CN101119632A - A mat for seeds and the method for producing the same - Google Patents
A mat for seeds and the method for producing the same Download PDFInfo
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- CN101119632A CN101119632A CNA200580041869XA CN200580041869A CN101119632A CN 101119632 A CN101119632 A CN 101119632A CN A200580041869X A CNA200580041869X A CN A200580041869XA CN 200580041869 A CN200580041869 A CN 200580041869A CN 101119632 A CN101119632 A CN 101119632A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
- A01C1/04—Arranging seed on carriers, e.g. on tapes, on cords ; Carrier compositions
- A01C1/044—Sheets, multiple sheets or mats
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Abstract
The invention provides a new mat for seeds and a method for producing the same comprising: a) at least one animal pesticidal active ingredient and/or at least one fungicidal active ingredient, b) at least one release controllable material comprising surfactant, solvent, polymer resin and filler, and c) as bed soil a mix of organic raw materials and/or paper fibers.
Description
The present invention relates to be applicable to the novel mat for seeds (mat) of sowing, rudiment and gained growth of seedling and produce the method that one or more kill the described mat of animal pest agent and/or fungicide that is impregnated with.Described mat for seeds becomes seedling and uses mat after seed germination.Mat for seeds of the present invention is preferred for seed and/or the seedling of paddy rice.In the process of production stage, mat for seeds is mixed with at least a animal pest agent extremely and/or at least a fungicide.
Kill in routine under the situation of animal pest agent and/or fungicide preparation, application process mainly be after dilute with water foliage application, after transplanting, be applied directly in the rice field or before being about to transplant, carry out the processing of seedling case.But the time that the application process of these types need be grown and a large amount of manpower.The peasant is exposed to insecticide, and needs a large amount of manual labors to carry out suitable damage by disease and insect (for example disease and/or insect) control in the suitable time.
In Korean Patent KR438049, bed soil (bed soil) composition that is used for rice paddy seed and seedling usefulness mat has been described.The bed local soil type compound of this patent has improved the absorption of moisture and has made mat more smooth.Yet it is not about insecticide fungicide and/or kill the commentary of the release control of animal pest agent for example.Therefore, the mat for seeds that the significant need exploitation is new, it can control damage by disease and insect such as insect and/or disease, and saves labour and the exposure of minimizing in plant (for example paddy rice) rudiment and process of growth.
Therefore, the present invention provides mat for seeds (especially for the seed of agronomy plant or plant) in first aspect, and it comprises:
A) at least a animal pest active component and/or at least a Fungicidal active ingredient of killing,
B) at least a release controllable material, comprise surfactant, solvent, polymer resin and filler and
C) as the organic material of bed soil and/or the mixture (claim 1) of paper fiber.
Mat of the present invention is with fungicide and/or kill the animal pest agent and flood.Therefore, described mat can be controlled animal pest and/or disease, particularly insect and/or disease, and does not need seed or seedling are applied any other active component, particularly in the fields.
Mat of the present invention can also flood with useful key element.Useful key element for example is a fertilizer, as nitrogen, potassium, phosphate, sulphur and/or micro-as zinc, molybdenum, manganese and iron.
By before placing seed on the mat with fungicide and/or kill that the animal pest agent is impregnated into mat and can be easily and prepare novel mat for seeds of the present invention easily.Therefore, no longer need and/or kill the animal pest agent with after-applied fungicide.
The invention still further relates to the purposes of controlled release preparation, it comprises and mat for seeds at least a animal pest active component and/or at least a Fungicidal active ingredient of killing together, is used to control insect and/or pathogene (claim 14).
In first embodiment, mat is used for seed and/or the seedling (claim 15) of paddy rice.
In second embodiment, mat is used to be selected from following agronomy plant or the seed of crop: cereal, for example wheat, barley, rye, oat, paddy rice, corn or Chinese sorghum; Beet, for example sugar beet or fodder beet; Fruit, for example pomaceous fruit (pome fruit), drupe (stone fruit) and soft fruit (soft fruit), for example apple, pears, Lee, peach, apricot, cherry or berry are as strawberry, raspberry or blackberry, blueberry; Beans, for example Kidney bean, Lens culinaris, pea or soybean; Oil crop, for example oilseed rape, mustard, opium poppy, olive, sunflower, coconut, castor-oil plant, cocoa or peanut; Cucurbitaceous plant, for example pumpkin, cucumber or muskmelon; Fibre plant, for example cotton, flax, hemp or jute; Both citrus fruit, for example orange, lemon, grapefruit or oranges and tangerines; Greengrocery is as spinach, lettuce, asparagus, cabbage class, carrot, onion, red pepper (chillis), tomato, potato or capsicum (capsicums); Canella, for example avocado, camphor tree (Cinnamonium) or camphor; With tobacco, nut, coffee, eggplant, sugarcane, tea, pepper, grape, humulus grass (hops), Musaceae plant, latex plant (latex plants), ornamental plants, flowers and turf grass (claim 16).
In preferred embodiments, the invention provides seedling and use mat.
Mat of the present invention is advantageously used in the infringement that control is caused seed and/or seedling by animal pests and/or pathogene.
The example of animal pest is:
-insect, for example, mythimna separata (Pseudaletia separate), brown planthopper (Nilaparvata lugens), small brown rice planthopper (Laodelphax striatellus), white back of the body rice lice (Sogatella furcifera), rice leafhopper (Nephotettix cincticeps), rice water resembles (Lissorhoptrus oryzophilus), Mai Yemao eye ephydrid (Hydrelliagriseola), Oulema oryzae (Oulema oryzae), aphelenchoides besseyi (Aphelenchoides besseyi), ricestem-fly (Chlorops oryzae), striped rice borer (Chilo suppressalis), cnaphalocrocis medinalls guenee (Cnaphalocrocis medinalis), Thrips (Thrips) insect, rice midge (Chironomus oryzae), corn Rhopalosiphum spp (Rhopalosiphum maidis), paddy stem borer (Tryporyzae incertulas), rice hesperiidae (Parnara guttata), (Neranga aenescens), day rice hair eye ephydrid (Hydrellia sasakii), Japanese rice maggot (Agromyza oryzae), scotinophora lurida (Scotinophara lurida), niphe elongata (Lagynotomus elongates), brown Leptocorisa spp (Leptocorixa coretti), long shoulder sour jujube coried (Cletus trigonus), long leg waterleaf first (Donacia pravostii), rice thorn angle ephydrid (Notiphila sekiyai), Susumia exigua (Susumia exigua), Sesamia inferens (Sesamia inferens), mythimna separata (Leucania separate), Tipula spp (Tipula aino), rice resembles (Echinocnemussquameus), China looks butterfly (Mycalesis gotama), Japanese grass Zhong (Conocephalusjaponicus), rice Zhong (Homorocoryphus jezoensis) and gypsymoth (Lymantriadispar);
-from Lepidoptera (Lepidoptera), for example, Acleris spp species (Aclerisspp.), Adoxophyes spp species (Adoxophyes spp.), clearwing moth species (Aegeriaspp.), ground Noctua species (Agrotis spp.), cotton leaf noctuid (Alabamaargillaceae), Amylois spp., soybean noctuid (Anticarsia gemmatalis), Archips spp species (Archips spp.), Argyrotaenia spp species (Argyrotaenia spp.), gamma species (Autographa spp.), corn is in noctuid (Busseola fusca), Cadra cautella (Cadra cautella), peach fruit moth (Carposina nipponensis), straw borer spp species (Chilo spp.), Choristoneura spp species (Choristoneura spp.), grape codling moth (Clysia ambiguella) (Clysia ambiguella), Cnaphalocrocis spp species (Cnaphalocrocis spp.), cloud volume moth species (Cnephasia spp.), Cochylisspp species (Cochylis spp.), casebearer moth species (Coleophora spp.), fine hair snout moth's larva species (Crocidolomia spp.), peach abnormity steinernema (Cryptophlebialeucotreta), Crysodeixis includens, steinernema species (Cydia spp.), bar crambid species (Diatraea spp.), the Sudan cotton bollworm (Diparopsis castanea), Earias species (Earias spp.), maize seedling phycitid species (Elasmopalpusspp.), meal moth species (Ephestia spp.), flower steinernema species (Eucosmaspp.), ligustrum fine tortricidae (Eupoecilia ambiguella), Euproctis species (Euproctis spp.), cut leaf moth species (Euxoa spp.), Grapholita spp species (Grapholita spp.), the wide wing steinernema of cloud and mist (Hedya nubiferana), Heliothis species (Heliothis spp.), Hellula undalis (Hellula undalis), fall webworm (Hyphantria cunea), tomato stem gelechiid (Keiferia lycopersicella), pear leaf blister moth (Leucoptera scitella), the thin moth species of leaf mining (Lithocollethisspp.), Table Grape steinernema (Lobesia botrana), Euproctis species (Lymantriaspp.), lyonetid species (Lyonetia spp.), tent caterpillar species (Malacosomaspp.), tomato moth (Mamestra brassicae), maduca sexta (Manduca sexta), autumn geometrid moth species (Operophtera spp.), European corn borer (Ostrinianubilalis), super steinernema species (Pammene spp.), brown epiblema species (Pandemis spp.), small noctuid (Panolis flammea), pink bollworm (Pectinophora gossypiella), tobacco split worm (Phthorimaeaoperculella), imported cabbageworm (Pieris rapae), Pier species (Pieris spp.), diamond-back moth (Plutella xylostella), Xiao Bai Yponomeuta species (Prays spp.), white standing grain snout moth's larva species (Scirpophaga spp.), moth stem Noctua species (Sesamia spp.), long palpus volume moth species (Sparganothis spp.), greedy Noctua species (Spodopteraspp.), clearwing moth species (Synanthedon spp.), band moth species (Thaumetopoeaspp.), volume moth species (Tortrix spp.), cabbage looper (Trichoplusia ni) and Yponomeuta species (Yponomeuta spp.);
-from coleoptera (Coleoptera), for example, click beetle species (Agriotes spp.), flower resembles species (Anthonomus spp.), Atomaria linearis (Atomaria linearis), tortoise resembles species (Ceutorhynchus spp.), recessed shin phyllotreta species (Chaetocnematibialis), collar resembles species (Cosmopolites spp.), Curculio species (Curculio spp.), khapra beetle species (Dermestes spp.), chrysomelid species (Diabrotica spp.), epilachna species (Epilachna spp.), Eremnusspp., the latent species (Gonocephalum spp.) of soil, Europe Sarcophaga species (Heteronychusspp.), colorado potato beetles (Leptinotarsa decemlineata), rice water resembles species (Lissorhoptrus spp.), gill cockchafer species (Melolontha spp.), Orycaephilus spp., ear resembles species (Otiorhynchus spp.), spot resembles species (Phlyctinus spp.), dish phyllotreta species (Phyllotreta spp.), cloud Pier species (Popillia spp.), Protostrophus spp., flea phyllotreta species (Psylliodes spp.), lesser grain borer species (Rhizopertha spp.), Scarabaeidae species (Scarabeidae), Sitophilus species (Sitophilus spp.), gelechiid species (Sitotroga spp.), powder genus species (Tenebrio spp.), Tribolium species (Tribolium spp.) and spot khapra beetle species (Trogoderma spp.);
-from orthoptera (Orthoptera), for example, blattaria species (Blatta spp.), Blatella species (Blattella spp.), Gryllotalpa spp species (Gryllotalpa spp.), leucophaea maderae (Leucophaea maderae), migratory locusts species (Locusta spp.), Periplaneta species (Periplaneta spp.) and desert locust species (Schistocerca spp.);
-from Isoptera (Isoptera), for example, Reticulitermes species (Reticulitermesspp.);
-from Corrodentia (Psocoptera), for example, powder corrodent species (Liposcelisspp.);
-from Anoplura (Anoplura), for example, Haematopinus species (Haematopinus spp.), Linognathus species (Linogna thus spp.), Pediculus species (Pediculus spp.), goitre woolly aphid species (Pemphigus spp.) and Phylloxera spp species (Phylloxera spp.);
-from Mallophaga (Mallophaga), for example, Damalinia species (Damalinea spp.) and Trichodectes species (Trichodectes spp.);
-from thrips (Thysanoptera), for example, flower thrips species (Frankliniella spp.), hedge Thrips species (Hercinothrips spp.), Taeniothrips species (Taeniothrips spp.), palm thrips (Thrips palmi), onion thrips (Thrips tabaci) and hard Thrips species (Scirtothrips aurantii);
-from Semiptera (Heteroptera), for example, (Dichelops melacanthus), cocoa Di fleahopper (Distantiella theobroma), red cotton bug species (Dysdercusspp.), Euchistus spp., Eurygasterspp species (Eurygaster spp.), Leptocorisa spp species (Leptocorisa spp.), Bemisia spp species (Nezara spp.), skin stinkbug species (Piesma spp.), Rhodnius species (Rhodnius spp.), Sahlbergella singularis (Sahlbergella singularis), black stinkbug species (Scotinophara spp.) and vertebra Reduvius species (Triatoma spp.);
-from Homoptera (Homoptera), for example, fur aleyrodid (Aleurothrixusfloccosus), wild cabbage aleyrodid (Aleyrodes brassicae), kidney Aspidiotus species (Aonidiella spp.), Aphidiadae (Aphididae) insect, Aphis species (Aphis spp.), Aspidiotus species (Aspidiotus spp.), sweet potato whitefly (Bemisia tabaci), lecanium species (Ceroplaster spp.), dark brown Aspidiotus (Chrysomphalusaonidium), Chrysomphalus ficus (Chrysomphalus dictyospermi), wide food Coccushesperidum (Coccus hesperidum), green jassids species (Empoasca spp.), apple aphid (Eriosoma larigerum), Erythroneura spp species (Erythroneura spp.), Gascardia spp., small brown rice planthopper species (Laodelphax spp.), east ball lecanium (Lecanium corni), lepidosaphes shimer species (Lepidosaphes spp.), Macrosiphus spp species (Macrosiphus spp.), tumor aphid genus species (Myzus spp.), rice leafhopper species (Nephotettix spp.), brown planthopper species (Nilaparvata spp.), Paratoria spp., goitre cotten aphid species (Pemphigus spp.), stern line mealybug species (Planococcus spp.), white armored scale species (Pseudaulacaspis spp.), mealybug species (Pseudococcus spp.), Psylla spp species (Psylla spp.), (Pulvinaria aethiopica), large bamboo hat with a conical crown and broad brim Aspidiotus species (Quadraspidiotusspp.), Rhopalosiphum species (Rhopalosiphum spp.), black bourch species (Saissetia spp.), band leafhopper species (Scaphoideus spp.), Schizaphis spp species (Schizaphis spp.), paddy net Aphis species (Sitobion spp.), greenhouse whitefly (Trialeurodes vaporariorum), a mandarin orange wood louse (Trioza erytreae) and oranges and tangerines point armored scale (Unaspis citri);
-from Hymenoptera (Hymenoptera), for example, the bacteria ant belongs to (Acromyrmex), rose cabbage sawfly (Athalia rosae), leaf cutting ant species (Atta spp.), stem honeybee species (Cephus spp.), pine sawfoy species (Diprion spp.), diprionidae (Diprionidae) insect, the lucky pine sawfoy (Gilpinia polytoma) of dragon spruce, fertile leaf honeybee species (Hoplocampa spp.), hair ant species (Lasius spp.), MonomoriumMayr (Monomorium pharaonis), new pine sawfoy species (Neodiprion spp.), Solenopsis species (Solenopsis spp.) and Vespa species (Vespa spp.);
-from diptera (Diptera), for example, Antherigona soccata, garden hair ant (Bibio hortulanus), little Anastrepha species (Ceratitis spp.), Carysomyia species (Chrysomyia spp.), Culex species (Culex spp.), Cuterebra species (Cuterebra spp.), few hair on the neck Anastrepha species (Dacus spp.), Delia species (Delia spp.), Drosophila melanogaster (Drosophila melanogaster), liriomyza bryoniae species (Liriomyza spp.), black Hippelates species (Melanagromyza spp.), cecidomyiia species (Orseolia spp.), Sweden's wheat stem chloropid fly (Oscinella frit), spinach spring fly (Pegomyia hyoscyami), grass seeds fly species (Phorbia spp.), apple is around trypetid (Rhagoletis pomonella), mushroom fly species (Sciara spp.);
-from Acarina (Acarina), for example, Acarus siro (Acarus siro), oranges and tangerines aceria (Aceria sheldoni), steinman pin thorn goitre mite (Aculusschlechtendali), Amblyomma species (Amblyomma spp.), Argas species (Argas spp.), short whisker Acarapis species (Brevipalpus spp.), Bryobia praetiosa (Bryobiapraetiosa), Calipitrimerus spp., Chorioptes species (Chorioptes spp.), Dermanyssus gallinae (Dermanyssus gallinae), carpinus turczaninowii beginning tetranychid (Eotetranychuscarpini), Eriophyes species (Eriophyes spp.), Hyalomma species (Hyalommaspp.), meadow unguiculus mite (Olygonychus pratensis), Ornithodoros species (Ornithodoros spp.), Panonychus citri species (Panonychus spp.), citrus rust goitre mite (Phyllocoptruta oleivora), Polyphagotarsonemus latus Banks (Polyphagotarsonemuslatus), Psoroptes species (Psoroptes spp.), Rh species (Rhipicephalusspp.), Rhizoglyphus species (Rhizoglyphus spp.), itch mite species (Sarcoptesspp.), tarsonemid species (Tarsonemus spp.) and Tetranychus species (Tetranychusspp.); With
-from Nematoda (Nematoda), for example, root-knot nematode species (Meloidogynespp.) (for example Meloidogyne incognita (Meloidogyne incoginita) and javanese root knot nematode (Meloidogyne javanica)), golden nematode species (Heterodera spp.) (soybean cyst nematode (Heterodera glycines) for example, beet golden nematode (Heteroderaschachtii), oat golden nematode (Heterodora avenae) and clover golden nematode (Heterodora trifolii)), ball golden nematode species (Globodera spp.) (for example globodera rostochiensis (Globodera rostochiensis)), similes thorne species (Radopholus spp.) (for example similar similes thorne (Radopholus similes)), kidney shape Turbatrix species (Rotylenchulus spp.), Pratylenchidae species (Pratylenchusspp.) (for example unelected Pratylenchidae (Pratylenchus neglectans) and Cobb root (Pratylenchus penetrans)), aphelenchoides species (Aphelenchoidesspp.), helicotylenchus species (Helicotylenchus spp.), tie Turbatrix species (Hoplolaimus spp.), class burr Turbatrix species (Paratrichodorus spp.), long capsule Turbatrix species (Longidorus spp.), natural pearls Turbatrix species (Nacobbusspp.), inferior serpentine Eimeria species (Subanguina spp.), thorn Turbatrix species (Belonlaimus spp.), little loop wire Eimeria species (Criconemella spp.), wheel Turbatrix species (Criconemoides spp.), Ditylenchus species (Ditylenchus spp.), awl Turbatrix species (Dolichodorus spp.), partly take turns Turbatrix species (Hemicriconemoides spp.), sheath Turbatrix species (Hemicycliophora spp.), latent root Turbatrix species (Hirschmaniella spp.), root-knot nematode species (Hypsoperine spp.), big nodal plate Turbatrix species (Macroposthonia spp.), Melinius spp., spot rubber-insulated wire Eimeria species (Punctodera spp.), five ditch Turbatrix species (Quinisulcius spp.), peltate Turbatrix species (Scutellonema spp.), Xiphinema species (Xiphinema spp.) and dwarfing Turbatrix species (Tylenchorhynchusspp.).
The example of pathogene is:
-Microdichium oryzae, palace portion cochliobolus (Cochliobolusmiyabeanus), pythium species (Pythium spp.), Achyla species (Achiyaspp.), rice blast pears spore mould (Magnaporthe grisea), pod shell bulkholderia cepasea (Burkholderia glumae), the green pyrenomycetes of rice (Ustilaginoidea virens), Rhizoctonia species (Rhizoctonia spp), rice blast pears spore mould (Magnaporthe grisea), thanatephorus cucumeris(frank) donk (Thanateporus cucumeris), rice fore-set mould (Acrocylindriumoryzae), rice ball cavity bacteria (Magnaporthe salvinii), rice blast pears spore mould (Magnaporthe grisea), palace portion cochliobolus (Cochliobolus miyabeanus), gibberella fujikuroi (Gibberella fujikuroi), the mutation (Xanthomonas oryzae pv.oryzae) of causing a disease of rice Xanthomonas paddy rice, rice black-streaked dwarf virus (Riceblack-streaked dwarf virus), fractilinea oryzae (Rice dwarf virus), oryza virus 3 (Rice stripe virus), oat acidovorax avenae (Acidovoraxavenae), Puntoea herbicola, false rice blast (False rice blast), rice tail spore (Cercospora oryzae), draft branch spore (Clodosporium herbarum), Brachysporium blotch, rice leaf smut (Entyloma oryzae), Gaumanomyces graminis, gibberella fujikuroi (Gibberella fujikuroi), Gibberella zeae (Gibberella zeae), the rice husk spore (Hendersonia oryzae) of wriggling, rock ball cavity bacteria (Leptosphaeria iwamotori) in this, rice YRENOCHAETA (Pyrenochaetaoryzae), Phyllosticta species (Phyllostricta spp.), awns spore corruption mould (Pythiumaristosporum), cereal rhizoctonia (Rhizoctonia cerealis), sootiness rhizoctonia (Rhizoctonia fumigate), rice rhizoctonia (Rhizoctonia oryzae), paddy rice rhizoctonia (Rhizoctonia oryzae-sativa), big spore refers to epidemic disease mould (Sclerophthoramacrospore), Sclerotium hydrophilum (Sclerotium hydrophilum), sclerotium species (Sclerotium spp.) and pearl millet Tilletia foetida (Tilletia berclayana);
-fungal pathogens, the disease that has with soil that it comprises that seed has, for example, Ascomycetes (Ascomycetes) (for example Venturia (Venturia), Podosphaera (Podosphaera), Erysiphe (Erysiphe), chain sclerotinia sclerotiorum belong to (Monilinia), Mycosphaerella (Mycosphaerella), Uncinula (Uncinula)); Basidiomycetes (Basidiomycetes) (for example hunchbacked spore Rust (Hemileia), Rhizoctonia (Rhizoctonia), Puccinia (Puccinia), Ustilago (Ustilago), Tilletia (Tilletia); Fungi imperfect (Fungi imperfecti) (has another name called deuteromycetes (Deuteromycetes); For example Botrytis (Botrytis), Helminthosporium (Helminthosporium), Rhynchosporium spp (Rhynchosporium), Fusarium (Fusarium), septoria musiva (Septoria), Cercospora (Cercospora), Alternaria (Alternaria), Pyricularia Sacc. (Pyricularia) and Pseudocercosporella herpotrichoides; Oomycete (Oomycetes) (for example, Phytophthora (Phytophthora), Peronospora (Peronospora), false Peronospora (Pseudoperonospora), Albugo (Albugo), Bremia (Bremia), pythium (Pythium), Pseudosclerospora, Plasmopara (Plasmopara); Specific example is Alternaria species (Alternaria spp.), Ascochyta species (Ascochyta spp.), Botrytis cinerea (Botrytis cinerea), Cercospora species (Cercospora spp.), ergot (Claviceps purpurea), standing grain cochliobolus (Cochliobolus sativus), Colletotrichum species (Colletotrichumspp.), Epicoccum species (Epicoccum spp.), F.graminearum schw (Fusariumgraminearum), rice is disliked seedling sickle spore (Fusarium moniliforme), fusarium oxysporum (Fusarium oxysporum), Fusarium proliferatum, fusariun solani (Fusariumsolani), little glue sickle spore (Fusarium subglutinans), Gaumannomycesgraminis, Helminthosporium (Helminthosporium spp.), avenge rotten microtorr bacterium (Microdochium nivale), Penicillium species (Penicillium spp.), Phoma species (Phoma spp.), wheat class nuclear cavity bacteria (Pyrenophora graminea), rice blast pears spore mould (Pyricularia oryzae), Rhizoctonia solani Kuhn (Rhizoctonia solani), cereal rhizoctonia (Rhizoctonia cerealis), Sclerotinia species (Sclerotiniaspp.), Septoria species (Septoria spp.), silk axle smut (Sphacelothecareilliana), Tilletia foetida species (Tilletia spp.), meat spore nuclear coral bacterium (Typhulaincarnata), latent bar smut (Urocystis occulta), Ustilago species (Ustilago spp.) or Verticillium species (Verticillium spp.); Particularly at cereal (for example wheat, barley, rye or oat); Corn; Paddy rice; Cotton; Soybean; Turf; Sugar beet; Oilseed rape; Potato; Legume crop (for example pea, Lens culinaris or chickpea); Pathogene with sunflower.
The example that is used to prepare the fungicide of the mat for seeds through dipping of the present invention is: (a) strobilurin compounds, and it is from following one or more: strobilurin type: methoxy acrylate compound, strobilurin type: oxazolidinedione compound, strobilurin type: imidazolidinone compound, strobilurin type: oximinoacetamide compound, strobilurin analog: dihydro dioxazine compound, strobilurin type: oximide acetic acid ester compounds, with the strobilurin type: the methoxyl group carbamate compounds.
In one embodiment, be independent of other embodiments and aspect, (a) the strobilurin compounds is from following one or more: fluoxastrobin, Fenamidone, nitrile Fluoxastrobin, ZEN 90160, pyraclostrobin, Famoxate, ether bacterium amine, SSF 126, kresoxim-methyl and oxime bacterium ester.Favourable strobilurin compounds is fluoxastrobin and nitrile Fluoxastrobin.
In one embodiment, be independent of other embodiments and aspect, (b) the DMI compound is from following one or more: DMI: diethylenediamine compound, DMI: triazole compounds, DMI: imidazolium compounds and DMI: pyrimidine compound.
DMI: diethylenediamine compound is a triforine.
DMI: triazole compounds is selected from following one or more: oxygen ring azoles, bitertanol, bromuconazole, Cyproconazole, Difenoconazole, alkene azoles alcohol, fluorine ring azoles, RH-7592, Fluquinconazole, Flusilazole, Flutriafol, own azoles alcohol, glyoxalin, kind bacterium azoles, metconazole, nitrile bacterium azoles, paclobutrazol, propiconazole, prothioconazoles, simeconazoles, Tebuconazole, tetraconazole, triazolone, Triadimenol and triticonazole.
DMI: imidazolium compounds is selected from and presses down mould azoles, fumaric acid evil imidazoles, pefurazoate, penconazole, Prochloraz and fluorine bacterium azoles.
DMI: pyridine compounds is a pyrifenox.
DMI: pyrimidine compound is a Fenarimol.
In one embodiment, be independent of other embodiments and aspect, (b) the DMI compound is from following one or more: bitertanol, Cyproconazole, Difenoconazole, alkene azoles alcohol, Fluquinconazole, Flutriafol, metconazole, prothioconazoles, Tebuconazole, triazolone, Triadimenol, triticonazole, Prochloraz and press down mould azoles.
In one embodiment, be independent of other embodiments and aspect, (c) benzimidazoles compound is from following one or more: carbendazim, furidazol and probenazole; Advantageously, for from furidazol and the probenazole one or more.
In one embodiment, be independent of other embodiments and aspect, (d) the phentriazine compounds is a triazoxide.
In one embodiment, be independent of other embodiments and aspect, (e) the phenylpyrrole compounds is from fenpiclonil and the fludioxonil one or more.
In one embodiment, be independent of other embodiments and aspect, (f) the anilino-pyrimidine compounds is from cyprodinil and the phonetic mould amine one or more.
In one embodiment, be independent of other embodiments and aspect, (g) Carbox amide is from following one or more: Boscalid, carboxin and silicon metsulfovax (silthiofam); Advantageously, for from carboxin and the silicon metsulfovax one or more.
In one embodiment, be independent of other embodiments and aspect, (h) phenyl amide: the acyl group alanine compound is following one or more: M 9834, M 9834-M, metalaxyl, Metalaxyl-M; Advantageously be in metalaxyl and the Metalaxyl-M one or more.
In one embodiment, be independent of other embodiments and aspect, fungicide is selected from the compound of multidigit point classification, for example tmtd, Kocide SD, iminoctadine and mancozeb, particularly tmtd.
Preferably, fungicide is from following one or more: M 9834, M 9834-M, fuberdiazole, probenazole, the nitrile Fluoxastrobin, fluoxastrobin, bitertanol, Cyproconazole, Difenoconazole, alkene azoles alcohol, Fluquinconazole, Flutriafol, metalaxyl, Metalaxyl-M, prothioconazoles, Tebuconazole, Triadimenol, triticonazole, fludioxonil, triazoxide, cyprodinil, carboxin, the silicon metsulfovax, plant the bacterium azoles, oxime bacterium ester, press down mould azoles, guazatine acetate and 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-carboxylic acid (2-bicyclo-propyl-2-base-phenyl)-acid amides.
The Fungicidal active ingredient nitrile Fluoxastrobin of strobilurin type ((E)-2-{2-[6-(2-cyano-benzene oxygen) pyrimidine-4-base oxygen base] phenyl }-the 3-methoxy-methyl acrylate) be the preferred fungicide that is used to prepare the mat for seeds through flooding of the present invention.
Selectively, following Fungicidal active ingredient is used to prepare the mat for seeds through dipping of the present invention: thiadiazoles element-S-methyl (acibenzolar-S-methyl); Benzo [1,2,3] thiadiazoles-7-thiocarboxylic acid S-methyl esters, ring propionyl bacterium amine; Suitable, anti--3-chloro-4-[4-methyl-2-(1H-1,2,4-triazol-1-yl methyl)-1,3-dioxolane-2-yl] phenyl 4-chlorphenyl ether), edifenphos; (2RS, 3SR)-1-[3-(2-chlorphenyl)-2,3-epoxy-2-(4-fluorophenyl) propyl group]-1H-1,2, the 4-triazole), zarilamid; 85% (R)-N-[(RS)-1-cyano group-1, the 2-dimethyl propyl]-2-(2, the 4-dichlorophenoxy) propionamide and 15% (S)-N-[(RS)-1-cyano group-1, the 2-dimethyl propyl]-2-(2, the 4-dichlorophenoxy) mixture of propionamide, and 4-(2,2-two fluoro-1,3-benzo dioxole-4-yl) flutolanil pyrroles-3-formonitrile HCN); α, α, α-three fluoro-3 '-isopropoxy-adjacent toluyl aniline), Rabcide; (RS)-2-(2,4 dichloro benzene base)-1-(1H-1,2,4-triazol-1-yl) oneself-2-alcohol), hydroxyisoxazole (hymexazole); The different azoles of 5-methyl-3-alcohol, metalaxyl; N-(methoxyl group acetyl group)-N-(2, the 6-xylyl)-DL-methyl lactamine; N-(methoxyl group acetyl group)-N-(2, the 6-xylyl)-D-methyl lactamine; (E)-and 2-methoxyimino-N-methyl-2-(2-Phenoxyphenyl) acetamide), Pencycuron; 1-(4-benzyl chloride base)-1-cyclopenta-3-phenylurea), probenazole; (±)-1-[2-(2,4 dichloro benzene base)-4-propyl group-1,3-dioxolane-2-ylmethyl]-1H-1,2,4-triazole, pyroquilon; 2-(thiazole-4-yl) benzimidazole; 2-(1,3-thiazoles-4-yl) benzimidazole, thiadinil; 3 '-chloro-4,4 '-dimethyl-1,2,3-thiadiazoles-5-formailide, tricyclazole; The 5-methyl isophthalic acid, 2,4-triazol [3,4-b] [1,3] benzothiazole, valida; 1L-(1,3,4/2,6)-2,3-dihydroxy-6-methylol-4-[(1S, 4R, 5S, 6S)-4,5, and 6-trihydroxy-3-methylol hexamethylene-2-alkenyl amino] cyclohexyl-D-glucopyranoside (claim 8).
These Fungicidal active ingredients can use separately or to use with other Fungicidal active ingredients and/or the form of mixtures of killing the animal pest active component.
Depend on different parameters in the amount that is impregnated with the Fungicidal active ingredient of the seedling mat that is used for paddy rice that kills animal pest agent and/or fungicide of the present invention, for example the another kind of fungicide and/or the existence of animal pest agent extremely, the kind and the amount of release controllable material in the type of fungicide, the preparation.Preparation comprises the Fungicidal active ingredient of 0.01 to 5 weight % usually, the Fungicidal active ingredient of preferred 0.02 to 3 weight %, and they are parts of the composition of mat for seeds of the present invention.
The insect active composition that kills of thianicotinyl type is used to prepare the mat for seeds through dipping of the present invention.
Insect active composition thiophene worm piperazine (3-(the 2-chloro-1 extremely of thianicotinyl type, 3-thiazole-5-ylmethyl)-the 5-methyl isophthalic acid, 3,5- diazine alkane-4-subunit (nitro) amine) be the preferred animal pest agent extremely that is used to prepare the mat for seeds through flooding of the present invention.
The example that kills the animal pest agent that is used to prepare the mat for seeds through dipping of the present invention is: Acetamiprid, thiophene worm amine, MTI-446, Imidacloprid, Nitenpyram, thiophene worm quinoline, thiophene worm piperazine, α-cypermethrin, β-cyfloxylate, β-cypermethrin, Biphenthrin, bioallethrin, bioresmethrin, cycloprothrin, cyfloxylate, cyhalothrin, cypermethrin, cyphenothrin, decis, empenthrin, esfenvalerate, fenpropathrin, sumicidin, flucythrinate, flumethrin, gamma-cyhalothrin, alkynes miaow chrysanthemum ester, gamma cyhalothrin, methothrin, methoxy benzyl Flumethrin (metofluthrin), permethrin, phenothrin, prallethrin, resmethrin, taufluvalinate, tefluthrin, tetramethrin, θ-cypermethrin, tralomethrin, transfluthrin, ξ-cypermethrin, Avermectin, emaricin, pleocidin, doramectin, Eprinomectin, ivermectin, selamectin, with be substituted more visit for example compound of following formula of rhzomorph
Flubendiamide (flubendiamide) (3-iodo-N '-(2-mesyl-1,1-dimethyl ethyl)-N-{4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl) ethyl]-o-tolyl phthalamide), fluorine worm nitrile and following formula A-1 be to the compound of A-26
These kill that the animal pest active component can use separately or to use with the form of mixtures of its homicide animal pest active component and/or Fungicidal active ingredient.
The amount of killing the animal pest active component in the mat for seeds that is impregnated with extremely animal pest agent and/or fungicide of the present invention depends on different parameters, for example kills another kind of animal pest agent and/or the existence of fungicide, the type and the amount of release controllable material of killing in the type, preparation of animal pest agent.Preparation comprises the animal pest active component extremely of 0.01 to 10 weight % usually, the animal pest active component extremely of preferred 0.02 to 5 weight %, and they are parts of the composition of mat for seeds of the present invention.
Be used to prepare the form that animal pest or Fungicidal active ingredient are free form or the salt that can use for agrochemistry of killing of the mat for seeds through dipping of the present invention.
The example that kills the animal pest agent that is used to prepare the mat for seeds through dipping of the present invention is: Benfuracard micro; N-[2,3-dihydro-2, the 2-dimethyl benzofuran-amino sulfenyl of 7-base oxygen base carbonyl (methyl)]-N-isopropyl-Beta-alanine ethyl ester), Buprofezin; 2-tertbutylimido-3-isopropyl-5-phenyl-1,3,5-thiadiazine alkane-4-ketone), carbofuran; 2,3-dihydro-2,2-dimethyl benzofuran-7-base-methyl carbamate), carbosulfan; 2,3-dihydro-2,2-dimethyl benzofuran-7-base-(dibutylamino sulfenyl) methyl carbamate), cartap; S, S '-(2-dimethylamino trimethylene base)-two (thiocarbamates), fly eradication amine; N-cyclopropyl-1,3,5-triazines-2,4,6-triamine, ether chrysanthemum ester; 2-(4-ethoxyl phenenyl)-2-methyl-propyl 3-phenoxy benzyl ether, fenthion; 0,0-dimethyl-0-4-methyl mercapto-tolyl-thiophosphate, the fluorine third oxygen urea; (RS)-and 1-[2,5-two chloro-4-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl]-3-(2, the 6-difluoro benzoyl) urea, methidathion; S-2,3-dihydro-5-methoxyl group-2-oxo-1,3,4-thiadiazoles-3-ylmethyl-0,0-dimethyl-phosphorodithioate; 3-dimethoxy phosphinothioyl sulphomethyl-5-methoxyl group-1,3,4-thiadiazoles-2 (3H)-ketone), methoxyfenozide; The N-tert-butyl group-N '-(3-methoxyl group-toluoyl base)-3,5-dimethylbenzene hydrazides), pyrrole aphid ketone; (B)-4,5-dihydro-6-methyl-4-(3-pyridine radicals methene amido)-1,2,4-triazine-3 (2H)-ketone and worm hydrazides; The N-tert-butyl group-N-(4-ethylamino benzonitrile acyl group)-3,5-dimethyl benzene formylhydrazine) (claim 9).
Preferably insecticide is selected from following one or more: M 9834, M 9834-M, fuberdiazole, probenazole, the nitrile Fluoxastrobin, fluoxastrobin, bitertanol, Cyproconazole, Difenoconazole, alkene azoles alcohol, Fluquinconazole, Flutriafol, metalaxyl, Metalaxyl-M, prothioconazoles, Tebuconazole, Triadimenol, triticonazole, fludioxonil, triazoxide, cyprodinil, carboxin, the silicon metsulfovax, plant the bacterium azoles, oxime bacterium ester, press down mould azoles, guazatine acetate, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-carboxylic acid (2-bicyclo-propyl-2-base-phenyl)-acid amides, thiophene worm piperazine, Imidacloprid, Avermectin, pleocidin, bisamide (bisamide), thiophene worm quinoline, gamma cyhalothrin, thiophene worm amine, tefluthrin, β-cyfloxylate, cypermethrin, α-cypermethrin, β-cypermethrin, θ-cypermethrin, ξ-cypermethrin and fluorine worm nitrile.
Fungicidal active ingredient and/or kill the animal pest active component and use with not modified form perhaps preferably, uses with the adjuvant that is generally used for formulation art.For this reason, in known manner they are formulated as missible oil, the paste that can be coated with, the solution that can directly spray or dilute or suspension, rare emulsion, wetting powder, soluble powder, medicinal powder, granule easily, and encapsulated (for example in polymer).When adopting different types of compositions,, for example spray, atomize, dust, disseminate, be coated with or pour into according to predetermined target and general environmental selection application process.Composition also can comprise other adjuvant, for example stabilizing agent, defoamer, viscosity modifier, adhesive or tackifier, and fertilizer, micronutrient donor or be used to obtain other preparations of special effects.
Suitable carriers and adjuvant can be solid or liquid, and are material useful in preparation technique, for example natural or regeneration mineral matter, solvent, dispersant, wetting agent, tackifier, thickener, adhesive or fertilizer.Such carrier for example is described among the WO97/33890.
New mat for seeds can be controlled the rate of release of active insecticidal components.Can use release controllable material to be used for effective release, because just be difficult in time of needs with the concentration release of active ingredients of needs.Discharging control can be by for example encapsulated and extrude realization.The character of active component, the character of release controllable material and composition have determined releasable feature, for example time, temperature and other factors.The auxiliary agent that has several controlled to discharge, for example surfactant, solvent, oils, polymer resin and solid packing.The auxiliary agent of every kind of controlled release makes rate of release accelerate according to the purpose that discharges control or is slack-off.Can select to be used for release controllable material of the present invention with corresponding with purpose of the present invention.As surfactant, use polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene triphenylethylene base aryl ether, polyxyethylated ester, polyoxyethylene alkyl amine, the polyoxyethylene sorbitan aliphatic ester, polyox-yethylene-polyoxypropylene block copolymer, castor oil derivatives, sorbitan aliphatic ester, other nonionic surface active agent, sodium alkyl sulfonate, alkyl sulfosuccinate (alkyl sulfosuccinate), neopelex, diisopropyl naphthalene sulfonate, alkylaryl sulfonates formaldehyde condensation products and other ionic surfactants (claim 4).These surfactants can use separately or multiple use together.The amount of surfactant depends on the type and the amount of the auxiliary material that active insecticidal components and other controlled discharge, and whether there are other release controllable material, but with the surfactant of 0.01-10 weight %, the surfactant of preferred 0.5-5 weight % is impregnated in total composition.
As solvent, can use for example for example olive oil, soybean oil, rapeseed oil, corn oil, castor oil, cottonseed oil, cocoa butter and palm oil of paraffin, slab oil and vegetable oil of mineral oil, they use separately or multiple use together (claim 5).The amount of solvent depends on the type of solvent, the amount of active insecticidal components and other release controllable material, and whether have other release controllable material.Can make the solvent of 0.005-10 weight %, the solvent of preferred 0.1-5 weight % constitutes the part of total composition.
As polymer resin, can use for example for example gum Arabic, guar gum, xanthans and gellan gum (gellan gum) of starch and dextrin and natural gum of polyvinyl alcohol, polyvinyl acetate, Sodium Polyacrylate, sodium carboxymethylcellulose, hydroxyethylcellulose, polyvinylpyrrolidone, mosanom, polysaccharide, they use separately or multiple use together (claim 6).The amount of polymer resin depends on the amount of active insecticidal components and other release controllable material, and whether has release controllable material.Can make the polymer resin of 0.0005-20 weight %, the polymer resin of preferred 0.01-10 weight % constitutes the part of total composition.
As filler, can use pyrophyllite, talcum, bentonite, white carbon (white carbon), urea-formaldehyde condensation product, kaolin, calcium carbonate, clay, silica and zeolite, they use separately or multiple use together.Usually, use solid packing as filler (claim 7).The content of filler depends on the type and the amount of active insecticidal components and other release controllable material, and whether has other release controllable material.Can make the filler of 0.1-50 weight %, the filler of preferred 1-35 weight % constitutes the part of total composition.
In addition, also can make for example defoamer, anti-freezant, stabilizing agent constitute the part of mat of the present invention.
The bed soil or the raw material that are used for mat of the present invention comprise organic material and paper fiber, and it is known for those people that agricultural industry general knowledge is arranged.For example, as disclosed in Korean patent registration No. 380531, can lathe local soil type compound be arranged as the raw material in the mat of the present invention with what comprise the organic material of fixed ratio and paper fiber.Also be the organic material that disclosed seedling mat comprises 60-90%w/w in this Korea patent registration, paper fiber and the nonionic surface active agent of 0.1-0.5%w/w and the harmful biological repellant of 3-5%w/w of 10-40%w/w, can use it in the mat of the present invention.This seedling mat also can comprise the organic and inorganic material that can form mat in addition, for example the by product of sawdust, loess, zeolite and vermiculite and agricultural product (comprising straw).Raw-material other examples are open in korean patent application NO1020040097818 and 1020030012743, it has been described and has comprised organic raw-material local soil type's compound, organic material is by the husk of bog moss, coconut peat and expansion, and paper fiber (or cellulose) composition that derives from corrugated board, newspaper waste product or grafting paper (graft paper).
In preferred embodiments, the bed soil of 1-99 weight %, the bed soil of preferred 2-98 weight % constitutes the part of total composition.
Preferably, mat for seeds of the present invention comprises:
A) 0.01 to 10%w/w animal pest active component extremely, and/or
0.01 to the Fungicidal active ingredient of 5%w/w and
B) 0.01 to 10%w/w surfactant and
0.005 to the solvent of 10%w/w and
0.0005 to the polymer resin of 20%w/w and
0.1 to the filler of 50%w/w and
C) 1 to 99%w/w bed soil.(claim 10)
More preferably, mat for seeds of the present invention comprises:
A) 0.02 to 5%w/w animal pest active component extremely, and/or
0.02 to the Fungicidal active ingredient of 3%w/w and
B) 0.5 to 5%w/w surfactant and
0.1 to the solvent of 5%w/w and
0.01 to the polymer resin of 10%w/w and
0.1 to the filler of 35%w/w and
C) 2 to 98%w/w bed soil.
Further, the method that is used to prepare mat for seeds of the present invention may further comprise the steps:
A) at least a solid or insecticidal liquid active component are mixed with at least a composition that is used to prepare release controllable material, the described composition that is used to prepare release controllable material is selected from surfactant, solvent, polymer resin and filler,
B) mixture that will prepare in (a) carries out wet-milling up to 2 to 5 microns average particle size particle size,
The mixture through grinding that c) will in (b), prepare mix with the mixture of organic material and paper fiber and
D) use mat forming machine is used in the mixture that obtains in (c) and forms mat.(claim 11)
The mat forming machine is a kind of machine, and it allows to comprise the slurry of organic material especially and/or paper fiber and to form framework by suction to prepare mat of the present invention.This device is as known in the art.
In one aspect of the method, the method that is used to prepare mat for seeds of the present invention may further comprise the steps:
A) at least a solid or insecticidal liquid active component are mixed with at least a composition that is used to prepare release controllable material, the described composition that is used to prepare release controllable material is selected from surfactant, solvent, polymer resin and filler,
B) mixture that will prepare in (a) is extruded with the formation particle,
C) polymer resin that discharges with controlled is coated in the particle of preparation in (b),
The particle through applying that d) will in (c), prepare mix with the mixture of organic material and paper fiber and
E) use mat forming machine is used in the mixture that obtains in (d) and forms mat.(claim 12)
Further, the method that is used to prepare mat for seeds of the present invention may further comprise the steps:
A) at least a solid or insecticidal liquid active component are mixed with at least a composition that is used to prepare release controllable material, the described composition that is used to prepare release controllable material is selected from surfactant, solvent, polymer resin and filler,
B) mixture that will prepare in (a) carries out wet-milling up to 2 to 5 microns average particle size particle size,
The mixture through grinding that c) will prepare in (b) is extruded with the formation particle,
D) polymer resin that discharges with controlled be coated in preparation in (c) particle and
E) use mat forming machine is used in the mixture that obtains in (d) and forms mat.(claim 13)
Rice paddy seed of the present invention is described below with the illustration of the purposes of mat.Following process only is an illustration and not limiting the scope of the invention:
A) mat is placed on the seedling growing box (or seedling case),
B) at mat updip pouring so that fully expand,
C) with the seed before the rudiment for example rice paddy seed sowing on the mat that expands,
D) seed with sowing covers with soil, and keeps this state to occur up to seedling seedling growing box.The root of seedling penetrates mat and forms root mat (root mat).The mat that comprise seedling can be transplanted to field for example in rice field thereafter.
In addition, considered to sow seed-bearing mat of the present invention in the above and be directly used in purposes in the field, especially for ornamental plants and plant.
In the present invention, the agronomy plant of sowing on mat or the seed of crop also comprise the seed of for example handling with one or more active components.Processing can change to intermediateness (for example dressing (coating)) from the film that comprises formulations of active ingredients on seed (applying clothing (dressing)), change to thicker film again, under the situation of film, can discern original size and/or shape, under the situation of thicker film, for example use different materials (for example, the carrier clay for example of many layers; Different formulation example such as other formulations of active ingredients; Polymer; And colouring agent) carry out granulation, wherein the original-shape of seed and/or size no longer can be discerned.
Further specify the present invention with reference to following test case.These test cases are illustration and not limiting the scope of the invention.
Test case 1: the preparation of fungicide 1
Preparation is impregnated with the rice paddy seed mat of fungicide 1 by the following method:
In the 2L beaker, 410g nitrile Fluoxastrobin (98.4%, Syngenta/strobilurin type fungicide) is mixed with 15g polyoxyethylene naphthaldehyde condensation compound, 50g glycerine, 1g xanthans, 1g silicone antifoam agent and 523g running water.With mixture stir about 10 minutes and carry out wet-milling, it is 2 to 5 microns up to average particle size particle size.
Test case 2: the preparation of fungicide 2
Preparation is impregnated with the rice paddy seed mat of fungicide 2 by the following method:
In the 2L beaker, 410g nitrile Fluoxastrobin (98.4%, Syngenta/strobilurin type fungicide) is mixed with the 590g paraffin oil.With mixture stir about 10 minutes and carry out wet-milling, it is 2 to 5 microns up to average particle size particle size.
Test case 3: the preparation of fungicide 3
Preparation is impregnated with the rice paddy seed mat of fungicide 3 by the following method:
In the 2L beaker, 410g nitrile Fluoxastrobin (98.4%, Syngenta/strobilurin type fungicide) is mixed with castor oil, 20g calcium salt of dodecylbenzene sulfonate, 50g polyoxyethylene lauryl ether and the 490g paraffin oil of 30g ethoxylation.With mixture stir about 10 minutes and carry out wet-milling, it is 2 to 5 microns up to average particle size particle size.
Test case 4: the preparation of fungicide 4
Preparation is impregnated with the rice paddy seed mat of fungicide 4 by the following method:
In blender, 100g nitrile Fluoxastrobin (98.4%, Syngenta/strobilurin type fungicide) is mixed with 50g pre-gelatinized starch, 137g zeolite powder, 5g atoleine, 5g talcum and 488g pyrophyllite.With the dry mill milled mixtures up to 98% particle by 250 purposes sieve.With the powder of water-wet, and extrude with extruder through grinding.With the particle drying of extruding, and change in the container that applies.Use 430g polyvinyl acetate emulsion to apply described particle by spraying repeatedly and dried particles.
Test case 5: the preparation of insecticide 1
Preparation is impregnated with the rice paddy seed mat of insecticide 1 by the following method:
In the 2L beaker, 410g thiophene worm piperazine (98.5%, Syngenta/thianicotinyl type insecticide) is mixed with 20g polyoxyethylene triphenylethylene base phenyl ether sylvite, 20g lignin sulfonic acid sodium salt, 50g glycerine, 1g xanthans, 1g silicone antifoam agent and 498g running water.With mixture stir about 10 minutes and carry out wet-milling, it is 2 to 5 microns up to average particle size particle size.
Test case 6: the preparation of insecticide 2
Preparation is impregnated with the rice paddy seed mat of insecticide 2 by the following method:
In the 2L beaker, 410g thiophene worm piperazine (98.5%, Syngenta/thianicotinyl type insecticide) is mixed with polyoxyethylene naphthaldehyde condensation compound, 50g glycerine, 1g xanthans, 1g silicone antifoam agent and the 523g running water of 15g.With mixture stir about 10 minutes and carry out wet-milling, it is 2 to 5 microns up to average particle size particle size.
Test case 7: the preparation of insecticide 3
Preparation is impregnated with the rice paddy seed mat of insecticide 3 by the following method:
In the 2L beaker, 410g thiophene worm piperazine (98.5%, Syngenta/thianicotinyl type insecticide) is mixed with the 590g paraffin oil.With mixture stir about 10 minutes and carry out wet-milling, it is 2 to 5 microns up to average particle size particle size.
Test case 8: the preparation of insecticide 4
Preparation is impregnated with the rice paddy seed mat of insecticide 4 by the following method:
In the 2L beaker, 410g thiophene worm piperazine (98.5%, Syngenta/thianicotinyl type insecticide) is mixed with castor oil, 20g calcium salt of dodecylbenzene sulfonate, 50g polyoxyethylene lauryl ether and the 490g paraffin oil of 30g ethoxylation.With mixture stir about 10 minutes and carry out wet-milling, it is 2 to 5 microns up to average particle size particle size.
Test case 9: the preparation of insecticide 5
Preparation is impregnated with the rice paddy seed mat of insecticide 5 by the following method:
In blender, 44g thiophene worm piperazine (98.5%, Syngenta/thianicotinyl type insecticide) is mixed with 50g pre-gelatinized starch, 137g zeolite powder, 5g atoleine, 5g talcum and 544g pyrophyllite.With the dry mill milled mixtures up to 98% particle by 250 purposes sieve.With the powder of water-wet, and extrude with extruder through grinding.With the particle drying of extruding, and change in the container that applies.430g polyvinyl acetate emulsion is coated on the particle with drying by spraying repeatedly.
Test case 10: the rice paddy seed that is impregnated with fungicide preparation 1 is with mat N ° 1
The preparation rice paddy seed that is impregnated with fungicide preparation 1 is with mat N ° 1 by the following method:
200g is mixed in the raw material that are used to form the rice seedling mat (Korean patent No. KR438049) (it is sold with trade name " Choabang Topsoil Mat " by National Agro Co.) of dry matter with 1000g by the fungicide 1 of test case 1 preparation, be impregnated with the seed mat composition 1 that is used for paddy rice of fungicide preparation 1 with formation.
Test case 11: the rice paddy seed that is impregnated with fungicide preparation 2 is with mat N ° 2
The rice paddy seed that is impregnated with fungicide preparation 2 with the method preparation identical with test case 10 is with mat N ° 2, and difference is to add fungicide 2 and replaces fungicides 1.
Test case 12: the rice paddy seed that is impregnated with fungicide preparation 3 is with mat N ° 3
The rice paddy seed that is impregnated with fungicide preparation 3 with the method preparation identical with test case 10 is with mat N ° 3, and difference is to add fungicide 3 and replaces fungicides 1.Test case 13: the rice paddy seed that is impregnated with fungicide preparation 4 is with mat N ° 4
The rice paddy seed that is impregnated with fungicide preparation 4 with the method preparation identical with test case 10 is with mat N ° 4, and difference is that replacing fungicides 1 and 400g to be used to form rice paddy seed the fungicide 4 of 800g by test case 4 preparations mixes with the raw material of mat.
Test case 14: the rice paddy seed that is impregnated with insecticide preparation 1 is with mat N ° 5
The preparation rice paddy seed that is impregnated with insecticide preparation 1 is with mat N ° 5 by the following method:
20g is mixed in the raw material that are used to form the rice seedling mat (Korean patent No. KR438049) (it is sold with trade name " Choabang Topsoil Mat " by National Agro Co.) of dry matter with 1180g by the insecticide 1 of test case 5 preparations, and form the seed mat composition 5 that is used for paddy rice that is impregnated with insecticide preparation 1.
Test case 15: the rice paddy seed that is impregnated with insecticide preparation 2 is with mat N ° 6
The rice paddy seed that is impregnated with insecticide preparation 2 with the method preparation identical with test case 14 is with mat N ° 6, and difference is that the insecticide 2 that adds by test case 6 preparations replaces insecticides 1.
Test case 16: the rice paddy seed that is impregnated with insecticide preparation 3 is with mat N ° 7
The rice paddy seed that is impregnated with insecticide preparation 3 with the method preparation identical with test case 14 is with mat N ° 7, and difference is that the insecticide 3 that adds by test case 7 preparations replaces insecticides 1.
Test case 17: the rice paddy seed that is impregnated with insecticide preparation 4 is with mat N ° 8
The rice paddy seed that is impregnated with insecticide preparation 4 with the method preparation identical with test case 14 is with mat N ° 8, and difference is that the insecticide 4 that adds by test case 8 preparations replaces insecticides 1.
Test case 18: the rice paddy seed that is impregnated with insecticide preparation 5 is with mat N ° 9
The rice paddy seed that is impregnated with insecticide preparation 5 with the method preparation identical with test case 14 is with mat N ° 9, and difference is to replace insecticides 1 to mix with the raw material that 1000g is used to form the rice paddy seed mat insecticide 5 of 200g by test case 9 preparations.Test case 19: the rice paddy seed that is impregnated with fungicide preparation 1 and insecticide preparation 1 is with mat N ° 10
The preparation rice paddy seed that is impregnated with fungicide preparation 1 and insecticide preparation 1 is with mat N ° 10 by the following method:
200g is mixed in the raw material that are used to form the rice seedling mat (Korean patent No. KR438049) (it is sold with trade name " Choabang Topsoil Mat " by National Agro Co.) of dry matter with 980g by the insecticide 1 that test case 5 prepares by the fungicide 1 and the 20g of test case 1 preparation, and form the paddy rice usefulness mat composition 10 that is impregnated with fungicide preparation 1 and insecticide preparation 1.
Test case 20: the rice paddy seed land used that is impregnated with fungicide preparation 2 and insecticide preparation 2
Seat N ° 11
The rice paddy seed that is impregnated with fungicide preparation 2 and insecticide preparation 2 with the method preparation identical with test case 19 is with mat N ° 11, and difference is to use fungicide 2 and insecticide 2 to replace fungicide 1 and insecticides 1.
Test case 21: the rice paddy seed land used that is impregnated with fungicide preparation 3 and insecticide preparation 3
Seat N ° 12
The rice paddy seed that is impregnated with fungicide preparation 3 and insecticide preparation 3 with the method preparation identical with test case 19 is with mat N ° 12, and difference is to use fungicide 3 and insecticide 3 to replace fungicide 1 and insecticides 1.
Test case 22: the rice paddy seed land used that is impregnated with fungicide preparation 4 and insecticide preparation 4
Seat N ° 13
The rice paddy seed that is impregnated with fungicide preparation 4 and insecticide preparation 4 with the method preparation identical with test case 19 is with mat N ° 13, and difference is to use 800g fungicide 4 and 20g insecticide 4 to replace fungicides 1 and insecticide 1 to mix with the raw material that 380g is used to form the rice paddy seed mat.
Test case 23: the rice paddy seed land used that is impregnated with fungicide preparation 1 and insecticide preparation 5
Seat N ° 14
200g is mixed in the raw material that are used to form the rice seedling mat (Korean patent No. KR438049) (it is sold with trade name " Choabang Topsoil Mat " by National Agro Co.) of dry matter with 800g by the insecticide 1 that test case 9 prepares by the fungicide 1 and the 200g of test case 1 preparation, and form the seed mat composition 14 that is used for paddy rice that is impregnated with fungicide preparation 1 and insecticide preparation 5.
Test case 24: the rice paddy seed land used that is impregnated with fungicide preparation 1 and insecticide preparation 5
Seat N ° 15
The rice paddy seed that is impregnated with fungicide preparation 1 and insecticide preparation 5 with the method preparation identical with test case 23 is with mat N ° 15, and difference is to use fungicide 2 to replace fungicides 1.
Test case 25: the rice paddy seed land used that is impregnated with fungicide preparation 3 and insecticide preparation 5
Seat N ° 16
The rice paddy seed that is impregnated with fungicide preparation 3 and insecticide preparation 5 with the method preparation identical with test case 23 is with mat N ° 16, and difference is to use fungicide 3 to replace fungicides 1.
Test case 26: the rice paddy seed land used that is impregnated with fungicide preparation 4 and insecticide preparation 5
Seat N ° 17
The rice paddy seed that is impregnated with fungicide preparation 4 and insecticide preparation 5 with the method preparation identical with test case 23 is with mat N ° 17, and difference is to use 800g fungicide 4 to replace fungicides 1 to mix with the raw material that 200g is used to form the rice paddy seed mat.
Test case 27: be impregnated with fungicide preparation 1﹠amp; 4 and insecticide preparation 1﹠amp; 5 paddy rice
Mat for seeds N ° 18
Be impregnated with fungicide preparation 1﹠amp with the method preparation identical with test case 23; 4 and insecticide preparation 1﹠amp; 5 rice paddy seed is with mat N ° 18, and difference is to use 100g fungicide 1,400g fungicide 4,10g insecticide 1 and 100g insecticide 5 to mix with the raw material that 390g is used to form the rice paddy seed mat.
Comparative example 1
The product that is used for seed treatment on the market is used as comparative example 1.Seed was soaked 3 to 4 days, remove the water that is used to handle subsequently.Product (wetting powder) is applied on the seed.Impel rudiment, reach 1 to 3mm stem.The planting seed of rudiment is being filled up on the seedling growing box of half with seed bed soil.Before sowing that bed soil is saturated.Cover with dry ground above the seed of sowing.Under enough temperature after 10 to 25 days nursery stage, with sprigging.
Comparative example 2
Select the conventional granular pattern product that comprises insecticide and Fungicidal mixtures that the seedling case uses as a comparative example 2 that is used for.Will be on the seedbed with the seedling-cultivating method identical without the planting seed of the rudiment of pesticide treatments with comparative example 1.Handling-disseminate insecticide before transplanting in 0 to 7 day transplants after to seedling growing box.
The evaluation of biological efficiency and crop safety
The plot that is designed for potency test is 30m
2(5m*6m can transplant 1 mat for seeds usually), and the degree of depth of paddy field water either is controlled at 3-5cm.By being compared with treated plot, the disease severity in undressed plot calculates the evaluation of antifungal efficacy.In order to estimate insect usefulness extremely, count the target insect number of every strain plant, to be used for coming comparison usefulness with undressed plot.Usefulness is expressed as percentage (%).The observation of crops safety is carried out in seedling growing box, up to the previous day of transplanting, and is extended to biological efficiency evaluation end.
[table 1] is impregnated with the seed mat composition that is used for paddy rice of fungicide
Biological efficiency and phytotoxic evaluation
| Phytotoxicity (0 to 5) | Biological efficiency (%, 0 to 100) | ||||
| Before the transplanting | After the transplanting | Leaf pest (leaf blast) | Fringe pest (ear blast) | Dry sheath rot (sheath blight) | |
| Test case 10 | 0.5 | 0 | 92 | 88.3 | 86.2 |
| Test case 11 | 0.3 | 0 | 92.3 | 88.8 | 86.5 |
| Test case 12 | 0.1 | 0 | 96.4 | 92.2 | 89.9 |
| Test case 13 | 0 | 0 | 95.1 | 90.8 | 88.3 |
| Comparative example 1 | 0.3 | 0 | 93.3 | 68.5 | 50.4 |
| The infection rate in undressed plot (%) | - | - | 5 | 20 | 20 |
Above-mentioned table 1 shows that the seed mat that is used for paddy rice that is impregnated with fungicide has good biological efficiency and enough persistence.
[table 2] is impregnated with the seed mat composition that is used for paddy rice of insecticide
Biological efficiency and phytotoxic evaluation
| Phytotoxicity (0 to 5) | Biological efficiency (%, 0 to 100) | |||
| Before the transplanting | After the transplanting | Rice water resembles | Brown planthopper | |
| Test case 14 | 0.2 | 0 | 99.7 | 87.2 |
| Test case 15 | 0.2 | 0 | 99.7 | 86.5 |
| Test case 16 | 0.1 | 0 | 100 | 89.2 |
| Test case 17 | 0.1 | 0 | 99.8 | 89.3 |
| Test case 18 | 0 | 0 | 99.2 | 94.3 |
| Comparative example 1 | 0.3 | 0 | 97.1 | 65.5 |
| The insect number of every strain plant in the undressed plot | - | - | 60 | 50 |
Above-mentioned table 2 shows that the seed mat that is used for paddy rice that is impregnated with insecticide has good biological efficiency and enough persistence.
[table 3] is impregnated with the seed mat that is used for paddy rice of fungicide and insecticide
The biological efficiency of composition and phytotoxic evaluation
| Phytotoxicity (0 to 5) | Biological efficiency (%, 0 to 100) | ||||||
| Before the transplanting | After the transplanting | Rice water resembles | The leaf pest | The fringe pest | Brown planthopper | Dry sheath rot | |
| Test case 19 | 0.3 | 0 | 100 | 97.2 | 86.6 | 85.1 | 81.4 |
| Test case 20 | 0.2 | 0 | 99.8 | 98.3 | 87.8 | 84.6 | 80.1 |
| Test case 21 | 0.1 | 0 | 99.6 | 97.5 | 88.1 | 87.3 | 84.6 |
| Test case 22 | 0.1 | 0 | 99.5 | 96.6 | 95.5 | 86.2 | 92.2 |
| Test case 23 | 0.3 | 0 | 99.8 | 97.2 | 87.1 | 92.8 | 80.5 |
| Test case 24 | 0.2 | 0 | 99.3 | 97.5 | 88.8 | 94.4 | 81.8 |
| Test case 25 | 0.2 | 0 | 99.5 | 97.2 | 88.5 | 93.8 | 82.3 |
| Test case 26 | 0.1 | 0 | 96.3 | 96.7 | 95.6 | 94.8 | 94.4 |
| Test case 27 | 0 | 0 | 99.8 | 99.2 | 99.9 | 98.9 | 98.8 |
| Comparative example 1 | 0.3 | 0 | 97.5 | 98.1 | 70.1 | 60.3 | 42.1 |
| Comparative example 2* | - | 0 | 98.2 | 92.5 | 72.5 | 60.7 | 45.8 |
| The infection rate in undressed plot (%) | - | - | - | 5 | 20 | 20 | - |
| The insect number of every strain plant in the undressed plot | - | - | 60 | - | - | 50 | - |
* because the time of application of comparative example 2 (it is just using on the same day of transplanting) can not compare the phytotoxicity observation of example 2
Above-mentioned table 3 shows that the seed mat composition that is used for paddy rice that is impregnated with fungicide and insecticide has good biological efficiency.Particularly, the controlled release composition that is impregnated with the seed mat that is used for paddy rice of fungicide and insecticide shows better biological efficiency.
According to the present invention, no longer need insecticide to use later on, therefore can save manpower and expect that the peasant can contact insecticide.Particularly, can realize the release control of pesticide active ingredient.
Claims (16)
1. mat for seeds, it comprises:
A) at least a animal pest active component and/or at least a Fungicidal active ingredient of killing,
B) at least a release controllable material, comprise surfactant, solvent, polymer resin and filler and
C) as the organic material of bed soil and/or the mixture of paper fiber.
2. the mat of claim 1, it is used for seed rice.
3. the mat of claim 1, it is used to be selected from the following agronomy plant or the seed of plant: cereal, for example wheat, barley, rye, oat, paddy rice, corn or Chinese sorghum; Beet, for example sugar beet or fodder beet; Fruit, for example pomaceous fruit, drupe and soft fruit, for example apple, pears, Lee, peach, apricot, cherry or berry are as strawberry, raspberry or blackberry, blueberry; Beans, for example Kidney bean, Lens culinaris, pea or soybean; Oil crop, for example oilseed rape, mustard, opium poppy, olive, sunflower, coconut, castor-oil plant, cocoa or peanut; Cucurbitaceous plant, for example pumpkin, cucumber or muskmelon; Fibre plant, for example cotton, flax, hemp or jute; Both citrus fruit, for example orange, lemon, grapefruit or oranges and tangerines; Greengrocery is as spinach, lettuce, asparagus, cabbage class, carrot, onion, red pepper, tomato, potato or capsicum; Canella, for example avocado, camphor tree or camphor; With tobacco, nut, coffee, eggplant, sugarcane, tea, pepper, grape, humulus grass, Musaceae plant, latex plant, ornamental plants, flowers and turf grass.
4. each mat in the claim 1 to 3, it comprises at least a following surfactant that is selected from: polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene triphenylethylene base aryl ether, polyxyethylated ester, polyoxyethylene alkyl amine, the polyoxyethylene sorbitan aliphatic ester, polyox-yethylene-polyoxypropylene block copolymer, castor oil derivatives, sorbitan aliphatic ester, sodium alkyl sulfonate, alkyl sulfosuccinate, neopelex, calcium dodecyl benzene sulfonate, diisopropyl naphthalene sulfonate, the alkylaryl sulfonates formaldehyde condensation products.
5. each mat in the claim 1 to 4, it comprises at least a following solvent that is selected from: paraffin oil, slab oil, olive oil, soybean oil, rapeseed oil, corn oil, castor oil, cottonseed oil, cocoa butter and palm oil.
6. each mat in the claim 1 to 5, it comprises at least a following polymer resin that is selected from: polyvinyl alcohol, polyvinyl acetate, Sodium Polyacrylate, sodium carboxymethylcellulose, hydroxyethylcellulose, polyvinylpyrrolidone, mosanom, starch, dextrin, gum Arabic, guar gum, xanthans and gellan gum.
7. each mat in the claim 1 to 6, it comprises at least a following filler that is selected from: pyrophyllite, talcum, bentonite, white carbon, urea-formaldehyde condensation product, kaolin, calcium carbonate, clay, silica and zeolite.
8. each mat in the claim 1 to 7, it comprises at least a following Fungicidal active ingredient that is selected from: thiadiazoles element-S-methyl, nitrile Fluoxastrobin, ring propionyl bacterium amine, Cyproconazole, cyprodinil, Difenoconazole, edifenphos, fluorine ring azoles, zarilamid, ferimzone, fludioxonil, flutolanil, Rabcide, own azoles alcohol, hydroxyisoxazole, metalaxyl, Metalaxyl-M, SSF 126, Pencycuron, probenazole, propiconazole, pyroquilon, probenazole, thiadinil, tricyclazole, valida, oxime bacterium ester, Tebuconazole and fluoxastrobin.
9. each mat in the claim 1 to 8, it comprises at least a following animal pest active component that kills that is selected from: Avermectin, Acetamiprid, Benfuracard micro, Buprofezin, carbofuran, carbosulfan, Padan, thiophene worm amine, fly eradication amine, MTI-446, ether chrysanthemum ester, fenthion, fluorine worm nitrile, Imidacloprid, gamma cyhalothrin, the fluorine third oxygen urea, methidathion, methoxyfenozide, pyrrole aphid ketone, thiophene worm piperazine, worm hydrazides and tefluthrin.
10. each mat in the claim 1 to 9, it comprises:
A) 0.01 to 10%w/w animal pest active component extremely, and/or
0.01 to the Fungicidal active ingredient of 5%w/w and
B) 0.01 to 10%w/w surfactant and
0.005 to the solvent of 10%w/w and
0.0005 to the polymer resin of 20%w/w and
0.1 to the filler of 50%w/w and
C) 1 to 99%w/w bed soil.
11. prepare the method for mat for seeds, may further comprise the steps:
A) at least a solid or insecticidal liquid active component are mixed with at least a composition that is used to prepare release controllable material, described active insecticidal components is selected from and kills animal pest active component and Fungicidal active ingredient, the described composition that is used to prepare release controllable material is selected from surfactant, solvent, polymer resin and filler
B) mixture that will prepare in (a) carries out wet-milling up to 2 to 5 microns average particle size particle size,
The mixture through grinding that c) will in (b), prepare mix with the mixture of organic material and paper fiber and
D) use mat forming machine is used in the mixture that obtains in (c) and forms mat.
12. prepare the method for mat for seeds, may further comprise the steps:
A) at least a solid or insecticidal liquid active component are mixed with at least a composition that is used to prepare release controllable material, described active insecticidal components is selected from and kills animal pest active component and Fungicidal active ingredient, the described composition that is used to prepare release controllable material is selected from surfactant, solvent, polymer resin and filler
B) mixture that will prepare in (a) is extruded with the formation particle,
C) polymer resin that discharges with controlled is coated in the particle of preparation in (b),
The particle through applying that d) will in (c), prepare mix with the mixture of organic material and paper fiber and
E) use mat forming machine is used in the mixture that obtains in (d) and forms mat.
13. prepare the method for mat for seeds, may further comprise the steps:
A) at least a solid or insecticidal liquid active component are mixed with at least a composition that is used to prepare release controllable material, described active insecticidal components is selected from and kills animal pest active component and Fungicidal active ingredient, the described composition that is used to prepare release controllable material is selected from surfactant, solvent, polymer resin and filler
B) mixture that will prepare in (a) carries out wet-milling up to 2 to 5 microns average particle size particle size,
The mixture through grinding that c) will prepare in (b) is extruded with the formation particle,
D) polymer resin that discharges with controlled be coated in preparation in (c) particle and
E) use mat forming machine is used in the mixture that obtains in (d) and forms mat.
14. comprise the purposes that is used to control animal pest and/or pathogene with the mat for seeds at least a controlled release preparation that kills animal pest active component and/or at least a Fungicidal active ingredient together.
15. the purposes of claim 14, wherein seed and/or seedling are seed and/or the seedling of paddy rice.
16. the purposes of claim 14, wherein seed and/or seedling are to be selected from following agronomy plant or seed and/or the seedling of crop: cereal, for example wheat, barley, rye, oat, paddy rice, corn or Chinese sorghum; Beet, for example sugar beet or fodder beet; Fruit, for example pomaceous fruit, drupe and soft fruit, for example apple, pears, Lee, peach, apricot, cherry or berry are as strawberry, raspberry or blackberry, blueberry; Beans, for example Kidney bean, Lens culinaris, pea or soybean; Oil crop, for example oilseed rape, mustard, opium poppy, olive, sunflower, coconut, castor-oil plant, cocoa or peanut; Cucurbitaceous plant, for example pumpkin, cucumber or muskmelon; Fibre plant, for example cotton, flax, hemp or jute; Both citrus fruit, for example orange, lemon, grapefruit or oranges and tangerines; Greengrocery is as spinach, lettuce, asparagus, cabbage class, carrot, onion, red pepper, tomato, potato or capsicum; Canella, for example avocado, camphor tree or camphor; With tobacco, nut, coffee, eggplant, sugarcane, tea, pepper, grape, humulus grass, Musaceae plant, latex plant, ornamental plants, flowers and turf grass.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020040101593A KR20060062673A (en) | 2004-12-06 | 2004-12-06 | New composition of seedling mat for rice and the method for producing the same |
| KR1020040101593 | 2004-12-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101119632A true CN101119632A (en) | 2008-02-06 |
Family
ID=35892591
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200580041869XA Pending CN101119632A (en) | 2004-12-06 | 2005-12-05 | A mat for seeds and the method for producing the same |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP2008522586A (en) |
| KR (2) | KR20060062673A (en) |
| CN (1) | CN101119632A (en) |
| AR (1) | AR051700A1 (en) |
| TW (1) | TW200628063A (en) |
| WO (1) | WO2006061164A1 (en) |
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| CN102613231A (en) * | 2008-12-31 | 2012-08-01 | 浙江世佳科技有限公司 | Seed coating agent of lufenuron and difenoconazole |
| CN103039221A (en) * | 2012-09-05 | 2013-04-17 | 苏州天宝工贸有限公司 | Composite soil plate and preparation method thereof |
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| GB0801589D0 (en) * | 2008-01-29 | 2008-03-05 | Syngenta Participations Ag | Mollusicide |
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| AU2020298287A1 (en) * | 2019-06-15 | 2022-01-27 | Iharabrás S.A. Indústrias Químicas | Synergistic fungicidal composition |
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- 2004-12-06 KR KR1020040101593A patent/KR20060062673A/en not_active Application Discontinuation
-
2005
- 2005-12-05 JP JP2007543797A patent/JP2008522586A/en active Pending
- 2005-12-05 WO PCT/EP2005/012996 patent/WO2006061164A1/en not_active Application Discontinuation
- 2005-12-05 TW TW094142766A patent/TW200628063A/en unknown
- 2005-12-05 AR ARP050105074A patent/AR051700A1/en not_active Application Discontinuation
- 2005-12-05 KR KR1020077012754A patent/KR20070085819A/en not_active Application Discontinuation
- 2005-12-05 CN CNA200580041869XA patent/CN101119632A/en active Pending
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Also Published As
| Publication number | Publication date |
|---|---|
| KR20060062673A (en) | 2006-06-12 |
| KR20070085819A (en) | 2007-08-27 |
| JP2008522586A (en) | 2008-07-03 |
| AR051700A1 (en) | 2007-01-31 |
| TW200628063A (en) | 2006-08-16 |
| WO2006061164A1 (en) | 2006-06-15 |
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