CN101343574A - Formulation process for synthesis of gasoline with methanol - Google Patents
Formulation process for synthesis of gasoline with methanol Download PDFInfo
- Publication number
- CN101343574A CN101343574A CNA2008100300388A CN200810030038A CN101343574A CN 101343574 A CN101343574 A CN 101343574A CN A2008100300388 A CNA2008100300388 A CN A2008100300388A CN 200810030038 A CN200810030038 A CN 200810030038A CN 101343574 A CN101343574 A CN 101343574A
- Authority
- CN
- China
- Prior art keywords
- gasoline
- methanol
- agent
- blending process
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Solid Fuels And Fuel-Associated Substances (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses a preparation process for methanol synthetic gasoline which is mixed by the following raw materials, in weight percentage: 40 percent to 95 percent of industrial methanol; national standard gasoline or basic gasoline or a mixture thereof in random proportion, or 0 percent to 70 percent of mixture of two or more basic gasoline in random proportion; 2 percent to 5 percent of fluxing denaturant; and 0.1 percent to 0.5 percent of composite functional agent. The preparation process adopts the steps: firstly the fluxing denaturant is added into the industrial methanol for stirring for 5 minutes to 10 minutes under the conditions of normal temperature, atmospheric pressure, no spark, fire prevention and explosion protection, the composite functional agent is then added thereto for the agitation for 5 minutes to 10 minutes, then the national standard gasoline or the basic gasoline or the mixture thereof in random proportion is added thereto for being continuously stirred for 5 minutes, finally completing the preparation. The methanol synthetic gasoline prepared by the process is to add inexpensive combustible liquid methanol and other liquid combustible substances with relatively large reserves in great proportions into the traditional gasoline, the substitution rate of the petroleum composition is extremely high, the energy can be saved, the national petroleum import pressure can be reduced, massive foreign exchange disbursement can be saved, and the socioeconomic performance is good, meanwhile, the process has technical advantages of environmental protection, good power performance, corrosion resistance, extensive use scope, stable quality and simple and convenient production, and being worth wide promotion.
Description
Technical field
The present invention relates to technical field of new energies, particularly a kind of blending process of methanol synthesized gasoline.
Technical background
Developing the environmental protection new forms of energy of fuel as an alternative, is the needs of national energy strategy and environment strategy, also is the needs of China's industry and even entire society's Sustainable development.Methanol gasoline a kind of new forms of energy that come to this, certain application is arranged in daily life, but existing methanol gasoline, just simply mixing a certain proportion of methanol mixed in gasoline forms, this is not have much problems under the low ratio situation of 3-5%, and along with the increase of methyl alcohol ratio, the methyl alcohol calorific value is low, be short of power, high oil consumption, cold starting difficulty, high temperature vapour lock, poor stability, corrosion swelling, with many problems such as dissolving each other of gasoline, will come out one by one, have a strong impact on result of use.
Summary of the invention
The technical problem to be solved in the present invention is to overcome the deficiencies in the prior art, and the blending process of methanol synthesized gasoline is provided, can realize substituting gasoline with the methyl alcohol vast scale, and energy-conserving and environment-protective, result of use is good.
For solving the problems of the technologies described above, technical scheme of the present invention is: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 40-95%
GB gasoline or base gasoline, or the two
The arbitrary proportion mixture, or two kinds with
The arbitrary proportion mixture 0-70% of last base gasoline
Hydrotropy denaturing agent 2-5%
Complex function agent 0.1-0.5%
Its blending process is: under normal temperature, normal pressure, sparkless, fire prevention, explosion-proof condition, earlier the hydrotropy denaturing agent is added in the industrial methanol, stir after 5-10 minute, add the complex function agent, restir 5-10 minute, add GB gasoline or base gasoline or the arbitrary proportion mixture of the two, continue to stir 5 minutes, promptly finish preparation.
The blending process of aforesaid methanol synthesized gasoline, described industrial methanol are various fusels, the thick alcohol of methanol content more than 80%.
The blending process of aforesaid methanol synthesized gasoline, described GB gasoline can be the wherein a kind of of GB 90#, 93#, 97#, described base gasoline can be the wherein a kind of of winterization gasoline, shifting block gasoline, straight-run spirit, petroleum naphtha, also can be the arbitrary proportion mixture of above several oil.
The blending process of aforesaid methanol synthesized gasoline, described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
The blending process of aforesaid methanol synthesized gasoline, described functional agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
The blending process of aforesaid methanol synthesized gasoline, described calorific value synergistic agent can be acetone, ferrocene, hydroxyquinoline, cyclohexane wherein two kinds, respectively account for 1/2nd.
The blending process of aforesaid methanol synthesized gasoline, described anti-oxygen resist can be that concentration is the wherein a kind of of 30% 2.6-ditertbutylparacresol liquid, trolamine, nitrous acid two ethylenimine.
The blending process of aforesaid methanol synthesized gasoline, described combustion-supporting smoke suppressor can be the wherein a kind of of cerous nitrate, hempa acid diamide, carboxymethyl cellulose, 200# solvent oil, also can be the mixture of two or more arbitrary proportion wherein.
The blending process of aforesaid methanol synthesized gasoline, described anti-vapour lock agent can be the wherein a kind of of butanone, cyclohexane, methyl propionate, methyl alcohol isobutyl ester, dipropyl ether, also can be the mixtures of two or more arbitrary proportion wherein.
The blending process of aforesaid methanol synthesized gasoline, described synchronousing combustion promotor is gasoline combustion promotor.
The useful technique effect that the present invention obtained is: the methanol synthesized gasoline of above-mentioned technology preparation, in traditional gasoline, add cheap and relative very big, combustible liquid methanol of reserves and other liquid combustiblematerials with vast scale, oil composition substitution rate is high, but save energy, reduce national petroleum import pressure, save a large amount of foreign exchange expenditures, have favorable social and economic benefits; Can make methyl alcohol and other component composition in engine inter-sync rapid combustion, heat release is even rapidly, and thermo-efficiency significantly improves, and has greatly improved fuel economy, and oil consumption reduces 5-10% on year-on-year basis; Methyl alcohol belongs to oxygenated fuel, by substituting alkene in the product, aromatic hydrocarbons, gelationus ratio is reduced. and can realize thorough burning, exhaust emissions is lower than national standard more than 50%, and environmental-protecting performance is good; Outward appearance and smell and traditional gasoline are as broad as long, and octane value can arbitrarily be modulated in gasoline, and octane value can reach 90--98 in the gasoline, than conventional gasoline label height, and anti-knocking property index height; Can remove carbon deposit, grease automatically, realize emission controls by improving combustion, prolong engine work-ing life; Dynamic performance is good, realizes and the complete same effect of gasoline; Engine cold-starting is easy, and each operating mode operates steadily, and noise greatly reduces; Engine system is not had corrosion, do not worry damaging component, pipeline etc.; Have a high temperature lubricating effect in unique machine, overcome the side effect that methanol crossover power is destroyed film lubrication by force; Gasoline car has been realized all standing, has really realized carefree use, both can use separately, also can with commercially available any trade mark gasoline with arbitrary proportion blending, the use of dissolving each other, use range is extensive; Constant product quality, chance water is not stratified, and the accumulating cycle is long; Production unit is simple, and raw material is easily purchased, less investment, three-waste free pollution.
Embodiment
Embodiment one: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 68%
GB gasoline 30%
Hydrotropy denaturing agent 2%
Complex function agent 0.1%
Its blending process is: under normal temperature, normal pressure, sparkless, fire prevention, explosion-proof condition, earlier the hydrotropy denaturing agent is added in the industrial methanol, stir after 5-10 minute, add the complex function agent, restir 5-10 minute, add GB gasoline or base gasoline or the arbitrary proportion mixture of the two, continue to stir 5 minutes, promptly finish preparation.
Described industrial methanol is that methanol content is the thick alcohol more than 80%.
Described GB gasoline is GB 90#.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is acetone, ferrocene, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is that 30% the refined butyl of 2.6-is to formic acid liquid.
Described combustion-supporting smoke suppressor is a cerous nitrate.
Described anti-vapour lock agent is a butanone.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment two: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 47%
GB gasoline 50%
Hydrotropy denaturing agent 2.5%
Complex function agent 0.15%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the thick alcohol more than 80%.
Described GB gasoline is GB 90#.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is acetone, ferrocene, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% 2.6-ditertbutylparacresol liquid.
Described combustion-supporting smoke suppressor is a cerous nitrate.
Described anti-vapour lock agent is a butanone.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment three: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 50%
Base gasoline 47%
Hydrotropy denaturing agent 3%
Complex function agent 0.15%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the thick alcohol more than 80%.
Described base gasoline is a winterization gasoline.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is acetone, ferrocene, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% 2.6-ditertbutylparacresol liquid.
Described combustion-supporting smoke suppressor is a cerous nitrate.
Described anti-vapour lock agent is a cyclohexane.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment four: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 50%
Base gasoline 47%
Hydrotropy denaturing agent 3%
Complex function agent 0.15%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the thick alcohol more than 80%.
Described base gasoline is a shifting block gasoline.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is ferrocene, hydroxyquinoline, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% 2.6-ditertbutylparacresol liquid.
Described combustion-supporting smoke suppressor is the hempa acid diamide.
Described anti-vapour lock agent is a cyclohexane.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment five: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 50%
Base gasoline 47%
Hydrotropy denaturing agent 3%
Complex function agent 0.15%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the thick alcohol more than 80%.
Described base gasoline is a straight-run spirit.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is ferrocene, hydroxyquinoline, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% 2.6-ditertbutylparacresol liquid.
Described combustion-supporting smoke suppressor is the hempa acid diamide.
Described anti-vapour lock agent is a methyl propionate.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment six: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 50%
The mixture 48% of base gasoline and GB gasoline
Hydrotropy denaturing agent 2%
Complex function agent 0.15%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the thick alcohol more than 80%.
Described base gasoline is a winterization gasoline, accounts for 28% ratio, and described GB gasoline is GB 93#, accounts for 20% ratio.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is ferrocene, hydroxyquinoline, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% trolamine.
Described combustion-supporting smoke suppressor is the hempa acid diamide.
Described anti-vapour lock agent is a methyl propionate.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment seven: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 50%
The mixture 48% of base gasoline and GB gasoline
Hydrotropy denaturing agent 2%
Complex function agent 0.15%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the thick alcohol more than 80%.
Described base gasoline is a condensation shifting block gasoline, accounts for 28% ratio, and described GB gasoline is GB 93#, accounts for 20% ratio.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is hydroxyquinoline, cyclohexane, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% trolamine.
Described combustion-supporting smoke suppressor is a carboxymethyl cellulose.
Described anti-vapour lock agent is the methyl alcohol isobutyl ester.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment eight: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 50%
Base gasoline 47%
Hydrotropy denaturing agent 3%
Complex function agent 0.15%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the thick alcohol more than 80%.
Described base gasoline is a petroleum naphtha, accounts for 27% ratio, and described GB gasoline is GB 97#, accounts for 20% ratio.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is hydroxyquinoline, cyclohexane, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% trolamine.
Described combustion-supporting smoke suppressor is a carboxymethyl cellulose.
Described anti-vapour lock agent is the methyl alcohol isobutyl ester.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment nine: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 46%
Base gasoline 50%
Hydrotropy denaturing agent 4%
Complex function agent 0.2%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the fusel more than 80%.
Described base gasoline is a petroleum naphtha.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is hydroxyquinoline, cyclohexane, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% trolamine.
Described combustion-supporting smoke suppressor is a carboxymethyl cellulose.
Described anti-vapour lock agent is a dipropyl ether.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment ten: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 48%
The mixture 50% of base gasoline and GB gasoline
Hydrotropy denaturing agent 2%
Complex function agent 0.15%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the fusel more than 80%.
Described base gasoline is a straight-run spirit, accounts for 30% ratio, and described GB gasoline is GB 97#, accounts for 20% ratio.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is acetone, hydroxyquinoline, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% trolamine.
Described combustion-supporting smoke suppressor is the 200# solvent oil.
Described anti-vapour lock agent is a dipropyl ether.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment 11: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 40%
The mixture 57% of two kinds of base gasolines
Hydrotropy denaturing agent 3%
Complex function agent 0.15%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the fusel more than 80%.
Described base gasoline is winterization gasoline and shifting block gasoline, accounts for 20% and 37% ratio respectively.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
First is stupid, diformazan is stupid or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is acetone, hydroxyquinoline, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% nitrous acid two ethylenimine.
Described combustion-supporting smoke suppressor is the 200# solvent oil.
The arbitrary proportion mixture that described anti-vapour lock agent is butanone, cyclohexane.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment 12: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 37%
The mixture 60% of two kinds of base gasolines
Hydrotropy denaturing agent 3%
Complex function agent 0.15%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the fusel more than 80%.
Described base gasoline is winterization gasoline and petroleum naphtha, accounts for 40% and 20% ratio respectively.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is acetone, hydroxyquinoline, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% nitrous acid two ethylenimine.
Described combustion-supporting smoke suppressor is the 200# solvent oil.
The arbitrary proportion mixture that described anti-vapour lock agent is cyclohexane, methyl propionate.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment 13: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 47%
The mixture 50% of two kinds of base gasolines
Hydrotropy denaturing agent 3%
Complex function agent 0.2%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the fusel more than 80%.
Described base gasoline is shifting block gasoline and petroleum naphtha, accounts for 20% and 30% ratio respectively.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is ferrocene, cyclohexane, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% nitrous acid two ethylenimine.
Described combustion-supporting smoke suppressor is the arbitrary proportion mixture of cerous nitrate and hempa acid diamide.
Described anti-vapour lock agent is the arbitrary proportion mixture of methyl propionate, methyl alcohol isobutyl ester.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment 14: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 95%
Hydrotropy denaturing agent 5%
Complex function agent 0.5%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the fusel more than 80%.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is ferrocene, cyclohexane, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% nitrous acid two ethylenimine.
The arbitrary proportion mixture that described combustion-supporting smoke suppressor is hempa acid diamide and carboxymethyl cellulose.
The arbitrary proportion mixture that described anti-vapour lock agent is methyl alcohol isobutyl ester, dipropyl ether.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
Embodiment 15: a kind of blending process of methanol synthesized gasoline is provided, and it is to be mixed by following weight percentages:
Industrial methanol 47%
The mixture 50% of three kinds of base gasolines
Hydrotropy denaturing agent 3%
Complex function agent 0.2%
Its blending process is identical with embodiment one.
Described industrial methanol is that methanol content is the fusel more than 80%.
Described base gasoline is shifting block gasoline, straight-run spirit and petroleum naphtha, accounts for 10%, 10% and 30% ratio respectively.
Described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or
Wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
Toluene, dimethylbenzene or the two mixture of 1: 1 1.5%
Described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%
Described calorific value synergistic agent is ferrocene, cyclohexane, and the two respectively accounts for 1/2nd.
Described anti-oxygen resist is that concentration is 30% nitrous acid two ethylenimine.
Described combustion-supporting smoke suppressor is the arbitrary proportion mixture of carboxymethyl cellulose and 200# solvent oil.
The arbitrary proportion mixture that described anti-vapour lock agent is butanone, methyl propionate.
Described synchronousing combustion promotor is commercially available gasoline combustion promotor.
The foregoing description is the preferred embodiments of the present invention, and all and the similar technology of the present invention and the equivalence of being done change, and all should belong to protection category of the present invention.
Claims (10)
1, a kind of blending process of methanol synthesized gasoline is characterized in that: it is to be mixed by following weight percentages:
Industrial methanol 40-95%
GB gasoline or base gasoline, or the arbitrary proportion mixture of the two, or the arbitrary proportion mixture 0-70% of two or more base gasolines
Hydrotropy denaturing agent 2-5%
Complex function agent 0.1-0.5%
Its blending process is: under normal temperature, normal pressure, sparkless, fire prevention, explosion-proof condition, earlier the hydrotropy denaturing agent is added in the industrial methanol, stir after 5-10 minute, add the complex function agent, restir 5-10 minute, add GB gasoline or base gasoline or the arbitrary proportion mixture of the two, continue to stir 5 minutes, promptly finish preparation.
2, the blending process of methanol synthesized gasoline according to claim 1 is characterized in that: described industrial methanol is various fusels, the thick alcohol of methanol content more than 80%.
3, the blending process of methanol synthesized gasoline according to claim 1, it is characterized in that: described GB gasoline can be the wherein a kind of of GB 90#, 93#, 97#, described base gasoline can be the wherein a kind of of winterization gasoline, shifting block gasoline, straight-run spirit, petroleum naphtha, also can be the arbitrary proportion mixture of above several oil.
4, the blending process of methanol synthesized gasoline according to claim 1 is characterized in that: described hydrotropy denaturing agent is to be mixed at normal temperatures by following weight percentages:
Methyl-formiate or ethyl formate or phenylformic acid, or wherein two or more arbitrary proportion mixture 20-35%
Mixed C 6 pure 25-40%
Lipid acid 20-25%
Aluminium silicophosphate or SODIUM PHOSPHATE, MONOBASIC 2-8%
Iron naphthenate 4-6%
Diisopropyl ether 1-1.5%
First is stupid, diformazan is stupid or the two mixture of 1: 1 1.5%.
5, the blending process of methanol synthesized gasoline according to claim 1 is characterized in that: described complex function agent is to be mixed at normal temperatures by following weight percentages:
Calorific value synergistic agent 20%
Anti-oxygen resist 20%
Combustion-supporting smoke suppressor 40%
Anti-vapour lock agent 10%
Synchronousing combustion promotor 10%.
6, the blending process of methanol synthesized gasoline according to claim 5 is characterized in that: described calorific value synergistic agent can be acetone, ferrocene, hydroxyquinoline, cyclohexane wherein two kinds, respectively accounts for 1/2nd.
7, the blending process of methanol synthesized gasoline according to claim 5 is characterized in that: described anti-oxygen resist can be that concentration is the wherein a kind of of 30% 2.6-ditertbutylparacresol liquid, trolamine, nitrous acid two ethylenimine.
8, the blending process of methanol synthesized gasoline according to claim 5, it is characterized in that: described combustion-supporting smoke suppressor can be the wherein a kind of of cerous nitrate, hempa acid diamide, carboxymethyl cellulose, 200# solvent oil, also can be the mixture of two or more arbitrary proportion wherein.
9, the blending process of methanol synthesized gasoline according to claim 5, it is characterized in that: described anti-vapour lock agent can be the wherein a kind of of butanone, cyclohexane, methyl propionate, methyl alcohol isobutyl ester, dipropyl ether, also can be the mixture of two or more arbitrary proportion wherein.
10, the blending process of methanol synthesized gasoline according to claim 5 is characterized in that: described synchronousing combustion promotor is gasoline combustion promotor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100300388A CN101343574A (en) | 2008-08-07 | 2008-08-07 | Formulation process for synthesis of gasoline with methanol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100300388A CN101343574A (en) | 2008-08-07 | 2008-08-07 | Formulation process for synthesis of gasoline with methanol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101343574A true CN101343574A (en) | 2009-01-14 |
Family
ID=40245692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008100300388A Pending CN101343574A (en) | 2008-08-07 | 2008-08-07 | Formulation process for synthesis of gasoline with methanol |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101343574A (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851535A (en) * | 2010-06-10 | 2010-10-06 | 湖北声荣环保节能科技有限公司 | Multi-function high-efficiency gasoline combustion improver and preparation method thereof |
| CN102373101A (en) * | 2010-08-20 | 2012-03-14 | 白玉林 | High-cleaning aged fuel |
| CN102399601A (en) * | 2010-09-17 | 2012-04-04 | 东莞市智造生物科技有限公司 | High-cleanliness methanol gasoline |
| CN102676241A (en) * | 2012-05-31 | 2012-09-19 | 龙晓群 | Synthetic gasoline and preparation method thereof |
| CN102911752A (en) * | 2012-11-08 | 2013-02-06 | 许建忠 | Methanol gasoline multipurpose additive and application thereof |
| CN101538491B (en) * | 2009-04-16 | 2013-02-13 | 陈斌 | Alcohol ether gasoline used in new energy vehicles |
| CN102977935A (en) * | 2012-12-12 | 2013-03-20 | 孙琪 | Methanol environment-friendly gasoline |
| CN103361128A (en) * | 2013-07-24 | 2013-10-23 | 杨成山 | Methanol gasoline for vehicles |
| CN103396840A (en) * | 2013-06-28 | 2013-11-20 | 江苏巨境新能源科技有限公司 | Environment-friendly methanol gasoline |
| CN103571538A (en) * | 2012-07-30 | 2014-02-12 | 通用电气公司 | Method for reducing acid corrosion to oil |
| CN104694190A (en) * | 2014-09-26 | 2015-06-10 | 广西绿球新科技开发有限公司 | Hydrogen-enriched environment-protective fuel gas and preparation method of hydrogen-enriched environment-protective fuel gas |
| CN104726149A (en) * | 2015-02-07 | 2015-06-24 | 兰州燚能生物科技有限责任公司 | Bio-based methanol gasoline composite auxiliary and bio-based high-proportion methanol gasoline |
| CN106190374A (en) * | 2016-08-23 | 2016-12-07 | 广西东奇能源技术有限公司 | Alcohol-based fuel additive |
| CN106701219A (en) * | 2016-12-26 | 2017-05-24 | 寇延华 | Navigation alcohol fuel combustion-supporting additive for automobile and manufacturing method thereof |
| CN107057783A (en) * | 2016-12-26 | 2017-08-18 | 寇延华 | A kind of automobile-used boat anti-choke additive of alcohol ate and preparation method |
| CN107245354A (en) * | 2016-12-26 | 2017-10-13 | 寇延华 | A kind of automobile-used EPM35 boat alcohol gasoline and preparation method |
| CN108913236A (en) * | 2018-07-11 | 2018-11-30 | 李永峰 | A kind of new automobile fuel cleaning additive and preparation method thereof |
| CN108929727A (en) * | 2018-07-18 | 2018-12-04 | 宁波蒙曼生物科技有限公司 | A kind of coal-based methanol gasoline and its preparation method and application of environment-friendly type purifying |
| CN110157497A (en) * | 2019-04-19 | 2019-08-23 | 寇延华 | A kind of automobile-used EPM55 boat alcohol fuel and production method |
-
2008
- 2008-08-07 CN CNA2008100300388A patent/CN101343574A/en active Pending
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101538491B (en) * | 2009-04-16 | 2013-02-13 | 陈斌 | Alcohol ether gasoline used in new energy vehicles |
| CN101851535B (en) * | 2010-06-10 | 2012-12-19 | 湖北声荣环保节能科技有限公司 | Multi-function high-efficiency gasoline combustion improver and preparation method thereof |
| CN101851535A (en) * | 2010-06-10 | 2010-10-06 | 湖北声荣环保节能科技有限公司 | Multi-function high-efficiency gasoline combustion improver and preparation method thereof |
| CN102373101B (en) * | 2010-08-20 | 2014-07-02 | 中氢联合能源科技（北京）有限公司 | High-cleaning aged fuel |
| CN102373101A (en) * | 2010-08-20 | 2012-03-14 | 白玉林 | High-cleaning aged fuel |
| CN102399601A (en) * | 2010-09-17 | 2012-04-04 | 东莞市智造生物科技有限公司 | High-cleanliness methanol gasoline |
| CN102399601B (en) * | 2010-09-17 | 2014-05-21 | 东莞市智造生物科技有限公司 | High-cleanliness methanol gasoline |
| CN102676241A (en) * | 2012-05-31 | 2012-09-19 | 龙晓群 | Synthetic gasoline and preparation method thereof |
| CN103571538B (en) * | 2012-07-30 | 2016-07-06 | 通用电气公司 | The method reducing the acid corrosion of oil |
| CN103571538A (en) * | 2012-07-30 | 2014-02-12 | 通用电气公司 | Method for reducing acid corrosion to oil |
| CN102911752A (en) * | 2012-11-08 | 2013-02-06 | 许建忠 | Methanol gasoline multipurpose additive and application thereof |
| CN102911752B (en) * | 2012-11-08 | 2014-09-03 | 许建忠 | Methanol gasoline multipurpose additive and application thereof |
| CN102977935B (en) * | 2012-12-12 | 2015-02-25 | 孙琪 | Methanol environment-friendly gasoline |
| CN102977935A (en) * | 2012-12-12 | 2013-03-20 | 孙琪 | Methanol environment-friendly gasoline |
| CN103396840A (en) * | 2013-06-28 | 2013-11-20 | 江苏巨境新能源科技有限公司 | Environment-friendly methanol gasoline |
| CN103361128B (en) * | 2013-07-24 | 2016-01-20 | 杨成山 | A kind of Vehicular methanol petrol |
| CN103361128A (en) * | 2013-07-24 | 2013-10-23 | 杨成山 | Methanol gasoline for vehicles |
| CN104694190A (en) * | 2014-09-26 | 2015-06-10 | 广西绿球新科技开发有限公司 | Hydrogen-enriched environment-protective fuel gas and preparation method of hydrogen-enriched environment-protective fuel gas |
| CN104726149A (en) * | 2015-02-07 | 2015-06-24 | 兰州燚能生物科技有限责任公司 | Bio-based methanol gasoline composite auxiliary and bio-based high-proportion methanol gasoline |
| CN106190374A (en) * | 2016-08-23 | 2016-12-07 | 广西东奇能源技术有限公司 | Alcohol-based fuel additive |
| CN106701219A (en) * | 2016-12-26 | 2017-05-24 | 寇延华 | Navigation alcohol fuel combustion-supporting additive for automobile and manufacturing method thereof |
| CN107057783A (en) * | 2016-12-26 | 2017-08-18 | 寇延华 | A kind of automobile-used boat anti-choke additive of alcohol ate and preparation method |
| CN107245354A (en) * | 2016-12-26 | 2017-10-13 | 寇延华 | A kind of automobile-used EPM35 boat alcohol gasoline and preparation method |
| CN108913236A (en) * | 2018-07-11 | 2018-11-30 | 李永峰 | A kind of new automobile fuel cleaning additive and preparation method thereof |
| CN108929727A (en) * | 2018-07-18 | 2018-12-04 | 宁波蒙曼生物科技有限公司 | A kind of coal-based methanol gasoline and its preparation method and application of environment-friendly type purifying |
| CN110157497A (en) * | 2019-04-19 | 2019-08-23 | 寇延华 | A kind of automobile-used EPM55 boat alcohol fuel and production method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101343574A (en) | Formulation process for synthesis of gasoline with methanol | |
| CN102559297A (en) | Composite gasoline and diesel oil with high energy-saving environmental protection used for vehicles | |
| CN101220301A (en) | Methanol gasoline fuel and process for fuel production | |
| CN101070501A (en) | Energy-saving environment-protective fuel-oil compounding agent | |
| CN102031163A (en) | Ethanol gasoline composite additive and preparation method thereof | |
| CN101024788A (en) | Methanol gasoline modified alcohol additive | |
| CN102260548A (en) | Methanol gasoline and preparation method thereof | |
| CN104178231B (en) | High-flash-point alcohol ether diesel oil | |
| CN101544915A (en) | Automobile-used methanol-based clean fuel and preparation method thereof | |
| CN104164258A (en) | Alcohol-based biological fuel oil by taking swill-cooked dirty oil as raw material | |
| CN103695049A (en) | Automotive methanol gasoline M40-M85 and preparation method thereof | |
| CN103194277A (en) | CRX gasoline efficiency-enhancing emission-reducing additive | |
| CN102559294B (en) | Alcohol ether diesel oil | |
| CN101914398A (en) | Methanol gasoline additive for vehicles and preparation method thereof | |
| CN100577777C (en) | Alcohol ether substituted clean fuel for automobile | |
| CN102899099A (en) | Alcohol ether gasoline for new energy vehicles | |
| CN101544916B (en) | Automobile-used methanol and ethanol-based clean fuel additive and preparation method thereof | |
| CN101760258B (en) | Component oil capable of reducing saturated vapor pressure of methanol gasoline | |
| CN101195769A (en) | Low carbon mixture alcohol gasoline | |
| CN109321288A (en) | A kind of automobile-used another name for gasoline and its preparation method | |
| CN102899101A (en) | Methanol gasoline | |
| CN103980960B (en) | Environmental protection composite gasoline | |
| CN102533356A (en) | Mixed fuel oil with energy-saving and environmental friendliness for vehicle | |
| CN102260546B (en) | Biological methanol large-proportion alternative diesel and preparation method thereof | |
| CN107099347B (en) | A kind of ether diesel oil of clean and environmental protection and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20090114 |