CN102264856A - 可湿气固化的热熔性胶粘剂 - Google Patents
可湿气固化的热熔性胶粘剂 Download PDFInfo
- Publication number
- CN102264856A CN102264856A CN2009801528977A CN200980152897A CN102264856A CN 102264856 A CN102264856 A CN 102264856A CN 2009801528977 A CN2009801528977 A CN 2009801528977A CN 200980152897 A CN200980152897 A CN 200980152897A CN 102264856 A CN102264856 A CN 102264856A
- Authority
- CN
- China
- Prior art keywords
- hot melt
- melt adhesive
- isocyanate compound
- moisture
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- -1 isocyanate compound Chemical class 0.000 claims abstract description 143
- 239000012948 isocyanate Substances 0.000 claims abstract description 124
- 238000006243 chemical reaction Methods 0.000 claims abstract description 55
- 238000000034 method Methods 0.000 claims abstract description 26
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims description 158
- 239000011347 resin Substances 0.000 claims description 158
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 58
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 32
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 abstract description 30
- 230000001070 adhesive effect Effects 0.000 abstract description 30
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 22
- 238000002156 mixing Methods 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 8
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- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 4
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- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 18
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- 230000001588 bifunctional effect Effects 0.000 description 4
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- BJZYYSAMLOBSDY-QMMMGPOBSA-N (2s)-2-butoxybutan-1-ol Chemical compound CCCCO[C@@H](CC)CO BJZYYSAMLOBSDY-QMMMGPOBSA-N 0.000 description 3
- 238000004566 IR spectroscopy Methods 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
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- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
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- 239000004902 Softening Agent Substances 0.000 description 2
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- 230000000996 additive effect Effects 0.000 description 2
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- 239000012964 benzotriazole Substances 0.000 description 2
- ZPFKRQXYKULZKP-UHFFFAOYSA-N butylidene Chemical group [CH2+]CC[CH-] ZPFKRQXYKULZKP-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
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- 238000009736 wetting Methods 0.000 description 2
- XXMCAWSEVMOGLO-UHFFFAOYSA-N 1,1-dichloro-1,6-diisocyanatohexane Chemical compound O=C=NC(Cl)(Cl)CCCCCN=C=O XXMCAWSEVMOGLO-UHFFFAOYSA-N 0.000 description 1
- IKYNWXNXXHWHLL-UHFFFAOYSA-N 1,3-diisocyanatopropane Chemical compound O=C=NCCCN=C=O IKYNWXNXXHWHLL-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
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- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6603—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3212—Polyhydroxy compounds containing cycloaliphatic groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/20—Compositions for hot melt adhesives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
Claims (2)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008-302038 | 2008-11-27 | ||
JP2008302038A JP5580982B2 (ja) | 2008-11-27 | 2008-11-27 | 湿気硬化型ホットメルト接着剤 |
PCT/JP2009/069534 WO2010061759A1 (ja) | 2008-11-27 | 2009-11-18 | 湿気硬化型ホットメルト接着剤 |
Publications (2)
Publication Number | Publication Date |
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CN102264856A true CN102264856A (zh) | 2011-11-30 |
CN102264856B CN102264856B (zh) | 2015-11-25 |
Family
ID=42225635
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN200980152897.7A Expired - Fee Related CN102264856B (zh) | 2008-11-27 | 2009-11-18 | 可湿气固化的热熔性胶粘剂 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8324299B2 (zh) |
EP (1) | EP2380939A1 (zh) |
JP (1) | JP5580982B2 (zh) |
CN (1) | CN102264856B (zh) |
BR (1) | BRPI0921170A2 (zh) |
WO (1) | WO2010061759A1 (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103320045A (zh) * | 2013-07-11 | 2013-09-25 | 苏州毫邦新材料有限公司 | 一种反应型异方导电热熔胶粘剂 |
CN106499152A (zh) * | 2016-10-21 | 2017-03-15 | 肖文辉 | Pvc复合地板 |
CN110229645A (zh) * | 2019-07-12 | 2019-09-13 | 重庆韩拓科技有限公司 | 高初粘单组份湿气固化反应型聚氨酯热熔胶及其制备方法 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6067969B2 (ja) * | 2011-12-12 | 2017-01-25 | 日東電工株式会社 | 熱伝導性粘着樹脂組成物および熱伝導性粘着シート |
JP6111190B2 (ja) * | 2013-12-25 | 2017-04-05 | 株式会社ブリヂストン | サイド補強式ランフラットタイヤ |
JP6660545B2 (ja) * | 2014-12-16 | 2020-03-11 | Dic株式会社 | 湿気硬化型ホットメルトウレタン組成物及び接着剤 |
JP7006803B2 (ja) * | 2018-09-28 | 2022-01-24 | 大日本印刷株式会社 | 化粧シート及びこれを用いた化粧材 |
WO2021041534A1 (en) * | 2019-08-26 | 2021-03-04 | H.B. Fuller Company | Fast set moisture curable hot melt adhesive composition and articles including the same |
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JPH05214312A (ja) * | 1992-02-07 | 1993-08-24 | Sunstar Eng Inc | 湿気硬化性熱溶融型ポリウレタン系接着剤 |
JPH07179559A (ja) * | 1993-12-24 | 1995-07-18 | Arakawa Chem Ind Co Ltd | ロジン骨格を有するポリウレタンおよび該ポリウレタンを含有してなるポリウレタン系接着剤 |
JPH07278498A (ja) * | 1994-04-11 | 1995-10-24 | Harima Chem Inc | 低水酸基価変性ロジン、ロジン誘導体の水酸基価を低下させる方法、感圧性接着剤の粘着付与剤並びに感圧性接着剤組成物 |
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JP2007051282A (ja) * | 2005-07-21 | 2007-03-01 | Sanyo Chem Ind Ltd | 反応性ホットメルト接着剤 |
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US6387449B1 (en) | 1999-12-01 | 2002-05-14 | H. B. Fuller Licensing & Financing, Inc. | Reactive hot melt adhesive |
US6660376B1 (en) * | 2000-06-06 | 2003-12-09 | H. B. Fuller Licensing & Financing Inc. | Method of bonding permeable substrates with hot melt moisture cure adhesive having low viscosity and high green strength |
-
2008
- 2008-11-27 JP JP2008302038A patent/JP5580982B2/ja not_active Expired - Fee Related
-
2009
- 2009-11-18 EP EP20090829007 patent/EP2380939A1/en not_active Withdrawn
- 2009-11-18 CN CN200980152897.7A patent/CN102264856B/zh not_active Expired - Fee Related
- 2009-11-18 WO PCT/JP2009/069534 patent/WO2010061759A1/ja active Application Filing
- 2009-11-18 BR BRPI0921170A patent/BRPI0921170A2/pt not_active IP Right Cessation
-
2011
- 2011-05-26 US US13/116,573 patent/US8324299B2/en not_active Expired - Fee Related
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US4377510A (en) * | 1981-11-30 | 1983-03-22 | Arizona Chemical Company | Urethane-modified rosin ester and process for preparing the same |
US4693846A (en) * | 1986-05-09 | 1987-09-15 | Ppg Industries, Inc. | Urethane-modified rosin esters |
JPH05214312A (ja) * | 1992-02-07 | 1993-08-24 | Sunstar Eng Inc | 湿気硬化性熱溶融型ポリウレタン系接着剤 |
JPH07179559A (ja) * | 1993-12-24 | 1995-07-18 | Arakawa Chem Ind Co Ltd | ロジン骨格を有するポリウレタンおよび該ポリウレタンを含有してなるポリウレタン系接着剤 |
JPH07278498A (ja) * | 1994-04-11 | 1995-10-24 | Harima Chem Inc | 低水酸基価変性ロジン、ロジン誘導体の水酸基価を低下させる方法、感圧性接着剤の粘着付与剤並びに感圧性接着剤組成物 |
JP2007051282A (ja) * | 2005-07-21 | 2007-03-01 | Sanyo Chem Ind Ltd | 反応性ホットメルト接着剤 |
CN1752169A (zh) * | 2005-09-28 | 2006-03-29 | 东北林业大学 | 湿固化聚氨酯热熔胶黏剂及其制备方法 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103320045A (zh) * | 2013-07-11 | 2013-09-25 | 苏州毫邦新材料有限公司 | 一种反应型异方导电热熔胶粘剂 |
CN106499152A (zh) * | 2016-10-21 | 2017-03-15 | 肖文辉 | Pvc复合地板 |
CN110229645A (zh) * | 2019-07-12 | 2019-09-13 | 重庆韩拓科技有限公司 | 高初粘单组份湿气固化反应型聚氨酯热熔胶及其制备方法 |
CN110229645B (zh) * | 2019-07-12 | 2021-10-08 | 重庆韩拓科技有限公司 | 高初粘单组份湿气固化反应型聚氨酯热熔胶及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN102264856B (zh) | 2015-11-25 |
US8324299B2 (en) | 2012-12-04 |
JP5580982B2 (ja) | 2014-08-27 |
WO2010061759A1 (ja) | 2010-06-03 |
BRPI0921170A2 (pt) | 2018-08-07 |
EP2380939A1 (en) | 2011-10-26 |
JP2010126615A (ja) | 2010-06-10 |
US20110275767A1 (en) | 2011-11-10 |
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