KR20060062673A - New composition of seedling mat for rice and the method for producing the same - Google Patents

Abstract

The present invention

Iii) bactericidal components, insecticidal components or both,

Ii) at least one dissolution regulator selected from the group consisting of surfactants, solvents, polymeric resins and fillers, and

Iii) soil material containing organic raw materials and paper fiber

As a composition comprising:

Based on the total composition,

The bactericidal component may be included in an amount of 0.01 to 10 weight percent,

The pesticidal component may be included in an amount of 0.01 to 5% by weight,

The surfactant may be included in an amount of 0.01 to 10% by weight,

Solvents may be included in amounts of 0.005 to 10% by weight,

Polymer resin may be included in an amount of 0.0005 to 20% by weight,

Fillers may be included in amounts of 0.1 to 50% by weight,

The topsoil material is characterized in that the remaining amount,

Provided is a mat composition for water and a method for producing the composition.

Sterilization, Insecticides, Mats, Compositions, Pesticides

Description

New composition of seed mat and method for producing the same {New composition of seedling mat for rice and the method for producing the same}

The present invention relates to a novel mat composition for water supply containing a fungicide, an insecticide or both thereof and a method for producing the same. More specifically, the present invention relates to a novel water mat composition prepared by mixing a fungicide, an insecticide or both thereof with a seedling top mat and a method of manufacturing the same.

Conventional water fungicides or insecticides have been used to remove pests by spraying the leaves directly after the transplant. Alternatively, as a viable agent, control has been carried out by spraying directly on seedlings immediately before transplanting. However, when spraying pesticides in this manner, there was a risk of the sprayer being directly exposed to the pesticide. There was also the hassle of spraying pesticides whenever needed. In addition, excessive labor was required because the sprayer had to spray it manually and whenever it was needed.

Republic of Korea Patent No. 438049 describes a water functional clay composition, a top soil mat using the same. The water works clay composition of this patent improves water adsorption and flatness by adding surfactant and optionally natural harmful repellent agent to a suitable range of concentration in the clay composition comprising the existing organic component and papermaking fiber. However, this patent makes no mention of controlling the release of pesticides by pre-containing pesticides such as fungicides or insecticides in the clay composition or the clay mat using the same.

Therefore, it was necessary to develop a new mat composition that can simultaneously control seedlings and control pests while reducing labor input during rice farming.

It is an object of the present invention to provide a novel mat composition for water containing a fungicide and / or a pesticide. The mat composition of the present invention can be used in place of the soil at the time of sowing to effectively control the pests generated over time after transplanting.

The present invention pre-mixes fungicides, insecticides or both to the waterborne clay mat, so that there is no need to spray fungicides and / or pesticides before or after transplanting, so that pesticides are contained in the clay at the same time as the preparation of seedling clay In that sense, it can be produced simply and conveniently.

In order to achieve the above object, the present invention

Iii) bactericidal components, insecticidal components or both,

Ii) at least one dissolution regulator selected from the group consisting of surfactants, solvents, polymeric resins and fillers, and

Iii) soil material containing organic raw materials and paper fiber

As a composition comprising:

Based on the total composition,

The bactericidal component may be included in an amount of 0.01 to 10 weight percent,

The pesticidal component may be included in an amount of 0.01 to 5% by weight,

The surfactant may be included in an amount of 0.01 to 10% by weight,

Solvents may be included in amounts of 0.005 to 10% by weight,

Polymer resin may be included in an amount of 0.0005 to 20% by weight,

Fillers may be included in amounts of 0.1 to 50% by weight,

The topsoil material is characterized in that the remaining amount,

The water mat composition and its manufacturing method are provided.

As the active ingredient (sterilization ingredient) included in the fungicide of the present invention, a strobillin-based bactericidal ingredient may be used. Preferably, azoxystrobin (methyl (E) -2-2- [6- (2-cyanophenoxy) pyridinin-4-yloxy] phenyl-3-methoxyacryl is used as a strobiliurin bactericidal component. Rate) and the like can be used. Other active ingredients included in the fungicides of the present invention include Acibenzolar-S-methyl; S-methylbenzo [1,2,3] thiadiazole-7-carbothioate, capropa Carpropamid; (1R, 3S) -2,2-dichloro-N-[(R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide (AR enantio (1S, 3R) -2,2-dichloro-N-[(R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide (BR enantio) (1S, 3R) -2,2-dichloro-N-[(S) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide and (1R) , 3S) -2,2-dichloro-N-[(S) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide), Cyproconazole (2RS , 3RS, 2RS , 3SR) -2- (4-chlorophenyl) -3-cyclopropyl-1- (1H-1,2,4-thiazol-1-yl) butan-2-ol), Cyprodinil (4-cyclopropyl-6-methyl-N-phen Nilpyrimidin-2-amine), difenoconazole (cis, trans-3-chloro-4- [4-methyl-2- (1H-1,2,4-thiazol-1-ylmethyl)- 1,3-dioxolan-2-yl] phenyl 4-chlorophenyl ether), Edifenphos ((RS) -1-methyl-2-nitro-3- (tetrahydro-3-furylmethyl) guanidine ), Epoxyconazole ((2RS, 3SR) -1- [3- (2-chlorophenyl) -2,3-epoxy-2- (4-fluorophenyl) propyl] -1H-1,2, 4-triazole), Fenoxanil; 85% (R) -N-[(RS) -1-cyano-1,2-dimethylpropyl] -2- (2,4-dichlorophenoxy) pro A mixture of pionamide and 15% (S) -N-[(RS) -1-cyano-1,2-dimethylpropyl] -2- (2,4-dichlorophenoxy) propionamide), perimzone ( Ferimzone (Z) -2'-methylacetophenone 4,6-dimethylpyrimidin-2-ylhydrazone), fludioxonil; 4- (2,2-difluoro-1,3-benzodioxol-4-yl) pyrrole-3-carbonitrile), flutolanyl (α, α, α-trifluoro-3'- Isopropoxy-O-toluanalide), phthalide (4,5,6,7-tetrachlorophthalide), hexaconazole ((RS) -2- (2,4-dichloro) Phenyl) -1- (1H-1,2,4-triazol-1-yl) hexan-2-ol), Hymexazole (5-methylisoxazol-3-ol), metaaxyl; Methyl-N- (methoxyacetyl) -N- (2,6-xylyl) -DL-alanineate; methyl 2-{[(2,6-dimethylphenyl) methoxyacetyl] amino} propionate) , Metaaxyl-M; methyl N- (methoxyacetyl) -N- (2,6-xylyl) -D-alanineate; methyl (R) -2-{[(2,6- Dimethylphenyl) methoxyacetyl] amino} propionate), metominostrobin ((E) -2-methoxyimino-N-methyl-2- (2-phenoxyphenyl) acetamide), fensai Curon (Pencycuron; 1- (4-chlorobenzyl) -1-cyclopentyl-3-phenylurea H), Probenazole; 3-allyloxy-1,2-benz [d] isothiazole 1,1-dioxide; Propicazole ((±) -1- [2- (2, 4-dichlorophenyl) -4-propyl-1,3-dioxolan-2-ylmethyl] -1H-1,2,4-triazole), Pyroquilon (1,2,5,6- Tetrahydropyrrolo [3,2,1-ij] quinolin-4-one), thiabendazole; 2- (thiazol-4-yl) benzimidazole; 2- (1,3-thiazole- 4-yl) benzimidazole), thiadidin (3'-chloro-4,4'-dimethyl-1,2,3-thiadiazole-5-carboxanilide), tricyclazole ( Tricyclazole; 5-methyl-1,2,4-triazolo [3,4-b] [1,3] benzothiazole), Validamycin; 1L- (1,3,4 / 2,6)- 2,3-dihydroxy-6-hydroxymethyl-4-[(1S, 4R, 5S , 6S) -4,5,6-trihydroxy-3-hydroxymethylcyclohex-2-enylamino] Cyclohexyl-D-glucopyranoside). These may be used alone or in mixtures of two or more, and may be used without being greatly influenced by the formulation or the physical and / or chemical properties. The content of the sterilizing component included in the composition of the present invention varies depending on the type of sterilizing component, whether other sterilizing or pesticidal components are included, the type, amount, etc. of the dissolution control agent, but is included in an amount of 0.01 to 10% by weight based on the total composition. . If the content of the bactericidal component is within this range, it exhibits inherent activity of the bactericidal component and is advantageous in working with the top soil mat to properly control the dissolution.

As the active ingredient (insect ingredient) included in the pesticide of the present invention, a tooth nicotinyl insecticide ingredient may be used. Preferably, as a thiacnicotinyl insecticide component, Thiamethoxam (3- (2-chloro-1,3-thiazol-5-ylmethyl) -5-methyl-1,3,5-oxadiazinane- 4-ylidene (nitro) amine) and the like can be used. Other active ingredients included in the pesticide of the present invention include Abamectin; (10E , 14E , 16E , 22Z)-(1R , 4S , 5'S , 6S , 6'R , 8R , 12S , 13S , 20R , 21R , 24S) -6 '-[(S) -sec-butyl] -21,24-dihydroxy-5', 11,13,22-tetramethyl-2-oxo-3,7,19-trioxatetracyclo [15.6.1.14,8.020,24] pentacosa-10,14,16,22-tetraen-6-spiro-α2 '-(5', 6'-dihydro-2'H-pyran) -12-yl 2,6-dideoxy-4-O- (2,6-dideoxy-3-O-methyl-L-arafibo-hexopyranosyl) -3-O-methyl-α-L-arabino-hex Sophiranoside and (10E , 14E , 16E , 22Z)-(1R , 4S , 5'S , 6S , 6'R , 8R , 12S , 13S , 20R , 21R , 24S) -21,24-dihydroxy -6'-isopropyl-5 ', 11,13,22-tetramethyl-2-oxo-3,7,19-trioxatetracyclo [15.6.1.14,8.020,24] pentacosa-10,14,16 , 22-tetraen-6-spiro-2 '-(5', 6'-dihydro-2'H-pyran) -12-yl 2,6-dideoxy-4-O- (2,6-dide Oxy-3-O-methyl-α-L-arabino-hexopyranosyl) -3-O-methyl-α-L-ara (4; 1) mixture of no-hexopyranoside (ii)), Acetamiprid; (E) -N1-[(6-chloro-3-pyridyl) methyl] -N2-cyano-N1 -Methylacetamidine), benfuracarb; ethyl N- [2,3-dihydro-2,2-dimethylbenzofuran-7-yloxycarbonyl (methyl) aminothio] -N-isopropyl- β-alananiate), buprofezin (2-tert-butylimino-3-isopropyl-5-phenyl-1,3,5-thiadiazin-4-one), Carbofuran; 2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate), Carbosulfan; 2,3-dihydro-2,2-dimethylbenzofuran-7-yl (dibutylamino Thio) methylcarbamate), Cartap; S, S '-(2-dimethylaminotrimethylene) bis (thiocarbamate), Clothianidin (E) -1- (2-chloro-1,3-thiazol-5-ylmethyl) -3-methyl-2-nitroguanidine), cyromazine; N-cyclopropyl-1,3,5-triazine-2,4,6-triamine), Dinotefuran (RS) -1-methyl-2-nitro-3- (tetrahydro-3-furylmethyl) guanidine), etofenprox (2- (4-ethoxyphenyl) -2-methylpropyl 3-phenoxybenzyl ether) , Penthion (O, O-dimethyl O-4-methylthio-m-tolyl phosphorothioate), Fipronil (<±> 5-amino-1- (2,6-dichloro-α) , α, α-trifluoro-p-tolyl) -4-trifluoromethylsulfinylpyrazole-3-carbonitrile), Imidacloprid; 1- (6-chloro-3-pyridylmethyl)- N-nitroimidazolidine-2-ylideneamine), lambda-cyhalothrin (S) -α-cyano-3-phenoxybenzyl (Z)-(1R, 3R)- 3- (2-chloro-3,3,3-trifluoroprop Ph-1-enyl) -2,2-dimethylcyclopropanecarboxylate and (R) -α-cyano-3-phenoxybenzyl (Z)-(1S , 3S) -3- (2-chloro-3 , 3,3-trifluoroprop-1-enyl) -2,2-dimethylcyclopropanecarboxylate), Lufenuron (RS) -1- [2,5-dichloro-4- (1, 1,2,3,3,3-hexafluoropropoxy) phenyl] -3- (2,6-difluorobenzoyl) urea), Methidathion (S-2,3-dihydro-5- Methoxy-2-oxo-1,3,4-thiadiazol-3-ylmethyl O, O-dimethylphosphorodithioate; 3-dimethoxyphosphinothioylthiomethyl-5-methoxy-1, 3,4-thiadiazole-2 (3H) -one), methoxyfenozide; N-tert-butyl-N ' -(3-methoxy-o-toluoyl) -3,5-xyl Lohydrazide), pymetrozine (E) -4,5-dihydro-6-methyl-4- (3-pyridylmethyleneamino) -1,2,4-triazine-3 (2H ) -On), Tebufenozide; N -tert - Butyl - N '- (4- ethyl) -3,5-dimethyl-benzo hydrazide), Te pulreu sseurin (Tefluthrin; -4- methyl-benzyl-2,3,5,6-tetrafluoroethane ( Z)-(1RS , 3RS) -3- (2-chloro-3,3,3-trifluoroprop-1-enyl) -2,2-dimethylcyclopropanecarboxylate, etc. These alone or It can be used as a mixture of two or more, and can be used without being greatly influenced by the formulation or the physical and / or chemical properties.

The content of the pesticidal component included in the composition of the present invention depends on the type of pesticidal component, whether other pesticides or bactericidal components are included, the type, amount, etc. of the dissolution regulator, but is 0.01 to 5% by weight based on the total composition, preferably Preferably 0.1 to 2% by weight. When the content of the pesticidal component is within this range, it exhibits inherent activity of the pesticidal component and is advantageous in working with the top soil mat to appropriately control the dissolution.

The mat composition of the present invention can control the dissolution of the pesticide active ingredient. Basically, it is not easy to elute as much as necessary at the time necessary only with the active ingredient of the pesticide itself, it can be used with dissolution regulators to assist this. The control of the dissolution can be carried out by the nature of the active ingredient itself and the nature, composition of the dissolution regulator. As such, dissolution regulators that assist the control of dissolution include surfactants, solvents, oils, polymer resins, and solid fillers (fillers). Each dissolution modifier may be used alone or in combination with other materials to speed up or slow the dissolution of the active ingredient depending on dissolution control purposes. Alternatively, it can be eluted at a time when needed. Dissolution regulators used in the present invention may be selected to meet the purposes of the present invention.

As surfactant, polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene tristyrylaryl ether, polyoxyethylene alkyl ester, polyoxyethylene alkylamine, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene Nonionic surfactants such as polyoxypropylene block polymers, polyoxyethylene castor oil derivatives, sorbitan fatty acid esters, sodium alkylsulfonates, alkyl sulfosuccinates, sodium dodecylbenzenesulfonates, calcium dodecylbenzenesulfonates, di Anionic surfactants such as isopropylnaphthalene sulfonate, formalin condensates of alkylaryl sulfonates, and naphthalene sulfonate formalin condensates can be used. These surfactants may be used alone or in combination of two or more thereof. The amount of the surfactant varies depending on the type and amount of the active ingredient of the pesticide, the inclusion of other dissolution control agents, the type and amount, etc., but 0.01 to 10% by weight, preferably 0.5 to 5% by weight based on the total composition do. If the content of the surfactant is within this range, it exhibits intrinsic activity of the pesticide component and is advantageous for appropriately controlling the dissolution of the pesticide.

As the solvent, mineral oils such as paraffin oil and white mineral oil and vegetable oils such as olive oil, soybean oil, rapeseed oil, corn oil, castor oil, cottonseed oil and palm oil may be used alone or in a mixture of two or more. The amount of the solvent varies depending on the type and amount of the active ingredient of the pesticide, the inclusion of other dissolution regulators, the type and amount, etc., but is included in an amount of 0.005 to 10% by weight based on the total composition. When the content of the solvent is within this range, it exhibits intrinsic activity of the pesticide component and is advantageous for appropriately controlling the dissolution of the pesticide.

Examples of the polymer resin include polyvinyl alcohol, polyvinylacetate, sodium polyacrylate, sodium carboxymethyl cellulose, hydroxyethyl cellulose, polyvinyl pyrrolidone, sodium alginate, polyoxyethylene, starch and dextrin. Gum, such as Drew, gum arabic, guar gum, xanthan gum, gellan gum and the like can be used alone or in a mixture of two or more. The content of the polymer resin varies depending on the type and amount of the active ingredient of the pesticide, the inclusion of other dissolution regulators, type and amount, etc., but is included in 0.0005 to 20% by weight based on the total composition. When the content of the polymer resin is within this range, it exhibits intrinsic activity of the pesticide component and is advantageous for appropriately controlling the dissolution of the pesticide.

As the filler, pyrophyllite, talc, bentonite, white carbon, urea formaldehyde condensate, kaolin, calcium carbonate, leadstone, silica, zeolite and the like may be used alone or in a mixture of two or more. Fillers are mainly used solid fillers. The amount of the filler varies depending on the type and amount of the active ingredient of the pesticide, the inclusion of other dissolution regulators, type and amount, but is included in an amount of 0.1 to 50% by weight based on the total composition. When the content of the filler is within this range, it exhibits intrinsic activity of the pesticide component and is advantageous for properly controlling the dissolution of the pesticide.

Other compositions of the present invention may include additives such as antifoaming agents, antifreeze agents, stabilizers, etc. as necessary.

The topsoil material included in the composition of the present invention is well known to those skilled in the art to contain organic raw materials and papermaking fiber. For example, as disclosed in Korean Patent Publication No. 380531, an organic top soil composition for raising seedlings containing an organic raw material and paper fiber in a constant ratio may be used as the topsoil material included in the composition of the present invention. In addition, a top soil mat comprising 60 to 90 parts by weight of organic raw material disclosed in the Patent No. 438049, 10 to 40 parts by weight of papermaking fiber, 0.1 to 0.5 parts by weight of nonionic surfactant and 3 to 5 parts by weight of natural harmful banner agent May be used as the topsoil material included in the composition of the present invention. In addition to these components, the clay material may further include organic and inorganic substances capable of forming a mat, such as by-products of agricultural products such as wood flour, loess, zeolite, vermiculite or crest.

Soil mat included in the mat composition of the present invention can store the pesticide components and dissolution control agent, so that the pesticide can be released at the desired time. The clay mat included in the composition of the present invention is included in the remaining amount except for the amount of bactericidal components, pesticidal components, or both, and the dissolution control agent, based on 100% by weight of the total composition. For example, if the bactericidal component is present in the composition of the present invention in an amount of 6.8% by weight and the solvent is 9.9% by weight as a dissolution control agent, the clay mat includes the remaining amount of 83.3% by weight.

Hereinafter, the present invention will be described in detail with reference to specific examples. These examples merely illustrate the invention in detail, and the scope of the invention is not limited thereto.

Example 1: Preparation of Fungicide (I)

2 liters of Strobillin-based azoxystrobin (azoxystrobin, 98.4%, available from Syngenta, UK), 15 g polyoxyethylene naphthaleneformaldehyde condensate, 50 g glycerin, 1 g xanthan gum, 1 g silicone antifoam, and 523 g tap water The mixture was added to a beaker, stirred for about 10 minutes, and then ground by using a wet mill to produce an average particle size of 2 to 5 microns.

Example 2: Preparation of Fungicide (II)

410 g of strobillin-based azoxystrobin (azoxystrobin, 98.4%, available from Syngenta, UK) and 590 g of paraffin oil were added to a 2-liter beaker, stirred for about 10 minutes, and then the average particle size was used using a wet mill. Prepared by grinding to 5 microns.

Example 3: Preparation of Fungicide (III)

Strobillin azoxystrobin (azoxystrobin, 98.4%, available from Syngenta, UK), 410 g, castor oil ethoxylate 30 g, dodecylbenzene sulfonate calcium salt 20 g, polyoxyethylene lauryl ether 50 g, paraffin oil 490 g was added to a 2 liter beaker, stirred for about 10 minutes, and then ground by using a wet mill to produce an average particle size of 2 to 5 microns.

Example 4: Preparation of Fungicide (IV)

100 g of strobiliurine azoxystrobin (azoxystrobin, 98.4% available from Syngenta, UK), 50 g of pregelatin starch, 137 g of powdered zeolite, 5 g of liquid paraffin, 5 g of talc, and 488 g of pyrophyllite Dry pulverization with a particle size of over 98% at 250 mesh, kneading with water, extrusion molding using a granulator, drying and screening, and slowly adding and coating 430 g of polyvinylacetate emulsion, and repeating coating and drying. Granules were prepared.

Example 5: Preparation of Insecticide (I)>

Chianicotinyl chiamethoxam (thiamethoxam, 98.5%, available from Syngenta, India) 410 g, polyoxyethylene tristyrylphenylether potassium salt 20 g, lignosulphonic acid sodium salt 20 g, glycerin 50 g, xanthan gum 1 g, 1 g of silicone antifoam, and 508 g of tap water were added to a 2 liter beaker, stirred for about 10 minutes, and then ground to a particle size of 2 to 5 microns using a wet mill.

Example 6: Preparation of Insecticide (II)

Chianicotinyl chiamethoxam (thiamethoxam, 98.5%, available from Syngenta, India), 410g, 15g polyoxyethylene naphthaleneformaldehyde condensate, 50g glycerin, 1g xanthan gum, 1g silicone antifoam, 533g tap water The mixture was added to a liter beaker, stirred for about 10 minutes, and then ground by using a wet mill to produce a particle size of 2 to 5 microns.

Example 7: Preparation of Insecticide (III)

Chianicotinyl chiamethoxam (98.5%, available from Syngenta, India) and 410 g of paraffin oil were added to a 2-liter beaker, stirred for about 10 minutes, and then wetted with a wet mill. Prepared by grinding to 5 microns.

Example 8: Preparation of Insecticide (IV)

Chianicotinyl thiamethoxam (98.5% Syngenta India) 410g, castor oil ethoxylate 30g, dodecylbenzene sulfonate calcium salt 20g, polyoxyethylene lauryl ether 50g, paraffin oil 490g in a 2 liter beaker After the addition and stirring for about 10 minutes it was prepared by grinding to a particle size of 2 to 5 microns using a wet mill.

Example 9: Preparation of Insecticide (V)

Chianicotinyl chiamethoxam (98.5%, available from Syngenta, India) 44 g, pregelatin starch 50 g, powder zeolite 137 g, liquid paraffin 5 g, talc 5 g, pyrophyllite 544 g Dry pulverize so that the particle size will pass more than 98% at 250 mesh, knead it with water, extrude it using a granulation machine, and dry and select it, and slowly apply 430 g of polyvinylacetate emulsion to coating and drying repeatedly. To prepare granules.

<Example 10: Preparation of the mat composition for water (I) containing the disinfectant (I)>

200 g of the disinfectant (I) made through Example 1 was marketed by National Agro Co., Ltd. under the product name "Superatlant Top Mat", as a top soil material for forming a top mat (As a top soil composition of the Patent Publication No. 0438049, dried matter) ) Was mixed with 1000g to prepare a water mat composition (I) containing a disinfectant.

Example 11 Preparation of Water Mat Composition (II) Containing Fungicide (II)

A water mat composition (II) containing a fungicide was prepared in the same manner as in Example 10 except that the fungicide (II) prepared in Example 2 was used instead of the fungicide (I).

<Example 12: Preparation of the mat composition for water (III) containing the disinfectant (III)>

A water mat composition (III) containing a bactericide was prepared in the same manner as in Example 10 except that the bactericide (III) prepared in Example 3 was used instead of the bactericide (I).

Example 13: Preparation of Water Mat Composition (IV) Containing Fungicide (IV)>

Instead of the disinfectant (I), 800 g of the disinfectant (IV) made through Example 4 was used, and 400 g of the topsoil material was used, except that the water mat composition (IV) containing the disinfectant in the same manner as in Example 10. Was prepared.

<Example 14: Preparation of the mat composition for water (I) containing insecticide (I)>

20 g of insecticide (I) made through the above Example 5 was sold by National Agro Co., Ltd. under the product name "Superatlant Top Mat", and as a topsoil material for forming a top mat (as topological composition and dried matter of Korean Patent Publication No. 0438049). ) Mixed with 1180g to prepare a mat composition for water containing the pesticide (I).

Example 15 Preparation of Mat Composition for Water (II) Containing Insecticide (II)>

A pesticide-containing mat composition (II) was prepared in the same manner as in Example 14 except that the pesticide (II) prepared in Example 6 was used instead of the pesticide (I).

<Example 16: Preparation of the mat composition for water (III) containing the insecticide (III)>

A pesticide-containing mat composition (III) was prepared in the same manner as in Example 14 except that the pesticide (III) prepared in Example 7 was used instead of the insecticide (I).

<Example 17: Preparation of the mat composition (IV) for water containing insecticide (IV)>

A pesticide-containing mat composition (IV) was prepared in the same manner as in Example 14 except that the insecticide (IV) prepared in Example 8 was used instead of the insecticide (I).

<Example 18: Preparation of the mat composition for water (V) containing the pesticide (V)>

Instead of insecticide (I), 200 g of insecticide (V) made through Example 9 was used, and the mat composition for water containing insecticide was carried out in the same manner as in Example 14, except that 1000 g of the top soil material was used (V). Was prepared.

<Example 19: Preparation of the mat composition for water (I) containing all the fungicide (I) and the insecticide (I)>

200 g of fungicide (I) made through Example 1 and 20 g of insecticide (I) made through Example 5 are commercially available from National Agro Co., Ltd. A water mat composition (I) containing both a fungicide and an insecticide was prepared by mixing with 980 g of the topsoil composition and the dried material of Korean Patent No. 0438049).

Example 20 Preparation of Mat Composition for Water (II) Containing Both Fungicide (II) and Pesticide (II)>

A water mat composition containing both a fungicide and an insecticide in the same manner as in Example 19 except that a fungicide (II) was used instead of a fungicide (I) and an insecticide (II) was used instead of the pesticide (I). (II) was prepared.

Example 21 Preparation of Water Mat Composition (III) Containing Both Fungicide (III) and Insecticide (III)

A water mat composition containing both a fungicide and an insecticide in the same manner as in Example 19 except that a fungicide (III) was used instead of a fungicide (I) and an insecticide (III) was used instead of the pesticide (I). (III) was prepared.

<Example 22: Preparation of the mat composition for water (IV) containing all the fungicide (IV) and insecticide (IV)>

In the same manner as in Example 19, except that 800 g of fungicide (IV) was used instead of fungicide (I), 20 g of pesticide (IV) was used instead of insecticide (I), and 380 g of topsoil was used. • A water mat composition (IV) containing all pesticides was prepared.

 Example 23 Preparation of Water Mat Composition (V) Containing Both Fungicide (I) and Insecticide (V)>

200 g of fungicide (I) made through Example 1 and 200 g of insecticide (V) made through Example 9, commercially available from National Agro Co., Ltd. under the product name "Chanbang Santo Mat", A water mat composition (V) containing both fungicides and insecticides was prepared by mixing with 800 g of the topsoil composition and dry matter of Korean Patent No. 0438049).

Example 24 Preparation of Water Mat Composition (VI) Containing Both Fungicide (II) and Insecticide (V)>

A water mat composition (VI) containing both fungicides and insecticides was prepared in the same manner as in Example 23 except that fungicides (II) were used instead of fungicides (I).

<Example 25: Preparation of the mat composition for water containing all disinfectant (III) and insecticide (V)>

A water mat composition containing all of fungicides and insecticides was prepared in the same manner as in Example 23, except that fungicides (III) were used instead of fungicides (I).

Example 26 Preparation of Water Mat Composition Containing Both Fungicide (IV) and Insecticide (V)>

In the same manner as in Example 23, except that 800 g of disinfectant (IV) was used instead of the disinfectant (I), and 200 g of the topsoil material was used, a mat for water containing the disinfectant and insecticide was prepared.

Example 27 Preparation of a Mat Composition for Water Containing Sterilizers and Insecticides

As a fungicide, 100 g of fungicide (I) and 400 g of fungicide (IV) were used, 10 g of pesticide (I) and 100 g of pesticide (V) were used as insecticides, and 590 g of topsoil was used. In the same manner, a water mat composition containing both fungicides and insecticides was prepared.

Comparative Example 1

A commercially available seed treatment hydrous was used for the control test. After soaking rice seed in water for 3-4 days, it was taken out to remove water, and then the drug was treated with powder (mixing the powdered drug with rice seed) and sprouted. When the shoots grew about 1-3mm, the tops were placed halfway in the seedling box, saturated with water, and then seeded sprouted rice seeds were covered with dry tops. This was seeded after seeding for 10 to 25 days at a constant temperature.

Comparative Example 2

A commercially available sterilizing and insecticidal compound for treating seedling boxes was used as a control test. Soybean seed that was not treated with the medicine was sown in seedling boxes, seeded, and seeded (7 days before-on the day of seedling).

Drug efficacy test

The efficacy test was carried out in paddy fields with the pavement area of about 30㎡ (5m × 6m-the width of the mat composition), adjusted to the water height of 3 to 5cm. The evaluation of the efficacy of the fungicides was carried out in terms of the incidence of the treatments as a percentage compared to the incidence of no treatment, and the evaluation of the efficacy of the pesticides was made as a percentage of the number of treatments compared to the untreated incidence. The drug test was conducted in the seedling box until the day before the transplanting, and was evaluated for the duration of the drug after transplanting.

[Table 1] Drug efficacy and weakness test results of water-containing mat composition containing disinfectant

Weak (0-5) Drug efficacy (0 to 100) Yiangjeon Yianghu Leaf Blight Neck fever Leaf blight Example 10 0.5 0 92 88.3 86.2 Example 11 0.3 0 92.3 88.8 86.5 Example 12 0.1 0 96.4 92.2 89.9 Example 13 0 0 95.1 90.8 88.3 Comparative Example 1 0.3 0 93.3 68.5 50.4 Untreated incidence (%) - - 5 20 20

As shown in Table 1, only the mat composition for water containing the fungicide can be seen a satisfactory effect, it can be seen that the drug duration is sufficient.

[Table 2] The efficacy and weakness test results of the soil top mat for seedlings containing insecticide

Weak (0 to 5) Drug efficacy (0 to 100) Yiangjeon Yianghu Rice weevil A light bulb Example 14 0.2 0 99.7 87.2 Example 15 0.2 0 99.7 86.5 Example 16 0.1 0 100 89.2 Example 17 0.1 0 99.8 89.3 Example 18 0 0 99.2 94.3 Comparative Example 1 0.3 0 97.1 65.5 Non-Treatment Amount (Number of Birds Per Week) - - 60 50

As shown in Table 2, only the mat composition for the water containing the pesticide can be seen a satisfactory effect, it can be seen that the duration of the drug is sufficient.

[Table 3] The efficacy and weakness test results of the soil mat on the seedlings for water containing bactericides and insecticides

Weak (0 to 5) Drug efficacy (0 to 100) Yiangjeon Yianghu Rice weevil Leaf Blight Neck fever A light bulb Leaf blight Example 19 0.3 0 100 97.2 86.6 85.1 81.4 Example 20 0 99.8 98.3 87.8 84.6 80.1 Example 21 0.1 0 99.6 97.5 88.1 87.3 84.6 Example 22 0.1 0 99.5 96.6 95.5 86.2 92.2 Example 23 0.3 0 99.8 97.2 87.1 92.8 80.5 Example 24 0.2 0 99.3 97.5 88.8 94.4 81.8 Example 25 0.2 0 99.5 97.2 88.5 93.8 82.3 Example 26 0.1 0 96.3 96.7 95.6 94.8 94.4 Example 27 0 0 99.8 99.2 99.9 98.9 98.8 Comparative Example 1 0.3 0 97.5 98.1 70.1 60.3 42.1 Comparative Example 2 - 0 98.2 92.5 72.5 60.7 45.8 Untreated incidence (%) - 5 20 20 - No-Treatment Number of Birds Per Week) 60 - - 50 -

* Since Comparative Example 2 is a treatment agent on the same day of migration, the weakening before migration is not possible.

As shown in Table 3 above, only the mat composition for water containing bactericides and insecticides can satisfactorily be seen. Particularly, the dissolution-controlled bactericidal / pesticides containing the active ingredient are released in the mat composition for water when the expression of the medicinal effect is required. We can get very satisfactory results.

According to the present invention, no more pesticide spraying is required, so labor can be saved, and there is no fear of workers being exposed to pesticides when spraying pesticides, and the active ingredient of the pesticide can be released according to the onset of pests, so that dissolution can be controlled. .

Although the present invention has been described in detail by the specific examples described above, various modifications and variations are possible in the technical aspects of the present invention and it is obvious that such modifications and modifications belong to the appended claims.

Claims (10)

Iii) bactericidal components, insecticidal components or both, Ii) at least one dissolution regulator selected from the group consisting of surfactants, solvents, polymeric resins and fillers, and Iii) soil material containing organic raw materials and paper fiber As a composition comprising: Based on the total composition, The bactericidal component may be included in an amount of 0.01 to 10 weight percent, The pesticidal component may be included in an amount of 0.01 to 5% by weight, The surfactant may be included in an amount of 0.01 to 10% by weight, Solvents may be included in amounts of 0.005 to 10% by weight, Polymer resin may be included in an amount of 0.0005 to 20% by weight, Fillers may be included in amounts of 0.1 to 50% by weight, Topsoil material is to include remaining amount Characterized in that, the mat composition for water. The method of claim 1, wherein the surfactant is polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene tristyrylaryl ether, polyoxyethylene alkyl ester, polyoxyethylene alkylamine, polyoxyethylene sorbitan fatty acid Esters, polyoxyethylene polyoxypropylene block polymers, polyoxyethylene castor oil derivatives, sorbitan fatty acid esters, sodium alkylsulfonates, alkyl sulfosuccinates, sodium dodecylbenzenesulfonates, calcium dodecylbenzenesulfonates, diiso A mat composition for water, characterized in that at least one surfactant selected from the group consisting of propylnaphthalene sulfonate, formalin condensates of alkylaryl sulfonates, naphthalene sulfonate formalin condensates. The method of claim 1, wherein the solvent is at least one solvent selected from the group consisting of paraffin oil, white mineral oil, olive oil, soybean oil, rapeseed oil, corn oil, castor oil, cottonseed oil, palm oil, water mat composition . The method of claim 1, wherein the polymer resin is polyvinyl alcohol, polyvinylacetate, sodium polyacrylate, sodium carboxymethyl cellulose, hydroxyethyl cellulose, polyvinyl pyrrolidone, sodium alginate, polyoxyethylene, starch, Water mat composition, characterized in that at least one polymer resin selected from the group consisting of dextrin, gum arabic, guar gum, xanthan gum, gellan gum. The method of claim 1, wherein the filler is pyrophyllite, talc, bentonite, white carbon, urea formaldehyde condensate, kaolin, calcium carbonate, leadstone, silica, zeolite, characterized in that at least one filler selected from the group consisting of Mat composition for water supplies. The method of claim 1, wherein the bactericidal component is Acibenzolar-S-methyl; S-methylbenzo [1,2,3] thiadiazole-7-carbothioate), caproamide ( Carpropamid; (1R, 3S) -2,2-dichloro-N-[(R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide (called AR enantiomer ), (1S, 3R) -2,2-dichloro-N-[(R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide (BR enantiomer is called ), (1S, 3R) -2,2-dichloro-N-[(S) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide and (1R, 3S) -2,2-dichloro-N-[(S) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide), Cyproconazole; (2RS , 3RS, 2RS , 3SR) -2- (4-chlorophenyl) -3-cyclopropyl-1- (1H-1,2,4-thiazol-1-yl) butan-2-ol), cyprodinyl (Cyprodinil; 4-cyclopropyl-6-methyl-N-phenylpyrimidin-2-amine) , Difenoconazole (cis, trans-3-chloro-4- [4-methyl-2- (1H-1,2,4-thiazol-1-ylmethyl) -1,3-dioxolane- 2-yl] phenyl 4-chlorophenyl ether), Edifenphos ((RS) -1-methyl-2-nitro-3- (tetrahydro-3-furylmethyl) guanidine), epoxyconazole (Epoxiconazole; (2RS, 3SR) -1- [3- (2-chlorophenyl) -2,3-epoxy-2- (4-fluorophenyl) propyl] -1H-1,2,4-triazole), phenoxa Fenoxanil; 85% (R) -N-[(RS) -1-cyano-1,2-dimethylpropyl] -2- (2,4-dichlorophenoxy) propionamide with 15% (S) -N-[(RS) -1-cyano-1,2-dimethylpropyl] -2- (2,4-dichlorophenoxy) propionamide), Ferrimzone; (Z) -2 ' -Methylacetophenone 4,6-dimethylpyrimidin-2-ylhydrazone), fludioxonil; 4- (2,2-difluoro-1,3-benzodioxol-4-yl) pyrrole-3-carbonitrile), flutolanyl (α, α, α-trifluoro-3'- Isopropoxy-O-toluanalide), phthalide (4,5,6,7-tetrachlorophthalide), hexaconazole ((RS) -2- (2,4-dichloro) Phenyl) -1- (1H-1,2,4-triazol-1-yl) hexan-2-ol), Hymexazole (5-methylisoxazol-3-ol), metaaxyl; Methyl-N- (methoxyacetyl) -N- (2,6-xylyl) -DL-alanineate; methyl 2-{[(2,6-dimethylphenyl) methoxyacetyl] amino} propionate) , Metaaxyl-M; methyl N- (methoxyacetyl) -N- (2,6-xylyl) -D-alanineate; methyl (R) -2-{[(2,6- Dimethylphenyl) methoxyacetyl] amino} propionate), metominostrobin ((E) -2-methoxyimino-N-methyl-2- (2-phenoxyphenyl) acetamide), fensai Curon (Pencycuron; 1- (4-chlorobenzyl) -1-cyclopentyl-3-phenylurea ), Probenazole; 3-allyloxy-1,2-benz [d] isothiazole 1,1-dioxide, Propicazole ((±) -1- [2- (2,4) -Dichlorophenyl) -4-propyl-1,3-dioxolan-2-ylmethyl] -1H-1,2,4-triazole), Pyroquilon (1,2,5,6-tetra) Hydropyrrolo [3,2,1-ij] quinolin-4-one), thiabendazole; 2- (thiazol-4-yl) benzimidazole; 2- (1,3-thiazole-4 -Yl) benzimidazole), thiadidin (3'-chloro-4,4'-dimethyl-1,2,3-thiadiazole-5-carboxanilide), tricyclazole 5-methyl-1,2,4-triazolo [3,4-b] [1,3] benzothiazole), Validamycin; 1L- (1,3,4 / 2,6) -2; , 3-dihydroxy-6-hydroxymethyl-4-[(1S, 4R, 5S , 6S) -4,5,6-trihydroxy-3-hydroxymethylcyclohex-2-enylamino] cyclo Hexyl-D-glucopyranoside) at least one bactericidal component selected from the group consisting of Water works mat composition. The method of claim 1, wherein the pesticidal ingredient is Abamectin (Abamectin; (10E , 14E , 16E , 22Z)-(1R , 4S , 5'S , 6S , 6'R , 8R , 12S , 13S , 20R , 21R , 24S) -6 '-[(S) -sec-butyl] -21,24-dihydroxy-5', 11,13,22-tetramethyl-2-oxo-3,7,19-trioxatetracyclo [15.6 .1.14,8.020,24] pentacosa-10,14,16,22-tetraen-6-spiro-α2 '-(5', 6'-dihydro-2'H-pyran) -12-day 2, 6-dideoxy-4-O- (2,6-dideoxy-3-O-methyl-L-arafibo-hexopyranosyl) -3-O-methyl-α-L-arabino-hexopyrano Side and (10E , 14E , 16E , 22Z)-(1R , 4S , 5'S , 6S , 6'R , 8R , 12S , 13S , 20R , 21R , 24S) -21,24-dihydroxy-6 '-Isopropyl-5', 11,13,22-tetramethyl-2-oxo-3,7,19-trioxatetracyclo [15.6.1.14,8.020,24] pentacosa-10,14,16,22 -Tetraen-6-spiro-2 '-(5', 6'-dihydro-2'H-pyran) -12-yl 2,6-dideoxy-4-O- (2,6-dideoxy- 3-O-Methyl-α-L-arabino-hexopyranosyl) -3-O-methyl-α-L-arabino-hexopyranosa (4; 1) mixture of de (ii)), Acetamiprid; (E) -N1-[(6-chloro-3-pyridyl) methyl] -N2-cyano-N1-methylacetamidine Benfuracarb; ethyl N- [2,3-dihydro-2,2-dimethylbenzofuran-7-yloxycarbonyl (methyl) aminothio] -N-isopropyl-β-alanineate ), Buprofezin (2-tert-butylimino-3-isopropyl-5-phenyl-1,3,5-thiadiazin-4-one), Carbofuran (2,3-di) Hydro-2,2-dimethylbenzofuran-7-yl methylcarbamate), Carbosulfan; 2,3-dihydro-2,2-dimethylbenzofuran-7-yl (dibutylaminothio) methylcarba Mate), Cartap; S, S '-(2-dimethylaminotrimethylene) bis (thiocarbamate), Clothianidin (E) -1- (2-chloro-1,3-thiazol-5-ylmethyl) -3-methyl-2-nitroguanidine), cyromazine; N-cyclopropyl-1,3,5-triazine-2,4,6-triamine), Dinotefuran (RS) -1-methyl-2-nitro-3- (tetrahydro-3-furylmethyl) guanidine), etofenprox (2- (4-ethoxyphenyl) -2-methylpropyl 3-phenoxybenzyl ether) , Penthion (O, O-dimethyl O-4-methylthio-m-tolyl phosphorothioate), Fipronil (<±> 5-amino-1- (2,6-dichloro-α) , α, α-trifluoro-p-tolyl) -4-trifluoromethylsulfinylpyrazole-3-carbonitrile), Imidacloprid; 1- (6-chloro-3-pyridylmethyl)- N-nitroimidazolidine-2-ylideneamine), lambda-cyhalothrin (S) -α-cyano-3-phenoxybenzyl (Z)-(1R, 3R)- 3- (2-chloro-3,3,3-trifluoroprop Ph-1-enyl) -2,2-dimethylcyclopropanecarboxylate and (R) -α-cyano-3-phenoxybenzyl (Z)-(1S , 3S) -3- (2-chloro-3 , 3,3-trifluoroprop-1-enyl) -2,2-dimethylcyclopropanecarboxylate), Lufenuron (RS) -1- [2,5-dichloro-4- (1, 1,2,3,3,3-hexafluoropropoxy) phenyl] -3- (2,6-difluorobenzoyl) urea), Methidathion (S-2,3-dihydro-5- Methoxy-2-oxo-1,3,4-thiadiazol-3-ylmethyl O, O-dimethylphosphorodithioate; 3-dimethoxyphosphinothioylthiomethyl-5-methoxy-1, 3,4-thiadiazole-2 (3H) -one), methoxyfenozide; N-tert-butyl-N ' -(3-methoxy-o-toluoyl) -3,5-xyl Lohydrazide), pymetrozine (E) -4,5-dihydro-6-methyl-4- (3-pyridylmethyleneamino) -1,2,4-triazine-3 (2H ) -On), Tebufenozide; N -tert - Butyl -N '- (4- ethyl) -3,5-dimethyl-benzo hydrazide), Te pulreu sseurin (Tefluthrin; -4- methyl-benzyl-2,3,5,6-tetrafluoroethane ( Z)-(1RS , 3RS) -3- (2-chloro-3,3,3-trifluoroprop-1-enyl) -2,2-dimethylcyclopropanecarboxylate It is the above pesticidal component, The water-matte mat composition characterized by the above-mentioned. 1) mixing a solid or liquid pesticide active ingredient with at least one dissolution regulator selected from the group consisting of surfactants, solvents, polymer resins and fillers and wet grinding to a particle size of 2 to 5 microns, 2) mixing the mixture prepared in step 1) with the top mat, 3) molding and processing the mixture prepared in step 2) with a mat molding machine; 4) quantifying the mixture prepared in step 3), packaging and post-treatment Method for producing a water-matting mat composition of claim 1, comprising a. 1) mixing a solid or liquid pesticide active ingredient with at least one dissolution regulator selected from the group consisting of surfactants, solvents, polymer resins and fillers, pulverizing and extruding and shaping; 2) coating the polymer resin for dissolution control to the extruded granules prepared in step 1), 3) mixing the mixture prepared in step 2) with the top mat, 4) molding and processing the mixture prepared in step 3) with a mat molding machine; 5) quantifying the mixture prepared in step 4), packaging and post-treatment Method for producing a water-matting mat composition of claim 1, comprising a. 1) a mixture (a) of a solid or liquid pesticide active ingredient mixed with at least one dissolution regulator selected from the group consisting of surfactants, solvents, polymer resins and fillers and wet milled to a particle size of 2 to 5 microns, The solid or liquid pesticide active ingredient is mixed with one or more dissolution modifiers selected from the group consisting of surfactants, solvents, polymer resins and fillers, pulverized, extruded and molded, and then the dissolution controlled polymer resin is added to the extruded granules. Mixing the coated mixture (b) with a top mat, 2) molding and processing the mixture prepared in step 1) with a mat molding machine; 3) quantifying, packing and post-treatment of the mixture prepared in step 2) Method for producing a water-matting mat composition of claim 1, comprising a.