CN102017958A - Composite insecticidal composition containing pymetrozine and propylene glycol alginate and application thereof - Google Patents

Composite insecticidal composition containing pymetrozine and propylene glycol alginate and application thereof Download PDF

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Publication number
CN102017958A
CN102017958A CN2009101834921A CN200910183492A CN102017958A CN 102017958 A CN102017958 A CN 102017958A CN 2009101834921 A CN2009101834921 A CN 2009101834921A CN 200910183492 A CN200910183492 A CN 200910183492A CN 102017958 A CN102017958 A CN 102017958A
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Prior art keywords
pyrrole aphid
aphid ketone
propylene glycol
alcohol ester
glycol alginate
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CN2009101834921A
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CN102017958B (en
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杨寿海
陈新春
陈文明
郭崇友
齐武
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Abstract

The invention discloses a composite insecticidal composition containing pymetrozine and propylene glycol alginate and the application thereof. The insecticidal composition uses pymetrozine and propylene glycol alginate as main active ingredients, wherein the weight ratio of the pymetrozine to the propylene glycol alginate is 0.1-80 to 0.1-60. The insecticidal composition can generate higher synergy, overcome and delay the drug resistance of pests, expand the prevention spectrum, have high desinsection speed, decrease the drug cost and lessen the toxicity. The insecticidal composition can prevent hemiptera pests on crops and particularly can be used for preventing paddy delphacidae and wheat aphids, and the effect of the insecticidal composition is significantly higher than that of single agent.

Description

A kind of compound pesticide compositions that contains pyrrole aphid ketone and propylene glycol alginate and uses thereof
Technical field
The invention belongs to pesticide field, being specifically related to a kind of is compound pesticide compositions of main active ingredient and uses thereof with pyrrole aphid ketone and propylene glycol alginate.
Background technology
Pyrrole aphid ketone (pymetrozine), chemical name: (E)-4,5-dihydro-6-methyl-4-(3-pyridine methylene amino)-1,2,4-triazine-3 (2H)-ketone.Being Switzerland Novartis Co.,Ltd eliminates aphis and the new type heterocycle class insecticidal materials of aleyrodid in exploitation in 1988 anti-, has efficient, low toxicity, high selectivity, characteristics such as environmentally friendly.Its mode of action uniqueness: mainly be the feed behavior that influences insect, make its food refusal and dead.This medicine is all effective to larva and adult, and its energy rapid osmotic is in plant leaf blade, and the longevity of residure reached more than one month, and did not have any cross resistance, to the natural enemies security height.Pyrrole aphid ketone is all effective to larva or adult, and this medicine can be penetrated in the plant leaf blade very soon, and residual effect reaches one month, because no cross resistance, to the natural enemy high safety, very suitable resistant insect control.Pyrrole aphid ketone has very high preventive effect to aphid, plant hopper, leafhopper, aleyrodid, the Chinese toon rubber of crops such as paddy rice, vegetables, cotton, wheat, fruit tree.This medicine is splendid to Semiptera insect selectivity, and the selectivity of aphid is better than best anti-aphid agent-Aphox at present, and this medicine also has good interior absorption, and its systemic activity is 2~3 times of Aphox, is more than 143 times of cypermethrin.The acute oral LD of its former medicine 50Be 5820mg/kg, acute through skin LD 50(24h)>2000mg/kg.Along with the whole world is more and more paid attention to environmental protection, low toxicity, demand efficient, eco-friendly insecticidal materials increase year by year, high poison, high residue, to ecotope, and its exploitation has good prospect, will bring huge social benefit and economic benefit.But its market price is higher.
Propylene glycol alginate gets Main Ingredients and Appearance by the marine algae extract alginic acid through esterification: its part carboxyl of alginate esters class is by the propane diols esterification.It is a kind of Biocidal medicine of physical action mechanism, and the mode of action is for tagging, and with its distinctive viscosity and tagging property of physics, sealing or obstruction insect are blocked metabolism and the circulation canal of insect in order to the pore of respiratory metabolism fast, and it is dead that it is suffocated.It has lethal effect to small-sized soft-bodied insects, can prevent and treat adult and the larva of insects such as trialeurodes vaporariorum, rice fulgorid, Bemisia tabaci, small brown rice planthopper, pear sucker, leafhopper, tetranychid effectively.The propylene glycol alginate edible at home and abroad is widely used in the food service industry as food additives, and is all harmless to people and environment, slight to the influence of insect pollinator and natural enemy, belongs to the low toxicity insecticidal materials.
Pyrrole aphid ketone is to inhale infiltrative acetylcholinesteraseinhibitors inhibitors in having, and propylene glycol alginate is typical physics contact insecticide, the inventor finds that both are composite and can improve insecticidal effect, enlarge insecticidal spectrum, improve the quick-acting of medicament, reduce dosage, alleviate the medicament selection pressure, the generation of delaying drug resistance and development.
Summary of the invention
The purpose of this invention is to provide a kind of compound pesticide compositions that contains pyrrole aphid ketone and propylene glycol alginate.
Another object of the present invention provides a kind of this compound pesticide compositions and prevents and treats application on the insecticidal materials of resistance Semiptera insect in preparation.
For achieving the above object, pyrrole aphid ketone and propylene glycol alginate that the present invention will grow the lasting period are composite, obtain the present invention's multifunctional insecticide composition efficiently.This insecticidal materials has good preventive effect to the various pests that rice fulgorid and wheat aphid are easy to generate resistance; And the inhibition insect is to the pesticide resistance generation of pyrrole aphid ketone.
The present invention is by following scheme implementation:
A kind of compound pesticide compositions that contains pyrrole aphid ketone and propylene glycol alginate is characterized in that it contains pyrrole aphid ketone and propylene glycol alginate is main active ingredient, and wherein, the weight ratio of pyrrole aphid ketone and alginic acid malonic acid alcohol ester is 0.1~80: 0.1~60.The effective ingredient of above-mentioned desinsection combination is present in the composition with the synergy effective dose.
The weight ratio preferred 1~60: 0.5~30 of pyrrole aphid ketone and alginic acid malonic acid alcohol ester in this Synergistic insecticidal compositions, the best is 5~40: 0.5~20.
In the present composition, the two percentage by weight that accounts for composition of pyrrole aphid ketone and alginic acid malonic acid alcohol ester is 1~80%.Be preferably 5~50%, most preferably 5~30%.
Above-mentioned desinsection combination is that main active ingredient (active component) and insecticides adjuvant, excipients are mixed with any one formulation that allows on the agricultural chemicals with pyrrole aphid ketone and propylene glycol alginate.The preferred pulvis of described formulation, wetting powder, aqueous emulsion, suspending agent, microemulsion, missible oil and water dispersion granule.Described auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound (as farming breast 33 #, farming breast 1601 #), the one or more combinations in the polyoxyethylene nonylphenol ether, excipient comprises cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient can be singly with or and also can add other auxiliary material with reaching.
Above-mentioned Pesticidal combination is prevented and treated the application on the insecticidal materials of resistance Semiptera insect in preparation, especially use on the insecticidal materials of preparation control water rice hopper, aleyrodid and wheat aphid.
Pesticidal combination of the present invention has following beneficial effect: (1) is compared with single agent, and said composition has notable synergistic to insect, has obviously improved control efficiency; (2) alternative high-toxic pesticide, and reduce the field dosage significantly, effectively reduce environmental pollution and residue of pesticide; (3) have concurrently quick-acting and long-acting; (4) compare with the agent of pyrrole aphid ketone list, produce and the use cost reduction; (5) suppress the resistance enhancing of insect to agricultural chemicals.
Embodiment
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.Pass through indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage earlier; On this basis, carry out field trial again.
Embodiment 1:
Taking by weighing pyrrole aphid ketone, ether chrysanthemum ester, to adopt the conventional formulation method to be mixed with main effectively composition quality percentage composition by different proportion be 30% pyrrole aphid ether ketone chrysanthemum emulsifiable concentrate.Concrete ratio sees Table 1,2.
Adopt rice stem infusion process to measure pyrrole aphid ketone and propylene glycol alginate and composite sample thereof the virulence to the paddy rice brown planthopper, every processing repeats 3 times, and every concentration is handled 30, uses LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
The compound pesticide compositions of table 1 pyrrole aphid ketone and propylene glycol alginate is to toxicity test and the co-toxicity coefficient of paddy rice brown planthopper
Data show in the table, and pyrrole aphid ketone and the propylene glycol alginate back that is mixed has synergistic effect to the paddy rice brown planthopper, and three listed in table proportioning co-toxicity coefficients are all greater than 120, so pyrrole aphid ketone and propylene glycol alginate are mixed and have significant synergies.Wherein classify 1: 10 mixed synergies maximum as when both ratios, co-toxicity coefficient is 180.56.
Employing is soaked the leaf dip method and is measured pyrrole aphid ketone and Biphenthrin and composite sample thereof the virulence to wheat aphid, and every processing repeats 3 times, uses LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
The compound pesticide compositions of table 2 pyrrole aphid ketone and propylene glycol alginate is to the toxicity test and the co-toxicity coefficient of wheat aphid
Data show in the table, and pyrrole aphid ketone and the propylene glycol alginate back that is mixed has synergistic effect to wheat aphid, and three listed proportionings have two co-toxicity coefficients greater than 120 in the table, so pyrrole aphid ketone and propylene glycol alginate are mixed and have significant synergies.Wherein classify 1: 20 mixed synergies maximum as when both ratios, co-toxicity coefficient is 128.20.
Embodiment 2:
Take by weighing 21g pyrrole aphid ketone, 4g propylene glycol alginate, wetting agent 10g, auxiliary agent 2g, add to 100g, above raw material is mixed in micronizer, form 25% pyrrole aphid ketone methyl poison wetting powder with filler.
Adopt the field trial that sample carries out control in field paddy rice small brown rice planthopper that embodiment 2 joins, the contrast medicament is 25% pyrrole aphid ketone and 40% propylene glycol alginate EC, and concrete consumption sees Table 3, every mu of water consumption is 30kg, looks into 7 days behind the medicine 3 days, 14 days, 28 days results, result of the test sees Table 3:
Table 3 example 2 samples are to the field test results of paddy rice brown planthopper
2 pairs of paddy rice brown planthoppers of example have fabulous quick-acting as can be seen from Table 3, and the lasting period is long, performance is good in the field, the pyrrole aphid ketone wetting powder of effect apparently higher than 25%, anti-usefulness reaches about 90% when mu consumption 15ml, the effect that obviously is better than 25% pyrrole aphid ketone mu consumption 16ml is the outstanding medicament of control paddy rice brown planthopper.
Adopt the field trial that sample carries out the control in field wheat aphid that embodiment 2 joins, the contrast medicament is 25% pyrrole aphid ketone and 40% propylene glycol alginate EC, and concrete consumption sees Table 4, every mu of water consumption is 30kg, looks into 7 days behind the medicine 3 days, 14 days, 28 days results, result of the test sees Table 4:
Table 4 example 2 samples are to the wheat aphid field test results
2 pairs of wheat aphids of example have fabulous quick-acting as can be seen from Table 4, and the lasting period is long, and are good in field performance, and the pyrrole aphid ketone wetting powder of effect apparently higher than 25% is the outstanding medicament of control wheat aphid.
Measure through indoor synergism test and to show: water rice hopper and two kinds of insects of wheat aphid are all had significant synergistic insecticidal action by composite dose of pyrrole aphid ketone and propylene glycol alginate; Field control effectiveness test equally also shows the composite dose of effect that the insecticidal effect of water rice hopper and wheat aphid all is significantly higher than corresponding single agent agricultural chemicals that the present invention is all.
Embodiment 3:
Take by weighing 30g pyrrole aphid ketone, 2g propylene glycol alginate, lignin 10g, naphthalene sulfonate 2g, add to 100g, above raw material is mixed in micronizer, form 32% pyrrole aphid ketone methyl poison wetting powder with diatomite.
Embodiment 4:
Take by weighing 10g pyrrole aphid ketone, 1g propylene glycol alginate, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms pyrrole aphid ketone propylene glycol alginate missible oil.
Embodiment 5:
Take by weighing 20g pyrrole aphid ketone, 2g propylene glycol alginate, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butanol 5g, dimethylbenzene 30g and pyrrolidones 20g, the xanthans of 0.1g, all the other waters are supplied, stabilizing agent n-butanol and the water-soluble formation water of separating, former medicine, solvent, emulsifier, cosolvent mix stirring and form oil phase, slowly water are added in the oil phase under the clipper effect and go, and continue to shear 10~30 minutes, form 22% pyrrole aphid ketone propylene glycol alginate aqueous emulsion.
Embodiment 6:
Take by weighing 20g pyrrole aphid ketone, 20g propylene glycol alginate, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, the solvent xylene of 30g and the pyrrolidones of 15g, all the other waters are supplied, former medicine, solvent, emulsifier, cosolvent mix stirring and form homogeneous phase transparent solution, slowly add entry then and stir the formation clear solution, be 40% pyrrole aphid ketone propylene glycol alginate microemulsion.
Embodiment 7:
Take by weighing 5g pyrrole aphid ketone, 60g propylene glycol alginate, the 2g of lignin salt, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, defoamer silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water is supplied 100g, forms 65% pyrrole aphid ketone propylene glycol alginate suspending agent under the effect of sand mill.
Embodiment 8:
Take by weighing 10g pyrrole aphid ketone, 1g propylene glycol alginate, methyl naphthalene sulfonate formaldehyde condensate 6g, polyoxyethylene nonylphenol ether 3g, aluminium-magnesium silicate 0.5g, ethylene glycol 7g, tributyl phosphate 2g, silicone oil 0.2g, surplus is a water, above raw material is prepared the method for suspending agent routinely, form 11% pyrrole aphid ketone propylene glycol alginate suspending agent.
Embodiment 9:
Take by weighing 45g pyrrole aphid ketone, 45g propylene glycol alginate, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g forms 50% pyrrole aphid ketone propylene glycol alginate water dispersible granules with above raw material by the method for water dispersion granule.
Embodiment 10:
Take by weighing 70g pyrrole aphid ketone, 10g propylene glycol alginate, alkylphenol polyoxyethylene 5g, phenethyl phenol polyethenoxy ether 5g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 80% pyrrole aphid ketone propylene glycol alginate missible oil.
Embodiment 11:
Take by weighing 55g pyrrole aphid ketone, 0.5g propylene glycol alginate, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 55.5% pyrrole aphid ketone propylene glycol alginate missible oil.

Claims (9)

1. compound pesticide compositions that contains pyrrole aphid ketone and propylene glycol alginate, it is characterized in that this compound pesticide compositions is main active ingredient with pyrrole aphid ketone and propylene glycol alginate, wherein, the weight ratio of pyrrole aphid ketone and alginic acid malonic acid alcohol ester is 0.1~80: 0.1~60.
2. compound pesticide compositions according to claim 1 is characterized in that the effective ingredient pyrrole aphid ketone of this compound pesticide compositions and the weight ratio of alginic acid malonic acid alcohol ester are 1~60: 0.5~30.
3. compound pesticide compositions according to claim 2 is characterized in that the effective ingredient pyrrole aphid ketone of this compound pesticide compositions and the weight ratio of alginic acid malonic acid alcohol ester are 5~40: 0.5~20.
4. the Synergistic insecticidal compositions that contains pyrrole aphid ketone and alginic acid malonic acid alcohol ester according to claim 1 is characterized in that the two weight percentage that accounts for composition of pyrrole aphid ketone and alginic acid malonic acid alcohol ester is 1~80%.
5. the Synergistic insecticidal compositions that contains pyrrole aphid ketone and alginic acid malonic acid alcohol ester according to claim 4 is characterized in that the two weight percentage that accounts for composition of pyrrole aphid ketone and alginic acid malonic acid alcohol ester is 5~50%.
6. the Synergistic insecticidal compositions that contains pyrrole aphid ketone and alginic acid malonic acid alcohol ester according to claim 1 is characterized in that it is that main active ingredient and insecticides adjuvant, excipients are mixed with any one formulation that allows on the agricultural chemicals with pyrrole aphid ketone and alginic acid malonic acid alcohol ester.
7. the Synergistic insecticidal compositions that contains pyrrole aphid ketone and alginic acid malonic acid alcohol ester according to claim 6 is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
8. the described Synergistic insecticidal compositions that contains pyrrole aphid ketone and alginic acid malonic acid alcohol ester of claim 1 is prevented and treated the application on the insecticidal materials of resistance Semiptera insect in preparation.
9. application according to claim 8 is characterized in that described Semiptera insect is wheat aphid, aleyrodid and water rice hopper.
CN 200910183492 2009-09-22 2009-09-22 Composite insecticidal composition containing pymetrozine and propylene glycol alginate and application thereof Active CN102017958B (en)

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CN103563965A (en) * 2012-07-24 2014-02-12 陕西美邦农药有限公司 Insecticidal composition containing propylene glycol alginate and pyrethroids
CN103563950A (en) * 2012-07-19 2014-02-12 陕西美邦农药有限公司 Pesticide composition
CN103563962A (en) * 2012-07-20 2014-02-12 陕西美邦农药有限公司 Insecticide composition containing propylene glycol alginate and anabasine
CN104472509A (en) * 2012-07-30 2015-04-01 陕西美邦农药有限公司 Pesticide compound containing propylene glycol alginate
CN105918337A (en) * 2016-07-08 2016-09-07 李祥英 Pesticide composition containing propylene glycol alginate and diafenthiuron
CN105941401A (en) * 2016-06-27 2016-09-21 山东美罗福农业科技股份有限公司 Propylene glycol alginate and icaritin compound oil suspension agent and preparation method
CN106106465A (en) * 2016-07-06 2016-11-16 李祥英 A kind of containing propylene glycol alginate with the composition pesticide of etoxazole
CN107736382A (en) * 2017-10-17 2018-02-27 张锡林 It is a kind of to contain the composition pesticide for killing aphid element and pymetrozine

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KR20060062673A (en) * 2004-12-06 2006-06-12 신젠타코리아 주식회사 New composition of seedling mat for rice and the method for producing the same
JP2008150302A (en) * 2006-12-15 2008-07-03 Nissan Chem Ind Ltd Insecticidal or acaricidal composition
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CN103563950A (en) * 2012-07-19 2014-02-12 陕西美邦农药有限公司 Pesticide composition
CN103563950B (en) * 2012-07-19 2015-07-08 陕西美邦农药有限公司 Pesticide composition
CN103563962B (en) * 2012-07-20 2015-08-19 陕西美邦农药有限公司 A kind of Pesticidal combination containing propylene glycol alginate and anabasine
CN103563962A (en) * 2012-07-20 2014-02-12 陕西美邦农药有限公司 Insecticide composition containing propylene glycol alginate and anabasine
CN103563965B (en) * 2012-07-24 2015-04-15 陕西美邦农药有限公司 Insecticidal composition containing propylene glycol alginate and pyrethroids
CN103563965A (en) * 2012-07-24 2014-02-12 陕西美邦农药有限公司 Insecticidal composition containing propylene glycol alginate and pyrethroids
CN104472509A (en) * 2012-07-30 2015-04-01 陕西美邦农药有限公司 Pesticide compound containing propylene glycol alginate
CN105941401A (en) * 2016-06-27 2016-09-21 山东美罗福农业科技股份有限公司 Propylene glycol alginate and icaritin compound oil suspension agent and preparation method
CN106106465A (en) * 2016-07-06 2016-11-16 李祥英 A kind of containing propylene glycol alginate with the composition pesticide of etoxazole
CN106106465B (en) * 2016-07-06 2018-06-26 青岛好利特生物农药有限公司 A kind of composition pesticide containing propylene glycol alginate and etoxazole
CN105918337A (en) * 2016-07-08 2016-09-07 李祥英 Pesticide composition containing propylene glycol alginate and diafenthiuron
CN107736382A (en) * 2017-10-17 2018-02-27 张锡林 It is a kind of to contain the composition pesticide for killing aphid element and pymetrozine

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