CN103361128A - Methanol gasoline for vehicles - Google Patents
Methanol gasoline for vehicles Download PDFInfo
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- CN103361128A CN103361128A CN2013103124251A CN201310312425A CN103361128A CN 103361128 A CN103361128 A CN 103361128A CN 2013103124251 A CN2013103124251 A CN 2013103124251A CN 201310312425 A CN201310312425 A CN 201310312425A CN 103361128 A CN103361128 A CN 103361128A
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- Prior art keywords
- gasoline
- methanol
- additive
- agent
- raw material
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 225
- 239000003502 gasoline Substances 0.000 title claims abstract description 55
- 239000000654 additive Substances 0.000 claims abstract description 33
- 230000000996 additive effect Effects 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 25
- 239000000314 lubricant Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 26
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 22
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 22
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical group C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 13
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
- JBTHDAVBDKKSRW-UHFFFAOYSA-N chembl1552233 Chemical compound CC1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 JBTHDAVBDKKSRW-UHFFFAOYSA-N 0.000 claims description 12
- 229940073450 sudan red Drugs 0.000 claims description 12
- ZFAKTZXUUNBLEB-UHFFFAOYSA-N dicyclohexylazanium;nitrite Chemical compound [O-]N=O.C1CCCCC1[NH2+]C1CCCCC1 ZFAKTZXUUNBLEB-UHFFFAOYSA-N 0.000 claims description 11
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims description 10
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 10
- KAJRUHJCBCZULP-UHFFFAOYSA-N 1-cyclohepta-1,3-dien-1-ylcyclohepta-1,3-diene Chemical compound C1CCC=CC=C1C1=CC=CCCC1 KAJRUHJCBCZULP-UHFFFAOYSA-N 0.000 claims description 9
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical compound CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- ZVHAANQOQZVVFD-UHFFFAOYSA-N 5-methylhexan-1-ol Chemical compound CC(C)CCCCO ZVHAANQOQZVVFD-UHFFFAOYSA-N 0.000 claims description 5
- 235000013773 glyceryl triacetate Nutrition 0.000 claims description 5
- 239000001087 glyceryl triacetate Substances 0.000 claims description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 5
- 229920002552 poly(isobornyl acrylate) polymer Polymers 0.000 claims description 5
- 229960002622 triacetin Drugs 0.000 claims description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical class NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- 229920002367 Polyisobutene Polymers 0.000 claims description 4
- SNCZNSNPXMPCGN-UHFFFAOYSA-N butanediamide Chemical compound NC(=O)CCC(N)=O SNCZNSNPXMPCGN-UHFFFAOYSA-N 0.000 claims description 4
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
- UZUXFDNZZXKBTO-UHFFFAOYSA-N cyclohexa-1,3-diene nickel Chemical compound [Ni].C1=CC=CCC1 UZUXFDNZZXKBTO-UHFFFAOYSA-N 0.000 claims description 3
- GUIDQJMMEZDOIW-UHFFFAOYSA-N cyclohexa-1,3-diene;iron Chemical compound [Fe].C1CC=CC=C1 GUIDQJMMEZDOIW-UHFFFAOYSA-N 0.000 claims description 3
- NQLVCAVEDIGMMW-UHFFFAOYSA-N cyclopenta-1,3-diene;cyclopentane;nickel Chemical group [Ni].C=1C=C[CH-]C=1.[CH-]1[CH-][CH-][CH-][CH-]1 NQLVCAVEDIGMMW-UHFFFAOYSA-N 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 239000006079 antiknock agent Substances 0.000 abstract 2
- 239000012459 cleaning agent Substances 0.000 abstract 2
- 239000006184 cosolvent Substances 0.000 abstract 2
- 239000003755 preservative agent Substances 0.000 abstract 2
- 230000002335 preservative effect Effects 0.000 abstract 2
- 238000009776 industrial production Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 208000019901 Anxiety disease Diseases 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000036642 wellbeing Effects 0.000 description 1
Abstract
The invention relates to methanol gasoline for vehicles. The methanol gasoline for the vehicles comprises the following raw materials: by volume ratio, 15-100 of methanol, 0-85 of gasoline, 1-2 of an additive. The additive comprises the following components: by volume ratio, 4-10 of a cosolvent, 50-70 of an antiknock agent, 5-20 of a lubricant, 1-10 of a preservative, 3-15 of a cleaning agent, 1-8 of a combustion improver and 1-8 of an anti-vapor-lock agent. The methanol gasoline for the vehicles has good mutual solubility due to the addition of the cosolvent. Due to the addition of the antiknock agent, the lubricant, the preservative, the cleaning agent, the combustion improver and the anti-vapor-lock agent, the methanol gasoline for the vehicles can prevent oxidation corrosion of metal parts and wearing of cylinders, and has the advantages of strong dynamic property, full combustion, high antiknock property, no vapor lock and the like. Because the main raw materials are the gasoline and the methanol and cost of the raw materials is low, the methanol gasoline for the vehicles is convenient for industrial production.
Description
Technical field
The present invention relates to energy technology field, relate in particular to a kind of Vehicular methanol petrol.
Background technology
The world today is faced with petroleum-based energy crisis and environmental pollution two large problems, and oneself becomes the important factor that affects China and even world economy and social development the energy and environment problem.Therefore, actively seek and develop the cardinal task that clean energy has become various countries.Change oil shortage, with serious pollution unique method, reduce exactly the dependence to oil, developing green high-efficiency cleaning substitute energy.
China promotes the use of methanol gasoline, can directly substitute regular gasoline, alleviates the situation of gasoline anxiety, because the methyl alcohol in the methanol gasoline is a kind of energy, is again modifying agent and the green oxygenation agent of gasoline quality.Because methyl alcohol contains Sauerstoffatom, and gasoline is fully burnt, and can effectively reduce more than 50% of motor vehicle exhaust obnoxious flavour total amount, is conducive to environment protection.So methanol gasoline environmental protection, cost are low, saving resource is saved foreign exchange and is promoted the well-being of mankind, and the market competitiveness is strong, has fabulous development prospect.
At present, in the methanol gasoline of selling on the market, because the restriction of the physico-chemical property of methanol gasoline more or less all some problems can occur, poor etc. such as: erosion resistance, anti-knocking property, oilness, anti-vapour lock.
Summary of the invention
The technical problem to be solved in the present invention is: overcome the problems of the prior art, a kind of Vehicular methanol petrol is provided.
The technical solution adopted for the present invention to solve the technical problems is: a kind of Vehicular methanol petrol, by following raw material by volume proportioning form:
Methyl alcohol 15-100
Gasoline 0-85
Additive 1-2;
Each component volume proportion is in the described additive:
Solubility promoter 4-10
Octane promoter 50-70
Lubricant 5-20
Sanitas 1-10
Sanitising agent 3-15
Ignition dope accounts for 1-8
Anti-vapour lock agent 1-8.
Particularly, described raw material by volume proportioning consists of methyl alcohol 15, gasoline 85, additive 1.
Particularly, described raw material by volume proportioning consists of methyl alcohol 50, gasoline 50, additive 1.
Particularly, described raw material by volume proportioning consists of methyl alcohol 85, gasoline 15, additive 1.
Particularly, described raw material by volume proportioning consists of methyl alcohol 100, gasoline 0, additive 2.
Particularly, described gasoline is GB 90# or 93# white gasoline.
Particularly, described solubility promoter is one or more of Virahol, isopropylcarbinol, primary isoamyl alcohol, isohexyl alcohol, iso-heptanol.
Particularly, described octane promoter is the mixture of Resorcinol and Virahol.
Particularly, described lubricant is triphenylphosphate or isopropylated triphenyl phosphates.
Particularly, described sanitas is the mixture of any one or two kinds in dicyclohexyl amine nitrite and Virahol, dibutylamine, the triacetin.
Particularly, described sanitising agent is one or more in amino amides, polyisobutene succinic diamide, PIBA, polyisobutenyl succimide, the polyetheramine.
Particularly, described ignition dope is dicyclopentadienylnickel, Dicyclopentadiene (DCPD) iron, Dicyclopentadiene (DCPD) palladium, two cyclohexadiene iron, two cyclohexadiene nickel, two cyclohexadiene palladiums, bicycloheptadiene iron, bicycloheptadiene nickel, bicycloheptadiene palladium.
Particularly, described anti-vapour lock agent is the anti-vapour lock agent of commercial methanol.
Particularly, contain Sudan red in the described methanol gasoline, described Sudan red content is 10-50mg/Kg.
The invention has the beneficial effects as follows: a kind of Vehicular methanol petrol provided by the invention, the adding of solubility promoter makes methanol gasoline have good mutual solubility, because the adding of octane promoter, lubricant, sanitas, sanitising agent, ignition dope and anti-vapour lock agent, so that methanol gasoline of the present invention can prevent the oxidation corrosion of metal parts and the wearing and tearing of cylinder, dynamic property is strong, sufficient combustion, high anti-knocking property and without advantages such as vapour locks, because raw material mainly is gasoline and methyl alcohol, raw materials cost is low, is convenient to suitability for industrialized production.
Embodiment
Embodiment 1
A kind of Vehicular methanol petrol, by following raw material by volume proportioning form:
Methyl alcohol 15
GB 90# white gasoline 85
Additive 1;
Each component volume proportion is in the additive:
Virahol 4
The mixture of Resorcinol and Virahol (volume ratio is 5: 5) 65
Triphenylphosphate 14
The mixture of dicyclohexyl amine nitrite and dibutylamine, triacetin (arbitrary proportion) 1
Polyisobutene succinic diamide 3
Dicyclopentadiene (DCPD) iron 8
The anti-vapour lock agent 5 of commercial methanol
Sudan red 10mg/Kg
Embodiment 2
A kind of Vehicular methanol petrol, by following raw material by volume proportioning form:
Methyl alcohol 85
GB 90# white gasoline 15
Additive 1;
Each component volume proportion is in the additive:
The mixture of isopropylcarbinol and isohexyl alcohol (arbitrary proportion) 10
Resorcinol and Virahol (volume ratio is 2: 8) 70
Isopropylated triphenyl phosphates 5
The mixture of dicyclohexyl amine nitrite and Virahol, dibutylamine (arbitrary proportion) 10
The mixture 3 of amino amides and polyisobutene succinic diamide
Dicyclopentadienylnickel 1
The anti-vapour lock agent 1 of commercial methanol
Embodiment 3
A kind of Vehicular methanol petrol, by following raw material by volume proportioning form:
Methyl alcohol 50
GB 90# white gasoline 50
Additive 1;
Each component volume proportion is in the additive:
The mixture of primary isoamyl alcohol and isohexyl alcohol (arbitrary proportion) 6
The mixture of Resorcinol and Virahol (volume ratio is 7: 3) 50
Isopropylated triphenyl phosphates 20
The mixture of dicyclohexyl amine nitrite and Virahol (arbitrary proportion) 7
Polyisobutenyl succimide 8
Dicyclopentadiene (DCPD) palladium 1
The anti-vapour lock agent 8 of commercial methanol
Sudan red 50mg/Kg
Embodiment 4
A kind of Vehicular methanol petrol, by following raw material by volume proportioning form:
Methyl alcohol 100
GB 90# white gasoline 0
Additive 2;
Each component volume proportion is in the additive:
Iso-heptanol 8
The mixture of Resorcinol and Virahol (volume ratio is 4: 6) 55
Triphenylphosphate 5
The mixture of dicyclohexyl amine nitrite and triacetin (arbitrary proportion) 10
The mixture of PIBA and polyisobutenyl succimide (arbitrary proportion) 15
Bicycloheptadiene palladium 6
The anti-vapour lock agent 1 of commercial methanol
Sudan red 20mg/Kg
Embodiment 5
A kind of Vehicular methanol petrol, by following raw material by volume proportioning form:
Methyl alcohol 85
GB 93# white gasoline 15
Additive 1;
Each component volume proportion is in the additive:
The mixture of primary isoamyl alcohol, isohexyl alcohol and iso-heptanol (arbitrary proportion) 4
The mixture of Resorcinol and Virahol (volume ratio is 9: 1) 65
Isopropylated triphenyl phosphates 6
The mixture of dicyclohexyl amine nitrite and Virahol (arbitrary proportion) 7
PIBA 9
Bicycloheptadiene nickel 7
The anti-vapour lock agent 2 of commercial methanol
Sudan red 45mg/Kg
Embodiment 6
A kind of Vehicular methanol petrol, by following raw material by volume proportioning form:
Methyl alcohol 50
GB 93# white gasoline 50
Additive 1;
Each component volume proportion is in the additive:
Virahol 6
The mixture of Resorcinol and Virahol (volume ratio is 5: 5) 65
Triphenylphosphate 10
The mixture of dicyclohexyl amine nitrite and Virahol (arbitrary proportion) 5
Amino amides 5
Two cyclohexadiene iron 5
The anti-vapour lock agent 4 of commercial methanol
Sudan red 45mg/Kg
Embodiment 7
A kind of Vehicular methanol petrol, by following raw material by volume proportioning form:
Methyl alcohol 100
GB 93# white gasoline 0
Additive 2;
Each component volume proportion is in the additive:
Iso-heptanol 10
The mixture of Resorcinol and Virahol (volume ratio is 2: 8) 55
Triphenylphosphate 14
The mixture of dicyclohexyl amine nitrite and triacetin (arbitrary proportion) 10
Polyisobutenyl succimide 4
Bicycloheptadiene iron 3
The anti-vapour lock agent 4 of commercial methanol
Sudan red 45mg/Kg
Embodiment 8
A kind of Vehicular methanol petrol, by following raw material by volume proportioning form:
Methyl alcohol 15
GB 93# white gasoline 85
Additive 1;
Each component volume proportion is in the additive:
Isopropylcarbinol 8
The mixture of Resorcinol and Virahol (volume ratio is 1: 9) 60
Triphenylphosphate 15
The mixture of dicyclohexyl amine nitrite and dibutylamine (arbitrary proportion) 10
PIBA 3
Two cyclohexadiene nickel 2
The anti-vapour lock agent 2 of commercial methanol
Sudan red 45mg/Kg
Embodiment 9
A kind of Vehicular methanol petrol, by following raw material by volume proportioning form:
Methyl alcohol 85
GB 93# white gasoline 15
Additive 1;
Each component volume proportion is in the additive:
Isohexyl alcohol 6
The mixture of Resorcinol and Virahol (volume ratio is 4: 6) 65
Isopropylated triphenyl phosphates 10
The mixture of dicyclohexyl amine nitrite and Virahol (arbitrary proportion) 6
Polyetheramine 5
Two cyclohexadiene palladiums 4
The anti-vapour lock agent 4 of commercial methanol
Sudan red 45mg/Kg
Embodiment 10
The method of the methanol gasoline of a kind of embodiment of preparation 1-9 is: add successively methyl alcohol, gasoline and additive by described proportioning raw materials, fully stir 1-2h in pressurized vessel after, its colour-change is observed in sampling, when it becomes transparent and homogeneous, can stop to stir, obtain the finished product methanol gasoline.
Take above-mentioned foundation desirable embodiment of the present invention as enlightenment, by above-mentioned description, the relevant staff can in the scope that does not depart from this invention technological thought, carry out various change and modification fully.The technical scope of this invention is not limited to the content on the specification sheets, must determine its technical scope according to the claim scope.
Claims (8)
1. Vehicular methanol petrol, it is characterized in that by following raw material by volume proportioning form:
Methyl alcohol 15-100
Gasoline 0-85
Additive 1-2;
Each component volume proportion is in the described additive:
Solubility promoter 4-10
Octane promoter 50-70
Lubricant 5-20
Sanitas 1-10
Sanitising agent 3-15
Ignition dope accounts for 1-8
Anti-vapour lock agent 1-8.
2. a kind of methanol gasoline as claimed in claim 1, it is characterized in that: described raw material by volume proportioning consists of methyl alcohol 15, gasoline 85, additive 1.
3. a kind of methanol gasoline as claimed in claim 1, it is characterized in that: described raw material by volume proportioning consists of methyl alcohol 50, gasoline 50, additive 1.
4. a kind of methanol gasoline as claimed in claim 1, it is characterized in that: described raw material by volume proportioning consists of methyl alcohol 85, gasoline 15, additive 1.
5. a kind of methanol gasoline as claimed in claim 1, it is characterized in that: described raw material by volume proportioning consists of methyl alcohol 100, gasoline 0, additive 2.
6. such as each the described a kind of methanol gasoline among the claim 1-4, it is characterized in that: described gasoline is GB 90# or 93# white gasoline.
7. a kind of methanol gasoline as claimed in claim 1 is characterized in that: described solubility promoter is one or more of Virahol, isopropylcarbinol, primary isoamyl alcohol, isohexyl alcohol, iso-heptanol; Described octane promoter is the mixture of Resorcinol and Virahol; Described lubricant is triphenylphosphate or isopropylated triphenyl phosphates; Described sanitas is the mixture of any one or two kinds in dicyclohexyl amine nitrite and Virahol, dibutylamine, the triacetin; Described sanitising agent is one or more in amino amides, polyisobutene succinic diamide, PIBA, polyisobutenyl succimide, the polyetheramine; Described ignition dope is dicyclopentadienylnickel, Dicyclopentadiene (DCPD) iron, Dicyclopentadiene (DCPD) palladium, two cyclohexadiene iron, two cyclohexadiene nickel, two cyclohexadiene palladiums, bicycloheptadiene iron, bicycloheptadiene nickel, bicycloheptadiene palladium; Described anti-vapour lock agent is the anti-vapour lock agent of commercial methanol.
8. such as each the described a kind of methanol gasoline among the claim 1-5, it is characterized in that: contain Sudan red in the described methanol gasoline, described Sudan red content is 10-50mg/Kg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310312425.1A CN103361128B (en) | 2013-07-24 | 2013-07-24 | A kind of Vehicular methanol petrol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310312425.1A CN103361128B (en) | 2013-07-24 | 2013-07-24 | A kind of Vehicular methanol petrol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103361128A true CN103361128A (en) | 2013-10-23 |
| CN103361128B CN103361128B (en) | 2016-01-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310312425.1A Expired - Fee Related CN103361128B (en) | 2013-07-24 | 2013-07-24 | A kind of Vehicular methanol petrol |
Country Status (1)
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Cited By (8)
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| CN106350136A (en) * | 2016-09-30 | 2017-01-25 | 广西东奇能源技术有限公司 | Multifunctional automotive fuel additive |
| CN106350135A (en) * | 2016-09-30 | 2017-01-25 | 广西东奇能源技术有限公司 | Automotive fuel additive |
| CN112708480A (en) * | 2020-12-23 | 2021-04-27 | 重庆山玖能源科技发展有限公司 | Methanol gasoline for vehicle |
| CN114717028A (en) * | 2021-07-06 | 2022-07-08 | 湖北清合新能源科技有限公司 | High-stability methanol gasoline and preparation method thereof |
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| CN103785291A (en) * | 2014-01-22 | 2014-05-14 | 天津清正然化工科技有限公司 | Automobile exhaust purifying agent and preparation method thereof |
| CN103785291B (en) * | 2014-01-22 | 2015-09-16 | 天津清正然化工科技有限公司 | A kind of car tail gas purificant and preparation method thereof |
| CN103965976A (en) * | 2014-03-25 | 2014-08-06 | 宁夏宝塔石化科技实业发展有限公司 | Technological formula of high-proportion methanol gasoline compound additive |
| CN104099147A (en) * | 2014-07-28 | 2014-10-15 | 周晓兰 | Novel nano welding-cutting gas |
| CN104987899A (en) * | 2015-06-08 | 2015-10-21 | 中润油新能源股份有限公司 | Non-pollution low-emission methanol gasoline and preparation method thereof |
| CN106350136A (en) * | 2016-09-30 | 2017-01-25 | 广西东奇能源技术有限公司 | Multifunctional automotive fuel additive |
| CN106350135A (en) * | 2016-09-30 | 2017-01-25 | 广西东奇能源技术有限公司 | Automotive fuel additive |
| CN112708480A (en) * | 2020-12-23 | 2021-04-27 | 重庆山玖能源科技发展有限公司 | Methanol gasoline for vehicle |
| CN114717028A (en) * | 2021-07-06 | 2022-07-08 | 湖北清合新能源科技有限公司 | High-stability methanol gasoline and preparation method thereof |
| CN114717028B (en) * | 2021-07-06 | 2023-11-10 | 湖北鑫悦兴能源有限公司 | High-stability methanol gasoline and preparation method thereof |
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