CN104449907A - Technological formula for composite emulsified diesel oil additive - Google Patents

Technological formula for composite emulsified diesel oil additive Download PDF

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Publication number
CN104449907A
CN104449907A CN201410541237.0A CN201410541237A CN104449907A CN 104449907 A CN104449907 A CN 104449907A CN 201410541237 A CN201410541237 A CN 201410541237A CN 104449907 A CN104449907 A CN 104449907A
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CN
China
Prior art keywords
percent
diesel oil
alcohol
formula
oleic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410541237.0A
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Chinese (zh)
Inventor
王文华
李红俊
马利海
郭玉生
李拥军
谢一民
李杨
刘晓燕
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Ningxia Baota Petrochemical Technology Industry Development Co Ltd
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Ningxia Baota Petrochemical Technology Industry Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ningxia Baota Petrochemical Technology Industry Development Co Ltd filed Critical Ningxia Baota Petrochemical Technology Industry Development Co Ltd
Priority to CN201410541237.0A priority Critical patent/CN104449907A/en
Publication of CN104449907A publication Critical patent/CN104449907A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a diesel oil emulsifier and belongs to the technical field of emulsifiers. The diesel oil emulsifier is prepared from the following components in percentage by weight: 20-30 percent of n-amyl-alcohol, 5-15 percent of sodium dodecyl benzene sulfonate, 1-3 percent of fatty alcohol-polyoxyethylene ether, 15-25 percent of span 80, 15-25 percent of Tween 80, 1-8 percent of p-tert-butylphenol, 5-20 percent of isopropanolamine, 0.5-3 percent of acetone and 0.5-2 percent of oleic acid. Emulsified diesel oil prepared by utilizing the diesel oil emulsifier is clear and transparent in appearance, strong in stability, large in mixing content of water and good in combustion performance, can be stored for a long time without layering and has obvious economical and environmental-friendly benefits.

Description

A kind of technical formula of diesel oil emulsification composite additive
Technical field
The invention belongs to clean energy technology field, be specifically related to a kind of technical formula of diesel oil emulsifier.
Background technology
In countries in the world under the background of environmental problem pay attention to day by day, for solving oil shortage and air pollution problems inherent, reach the object of energy saving standard, at present more and more extensive to the research of diesel motor clean fuel and fuel substitute, wherein adopting emulsifying technology to prepare emulsion fuel is a kind of mode than being easier to realize.
But it is short to there is stationary phase in diesel oil emulsification prepared by existing emulsifying agent art, the phenomenon of easy layering in storage process.Further, engine employs emulsion fuel, after a shutdown, can face again start more difficult problem because of fry dried food ingredients remaining in fuel system layer estranged.
Summary of the invention
The object of the invention is to solve the problem, a kind of diesel oil emulsifier technical formula is provided.
Compared with prior art, by the diesel oil emulsification of emulsifying agent technical formula of the present invention preparation, the amount of mixing of water reaches 5-25%, outward appearance clear, and stability is strong, can long-term storage and not stratified.The total cost of made diesel oil emulsification, lower than market available diesel oil price, has good burning performance, and has obvious economic benefit.
Emulsifiers formula of the present invention is made up of the component of following weight percent content:
Pentyl alcohol 20% ~ 30%
Sodium dodecylbenzene sulfonate 5% ~ 15%
Fatty alcohol-polyoxyethylene ether 1% ~ 3%
Class 80 15% ~ 25% of department
Tween 80 15% ~ 25%
P-tert-butylphenol 1% ~ 8%
α-amino isopropyl alcohol 5% ~ 20%
Acetone 0.5% ~ 3%
Oleic acid 0.5 ~ 2%.
Weigh in beaker by as above proportioning, beaker is placed in the water-bath of 20 ~ 45 DEG C, stirs with the rotating speed of 200 ~ 500 r/min, add Pentyl alcohol and 0.5% ~ 1% oleic acid of 0.5% ~ 8% simultaneously, wherein Pentyl alcohol amount higher than 40% of cumulative volume, can not stir 30 ~ 90min in adding procedure.Obtain diesel oil emulsification.
This process of preparing is simple, is applicable to large-scale production application.
Embodiment
In conjunction with specific embodiments, to further illustrate the present invention.
By following proportioning preparation emulsifying agent
Pentyl alcohol 20% ~ 30%
Sodium dodecylbenzene sulfonate 5% ~ 15%
Fatty alcohol-polyoxyethylene ether 1% ~ 3%
Class 80 15% ~ 25% of department
Tween 80 15% ~ 25%
P-tert-butylphenol 1% ~ 8%
α-amino isopropyl alcohol 5% ~ 20%
Acetone 0.5% ~ 3%
Oleic acid 0.5 ~ 2%.
Table 1 is the emulsifying agent allotment formula of embodiment 1-3.
Component Embodiment 1 Embodiment 2 Embodiment 3
Pentyl alcohol 30% 25% 22%
Sodium dodecylbenzene sulfonate 15% 8% 9%
Fatty alcohol-polyoxyethylene ether 1% 1.5% 1.5%
Class 80 of department 15% 20% 18%
Tween 80 15% 20% 18%
P-tert-butylphenol 6% 3% 8%
α-amino isopropyl alcohol 15% 20% 20%
Acetone 1.5% 1.5% 2.0%
Oleic acid 1.5% 1.0% 1.5%
Weigh in beaker by as above proportioning, beaker is placed in the water-bath of 30 DEG C, stir with the rotating speed of 350 r/min, suitable Pentyl alcohol amount is added so that all dissolve while stirring, wherein Pentyl alcohol amount can not higher than 40% of cumulative volume, in adding procedure, suitably instillation 1 ~ 5 oil dripping acid, continues stirring 60 min.Obtain emulsifying agent.
In sum, greatly can improve the amount of mixing (5-25%) of water by the diesel oil emulsification of emulsifying agent technical formula of the present invention preparation, outward appearance clear, stability is strong, can long-term storage and not stratified.The total cost of made diesel oil emulsification, lower than market available diesel oil price, has good burning performance, and has obvious economic benefit.

Claims (2)

1. a technical formula for diesel oil emulsification composite additive, is characterized in that formula is made up of the component of following weight percent content:
Pentyl alcohol 20% ~ 30%
Sodium dodecylbenzene sulfonate 5% ~ 15%
Fatty alcohol-polyoxyethylene ether 1% ~ 3%
Class 80 15% ~ 25% of department
Tween 80 15% ~ 25%
P-tert-butylphenol 1% ~ 8%
α-amino isopropyl alcohol 5% ~ 20%
Acetone 0.5% ~ 3%
Oleic acid 0.5 ~ 2%.
2. the technical formula of a kind of diesel oil emulsification composite additive as claimed in claim 1, it is characterized in that weighing in beaker by described proportioning, beaker is placed in 20 ~ 45 DEG C of water-baths, to stir under 200 ~ 500 r/min conditions, add Pentyl alcohol and 0.5% ~ 1% oleic acid of 2% ~ 8% more in addition simultaneously.
CN201410541237.0A 2014-10-15 2014-10-15 Technological formula for composite emulsified diesel oil additive Pending CN104449907A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410541237.0A CN104449907A (en) 2014-10-15 2014-10-15 Technological formula for composite emulsified diesel oil additive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410541237.0A CN104449907A (en) 2014-10-15 2014-10-15 Technological formula for composite emulsified diesel oil additive

Publications (1)

Publication Number Publication Date
CN104449907A true CN104449907A (en) 2015-03-25

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Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
CN (1) CN104449907A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106221835A (en) * 2016-08-23 2016-12-14 广西东奇能源技术有限公司 Diesel fueled combustion enhancement additive
CN106635196A (en) * 2016-11-10 2017-05-10 黑龙江省能源环境研究院 High-combustion-efficiency emulsified diesel fuel and preparation method thereof

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87104283A (en) * 1987-06-15 1988-02-24 吉安地区机电科学技术研究所 The preparation method of water mixing microemulsified gasoline (or oil fuel)
CN1161369A (en) * 1997-01-11 1997-10-08 覃戍文 High efficiency agent for reducing smoke during fuel oil combustion
EP1698681A1 (en) * 2003-11-27 2006-09-06 Revo International Inc. Process for producing diesel fuel oil from fat
CN101812333A (en) * 2010-05-10 2010-08-25 唐山市隆泰科技有限公司 Method for producing ethanol diesel oil by using industrial ethanol
CN101935559A (en) * 2010-07-21 2011-01-05 唐山市隆泰科技有限公司 Manufacturing method for preparing methanol diesel fuel from industrial methanol
CN101935558A (en) * 2010-07-21 2011-01-05 唐山市隆泰科技有限公司 Method for preparing environmentally-friendly methanol gasoline
CN102216436A (en) * 2008-10-20 2011-10-12 梅村一之 Water-mixed fuel, additive-modified fuel oil, additive, and methods for production of same
CN102399599A (en) * 2010-09-16 2012-04-04 陈若歆 Methanol diesel oil manufacturing mode
CN102952593A (en) * 2011-08-20 2013-03-06 张朝斌 Novel composite diesel oil
CN103409177A (en) * 2013-08-29 2013-11-27 胡荣汉 Marine methanol fuel oil and preparation method thereof
CN103695048A (en) * 2013-12-30 2014-04-02 湖南亿通新能源开发有限公司 Biomass methanol diesel oil and preparation method thereof

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87104283A (en) * 1987-06-15 1988-02-24 吉安地区机电科学技术研究所 The preparation method of water mixing microemulsified gasoline (or oil fuel)
CN1161369A (en) * 1997-01-11 1997-10-08 覃戍文 High efficiency agent for reducing smoke during fuel oil combustion
EP1698681A1 (en) * 2003-11-27 2006-09-06 Revo International Inc. Process for producing diesel fuel oil from fat
CN102216436A (en) * 2008-10-20 2011-10-12 梅村一之 Water-mixed fuel, additive-modified fuel oil, additive, and methods for production of same
CN101812333A (en) * 2010-05-10 2010-08-25 唐山市隆泰科技有限公司 Method for producing ethanol diesel oil by using industrial ethanol
CN101935559A (en) * 2010-07-21 2011-01-05 唐山市隆泰科技有限公司 Manufacturing method for preparing methanol diesel fuel from industrial methanol
CN101935558A (en) * 2010-07-21 2011-01-05 唐山市隆泰科技有限公司 Method for preparing environmentally-friendly methanol gasoline
CN102399599A (en) * 2010-09-16 2012-04-04 陈若歆 Methanol diesel oil manufacturing mode
CN102952593A (en) * 2011-08-20 2013-03-06 张朝斌 Novel composite diesel oil
CN103409177A (en) * 2013-08-29 2013-11-27 胡荣汉 Marine methanol fuel oil and preparation method thereof
CN103695048A (en) * 2013-12-30 2014-04-02 湖南亿通新能源开发有限公司 Biomass methanol diesel oil and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106221835A (en) * 2016-08-23 2016-12-14 广西东奇能源技术有限公司 Diesel fueled combustion enhancement additive
CN106635196A (en) * 2016-11-10 2017-05-10 黑龙江省能源环境研究院 High-combustion-efficiency emulsified diesel fuel and preparation method thereof
CN106635196B (en) * 2016-11-10 2018-06-22 黑龙江省能源环境研究院 Diesel oil emulsification of high burning efficiency and preparation method thereof

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Application publication date: 20150325