CN102250029A - 一种三嗪羟乙基乙二胺基多元羧酸的制备方法 - Google Patents
一种三嗪羟乙基乙二胺基多元羧酸的制备方法 Download PDFInfo
- Publication number
- CN102250029A CN102250029A CN2011101462822A CN201110146282A CN102250029A CN 102250029 A CN102250029 A CN 102250029A CN 2011101462822 A CN2011101462822 A CN 2011101462822A CN 201110146282 A CN201110146282 A CN 201110146282A CN 102250029 A CN102250029 A CN 102250029A
- Authority
- CN
- China
- Prior art keywords
- hydroxyethylethylene diamine
- triazine
- acid
- carboxylic acid
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002253 acid Substances 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- HNHNMLNQPOCWPR-UHFFFAOYSA-N 2-(2-aminoethylamino)ethanol triazine Chemical compound OCCNCCN.N1=NN=CC=C1 HNHNMLNQPOCWPR-UHFFFAOYSA-N 0.000 title abstract 4
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000006243 chemical reaction Methods 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 claims abstract description 10
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 230000000694 effects Effects 0.000 claims abstract description 7
- 238000003916 acid precipitation Methods 0.000 claims abstract description 3
- 238000006467 substitution reaction Methods 0.000 claims abstract description 3
- -1 triazine hydroxyethylethylene Chemical group 0.000 claims description 19
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 235000017550 sodium carbonate Nutrition 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 3
- 235000015320 potassium carbonate Nutrition 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 239000000654 additive Substances 0.000 abstract description 5
- 230000000996 additive effect Effects 0.000 abstract description 5
- 230000002401 inhibitory effect Effects 0.000 abstract description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 abstract description 2
- 125000001309 chloro group Chemical group Cl* 0.000 abstract description 2
- 238000006073 displacement reaction Methods 0.000 abstract description 2
- 125000000524 functional group Chemical group 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 230000021523 carboxylation Effects 0.000 abstract 1
- 238000006473 carboxylation reaction Methods 0.000 abstract 1
- 238000003889 chemical engineering Methods 0.000 abstract 1
- 229940106681 chloroacetic acid Drugs 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002173 cutting fluid Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000011182 sodium carbonates Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110146282.2A CN102250029B (zh) | 2011-05-16 | 2011-05-16 | 一种三嗪羟乙基乙二胺基多元羧酸的制备方法 |
Applications Claiming Priority (1)
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CN201110146282.2A CN102250029B (zh) | 2011-05-16 | 2011-05-16 | 一种三嗪羟乙基乙二胺基多元羧酸的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN102250029A true CN102250029A (zh) | 2011-11-23 |
CN102250029B CN102250029B (zh) | 2015-02-11 |
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CN201110146282.2A Expired - Fee Related CN102250029B (zh) | 2011-05-16 | 2011-05-16 | 一种三嗪羟乙基乙二胺基多元羧酸的制备方法 |
Country Status (1)
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CN (1) | CN102250029B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102764610A (zh) * | 2012-07-05 | 2012-11-07 | 陕西科技大学 | 一类含三嗪环的螯合性表面活性剂及其制备方法 |
CN104649989A (zh) * | 2013-11-25 | 2015-05-27 | 刘现梅 | 一种三(氨基丁二酸酰胺基)–均三嗪及其制备方法 |
CN104649988A (zh) * | 2013-11-26 | 2015-05-27 | 刘现梅 | 一种三(巯基丁二酸酰胺基)–均三嗪及其制备方法 |
CN109971898A (zh) * | 2019-04-10 | 2019-07-05 | 温州大学 | 一种环保型两性离子非金属鞣剂及其制备方法 |
CN110592594A (zh) * | 2019-10-16 | 2019-12-20 | 洛阳太平洋联合石油化工有限公司 | 一种四元羧酸金属防锈剂及其制备方法和应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1326887A (en) * | 1970-04-30 | 1973-08-15 | Ciba Geigy Ag | Triazine carboxylic acids and esters |
EP0072009A2 (de) * | 1981-08-11 | 1983-02-16 | Hoechst Aktiengesellschaft | Polytriazinylalkohole, -ester und -urethane, ein Verfahren zu ihrer Herstellung und ihre Verwendung als Stabilisatoren |
US4433145A (en) * | 1979-11-06 | 1984-02-21 | Hoechst Aktiengesellschaft | Triazine stabilizers |
CN101130523A (zh) * | 2007-08-27 | 2008-02-27 | 山东轻工业学院 | 三聚氰胺六乙酸螯合剂的制备方法 |
-
2011
- 2011-05-16 CN CN201110146282.2A patent/CN102250029B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1326887A (en) * | 1970-04-30 | 1973-08-15 | Ciba Geigy Ag | Triazine carboxylic acids and esters |
US4433145A (en) * | 1979-11-06 | 1984-02-21 | Hoechst Aktiengesellschaft | Triazine stabilizers |
EP0072009A2 (de) * | 1981-08-11 | 1983-02-16 | Hoechst Aktiengesellschaft | Polytriazinylalkohole, -ester und -urethane, ein Verfahren zu ihrer Herstellung und ihre Verwendung als Stabilisatoren |
CN101130523A (zh) * | 2007-08-27 | 2008-02-27 | 山东轻工业学院 | 三聚氰胺六乙酸螯合剂的制备方法 |
Non-Patent Citations (1)
Title |
---|
范存峰等: "2,4,6-三(N,N-甲基,羧甲基氨基)-1,3,5-三嗪的合成", 《化学通报》, no. 9, 31 December 1990 (1990-12-31), pages 32 - 33 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102764610A (zh) * | 2012-07-05 | 2012-11-07 | 陕西科技大学 | 一类含三嗪环的螯合性表面活性剂及其制备方法 |
CN102764610B (zh) * | 2012-07-05 | 2013-12-18 | 陕西科技大学 | 一类含三嗪环的螯合性表面活性剂及其制备方法 |
CN104649989A (zh) * | 2013-11-25 | 2015-05-27 | 刘现梅 | 一种三(氨基丁二酸酰胺基)–均三嗪及其制备方法 |
CN104649988A (zh) * | 2013-11-26 | 2015-05-27 | 刘现梅 | 一种三(巯基丁二酸酰胺基)–均三嗪及其制备方法 |
CN109971898A (zh) * | 2019-04-10 | 2019-07-05 | 温州大学 | 一种环保型两性离子非金属鞣剂及其制备方法 |
CN109971898B (zh) * | 2019-04-10 | 2021-06-22 | 温州大学 | 一种两性离子非金属鞣剂 |
CN110592594A (zh) * | 2019-10-16 | 2019-12-20 | 洛阳太平洋联合石油化工有限公司 | 一种四元羧酸金属防锈剂及其制备方法和应用 |
CN110592594B (zh) * | 2019-10-16 | 2021-08-17 | 洛阳太平洋联合石油化工有限公司 | 一种四元羧酸金属防锈剂及其制备方法和应用 |
Also Published As
Publication number | Publication date |
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CN102250029B (zh) | 2015-02-11 |
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Owner name: YANTAI HENGDIKE ENERGY TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: XIU JIANDONG Effective date: 20150104 |
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Effective date of registration: 20150104 Address after: 264006 C109 room, Yantai College Students Pioneer Park, 101 Aerospace Road, hi tech Zone, Shandong, Yantai Applicant after: Yantai Hengdike Energy Technology Co., Ltd. Address before: 264006 No. 1, unit 16, sunrise residential district, Yantai Development Zone, Shandong, 4 Applicant before: Xiu Jiandong |
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