CN102260546A - Biological methanol large-proportion alternative diesel and preparation method thereof - Google Patents
Biological methanol large-proportion alternative diesel and preparation method thereof Download PDFInfo
- Publication number
- CN102260546A CN102260546A CN2011101701927A CN201110170192A CN102260546A CN 102260546 A CN102260546 A CN 102260546A CN 2011101701927 A CN2011101701927 A CN 2011101701927A CN 201110170192 A CN201110170192 A CN 201110170192A CN 102260546 A CN102260546 A CN 102260546A
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- China
- Prior art keywords
- weight
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- diesel
- diesel oil
- methanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 189
- 238000002360 preparation method Methods 0.000 title abstract description 3
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000002283 diesel fuel Substances 0.000 claims description 48
- 239000012752 auxiliary agent Substances 0.000 claims description 17
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical group CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 5
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 5
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 4
- 239000003345 natural gas Substances 0.000 claims 2
- 235000009508 confectionery Nutrition 0.000 claims 1
- 238000007670 refining Methods 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 13
- 239000007788 liquid Substances 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 4
- 230000009972 noncorrosive effect Effects 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 3
- 239000012452 mother liquor Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Fats And Perfumes (AREA)
- Lubricants (AREA)
Abstract
The invention discloses biological methanol large-proportion alternative diesel and a preparation method thereof. The biological methanol large-proportion alternative diesel is prepared by mixing the following raw materials in percentage by weight: 60 to 80 percent of biological methanol, and 20 to 40 percent of national standard diesel or base diesel. The methanol synthetic diesel prepared by the process is obtained by adding liquid biological methanol which is cheap, has an extremely high relative reserve volume and is combustible and other liquid combustibles into the traditional diesel in a large proportion, and the substitution rate of oil components is extremely high, so energy sources can be saved; and the biological methanol large-proportion alternative diesel has good social and economic benefits, also has the advantages of environment friendliness, excellent power performance, wide application range, stable quality and the like, is non-corrosive, and is easy to produce. The biological methanol large-proportion alternative diesel can be directly used and mixed to be used under the condition of not changing any device of automobiles, ships, motor vehicles and other diesel engines. General methanol diesel No. 10.0 to 35 can be produced. Performance indexes of the methanol diesel reach the standard of model 94-GB252.
Description
Technical field
The present invention relates to a kind of biological methanol vast scale and substitute diesel oil and compound method thereof;
Technical background
Tellurian petroleum resources are limited, it is predicted; The average life of world oil exploitation approximately is 30 years;
This pessimistic estimation makes oil become the energy of striving unexpectedly in the world wide more, and automobile emission regulation is more and more harsher in recent years, thereby seeks a kind of cheap and easy to get, fuel substitute that pollution is little for automobile, is of great immediate significance;
Developing the environmental protection new forms of energy of fuel as an alternative, is the needs of national energy strategy, also be China's industry and even entire society can be special the needs of supervention exhibition.Methanol diesel-oil a kind of new forms of energy that come to this, certain application is arranged in daily life, but existing methanol diesel-oil, just simply mixing certain proportion in diesel oil analyses methanol mixed and forms, and along with the increase of methyl alcohol ratio, the methyl alcohol calorific value is low, be short of power, high oil consumption, cold starting difficulty, high temperature vapour lock, poor stability, corrosion swelling, with many problems such as dissolving each other of diesel oil, will come out one by one, have a strong impact on result of use;
The sharp increase of diesel car.Because the processed oil price rises suddenly, a large amount of auto vendors is increasing the Motor vehicles of diesel motor,, reduces cost promotion with developing target market.The listing of a large amount of diesel cars certainly will cause diesel oil to sell surge, and other businessman is with the popularizing of diesel oil in addition, and the requirement of diesel oil is big more and more more;
The needs of environment protection.By 2015, China's motor vehicle total amount will reach 1,000 ten thousand." the Chinese human evolution report " of United Nations Development Programme in 2003 pointed out, in contaminated 20 the most serious cities, the world, 16 in China.A large amount of travelling of motor vehicle are caused the objectionable impurities of exhaust emissions, the discharging that is applied to reduce tail gas objectionable impurities CO and HC etc. of methanol diesel-oil;
Summary of the invention:
The purpose of this invention is to provide a kind of vast scale and substitute diesel oil to have dynamic property strong, versatility, stability, biological methanol diesel oil that anti-knocking property are good and preparation method thereof;
Above-mentioned purpose realizes by following technical scheme;
A kind of biological methanol diesel oil, its composition comprises; Methyl alcohol, diesel oil, auxiliary agent, the parts by weight of described methyl alcohol are 60-80%; The parts by weight of described diesel oil are 20-40%; The parts by weight of described auxiliary agent are 5%;
Above-mentioned biological methanol diesel oil, described auxiliary agent comprises: the parts by weight that encircle penta ferrocene are 6-17, the parts by weight of carbon lauryl alcohol are 5-12, oleic parts by weight are 8-25, the parts by weight of acetone are 1-6, and the propyl carbinol parts by weight are 1-1.5, and the parts by weight of isopropylcarbinol are 0.5-1;
Above-mentioned biological methanol vast scale substitutes the diesel oil compound method, and according to the height that uses season and region temperature, the ratio that methyl alcohol and diesel oil respectively account for is different;
More than 18 ℃, the parts by weight of described biological methanol are 75% as areas to the south, the Changjiang river summer temperature, and the parts by weight of described diesel oil are 20%, and the parts by weight of described auxiliary agent are 5%;
To the north of the Changjiang river, areas to the south, the Yellow River temperature in spring and autumn is in the time of 5-18 ℃, and the parts by weight of described methyl alcohol are 65%; The parts by weight of described diesel oil are 30%; The parts by weight of described auxiliary agent are 5%;
Below 5 ℃, the parts by weight of described methyl alcohol are 55% as winter temperature to the north of the Yellow River; The parts by weight of described diesel oil are 40%; The parts by weight of described auxiliary agent are 5%.
Technical scheme of the present invention has following beneficial effect: 1. methyl alcohol is mixed and is burnt than reaching 60%-80%; 2. use this methanol diesel-oil engine cold starting normal; 3. power strengthens, oil consumption decline 0.7%-3.6%; 4. the exhaust emissions carbon monoxide reduces more than 95%, and hydrocarbon reduces more than 85%; 5. can use with the ordinary diesel oil cross exchanged, need not to change vehicle any structure and component; 6. the reduction per ton of the price ratio ordinary diesel oil of this methanol diesel-oil is 1200 yuan to 1800 yuan, reduces diesel oil simultaneously and uses 60%-80%, save energy; The present invention have excellent universality, anti-knocking property, stability,, save 15%-20%, this product is not stratified, inorganic, no colloid does not have corrosion, the octane value height, 8. product of the present invention, low cost, low price can be the petroleum resources that country saves 60%-95% every year of the present invention, economic benefit and social benefit can't be estimated, and do not have three wastes environmental protection, marketing is rapid, is 21st century high and new technology environmental protection new forms of energy; 9. product of the present invention is to automobile, steamer, and motor vehicle and other commercial diesel machine must not changed any device, can directly use and mix, and the wide model of use range has very big development prospect.10. compound method of the present invention has fundamentally solved the difficult problem that methyl alcohol and ordinary diesel oil can not be used with by adding auxiliary agent, the mixing of methyl alcohol and diesel oil made a gesture of measuring the important breakthrough that has had, methyl alcohol mixed to make a gesture of measuring rise to 60%-80% diesel oil from 10% and mix to make a gesture of measuring and be reduced to 20 from 70%, auxiliary agent 5%, after fully mixing, can produce 10.0-35 label universal methyl alcohol diesel.Its performance index reach 94-GB252 model standard.
Embodiment:
Embodiment 1:
This biological methanol diesel oil, it is that the combination of following weight proportion raw material is made: GB diesel oil 20kg, biological methanol 75kg, the parts by weight that encircle penta ferrocene are 6kg, the parts by weight of carbon lauryl alcohol are 5kg, and oleic parts by weight are 8kg, and the parts by weight of acetone are 1kg, the propyl carbinol parts by weight are 1kg, and the parts by weight of isopropylcarbinol are 0.5kg;
Earlier above six kinds of auxiliary agents being mixed into mother liquor and being 21.5kg, to take by weighing weight be 5kg, join in the 75kg biological methanol, mixing and stirring at normal temperatures, leave standstill more than 8 hours, and then with 20kg, in the methyl alcohol blending liquid after GB diesel oil joins and leaves standstill, mixing and stirring at normal temperatures, after 50 minutes, promptly obtain the biological methanol diesel product;
Embodiment 2:
This biological methanol diesel oil, it is that the combination of following weight proportion raw material is made: GB diesel oil 30kg, biological methanol 65kg, the parts by weight that encircle penta ferrocene are 10kg, the parts by weight of carbon lauryl alcohol are 8kg, and oleic parts by weight are 12kg, and the parts by weight of acetone are 1kg, the propyl carbinol parts by weight are 1kg, and the parts by weight of isopropylcarbinol are 0.5kg;
Compound method:
Earlier above six kinds of auxiliary agents being mixed into mother liquor and being 32.5kg, to take by weighing weight be 5kg, join in the 65kg biological methanol, mixing and stirring at normal temperatures, leave standstill more than 8 hours, and then with 30kg, in the methyl alcohol blending liquid after GB diesel oil joins and leaves standstill, mixing and stirring at normal temperatures, after 50 minutes, promptly obtain the biological methanol diesel product;
Embodiment 3:
This biological methanol diesel oil, it is that the combination of following weight proportion raw material is made: GB diesel oil 40kg, biological methanol 55kg, the parts by weight that encircle penta ferrocene are 10kg, the parts by weight of carbon lauryl alcohol are 12kg, and oleic parts by weight are 25kg, and the parts by weight of acetone are 6kg, the propyl carbinol parts by weight are 1.5kg, and the parts by weight of isopropylcarbinol are 1kg;
Compound method:
Earlier above six kinds of auxiliary agents being mixed into mother liquor and being 55.5kg, to take by weighing weight be 5kg, join in the 55kg biological methanol, mixing and stirring at normal temperatures, leave standstill more than 8 hours, and then with 40kg, in the methyl alcohol blending liquid after GB diesel oil joins and leaves standstill, mixing and stirring at normal temperatures, after 50 minutes, promptly obtain the biological methanol diesel product.
Claims (4)
1. the biological methanol vast scale substitutes diesel oil and compound method thereof, and its composition comprises; Methyl alcohol, diesel oil, auxiliary agent, the parts by weight of described methyl alcohol are 60-80%; The parts by weight of described diesel oil are 20-40%; The parts by weight of described auxiliary agent are 5%;
2. biological methanol diesel oil according to claim 1, it is characterized in that: described auxiliary agent comprises: the parts by weight that encircle penta ferrocene are 6-17, the parts by weight of carbon lauryl alcohol are 5-12, oleic parts by weight are 8-25, the parts by weight of acetone are 1-6, the propyl carbinol parts by weight are 1-1.5, and the parts by weight of isopropylcarbinol are 0.5-1;
3. vast scale biological methanol according to claim 1 and 2 substitutes the compound method of diesel oil, it is characterized in that: according to the height that uses season and region temperature, the ratio that biological methanol and diesel oil respectively account for is different;
More than 18 ℃, the parts by weight of described biological methanol are 75% as areas to the south, the Changjiang river summer temperature, and the parts by weight of described diesel oil are 20%, and the parts by weight of described auxiliary agent are 5%;
To the north of the Changjiang river, areas to the south, the Yellow River temperature in spring and autumn is in the time of 5-18 ℃, and the parts by weight of described methyl alcohol are 65%; The parts by weight of described diesel oil are 30%; The parts by weight of described auxiliary agent are 5%;
Below 5 ℃, the parts by weight of described methyl alcohol are 55% as winter temperature to the north of the Yellow River; The parts by weight of described diesel oil are 40%; The parts by weight of described auxiliary agent are 5%;
4. biological methanol diesel oil according to claim 1 is characterized in that: described methyl alcohol is that biological methanol is to have biogas to be purified to Sweet natural gas, the biological methanol that has natural gas refining to make.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110170192.7A CN102260546B (en) | 2011-06-23 | 2011-06-23 | Biological methanol large-proportion alternative diesel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110170192.7A CN102260546B (en) | 2011-06-23 | 2011-06-23 | Biological methanol large-proportion alternative diesel and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102260546A true CN102260546A (en) | 2011-11-30 |
| CN102260546B CN102260546B (en) | 2015-05-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110170192.7A Expired - Fee Related CN102260546B (en) | 2011-06-23 | 2011-06-23 | Biological methanol large-proportion alternative diesel and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN102260546B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105273773A (en) * | 2014-06-18 | 2016-01-27 | 雷菊花 | Low-carbon biological methanol high-proportion substitute diesel oil and preparation method thereof |
| CN105273776A (en) * | 2014-07-21 | 2016-01-27 | 雷菊花 | Energy-saving low-carbon diesel oil core agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040123518A1 (en) * | 2002-12-13 | 2004-07-01 | Eastman Alan D. | Alcohol enhanced alternative fuels |
| CN101235325A (en) * | 2008-03-06 | 2008-08-06 | 浙江赛孚能源科技有限公司 | Methanol diesel oil fuel and preparation method thereof |
| CN101475855A (en) * | 2009-01-13 | 2009-07-08 | 中国林业科学研究院林产化学工业研究所 | Fuel oil based on petrifaction diesel and coarse biodiesel and preparation thereof |
| CN101935561A (en) * | 2010-09-09 | 2011-01-05 | 上海化工研究院 | Methanol-diesel and preparation method thereof |
-
2011
- 2011-06-23 CN CN201110170192.7A patent/CN102260546B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040123518A1 (en) * | 2002-12-13 | 2004-07-01 | Eastman Alan D. | Alcohol enhanced alternative fuels |
| CN101235325A (en) * | 2008-03-06 | 2008-08-06 | 浙江赛孚能源科技有限公司 | Methanol diesel oil fuel and preparation method thereof |
| CN101475855A (en) * | 2009-01-13 | 2009-07-08 | 中国林业科学研究院林产化学工业研究所 | Fuel oil based on petrifaction diesel and coarse biodiesel and preparation thereof |
| CN101935561A (en) * | 2010-09-09 | 2011-01-05 | 上海化工研究院 | Methanol-diesel and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105273773A (en) * | 2014-06-18 | 2016-01-27 | 雷菊花 | Low-carbon biological methanol high-proportion substitute diesel oil and preparation method thereof |
| CN105273776A (en) * | 2014-07-21 | 2016-01-27 | 雷菊花 | Energy-saving low-carbon diesel oil core agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102260546B (en) | 2015-05-13 |
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Legal Events
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| DD01 | Delivery of document by public notice |
Addressee: Lei Juhua Document name: Notification of Passing Preliminary Examination of the Application for Invention |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| DD01 | Delivery of document by public notice |
Addressee: Han Demin Document name: Notification of Patent Invention Entering into Substantive Examination Stage |
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| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 100005 Beijing City, Dongcheng District Jianguomen Street No. 18, Henderson Center Huihao corner box 1110 Applicant after: Lei Juhua Address before: 101200 Beijing city Pinggu District North Road 17, box 505 Xinping Applicant before: Lei Juhua |
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| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 330000 Jiangxi province Nanchang Shuanggang economic and Technological Development Zone, 644 East Main Street Branch No. 210 Building 1 room 4 Applicant after: Lei Juhua Address before: 100005 Beijing City, Dongcheng District Jianguomen Street No. 18, Henderson Center Huihao corner box 1110 Applicant before: Lei Juhua |
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| C14 | Grant of patent or utility model | ||
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150513 Termination date: 20170623 |