CN102365393B - 生产3-叔丁基苯甲醛缩二甲醇的电化学方法 - Google Patents

生产3-叔丁基苯甲醛缩二甲醇的电化学方法 Download PDF

Info

Publication number
CN102365393B
CN102365393B CN201080014651.6A CN201080014651A CN102365393B CN 102365393 B CN102365393 B CN 102365393B CN 201080014651 A CN201080014651 A CN 201080014651A CN 102365393 B CN102365393 B CN 102365393B
Authority
CN
China
Prior art keywords
tert
formula
methylsulfuric acid
conducting salt
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201080014651.6A
Other languages
English (en)
Chinese (zh)
Other versions
CN102365393A (zh
Inventor
F·斯特克尔
A·菲舍尔
J·博岑
U·格里斯巴赫
R·派尔泽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN102365393A publication Critical patent/CN102365393A/zh
Application granted granted Critical
Publication of CN102365393B publication Critical patent/CN102365393B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/14—Unsaturated ethers
    • C07C43/17—Unsaturated ethers containing halogen
    • C07C43/174—Unsaturated ethers containing halogen containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/30—Compounds having groups
    • C07C43/303—Compounds having groups having acetal carbon atoms bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
    • C07C45/515—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups the singly bound functional group being an acetalised, ketalised hemi-acetalised, or hemi-ketalised hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/23—Oxidation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
CN201080014651.6A 2009-03-27 2010-03-22 生产3-叔丁基苯甲醛缩二甲醇的电化学方法 Expired - Fee Related CN102365393B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09156398 2009-03-27
EP09156398.1 2009-03-27
PCT/EP2010/053656 WO2010108874A1 (de) 2009-03-27 2010-03-22 Elektrochemisches verfahern zur herstellung von 3-tert.-butylbenzaldehyd-dimethylacetal

Publications (2)

Publication Number Publication Date
CN102365393A CN102365393A (zh) 2012-02-29
CN102365393B true CN102365393B (zh) 2014-10-29

Family

ID=42124639

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080014651.6A Expired - Fee Related CN102365393B (zh) 2009-03-27 2010-03-22 生产3-叔丁基苯甲醛缩二甲醇的电化学方法

Country Status (7)

Country Link
US (1) US8629304B2 (https=)
EP (1) EP2411564B1 (https=)
JP (1) JP5553884B2 (https=)
CN (1) CN102365393B (https=)
ES (1) ES2637018T3 (https=)
MX (1) MX2011010107A (https=)
WO (1) WO2010108874A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5553884B2 (ja) 2009-03-27 2014-07-16 ビーエーエスエフ ソシエタス・ヨーロピア ３−第三ブチルベンズアルデヒドジメチルアセタールを製造するための電気化学的方法
EP2616424B1 (de) 2010-09-16 2015-08-26 Basf Se Verfahren zur herstellung von 2-methyl-3-(4-tert-butylphenyl)-propanal mit hoher para-isomerenreinheit
KR20150023709A (ko) * 2012-06-15 2015-03-05 바스프 에스이 친핵체 존재 하의 유기 기판의 애노드 산화
US20130334058A1 (en) * 2012-06-15 2013-12-19 Basf Se Anodic oxidation of organic substrates in the presence of nucleophiles
WO2022023330A1 (en) * 2020-07-28 2022-02-03 Basf Se Cyclic compounds as aroma chemicals

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4539081A (en) * 1983-06-22 1985-09-03 Basf Aktiengesellschaft Preparation of benzaldehyde dialkyl acetals
US4820389A (en) * 1987-04-24 1989-04-11 Basf Aktiengesellschaft Novel benzaldehyde dialkyl acetals and preparation and use thereof
DE4201544A1 (de) * 1992-01-22 1993-07-29 Basf Ag Verfahren zur herstellung von benzaldehydacetalen
DE59400935D1 (de) * 1993-08-14 1996-12-05 Basf Ag Verfahren zur Herstellung von Bezaldehyddialkylacetalen

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2848397C2 (de) * 1978-11-08 1982-09-23 Basf Ag, 6700 Ludwigshafen Elektrochemische Herstellung von in 4-Stellung substituierten Benzaldehyddialkylacetalen
US4318783A (en) * 1978-11-30 1982-03-09 Bayer Aktiengesellschaft Process for the preparation of optionally substituted benzaldehyde dialkyl acetals
JPS5620174A (en) * 1979-07-27 1981-02-25 Fuso Kagaku Kogyo Kk Preparation of p-t-butylbenzaldehyde and its acetal
JP2738093B2 (ja) 1989-12-19 1998-04-08 三菱化学株式会社 第３級ブチルベンズアルデヒド異性体混合物の製造方法
JP3159471B2 (ja) * 1991-07-11 2001-04-23 三井化学株式会社 サリチル酸誘導体の製造方法
DE19904900A1 (de) 1998-06-26 1999-12-30 Basf Ag Verfahren zur Herstellung von Alkoxymethylaromaten
DE102004011427A1 (de) 2004-03-09 2005-09-29 Basf Ag Absorptionsmittel mit verbesserter Oxidationsbeständigkeit und Verfahren zum Entsäuern von Fluidströmen
WO2009059944A1 (de) 2007-11-06 2009-05-14 Basf Se Elektrochemisches verfahren zur herstellung von benzaldehyddimethylacetalen
US20100256421A1 (en) * 2009-03-23 2010-10-07 O'laughlin Industries, Co. Ltd. Propanal Production Methods
JP5553884B2 (ja) 2009-03-27 2014-07-16 ビーエーエスエフ ソシエタス・ヨーロピア ３−第三ブチルベンズアルデヒドジメチルアセタールを製造するための電気化学的方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4539081A (en) * 1983-06-22 1985-09-03 Basf Aktiengesellschaft Preparation of benzaldehyde dialkyl acetals
US4820389A (en) * 1987-04-24 1989-04-11 Basf Aktiengesellschaft Novel benzaldehyde dialkyl acetals and preparation and use thereof
DE4201544A1 (de) * 1992-01-22 1993-07-29 Basf Ag Verfahren zur herstellung von benzaldehydacetalen
DE59400935D1 (de) * 1993-08-14 1996-12-05 Basf Ag Verfahren zur Herstellung von Bezaldehyddialkylacetalen

Also Published As

Publication number Publication date
US20120016162A1 (en) 2012-01-19
CN102365393A (zh) 2012-02-29
US8629304B2 (en) 2014-01-14
MX2011010107A (es) 2011-10-19
JP2012522125A (ja) 2012-09-20
EP2411564A1 (de) 2012-02-01
EP2411564B1 (de) 2017-05-10
WO2010108874A1 (de) 2010-09-30
JP5553884B2 (ja) 2014-07-16
ES2637018T3 (es) 2017-10-10

Similar Documents

Publication Publication Date Title
Leech et al. Organic electrosynthesis: from academia to industry
Klein et al. Counter electrode reactions—important stumbling blocks on the way to a working electro‐organic synthesis
Sequeira et al. Electrochemical routes for industrial synthesis
CN102365393B (zh) 生产3-叔丁基苯甲醛缩二甲醇的电化学方法
JP5535215B2 (ja) 置換アリールアルコールのアノード脱水素二量化のための方法
US6822124B2 (en) Method for producing alcoxylated carbonyl compounds by an anodic oxidation method using a cathodic coupled reaction for organic synthesis
US8614358B2 (en) Process for preparing 2-methyl-3-(4-tert-butylphenyl)propanal with high para-isomer purity
Wendt et al. Anodic synthesis of benzaldehydes—II. Optimization of the direct anodic oxidation of toluenes in methanol and ethanol
CA2429542A1 (en) Production of butane tetracarboxylic acid derivatives by means of coupled electrosynthesis
WO2009059944A1 (de) Elektrochemisches verfahren zur herstellung von benzaldehyddimethylacetalen
MX2012009124A (es) Metodo para producir 4-isopropilciclohexilmetanol.
US8889920B2 (en) Process for preparing 4-isopropylcyclohexylmethanol
JP4755458B2 (ja) ２−アルキン−１−アセタールの製造方法
JP5015406B2 (ja) オルトカルボン酸トリアルキルエステルの製造方法
JPH0210814B2 (https=)
US3257298A (en) Method for the preparation of acetals
US5078838A (en) Preparation of benzaldehyde dialkyl acetals and novel benzaldehyde dialkyl acetals and benzyl esters
JP5138499B2 (ja) 脂肪族ジケトンの製造方法
JPH0143030B2 (https=)
JP2598010B2 (ja) エポキシケトンの開裂方法
JP2005503445A (ja) オルトカルボン酸トリアルキルエステルの製造方法
KR20250110162A (ko) 테트라알킬 1,2,3,4-부탄테트라카르복실레이트의 제조를 위한 전기화학적 방법
JPS6141994B2 (https=)
JPS5853075B2 (ja) クロルハイドロキノンモノメチルエ−テル類の製造方法
JPH08209372A (ja) ｐ−ヒドロキシベンズアルデヒドの製法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20141029

Termination date: 20180322