CN109054913A - The methanol diesel-oil of methanol diesel fuel additive and its preparation based on yeast grease - Google Patents
The methanol diesel-oil of methanol diesel fuel additive and its preparation based on yeast grease Download PDFInfo
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- CN109054913A CN109054913A CN201811038146.XA CN201811038146A CN109054913A CN 109054913 A CN109054913 A CN 109054913A CN 201811038146 A CN201811038146 A CN 201811038146A CN 109054913 A CN109054913 A CN 109054913A
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Abstract
The present invention relates to a kind of methanol diesel fuel additive based on yeast grease and its methanol diesel-oils of preparation.Yeast grease is obtained by the culture medium that microbial fermentation gutter oil, wastewater of starch factory and blackstrap are substrate；Using the yeast grease as major ingredient, prepare methanol diesel fuel additive, the additive presses volume unit percentages, containing anti-layering hydrotropy component, the anti-swelling component of anticorrosion, the clear glial component of carbon remover, mention flash-point pour point depression point component, carry make every effort to promote combustion components, above-mentioned function ingredients stir evenly at normal temperature obtains methanol diesel fuel additive；The methanol diesel-oil that a kind of Cetane number is high, dynamic property is strong, flash-point is high, condensation point is low is prepared by anhydrous methanol or higher alcohols 10 ~ 30%, diesel oil 70 ~ 90% and above-mentioned additive 0.1 ~ 0.5%.The present invention solves the emission pollution problem of gutter oil, wastewater of starch factory and blackstrap, while also solving the problems such as domestic product oil in short supply, methanol excess capacity, cannot efficiently use.
Description
Technical field
The present invention relates to alcohols substitute fuel field, specifically a kind of methanol diesel fuel additive based on yeast grease and its
The methanol diesel-oil of preparation.
Background technique
Aalcohols fuel is as a kind of cleaning, cheap, efficient fossil fuel substitute, with its cheap cost and abundant
Source is increasingly taken seriously, it is considered to be the most promising vehicle fuel in substitute fuel field.U.S.'s Nobel chemistry Prize obtains
It obtains person George A Aura to think by studying for a long period of time, " methanol economy " is used as alternative fuel, and the mankind is enable to be no longer dependent on
The increasingly oil and natural gas resource of reduction, this point especially meet China's fossil resources status increasingly in short supply.Methanol is oxygen-containing
Amount accounts for 50%, and inflammability limit is wide compared with diesel oil, and burning velocity is high, advantageously reduces granular material discharged；Methanol boiling point is lower than diesel oil,
Mixed Daqu fast speed, and it is relatively uniform, be conducive to completely burned；Methanol chemically correct fuel diesel oil is low, fires in engine
Burning is more complete, can be effectively reduced the discharge of greenhouse gases；But methanol as alternative fuel for diesel engine have it is following
Unfavorable factor: (1) being polar substances due to containing hydroxyl in methanol, so methanol and diesel oil mixing are extremely difficult, and easily
The phenomenon that being layered, storage stability are poor；(2) flash-point of methanol is only 12 DEG C, more much lower than 55 DEG C of Flash Point of Diesel, also
It is after saying and methylating in diesel oil, the flash-point of fuel combination can be rapidly reduced near the flash-point of methanol (12 DEG C), make to mix
Fuel becomes extremely unstable, meets the possibility that open fire just has explosion, and there are serious transport and storage are dangerous；(3) vaporization of methanol
Latent heat is big, and the operating condition when cooling effect that the high latent heat of vaporization generates is to low engine speed, underload can have an adverse effect；(4)
The viscosity of methanol is low, poor lubricity, directly fuel injection system original using diesel engine when, will cause system wear, even
The failures such as stuck, to influence the reliability and durability of engine；(5) burning point of methanol (> 200 more much higher than diesel ignition point
DEG C), therefore methanol is difficult to compression ignition, the ability of spontaneous ignition is poor；(6) the saturated vapor pressure ratio diesel oil of methanol is high, therefore holds very much
Easily there is the phenomenon that high temperature vapour lock；(7) calorific value of methanol is only the 43.6% of diesel oil, therefore the introducing of methanol will necessarily reduce combustion
The calorific value of material, to significantly reduce the power and torque of engine；(8) Cetane number of methanol is lower than diesel oil, and the latent heat of vaporization
Again higher than diesel oil, these mix the thermal efficiency and economy for burning methanol when all directly reducing engine low load.It can be seen that first
The poor, vapour lock of dissolving each other existing for alcohol itself is high, flash-point is low, calorific value is low, seriously corroded, it is less economical the problems such as be only and restrict methanol bavin
The key factor of fry dried food ingredients exhibition.
In order to solve the above problem of methanol fuel appearance, occur many novel patented technologies in recent years.The patent No.
For CN102161922A, disclose a kind of " methanol diesel fuel additive and methanol diesel-oil ", used with toxicity and flash-point it is non-
Often low acetone and toluene, and additive amount > 10%, dosage is very big, and cost is very high；Patent No. CN102229820A,
A kind of " denatured methyl alcohol diesel oil and its dissolve technique " is disclosed, polymethoxy first contracting ether has been used, has in fact been exactly gathering for dimethoxym ethane
Object is closed, the substance prohibited and added in diesel oil is belonged to；Patent No. CN1948443A discloses one kind " instead of diesel oil
Fuel and its preparation method and application ", described in the preferred sodium hydroxide of antifreezing agent, sodium hydroxide is inorganic strong alkali, to gold
Accessory has very strong corrosivity, while being strong acid and strong base salt again, has extraordinary electric conductivity, thus can increase considerably
The conductivity of oil product accelerates the electrochemical corrosion of oil piping system；Patent No. CN101955814A discloses a kind of " dimethyl ether
Methanol-diesel mixed fuel and preparation method thereof ", used at high cost, flash-point is low, easy inhalation poisoning, complex manufacturing technology, often
The storing dangerous dimethyl ether of temperature is as the main material for improving power；Patent No. CN101709234A discloses a kind of " methanol bavin
Oily compound additive and preparation method ", but the patent does not refer to the flash temperature of the embodiment in the content, fundamentally
Again without solving the problems, such as that methanol diesel-oil flash-point is low；Patent No. CN103911191A discloses a kind of " procetane
And preparation method thereof ", in the embodiment described, additive amount is up to 17%, but condensation point and cold filter plugging point relatively conventional 0#Diesel oil
It compares, does not reduce not only, slightly improve instead, it is seen that not only cost is very high but also produces little effect for it；Patent No.
CN107099345A discloses a kind of " biological alcohol-based fuel oil hydrotropy solubilizer ", Patent No. CN106947555A, discloses one
Kind " biological alcohol-based fuel power heat value agent ", Patent No. CN106906014A disclose a kind of " biological alcohol-based light Fuel sudden strain of a muscle
Point enhancer ", Patent No. CN107338114A, disclose a kind of " biological alcohol-based light Fuel pour point depression rheological agent ", above-mentioned four
Item patent is thorough to all kinds of case studies of alcohol-based fuel, and principle explanation is detailed, and solution is clear, but it is sour with yeast fat
Complex manufacturing technology, and the precious resources such as all kinds of plant chimney stalks, waste oil, waste saccharide liquid cannot be efficiently used turn waste into wealth, thus deposit
In process costs height, the low defect of trade waste utilization rate；Patent No. CN107739632A discloses a kind of " utilize micro-
The method and its application of methanol gasoline additive are prepared based on biofermentation trench oil product ", in the embodiment just
Pentane, hexamethylene, methyl formate, ethyl acetate, dimethyl carbonate etc. are at low-flash component is belonged to, since diesel oil is to flash-point
Particular/special requirement (is not less than 55 DEG C), and the flash-point of product oil follows " the minimum principle of flash-point ", thus the patent cannot refer to.By
This is as it can be seen that research and develop that a kind of dosage is few, at low cost, effect is good, has biodegradability, without endangering ingredient and electrolyte, no
The novel environment friendly methanol diesel fuel additive of secondary pollution can be caused to become extremely urgent environment.
Summary of the invention
The technical problem to be solved by the present invention is providing a kind of clear with anti-layering hydrotropy, the anti-swelling of anticorrosion, carbon remover
Colloid mentions flash-point pour point depression point, raising power promotion burning and other effects, effectively solves methanol diesel-oil and prepares, stores, promoted the use of
The methanol diesel fuel additive of all kinds of technical problems in journey；The invention solves another technical problem be: provide one kind 16
The methanol diesel-oil that alkane value is high, dynamic property is strong, flash-point is high, condensation point is low.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of methanol diesel fuel additive based on yeast grease, the yeast grease obtain as follows:
By the long-term domesticated strain HT-925 corium trichosporon bacteria in laboratory in constant temperature incubation on YPD culture medium, the corium hair spore
The deposit number of daughter bacteria: CGMCC 14875；Thallus after culture is eluted with physiological saline, obtaining concentration is 107~108A/ml
Bacteria suspension；By in the seed culture medium of above-mentioned bacterial suspension inoculation to glucose, yeast powder and urea composition, enrichment culture is obtained
Seed liquor；Seed liquor is inoculated into the fermentation medium based on gutter oil, wastewater of starch factory and blackstrap, through 25 ~ 32
DEG C, dissolved oxygen 20 ~ 60% fermented and cultured 5 ~ 7 days, obtains yeast grease；
It is grouped as by volume unit percentages by following functions group based on the methanol diesel fuel additive of the yeast grease: anti-
It is layered hydrotropy component 20 ~ 30%, the anti-swelling component 5 ~ 10% of anticorrosion, the clear glial component 5 ~ 10% of carbon remover proposes flash-point pour point depression point group
Divide 20 ~ 30%, combustion components 30 ~ 40% are made every effort to promote in actuating；
The anti-layering hydrotropy component, composed of the following components by volume unit percentages: yeast grease 10 ~ 15%, it is different
The mixture 4 ~ 9% of octanol or n-octyl alcohol and n-dodecanol 1:2, epoxy aliphatic acid methyl ester or fatty acid methyl ester and epoxyfatty acid
The mixture 4 ~ 9% of methyl esters 1:1；
The anti-swelling component of the anticorrosion, it is composed of the following components by volume unit percentages: yeast grease 1 ~ 2%, α-
The mixture 2 ~ 4% of three monooctyl ester 1:1 of methyl naphthalene or adjacent phthalandione tributyl and adjacent phthalandione, cyclohexanone or cyclohexanone and alkyl salicylate
The mixture 2 ~ 4% of 1:1；
The clear glial component of the carbon remover, it is composed of the following components by volume unit percentages: yeast grease 1 ~ 2%, second
The mixture 2 ~ 4% of the mixture 2 ~ 4% of glycol or ethylene glycol and polyethylene glycol 1:2, n-butanol or sec-butyl alcohol and hexylene glycol 1:1；
It is described to propose flash-point pour point depression point component, composed of the following components by volume unit percentages: yeast grease 10 ~ 15%,
Palm oil and the mixture of cottonseed oil 1:1 or the mixture 4 ~ 9% of butyl hexanoate and fatty glyceride 1:1, maleate and richness
The mixture 4 ~ 9% of fumaric ester copolymer or EVA and WHP1:1；
Combustion components are made every effort to promote in the actuating, composed of the following components by volume unit percentages: yeast grease 5 ~ 10%, nitre
The mixture or ten diester of nitric acid ring and 3- methyl-3-nitro -2- butyl nitrate 1:3 of sour cyclohexyl and isooctyl ester nitrate 1:1
Mixture 10 ~ 15%, the mixture or di-tert-butyl peroxide of 2- nitropropane and nitrobutane 2:1 and heptane peroxidating
The mixture 15 ~ 20% of object 1:3.
A kind of methanol diesel-oil containing the methanol diesel fuel additive, by volume unit percentages, by following components group
At: anhydrous methanol or higher alcohols 10 ~ 30%, diesel oil 70 ~ 90%, methanol diesel fuel additive 0.1 ~ 0.5%；The anhydrous methanol or
Higher alcohols, diesel oil, methanol diesel fuel additive component, are added in stirring container, stir evenly at normal temperature, as methanol bavin
Oil.
Above-mentioned technical proposal is designed based on following principle:
(1) design direction of methanol diesel fuel additive: have the effect of that good anti-layering is dissolved each other various components；There is no corrosion
The problem of with swelling；Oil-soluble is good；Antagonism is not generated between additive；With dispersion colloid, cleaning carbon distribution performance；Significantly mention
High-flash reduces condensation point, promotes power；
(2) design principle of methanol diesel fuel additive: there is biodegradability, secondary pollution will not be caused to environment；Density
It is appropriate, as principle, to be convenient for close to methanol density to carbinol-modified；There is certain universality；There are enough energy values, makes up
Methanol calorific value deficiency problem；Good film-forming property can effectively inhibit the secondary deposition of fuel tank, oil piping system carbon distribution；Manufacture craft letter
Single, dosage is few, low in cost without endangering ingredient and electrolyte；
(3) Design Mechanism of methanol diesel fuel additive: using synergistic effect special between classes of compounds and yeast grease,
Flexible very high interfacial film is formed between all kinds of molecules, by intermolecular active force and microencapsulation principle, is stablized in oil product
Various components；By establishing above-mentioned microemulsified systems, with " microexplosion is theoretical ", the combustion reaction of fuel combination is accelerated, from
And exhaust emissions is improved, play the effect of environmental protection；The foundation of above-mentioned microemulsified systems additionally aids between increasing fuel molecule
Active force, promoted fuel boiling point, improve fuel relative density, reduce fuel saturated vapour pressure, to play raising flash-point
Effect；In addition to this, the foundation of microemulsified systems destroys wax crystalline substance molecular structure, increases wax crystalline substance dispersion degree, thus significantly
Condensation point and cold filter plugging point are reduced, and bounce problem is not present.
The present invention by adopting the above technical scheme, compared with prior art, the beneficial effect is that:
(1) present invention has selected fermentation source of these substances of gutter oil, wastewater of starch factory and blackstrap as yeast grease, becomes useless
Giving up for precious, benefit is energy, efficiently solves emission pollution problem, while opening new way for development and utilization oil prodution industry waste
Diameter；
(2) compared with prior art, dosage is few, at low cost, effect is good, there is biology can drop for methanol diesel fuel additive of the invention
Xie Xing, without endangering ingredient and electrolyte, secondary pollution will not be brought to environment.
(3) methanol diesel fuel additive of the invention, appearance transparent is limpid, and fragrant odour is easily accepted.
(4) methanol diesel-oil of the invention, Cetane number is high, dynamic property is strong, flash-point is high, condensation point is low, has high popularization
Value and extensive market prospects.
(5) present invention prepare it is simple, easy to use, with anti-layering hydrotropy, the anti-swelling of anticorrosion, carbon remover gel resin matter,
Mention flash-point pour point depression point, improve power promotion burning and other effects, to solve to meet during methanol diesel-oil preparation, storage, popularization and use
To technical problem open it is a kind of newly by way of having extensive promotional value.
Specific embodiment
The following describes the present invention in detail with reference to examples, but is not limited to limitation of the invention.
Yeast grease used in following embodiment obtains in the steps below:
(1) strain: strain used is long-term by gutter oil, wastewater of starch factory and blackstrap composite fermentation culture medium in laboratory
Obtained yeast grease superior strain is screened, grease yield is up to 50%, number HT-925, is deposited on November 13rd, 2017
China Committee for Culture Collection of Microorganisms's common micro-organisms center (address: Yard 1, BeiChen xi Road, Chaoyang District, Beijing City 3
Number), deposit number: CGMCC NO .14875, classification naming be corium trichosporon bacteria (Trichosporon dermatis)；
(2) corium trichosporon bacteria actication of culture: is inoculated into the inclined-plane YPD being made of glucose, peptone, yeast powder and agar
Constant temperature incubation on culture medium obtains activated spawn；
(3) prepared by bacteria suspension: activated strain being eluted with physiological saline, obtaining concentration is 107~108The bacterium of a/ml is outstanding
Liquid；
(4) prepared by seed liquor: by above-mentioned bacteria suspension according to 3 ~ 5%(volume unit) it is inoculated by glucose, yeast powder and urea group
At fluid nutrient medium in, 25 ~ 32 DEG C of shaking table cultures for 24 hours, enrichment culture obtain seed liquor；
(5) fermented and cultured: by seed liquor according to 10 ~ 15%(volume unit) it is inoculated into gutter oil, wastewater of starch factory and blackstrap
Based on fermentation medium in, through 25 ~ 32 DEG C, dissolved oxygen 20 ~ 60% fermented and cultured 5 ~ 7 days, obtains fermentation liquid；
(6) it obtains yeast grease: after fermentation, fermentation liquid being collected, is handled through centrifugation, fermentation liquid remnants collect two
Secondary use, the thallus separated and collected and metabolite can be obtained yeast grease through the technical matters processing such as broken, purifying.
Embodiment 1:
1. methanol diesel fuel additive is grouped as by volume unit percentages by following functions group: 20% anti-layering hydrotropy group
Point, the anti-swelling component of 9% anticorrosion, the clear glial component of 6% carbon remover, 30% proposes flash-point pour point depression point component, 35% actuating
Make every effort to promote combustion components；Each component is added in container, and stirring evenly at normal temperature can be obtained transparent, limpid methanol diesel-oil and add
Add agent finished product.
Wherein, anti-layering hydrotropy component, including yeast grease 11%, the mixture 4% of n-octyl alcohol and n-dodecanol 1:2, ring
Oxygen fatty acid methyl ester 5%；The anti-swelling component of anticorrosion, including yeast grease 2%, alpha-methyl-naphthalene 4%, cyclohexanone and alkyl salicylate
The mixture 3% of 1:1；The clear glial component of carbon remover, including yeast grease 1%, the mixture 3% of ethylene glycol and polyethylene glycol 1:2,
N-butanol 2%；Mention flash-point pour point depression point component, including yeast grease 13%, the mixture 8% of palm oil and cottonseed oil 1:1, maleic acid
Ester and fumarate copolymer 9%；Combustion components, including yeast grease 5%, cyclohexyl nitrate and isooctyl ester nitrate 1 are made every effort to promote in actuating:
1 mixture 13%, the mixture 17% of 2- nitropropane and nitrobutane 2:1.
2. methanol diesel-oil, composed of the following components by volume unit percentages: 4% anhydrous methanol, 16% higher alcohols,
80% diesel oil, 0.2% methanol diesel fuel additive, each component is added in stirring container, and stirring evenly can obtain at normal temperature
To methanol diesel-oil product oil.
Embodiment 2:
1. methanol diesel fuel additive is grouped as by volume unit percentages by following functions group: 25% anti-layering hydrotropy group
Point, the anti-swelling component of 6% anticorrosion, the clear glial component of 9% carbon remover, 28% proposes flash-point pour point depression point component, 32% actuating
Make every effort to promote combustion components, each component is added in container, and stirring evenly at normal temperature can be obtained transparent, limpid methanol diesel-oil and add
Add agent finished product.
Wherein, anti-layering hydrotropy component, including yeast grease 12%, the mixture 7% of n-octyl alcohol and n-dodecanol 1:2, rouge
The mixture 6% of fatty acid methyl esters and epoxy aliphatic acid methyl ester 1:1；The anti-swelling component of anticorrosion, including yeast grease 1%, adjacent phthalandione
The mixture 2% of three monooctyl ester 1:1 of tributyl and adjacent phthalandione, the mixture 3% of cyclohexanone and alkyl salicylate 1:1；Carbon remover gel resin
Matter component, including yeast grease 2%, ethylene glycol 3%, the mixture 4% of sec-butyl alcohol and hexylene glycol 1:1；Flash-point pour point depression point component is proposed,
Including yeast grease 11%, the mixture 9% of butyl hexanoate and fatty glyceride 1:1, maleate and fumarate copolymer
8%；Combustion components, including yeast grease 6%, the mixture 11% of cyclohexyl nitrate and isooctyl ester nitrate 1:1, two uncles are made every effort to promote in actuating
The mixture 15% of butylperoxide and heptane peroxide 1:3.
2. methanol diesel-oil, composed of the following components by volume unit percentages: 2% anhydrous methanol, 10% higher alcohols,
88% diesel oil, 0.1% methanol diesel fuel additive, each component is added in stirring container, and stirring evenly can obtain at normal temperature
To methanol diesel-oil product oil.
Embodiment 3:
1. methanol diesel fuel additive is grouped as by volume unit percentages by following functions group: 30% anti-layering hydrotropy group
Point, the anti-swelling component of 6% anticorrosion, the clear glial component of 6% carbon remover, 22% proposes flash-point pour point depression point component, 36% actuating
Make every effort to promote combustion components；Each component is added in container, and stirring evenly at normal temperature can be obtained transparent, limpid methanol diesel-oil and add
Add agent finished product.
Wherein, anti-layering hydrotropy component, including yeast grease 15%, the mixture 9% of n-octyl alcohol and n-dodecanol 1:2, ring
Oxygen fatty acid methyl ester 6%；The anti-swelling component of anticorrosion, including yeast grease 1%, three monooctyl ester 1:1 of adjacent phthalandione tributyl and adjacent phthalandione
Mixture 3%, the mixture 2% of cyclohexanone and alkyl salicylate 1:1；The clear glial component of carbon remover, including yeast grease 1%, second
The mixture 2% of glycol and polyethylene glycol 1:2, n-butanol 3%；Mention flash-point pour point depression point component, including yeast grease 10%, palm oil
With the mixture 5% of cottonseed oil 1:1, the mixture 7% of EVA and WHP1:1；Combustion components, including yeast grease 6% are made every effort to promote in actuating,
The mixture 14% of ten diester of nitric acid ring and 3- methyl-3-nitro -2- butyl nitrate 1:3,2- nitropropane and nitrobutane 2:
1 mixture 16%.
2. methanol diesel-oil, composed of the following components by volume unit percentages: 6% anhydrous methanol, 18% higher alcohols,
76% diesel oil, 0.3% methanol diesel fuel additive, each component is added in stirring container, and stirring evenly can obtain at normal temperature
To methanol diesel-oil product oil.
Embodiment 4:
1. methanol diesel fuel additive is grouped as by volume unit percentages by following functions group: 24% anti-layering hydrotropy group
Point, the anti-swelling component of 9% anticorrosion, the clear glial component of 8% carbon remover, 21% proposes flash-point pour point depression point component, 38% actuating
Make every effort to promote combustion components；Each component is added in container, and stirring evenly at normal temperature can be obtained transparent, limpid methanol diesel-oil and add
Add agent finished product.
Wherein, anti-layering hydrotropy component, including yeast grease 10%, isooctanol 5%, fatty acid methyl ester and epoxyfatty acid first
The mixture 9% of ester 1:1；The anti-swelling component of anticorrosion, including yeast grease 2%, alpha-methyl-naphthalene 4%, cyclohexanone and alkyl salicylate
The mixture 3% of 1:1；The clear glial component of carbon remover, including yeast grease 1%, the mixture 3% of ethylene glycol and polyethylene glycol 1:2,
The mixture 4% of sec-butyl alcohol and hexylene glycol 1:1；Mention flash-point pour point depression point component, including yeast grease 10%, palm oil and cottonseed oil 1:
The mixture 4% of 1 mixture 7%, EVA and WHP1:1；Combustion components, including yeast grease 8%, nitric acid ring 12 are made every effort to promote in actuating
The mixture 12% of ester and 3- methyl-3-nitro -2- butyl nitrate 1:3, di-tert-butyl peroxide and heptane peroxide 1:
3 mixture 18%.
2. methanol diesel-oil, composed of the following components by volume unit percentages: 10% anhydrous methanol, 20% higher alcohols,
70% diesel oil, 0.5% methanol diesel fuel additive are added in stirring container, stir evenly methanol bavin can be obtained at normal temperature
Oily product oil.
Embodiment 5:
1. methanol diesel fuel additive is grouped as by volume unit percentages by following functions group: 20% anti-layering hydrotropy group
Point, the anti-swelling component of 9% anticorrosion, the clear glial component of 9% carbon remover, 28% proposes flash-point pour point depression point component, 34% actuating
Make every effort to promote combustion components；Each component is added in container, and stirring evenly at normal temperature can be obtained transparent, limpid methanol diesel-oil and add
Add agent finished product.
Wherein, anti-layering hydrotropy component, including yeast grease 12%, the mixture 4% of n-octyl alcohol and n-dodecanol 1:2, rouge
The mixture 4% of fatty acid methyl esters and epoxy aliphatic acid methyl ester 1:1；The anti-swelling component of anticorrosion, including yeast grease 2%, adjacent phthalandione
The mixture 3% of three monooctyl ester 1:1 of tributyl and adjacent phthalandione, the mixture 4% of cyclohexanone and alkyl salicylate 1:1；Carbon remover gel resin
Matter component, including yeast grease 2%, the mixture 4% of ethylene glycol and polyethylene glycol 1:2, n-butanol 3%；Propose flash-point pour point depression point group
Point, including yeast grease 12%, the mixture 8% of butyl hexanoate and fatty glyceride 1:1, the mixture 8% of EVA and WHP1:1；
Combustion components, including yeast grease 5% are made every effort to promote in actuating, and ten diester of nitric acid ring is with 3- methyl-3-nitro -2- butyl nitrate 1:3's
Mixture 11%, the mixture 18% of 2- nitropropane and nitrobutane 2:1.
2. methanol diesel-oil, composed of the following components by volume unit percentages: 8% anhydrous methanol, 22% higher alcohols,
70% diesel oil, 0.4% methanol diesel fuel additive, each component is added in stirring container, and stirring evenly can obtain at normal temperature
To methanol diesel-oil product oil.
Using main experimental index determining after methanol diesel fuel additive described herein (20 DEG C):
Above-described embodiment is only used for the description of the invention, and the various combination that wherein each ingredient different proportion of additive generates adds
Add different amounts of the agent in product oil, still there are many combinations, these combinations no longer repeat one by one；It should be understood that this
For the those of ordinary skill of field, it can be improved or converted according to above-described embodiment, and all these modifications and variations are all
It should belong to the protection scope of appended claims of the present invention.
Claims (2)
1. a kind of methanol diesel fuel additive based on yeast grease, the yeast grease obtains as follows:
By the long-term domesticated strain HT-925 corium trichosporon bacteria in laboratory in constant temperature incubation on YPD culture medium, the corium hair spore
The deposit number of daughter bacteria: CGMCC 14875；Thallus after culture is eluted with physiological saline, obtaining concentration is 107~108A/ml
Bacteria suspension；By in the seed culture medium of above-mentioned bacterial suspension inoculation to glucose, yeast powder and urea composition, enrichment culture is obtained
Seed liquor；Seed liquor is inoculated into the fermentation medium based on gutter oil, wastewater of starch factory and blackstrap, through 25 ~ 32
DEG C, dissolved oxygen 20 ~ 60% fermented and cultured 5 ~ 7 days, obtains yeast grease；
It is grouped as by volume unit percentages by following functions group based on the methanol diesel fuel additive of the yeast grease: anti-
It is layered hydrotropy component 20 ~ 30%, the anti-swelling component 5 ~ 10% of anticorrosion, the clear glial component 5 ~ 10% of carbon remover proposes flash-point pour point depression point group
Divide 20 ~ 30%, combustion components 30 ~ 40% are made every effort to promote in actuating；
It is characterized by:
The anti-layering hydrotropy component, composed of the following components by volume unit percentages: yeast grease 10 ~ 15%, it is different
The mixture 4 ~ 9% of octanol or n-octyl alcohol and n-dodecanol 1:2, epoxy aliphatic acid methyl ester or fatty acid methyl ester and epoxyfatty acid
The mixture 4 ~ 9% of methyl esters 1:1；
The anti-swelling component of the anticorrosion, it is composed of the following components by volume unit percentages: yeast grease 1 ~ 2%, α-
The mixture 2 ~ 4% of three monooctyl ester 1:1 of methyl naphthalene or adjacent phthalandione tributyl and adjacent phthalandione, cyclohexanone or cyclohexanone and alkyl salicylate
The mixture 2 ~ 4% of 1:1；
The clear glial component of the carbon remover, it is composed of the following components by volume unit percentages: yeast grease 1 ~ 2%, second
The mixture 2 ~ 4% of the mixture 2 ~ 4% of glycol or ethylene glycol and polyethylene glycol 1:2, n-butanol or sec-butyl alcohol and hexylene glycol 1:1；
It is described to propose flash-point pour point depression point component, composed of the following components by volume unit percentages: yeast grease 10 ~ 15%,
Palm oil and the mixture of cottonseed oil 1:1 or the mixture 4 ~ 9% of butyl hexanoate and fatty glyceride 1:1, maleate and richness
The mixture 4 ~ 9% of fumaric ester copolymer or EVA and WHP1:1；
Combustion components are made every effort to promote in the actuating, composed of the following components by volume unit percentages: yeast grease 5 ~ 10%, nitre
The mixture or ten diester of nitric acid ring and 3- methyl-3-nitro -2- butyl nitrate 1:3 of sour cyclohexyl and isooctyl ester nitrate 1:1
Mixture 10 ~ 15%, the mixture or di-tert-butyl peroxide of 2- nitropropane and nitrobutane 2:1 and heptane peroxidating
The mixture 15 ~ 20% of object 1:3.
2. a kind of methanol diesel-oil containing methanol diesel fuel additive described in claim 1, which is characterized in that press volume unit percentage
It is composed of the following components: anhydrous methanol or higher alcohols 10 ~ 30%, diesel oil 70 ~ 90%, methanol diesel fuel additive 0.1 ~ 0.5% than meter；
The anhydrous methanol or higher alcohols, diesel oil, methanol diesel fuel additive component, are added in stirring container, stir at normal temperature
Uniformly, as methanol diesel-oil.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110184099A (en) * | 2019-06-14 | 2019-08-30 | 上海应用技术大学 | A kind of diesel oil pour point reducer composition and its preparation method and application |
| CN110974735A (en) * | 2019-09-23 | 2020-04-10 | 田宇 | Plant essence yeast soft film powder |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402888A (en) * | 2008-11-12 | 2009-04-08 | 王宇 | Composite additive and process for producing methanol diesel oil thereof |
| CN101508918A (en) * | 2009-04-01 | 2009-08-19 | 厦门市沸捷新能源科技有限公司 | Methanol diesel oil and method of preparing the same |
| CN101935560A (en) * | 2010-09-09 | 2011-01-05 | 上海化工研究院 | Methanol diesel oil microemulsion and preparation method thereof |
| CN102399599A (en) * | 2010-09-16 | 2012-04-04 | 陈若歆 | Methanol diesel oil manufacturing mode |
| CN102690695A (en) * | 2012-06-08 | 2012-09-26 | 袁自远 | Methanol diesel additive |
| CN103415599A (en) * | 2010-11-25 | 2013-11-27 | 甘恩能源有限公司 | Fuel and process for powering a compression ignition engine |
| CN104745243A (en) * | 2015-03-04 | 2015-07-01 | 张东宁 | Methanol-diesel oil additive and preparation method thereof |
| CN107739632A (en) * | 2017-11-23 | 2018-02-27 | 黄晓磊 | It is method and its application of the main system for methanol gasoline additive using microbial fermentation trench oily product |
-
2018
- 2018-09-06 CN CN201811038146.XA patent/CN109054913B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402888A (en) * | 2008-11-12 | 2009-04-08 | 王宇 | Composite additive and process for producing methanol diesel oil thereof |
| CN101508918A (en) * | 2009-04-01 | 2009-08-19 | 厦门市沸捷新能源科技有限公司 | Methanol diesel oil and method of preparing the same |
| CN101935560A (en) * | 2010-09-09 | 2011-01-05 | 上海化工研究院 | Methanol diesel oil microemulsion and preparation method thereof |
| CN102399599A (en) * | 2010-09-16 | 2012-04-04 | 陈若歆 | Methanol diesel oil manufacturing mode |
| CN103415599A (en) * | 2010-11-25 | 2013-11-27 | 甘恩能源有限公司 | Fuel and process for powering a compression ignition engine |
| CN102690695A (en) * | 2012-06-08 | 2012-09-26 | 袁自远 | Methanol diesel additive |
| CN104745243A (en) * | 2015-03-04 | 2015-07-01 | 张东宁 | Methanol-diesel oil additive and preparation method thereof |
| CN107739632A (en) * | 2017-11-23 | 2018-02-27 | 黄晓磊 | It is method and its application of the main system for methanol gasoline additive using microbial fermentation trench oily product |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110184099A (en) * | 2019-06-14 | 2019-08-30 | 上海应用技术大学 | A kind of diesel oil pour point reducer composition and its preparation method and application |
| CN110974735A (en) * | 2019-09-23 | 2020-04-10 | 田宇 | Plant essence yeast soft film powder |
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