研究院林产化学工业研究所 | Fuel oil based on petrifaction diesel and coarse biodiesel and preparation thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101235325A (en) * | 2008-03-06 | 2008-08-06 | 浙江赛孚能源科技有限公司 | Methanol diesel oil fuel and preparation method thereof |
| CN101935561A (en) * | 2010-09-09 | 2011-01-05 | 上海化工研究院 | Methanol-diesel and preparation method thereof |
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| CN102260546A (en) | 2011-11-30 |
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| DD01 | Delivery of document by public notice |
Addressee: Lei Juhua Document name: Notification of Passing Preliminary Examination of the Application for Invention |
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| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| DD01 | Delivery of document by public notice |
Addressee: Han Demin Document name: Notification of Patent Invention Entering into Substantive Examination Stage |
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| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 100005 Beijing City, Dongcheng District Jianguomen Street No. 18, Henderson Center Huihao corner box 1110 Applicant after: Lei Juhua Address before: 101200 Beijing city Pinggu District North Road 17, box 505 Xinping Applicant before: Lei Juhua |
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| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 330000 Jiangxi province Nanchang Shuanggang economic and Technological Development Zone, 644 East Main Street Branch No. 210 Building 1 room 4 Applicant after: Lei Juhua Address before: 100005 Beijing City, Dongcheng District Jianguomen Street No. 18, Henderson Center Huihao corner box 1110 Applicant before: Lei Juhua |
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Granted publication date: 20150513 Termination date: 20170623 |