CN1021049C - 汽相氢化马来酸酐制备四氢呋喃和γ-丁内酯混合物的方法 - Google Patents
汽相氢化马来酸酐制备四氢呋喃和γ-丁内酯混合物的方法 Download PDFInfo
- Publication number
- CN1021049C CN1021049C CN 88108781 CN88108781A CN1021049C CN 1021049 C CN1021049 C CN 1021049C CN 88108781 CN88108781 CN 88108781 CN 88108781 A CN88108781 A CN 88108781A CN 1021049 C CN1021049 C CN 1021049C
- Authority
- CN
- China
- Prior art keywords
- tetrahydrofuran
- thf
- butyrolactone
- gamma
- maleic anhydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 title claims abstract 12
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 title claims abstract 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 title claims abstract 6
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 title claims abstract 4
- 238000005984 hydrogenation reaction Methods 0.000 title claims 4
- 239000012808 vapor phase Substances 0.000 title 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000001257 hydrogen Substances 0.000 claims abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 4
- 239000003054 catalyst Substances 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims 4
- 150000008065 acid anhydrides Chemical class 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 239000002994 raw material Substances 0.000 claims 2
- 238000009903 catalytic hydrogenation reaction Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 230000035484 reaction time Effects 0.000 claims 1
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical compound O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 claims 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 abstract 2
- 229940014800 succinic anhydride Drugs 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/06—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
- C07D307/08—Preparation of tetrahydrofuran
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13704287A | 1987-12-23 | 1987-12-23 | |
| US137,042 | 1987-12-23 | ||
| US23194088A | 1988-08-15 | 1988-08-15 | |
| US231,940 | 1988-08-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1034541A CN1034541A (zh) | 1989-08-09 |
| CN1021049C true CN1021049C (zh) | 1993-06-02 |
Family
ID=26834857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 88108781 Expired - Fee Related CN1021049C (zh) | 1987-12-23 | 1988-12-22 | 汽相氢化马来酸酐制备四氢呋喃和γ-丁内酯混合物的方法 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0322140B1 (enExample) |
| JP (1) | JPH02786A (enExample) |
| CN (1) | CN1021049C (enExample) |
| CA (1) | CA1327812C (enExample) |
| DE (1) | DE3876083T2 (enExample) |
| ES (1) | ES2052748T3 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5055599A (en) * | 1989-06-23 | 1991-10-08 | The Standard Oil Company | Process for the hydrogenation of maleic anhydride to tetrahydrofuran and gamma-butyrolactone |
| US5041564A (en) * | 1990-04-16 | 1991-08-20 | Gaf Chemicals Corporation | Vapor phase process for production of gamma-butyrolactone |
| US5347021A (en) * | 1990-04-16 | 1994-09-13 | Isp Investments Inc. | Process of vapor phase catalytic hydrogenation of maleic anhydride to gamma-butyrolactone in high conversion and high selectivity using an activated catalyst |
| IT1273320B (it) * | 1994-02-22 | 1997-07-08 | Alusuisse Italia Spa | Procedimento per la produzione di gamma-butirrolattone |
| US5637735A (en) * | 1994-08-10 | 1997-06-10 | China Petrochemical Corporation | Process for the preparation of gamma-butyrolactone |
| BE1011699A6 (fr) * | 1998-01-08 | 1999-12-07 | Pantochim Sa | Procede de production de tetrahydrofuranne et de gamma-butyrolactone. |
| IT1298535B1 (it) | 1998-02-02 | 2000-01-12 | Lonza Spa | Procedimento per la produzione di gamma-butirrolattone |
| DE10061558A1 (de) | 2000-12-11 | 2002-06-13 | Basf Ag | Verfahren zur Hydrierung von Maleinsäureanhydrid und verwandten Verbindungen in einem Wirbelschichtreaktor |
| DE10061556A1 (de) * | 2000-12-11 | 2002-06-13 | Basf Ag | Verfahren zur Herstellung von Tetrahydrofuran |
| DE10209633A1 (de) * | 2002-03-02 | 2003-09-11 | Basf Ag | Verfahren zur gleichzeitigen Herstellung von Tetrahydrofuran und Pyrrolidonen |
| DE10219224A1 (de) * | 2002-04-30 | 2003-11-13 | Basf Ag | Verfahren zur Herstellung von gamma-Butyrolacton |
| DE10225926A1 (de) | 2002-06-11 | 2003-12-24 | Basf Ag | Verfahren zur Herstellung von Butandiol |
| DE10225927A1 (de) | 2002-06-11 | 2003-12-24 | Basf Ag | Verfahren zur Herstellung von Butandiol durch kombinierte Gasphasen- und Flüssigphasensynthese |
| DE10225929A1 (de) | 2002-06-11 | 2003-12-24 | Basf Ag | Zweistufiges Verfahren zur Herstellung von Butandiol mit Zwischenabtrennung von Bernsteinsäureanhydrid |
| CN101502803B (zh) * | 2009-03-19 | 2011-11-02 | 复旦大学 | 用于马来酸二甲酯选择加氢制备1,4-丁二醇或四氢呋喃的催化剂及其制备方法 |
| US20130296585A1 (en) * | 2012-03-30 | 2013-11-07 | Basf Corporation | Catalyst For Tetrahydrofuran Synthesis |
| CN107108538B (zh) * | 2015-01-09 | 2020-10-27 | 巴斯夫欧洲公司 | 制备四氢呋喃、1,4-丁二醇或γ-丁内酯的方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE743652A (enExample) * | 1968-12-26 | 1970-05-28 | ||
| JPS4949953A (enExample) * | 1972-09-18 | 1974-05-15 | ||
| US4001282A (en) * | 1973-02-12 | 1977-01-04 | General Electric Company | Process for producing gamma-butyrolactone |
| US4083809A (en) * | 1976-08-20 | 1978-04-11 | Gaf Corporation | Hydrogenation catalyst and method of producing same |
-
1988
- 1988-12-01 CA CA 584709 patent/CA1327812C/en not_active Expired - Fee Related
- 1988-12-09 DE DE19883876083 patent/DE3876083T2/de not_active Expired - Fee Related
- 1988-12-09 EP EP19880311659 patent/EP0322140B1/en not_active Expired
- 1988-12-09 ES ES88311659T patent/ES2052748T3/es not_active Expired - Lifetime
- 1988-12-22 CN CN 88108781 patent/CN1021049C/zh not_active Expired - Fee Related
- 1988-12-23 JP JP63325724A patent/JPH02786A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| ES2052748T3 (es) | 1994-07-16 |
| DE3876083D1 (de) | 1992-12-24 |
| DE3876083T2 (de) | 1993-03-25 |
| CN1034541A (zh) | 1989-08-09 |
| JPH02786A (ja) | 1990-01-05 |
| JPH0575749B2 (enExample) | 1993-10-21 |
| CA1327812C (en) | 1994-03-15 |
| EP0322140B1 (en) | 1992-11-19 |
| EP0322140A1 (en) | 1989-06-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |