CN102149465B - 成型的非均相催化剂 - Google Patents

成型的非均相催化剂 Download PDF

Info

Publication number
CN102149465B
CN102149465B CN200980135459XA CN200980135459A CN102149465B CN 102149465 B CN102149465 B CN 102149465B CN 200980135459X A CN200980135459X A CN 200980135459XA CN 200980135459 A CN200980135459 A CN 200980135459A CN 102149465 B CN102149465 B CN 102149465B
Authority
CN
China
Prior art keywords
catalyst elements
catalyst
metal
scope
length
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN200980135459XA
Other languages
English (en)
Other versions
CN102149465A (zh
Inventor
D·J·伯德萨尔
M·巴波维克
M·P·U·卡尔森
S·A·弗兰切
M·尼杰梅兰德
W·M·森格楼
E·H·斯蒂提
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of CN102149465A publication Critical patent/CN102149465A/zh
Application granted granted Critical
Publication of CN102149465B publication Critical patent/CN102149465B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30223—Cylinder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/304—Composition or microstructure of the elements
    • B01J2219/30475—Composition or microstructure of the elements comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/31—Size details
    • B01J2219/312—Sizes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32279—Tubes or cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

描述了圆柱体形状的催化剂单元，具有长度C和直径D，其具有一个或多个延伸通过其的孔，其中所述圆柱体具有长度A和B的圆顶端，使得(A+B+C)/D在0.50-2.00范围内，且(A+B)/C在0.40-5.00范围内。该催化剂或催化剂单元优选具有一个或多个沿其长度延伸的沟槽。该催化剂可以特别用于蒸汽重整反应器中。

Description

成型的非均相催化剂
技术领域
本发明涉及成型的非均相催化剂。
背景技术
非均相催化剂典型地作为颗粒床提供，液体和/或气体反应混合物通常在升高的温度和压力通过其。因此，非均相催化材料通常以成型形式提供以提供催化剂活性和通过量的平衡。通常，较小的催化剂颗粒具有较高的表面积以及因此具有较高的活性，但提供较低的通过量，因为通过该催化剂床的压降较高。为了与此抗衡，已经使用了各种催化剂设计，其可以具有一个或多个通孔以尝试提高几何表面积并使压降最小化。
WO2004/014549公开了用于气态反应的成型的非均相催化剂，包括圆柱形单元，其具有在约0.5∶1-1∶1范围内的直径与高度比，并具有多个通过其的非圆形横截面的成型孔。一些实施方案另外具有沿该圆柱体的外部长度延伸的V形沟槽。
尽管沟槽和孔都可以提高理论几何表面积，我们发现在将该单元放置在所用的填料床中时通过装填该催化剂能够显著降低有效几何表面积。特别地，反应物通过该孔的流量能够比预测的小得多，因为该圆柱形催化剂单元的端面与其它端面或圆柱面未对齐。我们设计了克服与这种设计相关的问题的催化剂单元。
发明内容
因此，本发明提供了圆柱体形状的催化剂单元，具有长度C和直径D，其具有一个或多个延伸通过其的孔，其中所述圆柱体具有长度A和B的圆顶端，使得(A+B+C)/D在0.50-2.00范围内，且(A+B)/C在0.40-5.00范围内。
本发明进一步提供了催化剂单元的制备方法，包括以下步骤：(i)将粉末材料，非必要地与造粒助剂一起加料到造粒模具中；(ii)压制该粉末以形成成型的单元，和然后(iii)非必要地加热该成型单元以形成催化剂单元，所述模具的形状使得该催化剂单元是圆柱体形状，具有长度C和直径D，其具有一个或多个延伸通过其的孔，以及该圆柱体具有长度A和B的圆顶端，使得(A+B+C)/D在0.50-2.00范围内，且(A+B)/C在0.40-5.00范围内。
本发明进一步提供了使用该催化剂单元的催化方法，通过将反应混合物，优选气态反应混合物，与该催化剂单元在实现该催化反应的条件下接触而进行。
我们发现具有这些比例的本发明的催化剂单元(其中该圆顶端的尺寸相对提高)与现有技术的催化剂相比提供了更大的有效几何表面积。特别地，当堆积在相对直径为颗粒直径的4-25倍的管中时，高度圆顶形的颗粒的压降性能在与仅有很少的或没有圆顶形的相当直径和长度的颗粒相比时显然更好。这种性能的提高归因于在该颗粒上的圆顶的大小，其将使流动的介质具有更少的湍流行为并降低在该床中经历的总能量损失，由此降低总压降。同时，在该床的总径向传热性能方面，圆顶表面将促进管中流动的径向混合以补偿湍流混合中的损失。
该催化剂单元的长径比，其可以定义为总长度除以直径，即(A+B+C)/D，在0.5-2.0范围内。优选地，(A+B+C)/D在0.75-1.50范围内，因为这样降低了该单元堆叠的趋势，并同时提供了降低的破裂趋势。
该圆柱体的一端或两端，优选两端都是圆顶形的。该圆顶端具有长度A和B，其可以相同或不同。该催化剂单元的圆柱体部分的圆顶比(即(A+B)/C)在0.40-5.00范围内，以提供相对高度圆顶形的结构。低于约0.40，该圆顶的作用是不够的，而大于约5.0，该圆顶变得难于制备。在优选实施方案中，(A+B)/C在0.40-3.00范围内，更优选0.50-2.50。该圆顶端可以在横截面中形成一段圆或椭圆，适宜地具有R≥D/2的半径。
对于大多数催化用途，C优选在1-25mm范围内，D优选在4-40mm范围内。
该催化剂单元具有轴向延伸通过其的一个或多个孔。优选地，该单元具有延伸通过其的1-12个孔，更优选3-10个孔，特别3-6个孔。尽管具有7和10个孔的较大单元是已知的，但如果该孔的尺寸是用于提高几何表面积，那么这些能够降低该催化剂的强度。进一步地，具有1或2个孔的催化剂单元的效率和可达性可能较低，因此优选3-6个孔。该孔应当适宜地等距设置并关于该圆柱体的横截面对称设置以使所得到的催化剂的强度最大化。因此1个孔可以设置在中心，3个孔可以呈三角形图案，4个孔可以呈正方向图案，5个孔呈具有中心孔的正方形图案，6个孔可以呈六角形图案，等等。
该孔的横截面可以是圆形的，或者具有前述WO2004/014549中公开的多种横截面中的一种或多种。在优选实施方案中，所有孔的横截面都是圆形的，因为这样使得所得到的催化剂单元的强度最大化。
该孔可以具有相同尺寸或不同尺寸。优选孔具有圆形横截面且独立地具有在0.05D-0.5D，更优选0.15D-0.3D的范围内的直径d’。
适宜地，该催化剂单元具有一个或多个沿其长度延伸的沟槽或通道。该沟槽可以是弯曲的或直的或其组合。优选地，该沟槽是直的且沿该催化剂单元的外部轴向延伸，因为这样使制备简化。该沟槽的型状可以是半圆形的、椭圆形的、U型的、V型的、II型的或这些的变型。
该催化剂单元可以具有2-12个或更多的沟槽，其适宜地是对称设置的，即沿该催化剂单元的外周周围等距设置。在优选设置中，沟槽的数量等于孔的数量。在该设置中，其中存在多于一个孔，它们应当位于在沟槽或通道之间产生的凸部中。在该沟槽是半圆形或椭圆形时，它们可以独立地具有在0.05D-0.5D，优选0.15D-0.333D的范围内的直径d”、宽度或深度。我们特别发现将总沟槽宽度(即组合开口)限制到≤该单元圆周的35％(即≤0.35(πD))是适宜的，因为这样防止了催化剂床中相邻单元的不期望的咬合。咬合能够降低流速而且能够由于杠杆作用产生破裂的催化剂。
沟槽和孔的特别组合提供了优化的几何表面积、空隙度和强度。一种优选的实施方案是具有圆形孔和半圆形或椭圆形沟槽的4孔4沟槽单元。
为了有助于该制备方法，可以设置一个或两个圆顶端以在该成型单元的圆柱形部分的一端或两端上提供凸缘。该凸缘的宽度w’适宜地在0.2-2mm范围内。
该催化剂单元可以由包含一种或多种催化活性金属的粉末状组合物制成，由此直接生成该催化剂，或者也可以由一种或多种粉末状催化剂载体材料制成，然后将所得到的单元进行处理，例如通过用一种或多种金属化合物浸渍或沉积以生成该催化剂。
可以使用粉末状金属、金属氧化物、金属氢氧化物、金属碳酸盐、金属碱式碳酸盐或其混合物制备该催化剂单元。
包含催化活性金属的粉末状组合物可以通过将各金属氧化物、碳酸盐、氢氧化物或碱式碳酸盐混合而制备，或者可以通过已知的沉淀技术制备，由此例如使用碱沉淀剂沉淀出可溶盐的混合物并将其干燥和非必要地煅烧和/或还原和钝化。
优选的催化剂载体材料选自：粉末状的氧化铝、氧化钛、氧化锆、金属铝酸盐或其混合物，其可以包含一种或多种稳定化合物，例如氧化镧、二氧化硅和氧化钾。用这些制备的催化剂单元可以称作成型的催化剂载体单元，因此最终的催化剂将进一步包括已经浸渍到所述成型的催化剂载体单元中和/或沉积在其上的一种或多种金属化合物。
该催化剂单元优选包括一种或多种选自以下的金属：Na、K、Mg、Ca、Ba、Al、Si、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Y、Zr、Nb、Mo、Ru、Rh、Pd、Ag、Sn、Sb、La、Hf、W、Re、Ir、Pt、Au、Pb或Ce。
该催化剂单元可以使用任意已知的催化剂配制剂使用已有方法制备。
在一种实施方案中，该催化剂单元包括一种或多种过渡金属，例如镍、钴、铁或铜，和/或一种或多种贵金属，例如铂、钯、铑、铱或钌，其以金属、氧化物、氢氧化物、碳酸盐或碱式碳酸盐的形式存在。
在可替代的实施方案中，该催化剂单元包括一种或多种过渡金属，例如镍、铜、钴或铁，和/或贵金属，例如铂、钯、铑、铱或钌，其已经浸渍在耐火催化剂载体材料(例如氧化铝、铝酸钙、铝酸镁或氧化锆基成型催化剂载体单元)中或沉积在其上。
在该催化剂中的过渡金属和贵金属含量可以为至多85wt％，但优选在1-60wt％范围内。
造粒是本发明优选的制备方法。因此该催化剂单元的制备方法可以包括以下步骤：(i)将粉末材料，非必要地与造粒助剂或润滑剂(例如石墨或硬脂酸镁)加料到造粒模具中，(ii)压制该粉末以形成成型单元，和然后(iii)非必要地加热该成型单元以形成催化剂单元。可以进行可能包括煅烧的加热步骤，以提高该催化剂单元的强度。
该粉末材料可以包括还原和/或氧化形式的一种或多种催化活性的金属，或者可以是催化剂载体材料，在这种情况中，最终的催化剂可以通过将金属化合物浸渍到该成型的催化剂载体单元中和/或将金属化合物沉积在其上的单独步骤制备。为了实现如此，可以应用已知技术。例如，在一种实施方案中，可以将硝酸镍的溶液浸渍到该成型的催化剂载体单元中，干燥并煅烧以使该硝酸镍分解，由此形成含氧化镍的催化剂。可替代地，该粉末状材料可以是包括已经经过干燥和非必要的煅烧和/或还原和钝化的一种或多种催化金属的沉淀组合物。
也可以使用可替代的制备方法，例如注模，或者也可以是挤出以形成成型的挤出物然后在该挤出物上形成圆顶的两步工序。
包含催化金属化合物的催化剂单元可以经过各种处理，例如用含氢气和/或一氧化碳的气流还原，或硫化(例如用硫化氢)，以使其在使用中具有活性。该后处理可以在异位或原位进行，即在装设到使用其的反应器中之前或之后进行。
依照本发明制备的催化剂单元可以应用于任意非均相催化方法，但优选应用于固定床方法，更优选应用于使用气态反应物的固定床方法。因此该催化方法包括：将反应物混合物(优选气态反应物混合物)与该催化剂在实现该催化反应的条件下接触。该催化方法可以选自加氢处理(例如加氢脱硫、加氢)；蒸汽重整(包括预重整、催化蒸汽重整、自热重整和二段转化和用于直接还原铁的重整方法)、催化部分氧化、水煤气变换(包括等温变换、酸变换、低温变换、中间温变换、中温变换和高温变换反应)、甲烷化、通过费托反应的烃合成、甲醇合成、氨合成、氨氧化和一氧化二氮分解反应。该催化剂单元也可以用于从污染的气体或液体流体流中回收重金属(例如汞和砷)。
本发明的优选用途是烃的催化蒸汽重整，其中烃(例如天然气或石脑油)与蒸汽混合并在升高的温度和压力通过设置在多个外加热催化剂管中的典型地包括在耐火载体上的Ni或另一VIII族金属的催化剂单元的床。另一种优选应用是自热重整和二段转化，其中含烃气体混合物经过用氧气或空气的部分氧化然后所得到的经加热和部分氧化的气体混合物通过再次典型地包括在耐火载体上的Ni或另一VIII族金属的蒸汽重整催化剂的固定床。
附图说明
参照附图描述本发明，其中：
图1是描绘依照本发明的催化剂单元的侧视图，图2是显示图1的催化剂单元的顶部的端视图。
图1和2共同描绘了圆柱体12形状的催化剂单元10，具有长度C和直径D，其具有四个对称设置的延伸通过其的圆形横截面的孔14。四个孔的中心形成了近似正方形的图案。四个孔各自的直径(d’)约为0.18D。该圆柱体12具有长度A和B的圆顶端16、18，在横截面中形成段(segment)。A和B相同。(A+B+C)/D约为1.10。(A+B)/C约为0.75。该催化剂单元具有四个沿其长度延伸且在该单元外周周围等距设置的直沟槽20。该沟槽是等距的相邻孔，即相邻孔和沟槽的中心形成对称三角形。该沟槽都是半圆形的，且具有约0.25D的直径(d”)。该单元具有该圆顶端16、18与该圆柱形部分12相连接的凸缘22。
具体实施方式
进一步参照以下实施例描述本发明。
实施例1
进行一系列蒸汽重整催化剂单元的计算机模拟。实施例1a、1b和1c涉及类似于图1和2中所示但具有椭圆形沟槽的四孔四沟槽高圆顶圆柱形颗粒。对比形状X类似于实施例1a-d，但具有0.13的圆顶比[(A+B)/C]。
Figure BDA0000049732430000071
在相同重整器管中在相同条件下的模拟得到以下结果：
  GSA m2/m3   空隙度
  实施例1a   522   0.58
  实施例1b   609   0.58
  实施例1c   488   0.58
  X   468   0.65
该结果显示依照本发明的催化剂单元具有比对比催化剂更高的GSA。
实施例2
将粉末形式的经喷雾干燥的α-氧化铝催化剂载体材料与0.0-2.0％硬脂酸镁混合并使用水压机在标准操作条件下将其形成如图1和2中所示的成型单元。然后将该成型单元热处理到1100-1600℃以产生所需的孔隙率和强度。然后将该经热处理的成型单元用硝酸镍(II)的水溶液浸渍并在110℃干燥。重复浸渍。最后将该经浸渍的载体加热到550℃以将残余的硝酸盐转化为氧化物。最终的催化剂单元具有在5-20wt％范围内的氧化镍含量。
类似的程序可以应用于制备铝酸钙负载的催化剂单元。

Claims (25)

1.圆柱体形状的催化剂单元，具有长度C和直径D，其具有3-10个延伸通过其的圆形孔，其中所述圆柱体具有长度A和B的圆顶端，使得(A+B+C)/D在0.50-2.00范围内，且(A+B)/C在0.40-5.00范围内。
2.权利要求1的催化剂单元，其中A和B相等。
3.权利要求1的催化剂单元，其中(A+B+C)/D在0.75-1.50范围内。
4.权利要求1的催化剂单元，其中(A+B)/C在0.40-3.00范围内。
5.权利要求1的催化剂单元，具有3-6个延伸通过其的孔。
6.权利要求1的催化剂单元，其中所述孔具有圆形横截面，且独立地具有在0.05D-0.5D范围内的直径d’。
7.权利要求1的催化剂单元，其中该单元的外表面具有一个或多个沿其长度延伸的沟槽。
8.权利要求7的催化剂单元，其中该表面具有2-12个沟槽。
9.权利要求7的催化剂单元，其中该沟槽的数量等于孔的数量。
10.权利要求7的催化剂单元，其中总沟槽宽度≤该单元圆周的35％。
11.权利要求1的催化剂单元，其中设置一个或两个圆顶端以在该圆柱体的一端或两端提供凸缘。
12.权利要求1的催化剂单元，包括金属或选自金属氧化物、金属氢氧化物、金属碳酸盐、金属碱式碳酸盐或其混合物的金属化合物。
13.权利要求12的催化剂单元，其中该金属或金属化合物包括选自以下的一种或多种金属：Na、K、Mg、Ca、Ba、Al、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Y、Zr、Nb、Mo、Ru、Rh、Pd、Ag、Sn、Sb、La、Hf、W、Re、Ir、Pt、Au、Pb或Ce。
14.权利要求1的催化剂单元，包括氧化铝、氧化钛、氧化锆或金属铝酸盐或其混合物。
15.权利要求1的催化剂单元，包含一种或多种已经浸渍到所述单元中和/或沉积在所述单元上的金属化合物。
16.权利要求15的催化剂单元，其中该金属化合物包括一种或多种选自以下的金属：Na、K、Mg、Ca、Ba、Al、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Y、Zr、Nb、Mo、Ru、Rh、Pd、Ag、Sn、Sb、La、Hf、W、Re、Ir、Pt、Au、Pb或Ce。
17.权利要求1的催化剂单元的制备方法，包括以下步骤：（i）将粉末材料加料到造粒模具中，和（ii）压制该粉末以形成成型催化剂单元，所述模具的形状使得该催化剂单元是圆柱体形状，具有长度C和直径D，其具有3-10个延伸通过其的圆形孔，以及该圆柱体具有长度A和B的圆顶端，使得(A+B+C)/D在0.50-2.00范围内，且(A+B)/C在0.40-5.00范围内。
18.权利要求17的方法，其中将造粒助剂与粉末材料一起加料到造粒模具中。
19.权利要求17的方法，其中在压制步骤（ii）之后，加热该成型催化剂单元以形成催化剂单元。
20.权利要求17-19中任一项的方法，其中该粉末材料是包括一种或多种催化金属的沉淀组合物，其已经经过干燥和煅烧和/或还原和钝化。
21.权利要求17-19中任一项的方法，其中该粉末材料是催化剂载体材料。
22.权利要求21的方法，其中该方法进一步包括通过用一种或多种金属化合物浸渍或沉积而处理所得到的单元的步骤。
23.使用权利要求1-16中任一项的或权利要求17-22中任一项制备的催化剂单元的催化方法，包括将反应混合物与催化剂单元在实现催化反应的条件下接触。
24.权利要求23的催化方法，选自以下：加氢处理；蒸汽重整；催化部分氧化；水煤气变换；甲烷化；通过费托反应的烃合成；甲醇合成；氨合成；氨氧化和一氧化二氮分解反应，或用于从污染的气体或液体流体流中回收重金属。
25.权利要求23的催化方法，其中催化反应是加氢。
CN200980135459XA 2008-09-12 2009-08-24 成型的非均相催化剂 Active CN102149465B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0816703.3 2008-09-12
GBGB0816703.3A GB0816703D0 (en) 2008-09-12 2008-09-12 Shaped heterogeneous catalysts
PCT/GB2009/051051 WO2010029323A1 (en) 2008-09-12 2009-08-24 Shaped heterogeneous catalysts

Publications (2)

Publication Number Publication Date
CN102149465A CN102149465A (zh) 2011-08-10
CN102149465B true CN102149465B (zh) 2013-12-18

Family

ID=39930054

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200980135459XA Active CN102149465B (zh) 2008-09-12 2009-08-24 成型的非均相催化剂

Country Status (16)

Country Link
US (1) US8557728B2 (zh)
EP (1) EP2323762B1 (zh)
JP (1) JP5575772B2 (zh)
KR (1) KR101595598B1 (zh)
CN (1) CN102149465B (zh)
AU (1) AU2009290700B2 (zh)
BR (1) BRPI0918782A2 (zh)
CA (1) CA2735972A1 (zh)
DK (1) DK2323762T3 (zh)
EG (1) EG27134A (zh)
GB (1) GB0816703D0 (zh)
NZ (1) NZ591447A (zh)
PL (1) PL2323762T3 (zh)
RU (1) RU2488443C2 (zh)
WO (1) WO2010029323A1 (zh)
ZA (1) ZA201101860B (zh)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0907539D0 (en) 2009-05-01 2009-06-10 Johnson Matthey Plc Catalyst preparation method
MX2012010596A (es) * 2010-03-19 2012-10-03 Topsoe Haldor As Catalizador de reformado.
GB201014950D0 (en) * 2010-09-08 2010-10-20 Johnson Matthey Plc Catalyst manufacturing method
GB201018152D0 (en) 2010-10-27 2010-12-08 Johnson Matthey Plc Catalyst preparation method
CA3092028C (en) 2012-01-13 2022-08-30 Lummus Technology Llc Process for separating hydrocarbon compounds
US9969660B2 (en) 2012-07-09 2018-05-15 Siluria Technologies, Inc. Natural gas processing and systems
EP2716363A1 (en) 2012-10-04 2014-04-09 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Optimized catalyst shape for steam methane reforming processes
CN102909085A (zh) * 2012-10-12 2013-02-06 安徽工程大学 一种加氢催化剂颗粒
CN102909091A (zh) * 2012-10-20 2013-02-06 安徽工程大学 一种固体催化剂颗粒
AU2013355038B2 (en) 2012-12-07 2017-11-02 Lummus Technology Llc Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
WO2015081122A2 (en) 2013-11-27 2015-06-04 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
US10301234B2 (en) 2014-01-08 2019-05-28 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
AU2015204709B2 (en) 2014-01-09 2019-08-15 Lummus Technology Llc Oxidative coupling of methane implementations for olefin production
GB201403787D0 (en) 2014-03-04 2014-04-16 Johnson Matthey Plc Steam reforming
GB201403788D0 (en) 2014-03-04 2014-04-16 Johnson Matthey Plc Catalyst arrangement
TWI534131B (zh) 2014-11-27 2016-05-21 財團法人工業技術研究院 氫化４，４’－二胺基二苯甲烷的觸媒與方法
US10112830B2 (en) * 2014-12-08 2018-10-30 Clariant Corporation Shaped catalyst for sour gas shift reactions and methods for using them
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
EP3302751B1 (en) * 2015-06-02 2022-11-30 Scientific Design Company Inc. Porous bodies with enhanced pore architecture
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
CN106540727A (zh) * 2015-09-17 2017-03-29 刘清源 一种丁烷氧化制顺酐的异形催化剂颗粒
EP3362425B1 (en) 2015-10-16 2020-10-28 Lummus Technology LLC Separation methods and systems for oxidative coupling of methane
GB201519139D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
WO2017072481A1 (en) 2015-10-29 2017-05-04 Johnson Matthey Public Limited Company Water-gas shift catalyst
GB201519133D0 (en) * 2015-10-29 2015-12-16 Johnson Matthey Plc Process
US9944573B2 (en) 2016-04-13 2018-04-17 Siluria Technologies, Inc. Oxidative coupling of methane for olefin production
WO2018118105A1 (en) 2016-12-19 2018-06-28 Siluria Technologies, Inc. Methods and systems for performing chemical separations
EP3630707B1 (en) 2017-05-23 2023-09-06 Lummus Technology LLC Integration of oxidative coupling of methane processes
WO2019010498A1 (en) 2017-07-07 2019-01-10 Siluria Technologies, Inc. SYSTEMS AND METHODS FOR OXIDIZING METHANE COUPLING
US10626014B2 (en) 2017-07-25 2020-04-21 Praxiar Technology, Inc. Reactor packing with preferential flow catalyst
CN107999080A (zh) * 2018-01-08 2018-05-08 四川天科技股份有限公司 一种用于直接还原铁工艺的烃类重整催化剂、制备及应用
KR20210042158A (ko) * 2018-08-21 2021-04-16 셰브런 유.에스.에이.인크. 방향족 탄화수소를 제조하기 위한 촉매 개질 공정 및 시스템
EA202191639A1 (ru) * 2018-12-12 2021-09-23 Хальдор Топсёэ А/С Форма частиц катализатора
GB201907062D0 (en) 2019-05-20 2019-07-03 Johnson Matthey Plc Catalyst preparation method
KR20220091584A (ko) * 2019-10-31 2022-06-30 차이나 페트로리움 앤드 케미컬 코포레이션 담지 촉매, 그 제조 방법 및 그 용도
KR20220151163A (ko) * 2020-04-01 2022-11-14 스미또모 가가꾸 가부시끼가이샤 성형 촉매 및 할로겐의 제조 방법
WO2021239483A1 (en) * 2020-05-26 2021-12-02 Basf Se Shaped catalyst body with improved properties, its preparation and use
EP4188598A1 (en) 2020-07-29 2023-06-07 Basf Se Solid shaped body and use of the solid shaped body
US20230311108A1 (en) 2020-07-29 2023-10-05 Basf Se Solid shaped body and use of the solid shaped body
RU2753669C1 (ru) * 2020-11-17 2021-08-19 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Катализатор для гетерогенных реакций с пониженным гидравлическим сопротивлением слоя

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5371277A (en) * 1990-07-03 1994-12-06 Kuraray Co., Ltd. Carrier, catalyst and process for producing unsaturated ester

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2212932A (en) * 1938-10-28 1940-08-27 Fairlie Andrew Miller Filling material for reaction spaces
US2408164A (en) 1942-04-25 1946-09-24 Phillips Petroleum Co Catalyst preparation
US2684922A (en) * 1950-05-06 1954-07-27 Reynolds Metals Co Method of making planographic printing sheets
GB893987A (en) 1958-11-07 1962-04-18 Napier & Son Ltd Catalysts for decomposing hydrogen peroxide
US3764565A (en) 1970-03-09 1973-10-09 Standard Oil Co Catalyst for hydrocracking a resid hydrocarbon
SU957948A1 (ru) 1980-08-29 1982-09-15 Предприятие П/Я Р-6603 Носитель дл катализатора конверсии метана
US4328130A (en) 1980-10-22 1982-05-04 Chevron Research Company Shaped channeled catalyst
BE886363A (fr) * 1980-11-26 1981-03-16 Catalysts & Chem Europ Catalyseurs de reformage et leur utilisation
US4394303A (en) 1981-05-12 1983-07-19 Chevron Research Company Large pore shaped hydroprocessing catalysts
US4441990A (en) 1982-05-28 1984-04-10 Mobil Oil Corporation Hollow shaped catalytic extrudates
DE3221582A1 (de) 1982-06-08 1983-12-08 Basf Ag, 6700 Ludwigshafen Katalysator zur konvertierung schwefelhaltiger gase
US4517077A (en) 1983-11-14 1985-05-14 Katalco Corporation Shaped catalyst particle for use in hydroprocessing of petroleum oils
DE3445289A1 (de) * 1984-12-12 1986-06-19 Basf Ag, 6700 Ludwigshafen Geformter katalysator fuer heterogen katalysierte reaktionen
NZ217874A (en) 1985-10-25 1989-01-27 Mobil Oil Corp Quadrulobe catalysts
CA2110579C (en) 1991-07-08 2005-06-21 Jerry Rudolph Ebner High productivity process for the production of maleic anhydride
IT1256156B (it) 1992-10-06 1995-11-29 Montecatini Tecnologie Srl Catalizzatore in granuli particolarmente per la deidrogenazione ossidativa di metanolo a formaldeide
JP3592051B2 (ja) 1997-10-03 2004-11-24 任天堂株式会社 歩数計
DE19751962A1 (de) * 1997-11-24 1999-07-29 Wacker Chemie Gmbh Trägerkatalysator, Verfahren zu dessen Herstellung sowie Verwendung bei der Oxichlorierung von Ethylen
CN2388204Y (zh) 1998-07-07 2000-07-19 江西省萍乡市化工填料(集团)公司 一种多叶型凹凸椭球状孔式催化剂
EP0998976A1 (en) 1998-11-04 2000-05-10 Engelhard Corporation Star shaped alumina extrudates and catalyst based thereon
DE10009017A1 (de) * 2000-02-25 2001-09-06 Basf Ag Geformte Katalysatoren
DE10053494A1 (de) * 2000-10-27 2002-05-02 Basf Ag Katalysator und Verfahren zur Herstellung von Maleinsäureanhydrid
DE10101695A1 (de) * 2001-01-15 2002-07-18 Basf Ag Verfahren zur heterogen katalysierten Gasphasenpartialoxidation von Vorläuferverbindungen der (Meth)acrylsäure
WO2002087756A1 (fr) 2001-04-26 2002-11-07 INSTITUT KATALZA IMENI G.K. BORESKOVA Sibirskogo otdeleniya Rossiiskoi Akademii nauk Catalyseur et procede de fabrication d'un gaz de synthese par la conversion d'hydrocarbures en phase vapeur
BR0211583A (pt) * 2001-08-01 2004-07-13 Shell Int Research Partìcula conformada alongada, leito de proteção, processos para reduzir incrustação ou o impacto de deposição de incrustação em leitos de catalisadores, para a conversão de uma carga orgânica, para a produção de destilados médios a partir de gás de sìntese, e para a conversão de hidrocarbonetos
US20040043900A1 (en) 2002-08-12 2004-03-04 Combs Glenn A. Heterogeneous gaseous chemical reactor catalyst
CN2686721Y (zh) 2004-03-17 2005-03-23 张强 一种多孔催化剂载体
CN2684922Y (zh) 2004-03-25 2005-03-16 翁子斌 空心形水煤气变换催化剂
DE102005019596A1 (de) 2005-04-27 2006-11-02 Süd-Chemie AG Katalysatorträger
EP1792651A1 (de) 2005-11-23 2007-06-06 Süd-Chemie Ag Schalenkatalysator, insbesondere zur Oxidation von Methanol zu Formaldehyd sowie Verfahren zu dessen Herstellung
WO2008087149A1 (en) 2007-01-18 2008-07-24 Shell Internationale Research Maatschappij B.V. Catalyst, catalyst precursor, catalyst carrier, preparation and use of thereof in fischer-tropsch synthesis
EP2658829A4 (en) * 2010-12-29 2014-08-13 Saint Gobain Ceramics MULTILOBE POROUS CERAMIC BODY AND METHOD OF MANUFACTURING THE CERAMIC BODY

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5371277A (en) * 1990-07-03 1994-12-06 Kuraray Co., Ltd. Carrier, catalyst and process for producing unsaturated ester

Also Published As

Publication number Publication date
RU2488443C2 (ru) 2013-07-27
EP2323762A1 (en) 2011-05-25
DK2323762T3 (en) 2016-11-28
NZ591447A (en) 2012-11-30
KR20110055727A (ko) 2011-05-25
US20110201494A1 (en) 2011-08-18
BRPI0918782A2 (pt) 2015-12-01
JP5575772B2 (ja) 2014-08-20
EP2323762B1 (en) 2016-07-27
CN102149465A (zh) 2011-08-10
KR101595598B1 (ko) 2016-02-18
EG27134A (en) 2015-07-30
ZA201101860B (en) 2011-11-30
RU2011114153A (ru) 2012-10-20
AU2009290700B2 (en) 2014-03-13
JP2012501843A (ja) 2012-01-26
WO2010029323A1 (en) 2010-03-18
CA2735972A1 (en) 2010-03-18
AU2009290700A1 (en) 2010-03-18
PL2323762T3 (pl) 2017-09-29
GB0816703D0 (en) 2008-10-22
US8557728B2 (en) 2013-10-15

Similar Documents

Publication Publication Date Title
CN102149465B (zh) 成型的非均相催化剂
CN102149464B (zh) 成型的非均相催化剂
CN102149466B (zh) 成型异相催化剂
US20040013606A1 (en) Method and apparatus for obtaining enhanced production rate of thermal chemical reactions
CN106582468B (zh) 一种轴向微通道耦合反应器及应用
JP3574469B2 (ja) Ｃｏのｃｏ２への酸化方法及び燃料電池用の水素含有ガスの製造方法
JP3773967B2 (ja) 燃料電池用水素含有ガスの製造方法
JPS6261641A (ja) モノリス型メタノ−ル水蒸気改質触媒の製造方法
Becker et al. Fischer–Tropsch Catalysts
JP4209868B2 (ja) 燃料電池用水素含有ガスの製造方法
WO1999001210A1 (en) Reactor and method for carrying out a chemical reaction

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant