CN101978006A - 多功能涂覆液组合物 - Google Patents
多功能涂覆液组合物 Download PDFInfo
- Publication number
- CN101978006A CN101978006A CN2009801093636A CN200980109363A CN101978006A CN 101978006 A CN101978006 A CN 101978006A CN 2009801093636 A CN2009801093636 A CN 2009801093636A CN 200980109363 A CN200980109363 A CN 200980109363A CN 101978006 A CN101978006 A CN 101978006A
- Authority
- CN
- China
- Prior art keywords
- compound
- functional
- coat film
- chemical formula
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 105
- 239000011248 coating agent Substances 0.000 title claims abstract description 102
- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 229910052709 silver Inorganic materials 0.000 claims abstract description 43
- 239000004332 silver Substances 0.000 claims abstract description 40
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 37
- 150000001875 compounds Chemical class 0.000 claims abstract description 37
- 229910052751 metal Inorganic materials 0.000 claims abstract description 15
- 239000002184 metal Substances 0.000 claims abstract description 14
- 229940100890 silver compound Drugs 0.000 claims abstract description 8
- 150000003379 silver compounds Chemical class 0.000 claims abstract description 8
- -1 salt compound Chemical class 0.000 claims description 77
- 239000007788 liquid Substances 0.000 claims description 52
- 239000000126 substance Substances 0.000 claims description 44
- 239000000243 solution Substances 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 16
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 15
- 229910000765 intermetallic Inorganic materials 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 230000014509 gene expression Effects 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 9
- 125000000524 functional group Chemical group 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 239000004593 Epoxy Substances 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000005864 Sulphur Substances 0.000 claims description 6
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 6
- 229920000180 alkyd Polymers 0.000 claims description 6
- 229910052788 barium Inorganic materials 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- NKFIBMOQAPEKNZ-UHFFFAOYSA-N 5-amino-1h-indole-2-carboxylic acid Chemical compound NC1=CC=C2NC(C(O)=O)=CC2=C1 NKFIBMOQAPEKNZ-UHFFFAOYSA-N 0.000 claims description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- DYHSMQWCZLNWGO-UHFFFAOYSA-N di(propan-2-yloxy)alumane Chemical compound CC(C)O[AlH]OC(C)C DYHSMQWCZLNWGO-UHFFFAOYSA-N 0.000 claims description 5
- 235000019439 ethyl acetate Nutrition 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 229910052738 indium Inorganic materials 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- BPYXFMVJXTUYRV-UHFFFAOYSA-J octanoate;zirconium(4+) Chemical compound [Zr+4].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O BPYXFMVJXTUYRV-UHFFFAOYSA-J 0.000 claims description 5
- 229910052715 tantalum Inorganic materials 0.000 claims description 5
- 229910052718 tin Inorganic materials 0.000 claims description 5
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 4
- 239000004640 Melamine resin Substances 0.000 claims description 4
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims description 4
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 4
- 229910021505 gold(III) hydroxide Inorganic materials 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- HRRDCWDFRIJIQZ-UHFFFAOYSA-N naphthalene-1,8-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=CC2=C1 HRRDCWDFRIJIQZ-UHFFFAOYSA-N 0.000 claims description 4
- 229920000620 organic polymer Polymers 0.000 claims description 4
- 239000004417 polycarbonate Substances 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 239000002952 polymeric resin Substances 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 150000003377 silicon compounds Chemical class 0.000 claims description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 229910052772 Samarium Inorganic materials 0.000 claims description 3
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 3
- 229910052776 Thorium Inorganic materials 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052790 beryllium Inorganic materials 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- 229910052792 caesium Inorganic materials 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 229910052732 germanium Inorganic materials 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 229910052735 hafnium Inorganic materials 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052741 iridium Inorganic materials 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 229910052745 lead Inorganic materials 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910052753 mercury Inorganic materials 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- YPJKMVATUPSWOH-UHFFFAOYSA-N nitrooxidanyl Chemical compound [O][N+]([O-])=O YPJKMVATUPSWOH-UHFFFAOYSA-N 0.000 claims description 3
- 229910052762 osmium Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 229910052702 rhenium Inorganic materials 0.000 claims description 3
- 229910052703 rhodium Inorganic materials 0.000 claims description 3
- 229910052701 rubidium Inorganic materials 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 229910052716 thallium Inorganic materials 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims description 2
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 claims description 2
- IMUHIAGWLHIKLI-UHFFFAOYSA-N 1-(2-benzoylphenyl)hexan-1-one Chemical compound C(CCCCC)(=O)C1=C(C(=O)C2=CC=CC=C2)C=CC=C1 IMUHIAGWLHIKLI-UHFFFAOYSA-N 0.000 claims description 2
- QYIGOGBGVKONDY-UHFFFAOYSA-N 1-(2-bromo-5-chlorophenyl)-3-methylpyrazole Chemical compound N1=C(C)C=CN1C1=CC(Cl)=CC=C1Br QYIGOGBGVKONDY-UHFFFAOYSA-N 0.000 claims description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 claims description 2
- MMEDJBFVJUFIDD-UHFFFAOYSA-N 2-[2-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC=C1CC(O)=O MMEDJBFVJUFIDD-UHFFFAOYSA-N 0.000 claims description 2
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 claims description 2
- RIQGBMGSBMEAER-UHFFFAOYSA-L CO[Zr](Cl)(Cl)OC Chemical compound CO[Zr](Cl)(Cl)OC RIQGBMGSBMEAER-UHFFFAOYSA-L 0.000 claims description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims description 2
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- 239000004840 adhesive resin Substances 0.000 claims description 2
- 229920006223 adhesive resin Polymers 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- 235000010290 biphenyl Nutrition 0.000 claims description 2
- 239000004305 biphenyl Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 claims description 2
- AMFIJXSMYBKJQV-UHFFFAOYSA-L cobalt(2+);octadecanoate Chemical compound [Co+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AMFIJXSMYBKJQV-UHFFFAOYSA-L 0.000 claims description 2
- 229910000001 cobalt(II) carbonate Inorganic materials 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 2
- ZLNAFSPCNATQPQ-UHFFFAOYSA-N ethenyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C=C ZLNAFSPCNATQPQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000012634 fragment Substances 0.000 claims description 2
- OTCKNHQTLOBDDD-UHFFFAOYSA-K gold(3+);triacetate Chemical compound [Au+3].CC([O-])=O.CC([O-])=O.CC([O-])=O OTCKNHQTLOBDDD-UHFFFAOYSA-K 0.000 claims description 2
- 150000008282 halocarbons Chemical class 0.000 claims description 2
- CZWLNMOIEMTDJY-UHFFFAOYSA-N hexyl(trimethoxy)silane Chemical compound CCCCCC[Si](OC)(OC)OC CZWLNMOIEMTDJY-UHFFFAOYSA-N 0.000 claims description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 2
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 claims description 2
- FRVCGRDGKAINSV-UHFFFAOYSA-L iron(2+);octadecanoate Chemical compound [Fe+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O FRVCGRDGKAINSV-UHFFFAOYSA-L 0.000 claims description 2
- HDJUVFZHZGPHCQ-UHFFFAOYSA-L manganese(2+);oxalate;dihydrate Chemical compound O.O.[Mn+2].[O-]C(=O)C([O-])=O HDJUVFZHZGPHCQ-UHFFFAOYSA-L 0.000 claims description 2
- SLFVYFOEHHLHDW-UHFFFAOYSA-N n-(trifluoromethyl)aniline Chemical compound FC(F)(F)NC1=CC=CC=C1 SLFVYFOEHHLHDW-UHFFFAOYSA-N 0.000 claims description 2
- HZPNKQREYVVATQ-UHFFFAOYSA-L nickel(2+);diformate Chemical compound [Ni+2].[O-]C=O.[O-]C=O HZPNKQREYVVATQ-UHFFFAOYSA-L 0.000 claims description 2
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 claims description 2
- 229960003493 octyltriethoxysilane Drugs 0.000 claims description 2
- PZKNFJIOIKQCPA-UHFFFAOYSA-N oxalic acid palladium Chemical compound [Pd].OC(=O)C(O)=O PZKNFJIOIKQCPA-UHFFFAOYSA-N 0.000 claims description 2
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920001228 polyisocyanate Polymers 0.000 claims description 2
- 239000005056 polyisocyanate Substances 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 230000002829 reductive effect Effects 0.000 claims description 2
- 229920003987 resole Polymers 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
- 239000013008 thixotropic agent Substances 0.000 claims description 2
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 2
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 claims description 2
- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 claims description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 229940068475 zinc citrate Drugs 0.000 claims description 2
- 235000006076 zinc citrate Nutrition 0.000 claims description 2
- 239000011746 zinc citrate Substances 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 230000005611 electricity Effects 0.000 abstract description 3
- 150000001450 anions Chemical class 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract description 2
- 150000003378 silver Chemical class 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000002075 main ingredient Substances 0.000 abstract 1
- 229910052755 nonmetal Inorganic materials 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 24
- 239000002585 base Substances 0.000 description 16
- 238000002310 reflectometry Methods 0.000 description 11
- 239000011521 glass Substances 0.000 description 9
- 150000002500 ions Chemical class 0.000 description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000000123 paper Substances 0.000 description 6
- 230000003068 static effect Effects 0.000 description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910021393 carbon nanotube Inorganic materials 0.000 description 4
- 239000002041 carbon nanotube Substances 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- 239000007769 metal material Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 238000003618 dip coating Methods 0.000 description 3
- REYJJPSVUYRZGE-UHFFFAOYSA-O hydron;octadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCC[NH3+] REYJJPSVUYRZGE-UHFFFAOYSA-O 0.000 description 3
- 238000005240 physical vapour deposition Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000004528 spin coating Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- SPEUIVXLLWOEMJ-UHFFFAOYSA-N 1,1-dimethoxyethane Chemical compound COC(C)OC SPEUIVXLLWOEMJ-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- LXQMHOKEXZETKB-UHFFFAOYSA-N 1-amino-2-methylpropan-2-ol Chemical compound CC(C)(O)CN LXQMHOKEXZETKB-UHFFFAOYSA-N 0.000 description 2
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- KXLKRDONYDSHID-UHFFFAOYSA-N 2-methylpropylazanium;n-(2-methylpropyl)carbamate Chemical compound CC(C)C[NH3+].CC(C)CNC([O-])=O KXLKRDONYDSHID-UHFFFAOYSA-N 0.000 description 2
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- 229940043232 butyl acetate Drugs 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000009503 electrostatic coating Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000003053 piperidines Chemical class 0.000 description 2
- 229920000083 poly(allylamine) Polymers 0.000 description 2
- 229920001230 polyarylate Polymers 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 150000003233 pyrroles Chemical class 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000002411 thermogravimetry Methods 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N thiocyanic acid Chemical compound SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 1
- ZXSQEZNORDWBGZ-UHFFFAOYSA-N 1,3-dihydropyrrolo[2,3-b]pyridin-2-one Chemical compound C1=CN=C2NC(=O)CC2=C1 ZXSQEZNORDWBGZ-UHFFFAOYSA-N 0.000 description 1
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- KNYKHCLCBHSFCK-UHFFFAOYSA-N 1-methoxypropan-1-amine Chemical compound CCC(N)OC KNYKHCLCBHSFCK-UHFFFAOYSA-N 0.000 description 1
- LHENQXAPVKABON-UHFFFAOYSA-N 1-methoxypropan-1-ol Chemical compound CCC(O)OC LHENQXAPVKABON-UHFFFAOYSA-N 0.000 description 1
- LYIIBVSRGJSHAV-UHFFFAOYSA-N 2-aminoacetaldehyde Chemical compound NCC=O LYIIBVSRGJSHAV-UHFFFAOYSA-N 0.000 description 1
- HLCPWBZNUKCSBN-UHFFFAOYSA-N 2-aminobenzonitrile Chemical compound NC1=CC=CC=C1C#N HLCPWBZNUKCSBN-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 1
- ZYCMAPKFLBSECC-UHFFFAOYSA-N 2-cyanoethyl hydrogen carbonate Chemical compound OC(=O)OCCC#N ZYCMAPKFLBSECC-UHFFFAOYSA-N 0.000 description 1
- RWFITVTXAMYXFF-UHFFFAOYSA-N 2-cyanoethylcarbamic acid Chemical compound OC(=O)NCCC#N RWFITVTXAMYXFF-UHFFFAOYSA-N 0.000 description 1
- LTHNHFOGQMKPOV-UHFFFAOYSA-N 2-ethylhexan-1-amine Chemical compound CCCCC(CC)CN LTHNHFOGQMKPOV-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- UEOJRUGDGBIEIO-UHFFFAOYSA-N 2-ethylhexylcarbamic acid Chemical compound CCCCC(CC)CNC(O)=O UEOJRUGDGBIEIO-UHFFFAOYSA-N 0.000 description 1
- ASUDFOJKTJLAIK-UHFFFAOYSA-N 2-methoxyethanamine Chemical compound COCCN ASUDFOJKTJLAIK-UHFFFAOYSA-N 0.000 description 1
- NGUUMHKSNSFLOS-UHFFFAOYSA-N 2-methoxyethyl hydrogen carbonate Chemical compound COCCOC(O)=O NGUUMHKSNSFLOS-UHFFFAOYSA-N 0.000 description 1
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 1
- SZVUQKOTOXVFTL-UHFFFAOYSA-N 2-methylpropylazanium;2-methylpropyl carbonate Chemical compound CC(C)C[NH3+].CC(C)COC([O-])=O SZVUQKOTOXVFTL-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- SAKJVQIASONOAF-UHFFFAOYSA-N 4-(azepan-1-yl)morpholine Chemical compound C1COCCN1N1CCCCCC1 SAKJVQIASONOAF-UHFFFAOYSA-N 0.000 description 1
- 125000004172 4-methoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C([H])C([H])=C1* 0.000 description 1
- RBWNDBNSJFCLBZ-UHFFFAOYSA-N 7-methyl-5,6,7,8-tetrahydro-3h-[1]benzothiolo[2,3-d]pyrimidine-4-thione Chemical compound N1=CNC(=S)C2=C1SC1=C2CCC(C)C1 RBWNDBNSJFCLBZ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- VQHNLMYBSCCEIL-UHFFFAOYSA-M C(CCCCCCCCCCCCCCC)[N+](CC1=CC=CC=C1)(C)C.C(C1=CC=CC=C1)NC([O-])=O Chemical compound C(CCCCCCCCCCCCCCC)[N+](CC1=CC=CC=C1)(C)C.C(C1=CC=CC=C1)NC([O-])=O VQHNLMYBSCCEIL-UHFFFAOYSA-M 0.000 description 1
- WPOBXTQUFPEOFE-UHFFFAOYSA-N CCCCCCCCCC(C)OC(O)=O.CN Chemical compound CCCCCCCCCC(C)OC(O)=O.CN WPOBXTQUFPEOFE-UHFFFAOYSA-N 0.000 description 1
- XHWPOJFDBKAVGT-UHFFFAOYSA-M CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1.[O-]C(OCC1=CC=CC=C1)=O Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1.[O-]C(OCC1=CC=CC=C1)=O XHWPOJFDBKAVGT-UHFFFAOYSA-M 0.000 description 1
- LNKDZIJQXFZSRH-UHFFFAOYSA-N CCCCCCCCCCN(C)C(O)=O.CN Chemical compound CCCCCCCCCCN(C)C(O)=O.CN LNKDZIJQXFZSRH-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- HTJDQJBWANPRPF-UHFFFAOYSA-N Cyclopropylamine Chemical compound NC1CC1 HTJDQJBWANPRPF-UHFFFAOYSA-N 0.000 description 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 229920012266 Poly(ether sulfone) PES Polymers 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229920006387 Vinylite Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- CDVOLRIULPDDAB-UHFFFAOYSA-N [NH4+].OC([O-])=O.C1COCCN1.C1COCCN1 Chemical compound [NH4+].OC([O-])=O.C1COCCN1.C1COCCN1 CDVOLRIULPDDAB-UHFFFAOYSA-N 0.000 description 1
- 229910052946 acanthite Inorganic materials 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 229910052767 actinium Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- RZJRJXONCZWCBN-UHFFFAOYSA-N alpha-octadecene Natural products CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- KGZFQCYSZHOEFZ-UHFFFAOYSA-N azepan-1-ylazanium N-(azepan-1-yl)carbamate Chemical compound [NH3+]N1CCCCCC1.[O-]C(=O)NN1CCCCCC1 KGZFQCYSZHOEFZ-UHFFFAOYSA-N 0.000 description 1
- CZTHKWXLEIJUCS-UHFFFAOYSA-N azepan-1-ylazanium azepan-1-yl carbonate Chemical compound [NH3+]N1CCCCCC1.[O-]C(=O)ON1CCCCCC1 CZTHKWXLEIJUCS-UHFFFAOYSA-N 0.000 description 1
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N azepane Chemical compound C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DFFDSQBEGQFJJU-UHFFFAOYSA-N butyl hydrogen carbonate Chemical group CCCCOC(O)=O DFFDSQBEGQFJJU-UHFFFAOYSA-N 0.000 description 1
- ZZHGIUCYKGFIPV-UHFFFAOYSA-N butylcarbamic acid Chemical group CCCCNC(O)=O ZZHGIUCYKGFIPV-UHFFFAOYSA-N 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 125000004802 cyanophenyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 1
- HFXKQSZZZPGLKQ-UHFFFAOYSA-N cyclopentamine Chemical compound CNC(C)CC1CCCC1 HFXKQSZZZPGLKQ-UHFFFAOYSA-N 0.000 description 1
- 229960003263 cyclopentamine Drugs 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- QLVWOKQMDLQXNN-UHFFFAOYSA-N dibutyl carbonate Chemical compound CCCCOC(=O)OCCCC QLVWOKQMDLQXNN-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- KWBIXTIBYFUAGV-UHFFFAOYSA-N ethylcarbamic acid Chemical compound CCNC(O)=O KWBIXTIBYFUAGV-UHFFFAOYSA-N 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- NZYYSSZGIPELSX-UHFFFAOYSA-N hydrogen carbonate;pyridin-1-ium Chemical compound OC(O)=O.C1=CC=NC=C1 NZYYSSZGIPELSX-UHFFFAOYSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- BMFVGAAISNGQNM-UHFFFAOYSA-N isopentylamine Chemical compound CC(C)CCN BMFVGAAISNGQNM-UHFFFAOYSA-N 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical compound CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 description 1
- BEVIPXZYSPERIE-UHFFFAOYSA-N morpholine;morpholin-4-ium;carbamate Chemical compound NC([O-])=O.C1COCCN1.C1COCC[NH2+]1 BEVIPXZYSPERIE-UHFFFAOYSA-N 0.000 description 1
- NSBIQPJIWUJBBX-UHFFFAOYSA-N n-methoxyaniline Chemical compound CONC1=CC=CC=C1 NSBIQPJIWUJBBX-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- HOWGUJZVBDQJKV-UHFFFAOYSA-N n-propyl-nonadecane Natural products CCCCCCCCCCCCCCCCCCCCCC HOWGUJZVBDQJKV-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- FJDUDHYHRVPMJZ-UHFFFAOYSA-N nonan-1-amine Chemical compound CCCCCCCCCN FJDUDHYHRVPMJZ-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- WCVVIGQKJZLJDB-UHFFFAOYSA-N o-butylhydroxylamine Chemical compound CCCCON WCVVIGQKJZLJDB-UHFFFAOYSA-N 0.000 description 1
- 229940038384 octadecane Drugs 0.000 description 1
- YDKYIMZMZFEENX-UHFFFAOYSA-N octadecyl hydrogen carbonate Chemical compound CCCCCCCCCCCCCCCCCCOC(O)=O YDKYIMZMZFEENX-UHFFFAOYSA-N 0.000 description 1
- WBFJLQYCLUOFRY-UHFFFAOYSA-N octadecylazanium;n-octadecylcarbamate Chemical compound CCCCCCCCCCCCCCCCCC[NH3+].CCCCCCCCCCCCCCCCCCNC([O-])=O WBFJLQYCLUOFRY-UHFFFAOYSA-N 0.000 description 1
- XKFXSYSPQZRVOY-UHFFFAOYSA-N octadecylazanium;octadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCCC[NH3+].CCCCCCCCCCCCCCCCCCOC([O-])=O XKFXSYSPQZRVOY-UHFFFAOYSA-N 0.000 description 1
- BXXLBMBLLVIOKO-UHFFFAOYSA-N octadecylcarbamic acid Chemical class CCCCCCCCCCCCCCCCCCNC(O)=O BXXLBMBLLVIOKO-UHFFFAOYSA-N 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- QNIVIMYXGGFTAK-UHFFFAOYSA-N octodrine Chemical compound CC(C)CCCC(C)N QNIVIMYXGGFTAK-UHFFFAOYSA-N 0.000 description 1
- 229960001465 octodrine Drugs 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000007649 pad printing Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- TXLIUAKKTUQLOR-UHFFFAOYSA-N pentane-2,3-dione silver Chemical compound C(C)C(=O)C(=O)C.[Ag] TXLIUAKKTUQLOR-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 238000001259 photo etching Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229950008754 pyricarbate Drugs 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
- 229940071536 silver acetate Drugs 0.000 description 1
- 229910001958 silver carbonate Inorganic materials 0.000 description 1
- LKZMBDSASOBTPN-UHFFFAOYSA-L silver carbonate Substances [Ag].[O-]C([O-])=O LKZMBDSASOBTPN-UHFFFAOYSA-L 0.000 description 1
- LFAGQMCIGQNPJG-UHFFFAOYSA-N silver cyanide Chemical compound [Ag+].N#[C-] LFAGQMCIGQNPJG-UHFFFAOYSA-N 0.000 description 1
- 229940098221 silver cyanide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- KKKDGYXNGYJJRX-UHFFFAOYSA-M silver nitrite Chemical compound [Ag+].[O-]N=O KKKDGYXNGYJJRX-UHFFFAOYSA-M 0.000 description 1
- XNGYKPINNDWGGF-UHFFFAOYSA-L silver oxalate Chemical compound [Ag+].[Ag+].[O-]C(=O)C([O-])=O XNGYKPINNDWGGF-UHFFFAOYSA-L 0.000 description 1
- FJOLTQXXWSRAIX-UHFFFAOYSA-K silver phosphate Chemical compound [Ag+].[Ag+].[Ag+].[O-]P([O-])([O-])=O FJOLTQXXWSRAIX-UHFFFAOYSA-K 0.000 description 1
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 description 1
- 229940056910 silver sulfide Drugs 0.000 description 1
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 description 1
- 229910001494 silver tetrafluoroborate Inorganic materials 0.000 description 1
- LMEWRZSPCQHBOB-UHFFFAOYSA-M silver;2-hydroxypropanoate Chemical compound [Ag+].CC(O)C([O-])=O LMEWRZSPCQHBOB-UHFFFAOYSA-M 0.000 description 1
- DOQQTKLDEQSKIE-UHFFFAOYSA-N silver;isocyanate Chemical compound [Ag+].[N-]=C=O DOQQTKLDEQSKIE-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- RBNWAMSGVWEHFP-UHFFFAOYSA-N trans-p-Menthane-1,8-diol Chemical compound CC(C)(O)C1CCC(C)(O)CC1 RBNWAMSGVWEHFP-UHFFFAOYSA-N 0.000 description 1
- NESLVXDUKMNMOG-UHFFFAOYSA-N triethoxy-(propyltetrasulfanyl)silane Chemical compound CCCSSSS[Si](OCC)(OCC)OCC NESLVXDUKMNMOG-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
本发明涉及一种含有银化合物作为主要成分的多功能涂覆液组合物，更具体而言，涉及一种含有具有特定结构的银络合物以及金属或非金属化合物或至少一种其混合物的多功能涂覆液组合物。本发明的多功能涂覆液组合物能够呈现多种颜色，以及简单的银色，并表现出多功能的效果，即，表现出以下性质中的至少一种性质：导电性和/或导热性、抗菌性、抗静电性、阴离子和远红外线辐射性和反射性。
Description
技术领域
以下公开涉及一种基于银化合物的多功能涂覆液组合物，特别是，涉及一种含有具有特定结构的银络合物以及金属化合物、非金属化合物或包含它们中的至少一种的混合物的多功能涂覆液组合物。
背景技术
银(Ag)因其独特的性质，包括高导电性和抗菌活性，已被广泛应用于各种工业领域，包括贵金属饰物或硬币、器皿、电学、电器、照明、复印机、显示电极、电子波屏蔽、抗菌剂等。近来，具有多功能涂覆层的商品受到青睐，所述多功能涂覆层除具有如导电性、抗菌性、光泽、抗静电性以及阴离子和远红外线发射性等银所独有的性质外，还能够实现各种颜色。
一般说来，本领域技术人员已知的涂覆方法包括镀覆、磁控溅射、离子等离子沉积、化学气相沉积、物理气相沉积、浸涂、流化床涂覆、原子层沉积(ALD)、喷涂、旋涂、电极沉积、静电涂覆或凹版涂覆等。当然，这些方法可应用于银涂覆。当基于银前体的还原而使用银涂覆液组合物时，为实现除银的基本性质外作为多功能涂层的各种特性，需要涂布能够对基材赋予功能性的底涂层或者在银涂层上涂布另外的功能涂层。若以上述方式使银涂层多功能化，如传导性、抗菌性、抗静电性、阴离子和远红外线发射或光泽等银所独有的性质会劣化。近来，相关领域已经进行了积极的研究。然而，相关领域中所提出的多功能化方法繁琐且复杂。
发明内容
技术问题
如上所述，根据所述相关领域的银涂覆组合物需要复杂的方法来实现多功能涂层，因而成本效率低或会造成银涂层自身品质劣化。因此，本发明的一个实施方式涉及提供一种涂覆液组合物及其制备方法，所述涂覆液组合物能够实现各种颜色并可通过简单的方法获得，同时提供有多功能，包括导电和/或导热性、抗菌性、抗静电性、阴离子和远红外线发射线性或反射性。
本发明的另一个实施方式涉及提供一种制造多功能涂覆膜的方法，所述方法包括使用多功能涂覆液组合物在各种基材上形成多功能涂覆膜。
技术方案
为解决上述技术问题，本发明人进行了深入研究，并发现当向包含具有特定结构的银络合物的涂覆液中加入不同类型和量的金属化合物或非金属化合物时，除显色性外还可以实现选自导电和/或导热性、抗菌性和反射性中的一种或多种不同功能。本发明基于这一发现。
在一个一般性的方案中，提供了一种基于银络合物的多功能涂覆液组合物。更具体而言，提供了一种含银多功能涂覆液组合物及其制备方法，所述组合物包含具有特定结构的银络合物和金属化合物、非金属化合物或含有它们中的至少一种的混合物。此处所用的术语“多功能”是指涂覆组合物除显色性外还具有选自导电和/或导热性、抗菌性、抗静电性、阴离子和远红外线发射性和反射性的一种或多种功能。
在另一个一般性的方案中，提供了一种制备多功能涂覆膜的方法，所述方法包括使用所述多功能涂覆液在许多种基材的表面上形成涂覆膜，所述涂覆膜能够实现各种颜色，并具有选自导电和/或导热性、抗菌性和反射性中的一种或多种不同功能。
此处所公开的多功能涂覆液可以涂布于氧化铝、二氧化钛涂覆的云母或玻璃片，从而提供具有各种颜色和银所独有的性质的珠光颜料。也可以将所述多功能涂覆液涂覆在丙烯腈-丁二烯-苯乙烯(ABS)或聚碳酸酯(PC)上来提供主要芯料(master chip)，再将它们以适当比例混合并进行如注射或挤出等成型加工。以此方式，可以获得具有各种颜色和抗菌性的塑料产品。此外，当将多功能涂覆液涂覆在铝或铜超细粉上时，可以获得具有优异的导电性和氧化稳定性的导电性材料，并且所述材料的成本效率很高。
在一个具体实施方式中，提供了一种用于生成多功能涂覆膜的多功能涂覆液组合物，所述多功能涂覆膜能够实现各种颜色，并具有选自导电和/或导热性、抗菌性和反射性的一种或多种不同功能。所述多功能涂覆液组合物包含：银络合物；和选自金属化合物、非金属化合物及其混合物的显色剂。
在另一具体实施方式中，提供了一种用于制备具有优异的表面性质的多功能涂覆膜的方法，所述方法包括：
(i)形成含有银络合物的银涂覆液；
(ii)向所述银涂覆液中加入显色剂以提供多功能涂覆液；和
(iii)将所述多功能涂覆液涂布在基材上以形成多功能涂覆膜。
此处所使用的银络合物是指具有Ag[氨基甲酸铵化合物、碳酸铵化合物或碳酸氢铵化合物]络合物结构的银络合物，所述银络合物通过将银化合物与选自氨基甲酸铵化合物、碳酸铵化合物、碳酸氢铵化合物及其混合物中的至少一种物质反应而获得。本申请人提交的韩国专利申请第2006-0011083号中公开了这种银络合物。
通过以下对实施方式的描述，本发明的优点、特征和方案将会变得显而易见。
在一个方案中，提供了一种多功能涂覆液组合物，所述多功能涂覆液组合物包含：通过将由化学式1表示的银化合物与选自由化学式2表示的氨基甲酸铵化合物、由化学式3表示的碳酸铵化合物、由化学式4表示的碳酸氢铵化合物中的化合物或其混合物反应而获得的银络合物；和选自金属化合物、非金属化合物及其混合物的显色剂。
在另一方案中，提供了一种用于制备具有优异的表面性质的多功能涂覆膜的方法，所述方法包括：
(i)形成含有银络合物的银涂覆液，所述银络合物通过将由化学式1表示的银化合物与选自由化学式2表示的氨基甲酸铵化合物、由化学式3表示的碳酸铵化合物、由化学式4表示的碳酸氢铵化合物中的化合物或其混合物反应而获得；
(ii)向所述银涂覆液中加入显色剂以提供多功能涂覆液；和
(iii)将所述多功能涂覆液涂布在基材上以形成多功能涂覆膜。
[化学式1]
AgnX
[化学式2]
[化学式3]
[化学式4]
在以上化学式中，X是选自由氧、硫、卤素、氰基、氰酸根、碳酸根、硝酸根、亚硝酸根、硫酸根、磷酸根、硫氰酸根、氯酸根、高氯酸根、四氟硼酸根、乙酰丙酮基、羧酸根及其衍生物所组成的组的取代基；
n为1至4的整数；并且
R1至R6独立地表示氢、羟基、C1-C30烷氧基、C1-C30烷基、C3-C30环烷基、C6-C20芳基、(C6-C20)芳基(C1-C30)烷基、官能团取代的C1-C30烷基、官能团取代的C6-C20芳基、杂环化合物、聚合物或其衍生物，其中，当R1至R6表示没有取代基或取代有官能团的烷基或芳烷基时，各碳链还可以包含选自N、S和O的杂原子，并且R1和R2或者R4和R5可以独立地通过带有或不带有杂原子的C1-C10亚烷基彼此连接以形成环。
由化学式1表示的银化合物的具体实例包括但不限于：氧化银、硫氰酸酸、硫化银、氯化银、氰化银、氰酸银、碳酸银、硝酸银、亚硝酸银、硫酸银、磷酸银、高氯酸银、四氟硼酸银、乙酰丙酮银、乙酸银、乳酸银、草酸银及其衍生物。
在化学式2至4中，R1至R6的具体实例包括但不限于氢、甲基、乙基、丙基、异丙基、丁基、异丁基、戊基、己基、乙基己基、庚基、辛基、异辛基、壬基、癸基、十二烷基、十六烷基、十八烷基、二十二烷基、环丙基、环戊基、环己基、烯丙基、羟基、甲氧基、羟乙基、甲氧基乙基、2-羟基丙基、甲氧基丙基、氰基乙基、乙氧基、丁氧基、己氧基、甲氧基乙氧基乙基、甲氧基乙氧基乙氧基乙基、六亚甲基亚氨基、吗啉、哌啶、哌嗪、乙二胺、丙二胺、六亚甲基二胺、三亚乙基二胺、吡咯、咪唑、吡啶、羧甲基、三甲氧基甲硅烷基丙基、三乙氧基甲硅烷基丙基、苯基、甲氧基苯基、氰基苯基、苯氧基、甲苯基、苄基、及其衍生物、聚合物如聚烯丙胺或聚乙烯亚胺及其衍生物。
由化学式2表示的氨基甲酸铵化合物的具体实例包括选自由氨基甲酸铵、乙基氨基甲酸乙铵、异丙基氨基甲酸异丙铵、正丁基氨基甲酸正丁铵、异丁基氨基甲酸异丁铵、叔丁基氨基甲酸叔丁铵、2-乙基己基氨基甲酸2-乙基己铵、十八烷基氨基甲酸十八烷基铵、2-甲氧基氨基甲酸2-甲氧基乙铵、2-氰基乙基氨基甲酸2-氰基乙铵、二丁基氨基甲酸二丁铵、双十八烷基氨基甲酸双十八烷基铵、甲基癸基氨基甲酸甲基癸铵、六亚甲基亚氨基氨基甲酸六亚甲基亚氨基铵、吗啉氨基甲酸吗啉鎓、乙基己基氨基甲酸吡啶鎓、异丙基双氨基甲酸三亚乙基二铵、苄基氨基甲酸苄基铵、三乙氧基甲硅烷基丙基氨基甲酸三乙氧基甲硅烷基丙铵及其衍生物组成的组中的至少一种化合物或其混合物。由化学式3表示的碳酸铵化合物的具体实例包括选自由碳酸铵、乙基碳酸乙铵、异丙基碳酸异丙铵、正丁基碳酸正丁铵、异丁基碳酸异丁铵、叔丁基碳酸叔丁铵、2-乙基己基碳酸2-乙基己铵、2-甲氧基乙基碳酸2-甲氧基乙铵、2-氰基乙基碳酸2-氰基乙铵、十八烷基碳酸十八烷基铵、二丁基碳酸二丁铵、双十八烷基碳酸双十八烷基铵、甲基癸基碳酸甲基癸铵、六亚甲基亚氨基碳酸六亚甲基亚氨基铵、吗啉碳酸吗啉铵、苄基碳酸苄基铵、三乙氧基甲硅烷基丙基碳酸三乙氧基甲硅烷基丙铵、异丙基碳酸三亚乙基二铵及其衍生物组成的组中的至少一种化合物或其混合物。由化学式4表示的碳酸氢铵化合物的具体实例包括选自由碳酸氢铵、碳酸氢异丙铵、碳酸氢叔丁铵、碳酸氢2-乙基己铵、碳酸氢2-甲氧基乙铵、碳酸氢2-氰基乙铵、碳酸氢双十八烷基铵、碳酸氢吡啶鎓、碳酸氢三亚乙基二铵及其衍生物组成的组中的至少一种化合物或其混合物。
此处所用的银络合物通过本申请人递交的韩国专利申请第10-2006-0011083号中所公开的方法获得。银络合物可以作为固体从溶液中分离。据认为，获得的固体是包含银离子(Ag+)、阴离子(Xn-)和选自化学式2至4的氨基甲酸盐或碳酸盐化合物的络合物，或通过部分还原其银离子而由该络合物转变来的聚集体，由以下实验式表示：
[实验式]
Ag[A]m
其中，A为由化学式2至4中的任一化学式表示的化合物，并且m为0.7至2.5。
在所述方法中，含有银络合物的步骤(i)的银涂覆液除银络合物外还可包含溶剂。溶剂的具体实例包括水、如甲醇、乙醇、异丙醇或丁醇等醇、如乙二醇等二醇或甘油、如乙酸乙酯、乙酸丁酯或乙酸卡必醇酯等乙酸酯、如乙醚、四氢呋喃或二氧六环等醚、如甲乙酮或丙酮等酮、如己烷或庚烷等烃溶剂、如苯或甲苯等芳香溶剂、如氯仿、二氯甲烷或四氯化碳等卤代溶剂或其混合物。
步骤(ii)通过向含有银络合物的银涂覆液中加入选自金属化合物、非金属化合物及其混合物的显色剂而进行，从而提供多功能涂覆液组合物。
可加入银涂覆液中的金属化合物的具体实例包括含有如Li、Na、K、Rb、Cs、Be、Mg、Ca、Sr、Ba、Ti、V、Mn、Fe、Co、Ni、Cu、Zn、Y、Nb、Mo、Ru、Rh、Pd、Ag、Cd、Hf、Ta、W、Re、Os、Ir、Pt、Au、Hg、Al、Ga、In、Tl、Ge、Sn、Pb、Sb、Bi、As、Se、Eu、Sm、Th、Ac、Ce和Pr等金属的金属前体、金属有机酸盐、金属氧化物和合金氧化物。更具体而言，金属化合物可以包括但不限于草酸锰、乙酸金、草酸钯、2-乙基己酸铜、辛酸钴、辛酸锆、硬脂酸钴、萘二甲酸镍、萘二甲酸钴、2-乙基己酸铜、硬脂酸铁、甲酸镍、环烷酸钙、柠檬酸锌、新癸酸钡、氰化铜、碳酸钴、氯化铂、氯金酸、四丁氧基钛、二甲氧基二氯化锆、异丙醇铝、乙酰烷氧基二异丙醇铝、四氟硼酸锡、氧化钒、氧化铟锡、甲醇钽、醋酸铋、巯基金酸十二烷基酯、或乙酰丙酮铟等。
所述金属化合物可以以球形、线状、片状或其组合的形式提供。它们也可以以各种形式使用，如包括纳米颗粒的颗粒、粉末、薄片、胶体、混合物、浆料、溶胶、溶液或其组合。
可加入到银涂覆液中的非金属化合物的具体实例包括：硅化合物，如3-氨基丙基三乙氧基硅烷、甲基三乙氧基硅烷、正硅酸四乙酯、乙烯基三乙氧基硅烷、乙烯基甲基二甲氧基硅烷、辛基三乙氧基硅烷、苯基γ-氨基丙基三甲氧基硅烷、氨基新己基三甲氧基硅烷等；氟化合物，如2，2-双(4-羟基苯基)六氟丙烷、3，5-双(三氟甲基)苯胺、十二氟-1-庚醇、2，4-二氟苯胺、4-氟苯基酯、二己酰二苯甲酮(dicaprobenzophenone)、2-氟联苯、四氟氢醌等；和有机聚合树脂，如聚丙烯、聚碳酸酯、聚丙烯酸酯、聚甲基丙烯酸甲酯、乙酸纤维素、聚氯乙烯、聚氨酯、聚酯、醇酸树脂、环氧树脂、三聚氰胺树脂、酚醛树脂、苯酚改性醇酸树脂、环氧改性醇酸树脂、乙烯基改性醇酸树脂、硅改性醇酸树脂、丙烯酸三聚氰胺树脂、聚异氰酸酯树脂和环氧酯树脂等。在本发明范围内也可以使用其它非金属化合物。
在银涂覆液中可以加入需要量的显色剂，只要其不会对获得的涂覆液组合物的特性产生不利影响即可。一般而言，基于组合物的总重，显色剂的用量可以为0.01重量％至30重量％，更特别为0.1重量％至10重量％。若显色剂的用量低于0.01重量％，则不能充分显示所需要的颜色。另一方面，若显色剂的用量大于30重量％，则银络合物或其它成分的量相对降低，导致获得的涂覆膜的其它特性劣化。
步骤(ii)获得的多功能涂覆液组合物除包含银络合物和显色剂之外，还可以包含其它添加剂，如溶剂、稳定剂、分散剂、粘合剂树脂、还原剂、表面活性剂、湿润剂、触变剂或流平剂。
可用在涂覆液中的溶剂可选自水、醇、二醇、乙酸酯、醚、酮、脂肪烃、芳香烃或卤代烃溶剂。溶剂的具体实例包括选自水、甲醇、乙醇、异丙醇、1-甲氧基丙醇、丁醇、乙基己醇、萜品醇、乙二醇、甘油、乙酸乙酯、乙酸丁酯、乙酸甲氧基丙酯、乙酸卡必醇酯、乙酸乙基卡必醇酯、甲基溶纤剂、丁基溶纤剂、乙醚、四氢呋喃、二氧己环、甲乙酮、丙酮、二甲基甲酰胺、1-甲基-2-吡咯烷酮、二甲亚砜、己烷、庚烷、十二烷、石蜡油、溶剂油、苯、甲苯、二甲苯、氯仿、二氯甲烷、四氯化碳和乙腈中的至少一种。
可用在涂覆液中的稳定剂选自：带有或不带有羟基的伯胺、仲胺或叔胺化合物；选自氨基甲酸铵化合物、碳酸铵化合物和碳酸氢铵化合物的铵盐化合物；选自膦化合物、亚磷酸酯(盐)化合物和磷酸酯(盐)化合物的磷化合物；选自硫醇或硫化物的硫化合物；或其混合物。可用作稳定剂的胺化合物的具体实例包括甲胺、乙胺、正丙胺、异丙胺、正丁胺、异丁胺、异戊胺、正己胺、2-乙基己胺、正庚胺、正辛胺、异辛胺、壬胺、癸胺、十二烷胺、十六烷胺、十八烷胺、二十二烷胺(docodecylamine)、环丙胺、环戊胺、环己胺、烯丙胺、羟胺、氢氧化铵、甲氧基胺、2-乙醇胺、甲氧基乙基胺、2-羟基丙胺、2-羟基-2-甲基丙胺、甲氧基丙胺、氰基乙胺、乙氧基胺、正丁氧基胺、2-己氧基胺、甲氧基乙氧基乙胺、甲氧基乙氧基乙氧基乙胺、二乙胺、二丙胺、二乙醇胺、六亚甲基亚胺、吗啉(morphiline)、哌啶、哌嗪、乙二胺、丙二胺、六亚甲基二胺、三亚乙基二胺、2，2-(亚乙二氧基)双乙胺、三乙胺、三乙醇胺、吡咯、咪唑、吡啶、氨基乙醛、二甲基缩醛、3-氨基丙基三甲氧基硅烷、3-氨基丙基三乙氧基硅烷、苯胺、茴香胺、氨基苄腈、苄胺及其衍生物和聚合物，如聚烯丙胺或聚乙烯亚胺及其衍生物。
步骤(iii)通过将由步骤(ii)获得的多功能涂覆液涂布在基材上而进行，以形成多功能涂覆膜。
此处所用的基材可以是允许涂覆的任何基材。基材的具体实例包括但不限于：塑料，如聚酰亚胺(PI)、聚对苯二甲酸乙二醇酯(PET)、聚萘二甲酸乙二醇酯(PEN)、聚醚砜(PES)、尼龙、聚四氟乙烯(PTFE)、聚醚醚酮(PEEK)、聚碳酸酯(PC)、多芳基化合物(PAR)等；树脂，如各种丙烯酸树脂、氨基甲酸乙酯树脂、氟树脂、有机硅环氧树脂、乙烯基树脂等；聚合橡胶材料，如丁基橡胶、氯丁橡胶、苯乙烯-丁二烯橡胶(SBR)、乙丙橡胶(EPR)、苯乙烯-异戊二烯-苯乙烯(SIS)橡胶等；各种陶瓷材料，如二氧化硅、氧化铝、二氧化钛、粘土、石、滑石、云母等；各种金属或合金材料，如铝、铜、镍、铁、锌、黄铜等；非金属材料，如碳、碳纳米管(CNT)、硅、硫等；金属盐化合物，如盐、磺酸钡等；各种纸，如合成纸、印相纸(photographic paper)、包装纸、纸板等；和由上述材料获得的各种复合材料。
另外，基材可以以粉末、薄片、珠、球、纤维、膜、片材、碎片、棒、线、须等形式提供，不过不限于这些形式。
本文所公开的多功能涂覆液组合物可以对各种基材赋予均一的涂覆特性，因此可通过银络合物与显色剂的组合，在如上所述的具有各种形式和材料的基材表面上实现优异的显色。同时，根据银组分和显色剂的特定类型，所述多功能涂覆液组合物可形成具有如导电性和/或导热性、抗菌性、抗静电性、阴离子和远红外线发射性或反射性等一种以上性质的多功能涂覆膜。
根据涂覆液的物理性质和基材的特定类型，所述多功能涂覆液可以通过选自旋涂、辊涂、喷涂、浸涂、流涂、刮板涂覆、滴涂(dispensing)、喷墨印刷、胶版印刷、丝网印刷、移印(pad printing)、凹版印刷、柔版印刷、刻版印刷、盖印(imprinting)、静电印刷、光刻、流化涂覆、原子层沉积(ALD)涂覆、化学气相沉积(CVD)、物理气相沉积(PVD)、离子等离子体涂覆、静电涂覆、电沉积涂覆等中的任何一种方法来涂布。
在步骤(iii)中将多功能涂覆液涂布在基材上之后，可以将其干燥、烘烤或干燥并烘烤，以形成涂覆膜。当基材为塑料、树脂或橡胶基材时，可以在涂布后干燥涂覆液，以形成涂覆膜。当基材为由选自各种陶瓷材料、金属材料、非金属材料如碳、碳纳米管(CNT)、硅或硫、金属盐化合物和各种纸中的任一种制成的基材时，可以烘烤或者干燥并烘烤涂覆液，以形成涂覆膜。干燥和烘烤可以根据基材的特定类型在适当的温度范围内进行。涂覆液可以在80℃至200℃的温度干燥，或者在300℃至700℃的温度烘烤。当干燥温度低于80℃时，涂覆液会因干燥速率低而无法得到有效干燥。另一方面，当干燥温度过高时，某些类型的基材可能会劣化。当烘烤温度低于300℃时，涂膜对于基材的粘合不充分，并且不会形成均一的涂覆膜。另一方面，超过700℃的过高的烘烤温度会导致基材的劣化并且成本效益较低。
有利效果
本文所公开的多功能涂覆液组合物能够实现各种颜色和银色，还可以提供如导电性和/或导热性、抗菌性、抗静电性、阴离子和远红外线发射性和反射性等性质中的一种以上性质。
另外，还可以根据加入到多功能涂覆液组合物中的金属或非金属化合物的具体类型和量，来提供不同的颜色和功能，同时避免了需要采用复杂的方法。
具体实施方式
下面描述实施例。以下实施例仅出于说明性目的，并不意在限制本公开的范围。
[实施例1]
在配备有搅拌器的反应器中，将2.1kg(6.94mol)2-乙基己基氨基甲酸2-乙基己铵和0.825kg(5.08mol)异丁基氨基甲酸异丁铵溶解在5.2kg异丙醇中。接下来，向其中加入1kg(4.31mol)氧化银，并使反应在室温进行。观察到，最初作为黑色浆料存在的反应混合物随着反应进行而颜色变浅，之后变得透明，从而产生络合物。反应进行2小时后，获得无色透明溶液。向该溶液中加入0.125kg作为稳定剂的2-羟基-2-甲基丙胺，然后搅拌。之后，通过0.45μm的膜过滤器过滤反应混合物。进行热重量分析(TGA)后，获得银含量为10.05重量％的银涂覆液。
[实施例2]
向100g由实施例1获得的银涂覆液中加入5重量％的量的辛酸锆(Jinyang Chemical，Corp.)，并在室温进行反应12小时，获得稳定的多功能涂覆液。
[实施例3]
以与实施例1相似的方式获得多功能涂覆液，不同之处在于，以20重量％的量向由实施例1获得的银涂覆液中加入环烷酸钙(JinyangChemical，Corp.)。
[实施例4]
以与实施例1相似的方式获得多功能涂覆液，不同之处在于，以30重量％的量向由实施例1获得的银涂覆液中加入3-氨基丙基三乙氧基硅烷(Aldrich)。
[实施例5]
以与实施例1相似的方式获得多功能涂覆液，不同之处在于，以10重量％的量向由实施例1获得的银涂覆液中加入聚氨酯树脂HW-1217(Hosung Chemex)。
[实施例6]
以与实施例1相似的方式获得多功能涂覆液，不同之处在于，以5重量％的量向由实施例1获得的银涂覆液中加入丁醇钛(Aldrich)。
[实施例7]
以与实施例1相似的方式获得多功能涂覆液，不同之处在于，以5重量％的量向由实施例1获得的银涂覆液中加入乙酰烷氧基二异丙醇铝(Ajinomoto fine-techno，AL-M)。
多功能涂覆膜的制备
由实施例1至7获得的多功能涂覆液用于制备下述各种多功能涂覆膜，并对这些涂覆膜进行表征。
[实施例8]
为制备多功能涂覆膜，制备旋涂用玻璃基材，并使用乙醇清洁该玻璃基材以除去其表面上的灰尘，然后在干燥器中于50℃干燥。对玻璃基材干燥至少30分钟后，将玻璃基材放置在旋涂机中，并将20mL由实施例2获得的组合物倾注在玻璃基材上，然后以500rpm的速度旋转，以形成涂覆膜，继而在500℃处理所述涂覆膜5分钟。获得的涂覆膜呈闪亮的黑色，并显示出12.4Ω/□的表面电阻和40％的反射率。
[实施例9]
通过喷涂，使用由实施例3获得的涂覆液在除去了灰尘的玻璃基材上形成涂覆膜。在500℃处理该涂覆膜5分钟。获得的涂覆膜呈闪亮的黄色，并显示出150Ω/□的表面电阻和40％的反射率。
[实施例10]
通过微凹版涂覆，使用由实施例4获得的涂覆液在PET膜上形成涂覆膜。在150℃处理该涂覆膜5分钟。获得的涂覆膜呈淡红色。
[实施例11]
首先，将1kg玻璃薄片(NGF Canada Ltd.，RCF-150)引入流化床反应器中，并将反应器的内部温度升高至110℃。接下来，在使由实施例5获得的涂覆液组合物流化的同时，以所述涂覆液组合物涂覆该玻璃薄片20分钟。然后，在150℃对所获得的涂覆膜进行干燥，产生灰色珠光颜料，继而将该灰色珠光颜料引入烘烤炉中，以在500℃进行为时10分钟的烘烤。在此方式下，获得了闪亮的浅灰色珠光颜料，其表面电阻为300Ω/□并且反射率为50％。
[实施例12]
首先，将1kg铝粉(ECKA 20T，eckagranules)引入流化床反应器中，并将反应器的内部温度升高至110℃。接下来，在使由实施例1获得的涂覆液组合物流化的同时，以所述涂覆液组合物涂覆所述铝粉20分钟。然后，在150℃对所获得的涂覆膜进行干燥，产生银色导电颗粒，其表面电阻为200mΩ/□并且反射率为85％。
[实施例13]
通过浸涂，使用由实施例6获得的涂覆液在玻璃基材上形成涂覆膜。在500℃处理该涂覆膜5分钟。获得的涂覆膜呈闪亮的黑色，并显示出100Ω/□的表面电阻和35％的反射率。
[实施例14]
通过微凹版涂覆，使用由实施例7获得的涂覆液在PET膜上形成涂覆膜。在500℃处理该涂覆膜5分钟。获得的涂覆膜成暗蓝色，并显出2KΩ/□的表面电阻。
工业实用性
本文所公开的多功能涂覆液组合物能够实现各种颜色和银色，还可以提供如导电性和/或导热性、抗菌性、抗静电性、阴离子和远红外线发射性和反射性等性质中的一种以上性质。
另外，还可以根据加入到多功能涂覆液组合物中的金属或非金属化合物的具体类型和量，来提供不同的颜色和功能，同时避免了需要采用复杂的方法。
Claims (18)
1.一种具有优异的表面性质的多功能涂覆膜的制备方法，所述方法包括：
(i)形成含有银络合物的银涂覆液，所述银络合物通过将由化学式1表示的银化合物与由化学式2表示的氨基甲酸铵化合物、由化学式3表示的碳酸铵化合物、由化学式4表示的碳酸氢铵化合物或其混合物反应而获得；
(ii)向所述银涂覆液中加入显色剂以提供多功能涂覆液；和
(iii)将所述多功能涂覆液涂布在基材上以形成多功能涂覆膜：
[化学式1]
AgnX
[化学式2]
[化学式3]
[化学式4]
其中
X是选自由氧、硫、卤素、氰基、氰酸根、碳酸根、硝酸根、亚硝酸根、硫酸根、磷酸根、硫氰酸根、氯酸根、高氯酸根、四氟硼酸根、乙酰丙酮基、羧酸根及其衍生物所组成的组的取代基；
n为1至4的整数；并且
R1、R2、R3、R4、R5和R6独立地为选自由氢、羟基、C1-C30烷氧基、C1-C30烷基、C3-C30环烷基、C6-C20芳基、(C6-C20)芳基(C1-C30)烷基、官能团取代的C1-C30烷基、官能团取代的C6-C20芳基、杂环化合物、聚合物或其衍生物组成的组中的取代基，其中，当R1、R2、R3、R4、R5和R6为没有取代基或取代有官能团的烷基或芳烷基时，碳链能够包含选自N、S和O的杂原子，并且R1和R2或者R4和R5能够独立地通过带有或不带有杂原子的C1-C10亚烷基彼此连接以形成环。
2.如权利要求1所述的多功能涂覆膜的制备方法，其中，所述显色剂选自金属化合物、非金属化合物及其混合物，并且基于所述多功能涂覆液的总重，其含量为0.01重量％至30重量％。
3.如权利要求2所述的制备多功能涂覆膜的方法，其中，所述金属化合物选自含有选自Li、Na、K、Rb、Cs、Be、Mg、Ca、Sr、Ba、Ti、V、Mn、Fe、Co、Ni、Cu、Zn、Y、Nb、Mo、Ru、Rh、Pd、Ag、Cd、Hf、Ta、W、Re、Os、Ir、Pt、Au、Hg、Al、Ga、In、Tl、Ge、Sn、Pb、Sb、Bi、As、Se、Eu、Sm、Th、Ac、Ce和Pr中的至少一种金属的金属前体、金属有机酸盐和金属氧化物。
4.如权利要求3所述的多功能涂覆膜的制备方法，其中，所述金属化合物选自草酸锰、乙酸金、草酸钯、2-乙基己酸铜、辛酸钴、辛酸锆、硬脂酸钴、萘二甲酸镍、萘二甲酸钴、2-乙基己酸铜、硬脂酸铁、甲酸镍、环烷酸钙、柠檬酸锌、新癸酸钡、氰化铜、碳酸钴、氯化铂、氯金酸、四丁氧基钛、二甲氧基二氯化锆、异丙醇铝、乙酰烷氧基二异丙醇铝、四氟硼酸锡、氧化钒、氧化铟锡、甲醇钽、醋酸铋、巯基金酸十二烷基酯、乙酰丙酮铟及其混合物。
5.如权利要求2所述的多功能涂覆膜的制备方法，其中，所述非金属化合物选自硅化合物、氟化合物和有机聚合树脂。
6.如权利要求5所述的多功能涂覆膜的制备方法，其中，所述硅化合物选自3-氨基丙基三乙氧基硅烷、甲基三乙氧基硅烷、正硅酸四乙酯、乙烯基三乙氧基硅烷、乙烯基甲基二甲氧基硅烷、辛基三乙氧基硅烷、苯基γ-氨基丙基三甲氧基硅烷、氨基新己基三甲氧基硅烷及其混合物；所述氟化合物选自2，2-双(4-羟基苯基)六氟丙烷、3，5-双(三氟甲基)苯胺、十二氟-1-庚醇、2，4-二氟苯胺、4-氟苯基酯、二己酰二苯甲酮、2-氟联苯、四氟氢醌及其混合物；并且所述有机聚合树脂选自聚丙烯、聚碳酸酯、聚丙烯酸酯、聚甲基丙烯酸甲酯、乙酸纤维素、聚氯乙烯、聚氨酯、聚酯、醇酸树脂、环氧树脂、三聚氰胺树脂、酚醛树脂、苯酚改性醇酸树脂、环氧改性醇酸树脂、乙烯基改性醇酸树脂、硅改性醇酸树脂、丙烯酸三聚氰胺树脂、聚异氰酸酯树脂和环氧酯树脂。
7.如权利要求2所述的多功能涂覆膜的制备方法，其中，所述显色剂选自辛酸锆、环烷酸钙、四丁氧基钛、3-氨基丙基三乙氧基硅烷、乙酰烷氧基二异丙醇铝和聚氨酯树脂。
8.如权利要求1所述的多功能涂覆膜的制备方法，其中，所述多功能涂覆液还包含选自溶剂、稳定剂、分散剂、粘合剂树脂、还原剂、表面活性剂、湿润剂、触变剂和流平剂中的至少一种。
9.如权利要求8所述的多功能涂覆膜的制备方法，其中，所述溶剂为选自水、醇、二醇、乙酸酯、醚、酮、脂肪烃、芳香烃和卤代烃溶剂中的至少一种。
10.如权利要求1所述的多功能涂覆膜的制备方法，其中，所述基材以粉末、薄片、珠、球、纤维、膜、片材、碎片、棒、线或须的形式提供。
11.如权利要求1所述的多功能涂覆膜的制备方法，所述方法还包括其涂布后的干燥、烘烤或干燥并烘烤。
12.如权利要求11所述的多功能涂覆膜的制备方法，其中，所述干燥在80℃至200℃的温度进行，所述烘烤在300℃至700℃的温度进行。
13.一种多功能涂覆膜，所述多功能涂覆膜通过如权利要求1至12中任一项所述的方法获得。
14.一种多功能涂覆液组合物，所述多功能涂覆液组合物包含：
通过将由化学式1表示的银化合物与由化学式2表示的氨基甲酸铵化合物、由化学式3表示的碳酸铵化合物、由化学式4表示的碳酸氢铵化合物或其混合物反应而获得的银络合物；和
选自金属化合物、非金属化合物及其混合物的显色剂：
[化学式1]
AgnX
[化学式2]
[化学式3]
[化学式4]
其中
X是选自由氧、硫、卤素、氰基、氰酸根、碳酸根、硝酸根、亚硝酸根、硫酸根、磷酸根、硫氰酸根、氯酸根、高氯酸根、四氟硼酸根、乙酰丙酮基、羧酸根及其衍生物所组成的组的取代基；
n为1至4的整数；并且
R1、R2、R3、R4、R5和R6独立地为选自由氢、羟基、C1-C30烷氧基、C1-C30烷基、C3-C30环烷基、C6-C20芳基、(C6-C20)芳基(C1-C30)烷基、官能团取代的C1-C30烷基、官能团取代的C6-C20芳基、杂环化合物、聚合物或其衍生物组成的组中的取代基，其中，当R1、R2、R3、R4、R5和R6为没有取代基或取代有官能团的烷基或芳烷基时，碳链能够包含选自N、S和O的杂原子，并且R1和R2或者R4和R5能够独立地通过带有或不带有杂原子的C1-C10亚烷基彼此连接以形成环。
15.如权利要求14所述的多功能涂覆液组合物，其中，基于所述组合物的总重，所述显色剂的含量为0.01重量％至30重量％。
16.如权利要求14所述的多功能涂覆液组合物，其中，所述金属化合物选自含有选自Li、Na、K、Rb、Cs、Be、Mg、Ca、Sr、Ba、Ti、V、Mn、Fe、Co、Ni、Cu、Zn、Y、Nb、Mo、Ru、Rh、Pd、Ag、Cd、Hf、Ta、W、Re、Os、Ir、Pt、Au、Hg、Al、Ga、In、Tl、Ge、Sn、Pb、Sb、Bi、As、Se、Eu、Sm、Th、Ac、Ce和Pr中的至少一种金属的金属前体、金属有机酸盐和金属氧化物。
17.如权利要求14所述的多功能涂覆液组合物，其中，所述非金属化合物选自硅化合物、氟化合物和有机聚合树脂。
18.如权利要求15所述的多功能涂覆液组合物，其中，所述显色剂选自辛酸锆、环烷酸钙、四丁氧基钛、3-氨基丙基三乙氧基硅烷、乙酰烷氧基二异丙醇铝和聚氨酯树脂。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310651563.2A CN103665995B (zh) | 2008-03-18 | 2009-03-17 | 多功能涂覆液组合物 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020080024761A KR101675493B1 (ko) | 2008-03-18 | 2008-03-18 | 복합 기능 코팅액 조성물 |
| KR10-2008-0024761 | 2008-03-18 | ||
| PCT/KR2009/001333 WO2009116782A2 (ko) | 2008-03-18 | 2009-03-17 | 복합 기능 코팅액 조성물 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310651563.2A Division CN103665995B (zh) | 2008-03-18 | 2009-03-17 | 多功能涂覆液组合物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101978006A true CN101978006A (zh) | 2011-02-16 |
| CN101978006B CN101978006B (zh) | 2014-06-04 |
Family
ID=41091385
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200980109363.6A Active CN101978006B (zh) | 2008-03-18 | 2009-03-17 | 多功能涂覆液组合物 |
| CN201310651563.2A Active CN103665995B (zh) | 2008-03-18 | 2009-03-17 | 多功能涂覆液组合物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310651563.2A Active CN103665995B (zh) | 2008-03-18 | 2009-03-17 | 多功能涂覆液组合物 |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR101675493B1 (zh) |
| CN (2) | CN101978006B (zh) |
| WO (1) | WO2009116782A2 (zh) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105297232A (zh) * | 2014-07-22 | 2016-02-03 | 句容市润龙纺织品有限公司 | 一种远红外发热保暖纤维的制备方法 |
| CN106835687A (zh) * | 2017-02-07 | 2017-06-13 | 张耀忠 | 一种制备镀铝聚碳酸酯纤维导电材料的方法 |
| CN107459893A (zh) * | 2017-08-03 | 2017-12-12 | 合肥隆延科技有限公司 | 抗菌水性木器涂料 |
| CN107474680A (zh) * | 2017-08-03 | 2017-12-15 | 合肥隆延科技有限公司 | 环保型抗菌水性木器涂料 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101011301B1 (ko) * | 2010-08-23 | 2011-01-28 | 이찬봉 | 골판지원지 제조용 조성물과 이를 이용한 골판지원지 및 골판지합판의 제조방법 |
| KR101302571B1 (ko) * | 2011-07-04 | 2013-09-02 | 이상철 | 친환경 다기능 천연페인트 및 그 제조방법 |
| US20130022658A1 (en) * | 2011-07-23 | 2013-01-24 | Synos Technology, Inc. | Depositing material with antimicrobial properties on permeable substrate using atomic layer deposition |
| CN102795893B (zh) * | 2012-09-10 | 2013-12-11 | 山东电盾科技有限公司 | 防静电抗菌陶瓷釉 |
| KR101628441B1 (ko) * | 2013-11-26 | 2016-06-08 | 황문구 | 유무기 복합체 및 그 제조방법 |
| KR101919978B1 (ko) * | 2014-07-28 | 2018-11-20 | (주)잉크테크 | 카바메이트 전구체를 이용한 세라믹 잉크 또는 세라믹 피그먼트의 제조방법 및 이에 의해 제조되는 세라믹 잉크 또는 세라믹 피그먼트 |
| CN105001753A (zh) * | 2015-07-08 | 2015-10-28 | 当涂县科辉商贸有限公司 | 一种高冲击韧性的超级绝热保温涂料及其制备方法 |
| KR20170015813A (ko) * | 2015-07-31 | 2017-02-09 | 주식회사 잉크테크 | 금속 카바메이트 전구체를 이용한 세라믹 잉크 또는 세라믹 피그먼트의 제조방법과 이에 의해 제조되는 세라믹 잉크 또는 세라믹 피그먼트 |
| KR101654715B1 (ko) * | 2015-10-29 | 2016-09-07 | 라이프코어인스트루먼트 주식회사 | 고효율 용존 수소수의 제조 장치 및 방법 |
| KR20180054227A (ko) * | 2016-11-15 | 2018-05-24 | 주식회사 케이.피 | 내파티클성을 갖는 무광 플라스틱 시트 |
| CN109135256A (zh) * | 2018-08-01 | 2019-01-04 | 广东和润新材料股份有限公司 | 散热组合物、散热贴膜制备方法及散热屏蔽罩制备方法 |
| KR102129172B1 (ko) * | 2018-08-17 | 2020-07-06 | 주식회사 에스아이피 | 정전기 제거용 도전성 잉크 조성물 |
| KR102310784B1 (ko) * | 2021-04-26 | 2021-10-07 | 유지식 | 코일 포장용 결속 밴드의 코팅장치 및 방법 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53134759A (en) * | 1977-04-28 | 1978-11-24 | Fujikura Kasei Kk | Production of copmosite metal powder |
| US4652465A (en) * | 1984-05-14 | 1987-03-24 | Nissan Chemical Industries Ltd. | Process for the production of a silver coated copper powder and conductive coating composition |
| US6387542B1 (en) * | 2000-07-06 | 2002-05-14 | Honeywell International Inc. | Electroless silver plating |
| KR100727466B1 (ko) * | 2005-02-07 | 2007-06-13 | 주식회사 잉크테크 | 유기 은 착체 화합물, 이의 제조방법 및 이를 이용한박막형성방법 |
| KR100701851B1 (ko) * | 2006-03-14 | 2007-03-30 | 주식회사 잉크테크 | 유기 은 착체 화합물을 포함하는 항균성 조성물, 이를이용한 항균처리방법 및 항균성형품 |
| KR100727483B1 (ko) * | 2006-04-29 | 2007-06-13 | 주식회사 잉크테크 | 유기 은 착체 화합물을 포함하는 반사막 코팅액 조성물 및이를 이용한 반사막 제조방법 |
| KR100832002B1 (ko) * | 2006-08-07 | 2008-05-23 | 주식회사 잉크테크 | 저저항 금속 패턴 형성방법 |
| WO2008018718A1 (en) * | 2006-08-07 | 2008-02-14 | Inktec Co., Ltd. | Process for preparation of silver nanoparticles, and the compositions of silver ink containing the same |
| WO2008018719A1 (en) * | 2006-08-07 | 2008-02-14 | Inktec Co., Ltd. | Manufacturing methods for metal clad laminates |
-
2008
- 2008-03-18 KR KR1020080024761A patent/KR101675493B1/ko active IP Right Grant
-
2009
- 2009-03-17 CN CN200980109363.6A patent/CN101978006B/zh active Active
- 2009-03-17 WO PCT/KR2009/001333 patent/WO2009116782A2/ko active Application Filing
- 2009-03-17 CN CN201310651563.2A patent/CN103665995B/zh active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105297232A (zh) * | 2014-07-22 | 2016-02-03 | 句容市润龙纺织品有限公司 | 一种远红外发热保暖纤维的制备方法 |
| CN106835687A (zh) * | 2017-02-07 | 2017-06-13 | 张耀忠 | 一种制备镀铝聚碳酸酯纤维导电材料的方法 |
| CN107459893A (zh) * | 2017-08-03 | 2017-12-12 | 合肥隆延科技有限公司 | 抗菌水性木器涂料 |
| CN107474680A (zh) * | 2017-08-03 | 2017-12-15 | 合肥隆延科技有限公司 | 环保型抗菌水性木器涂料 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103665995A (zh) | 2014-03-26 |
| CN103665995B (zh) | 2016-05-04 |
| KR20090099646A (ko) | 2009-09-23 |
| KR101675493B1 (ko) | 2016-11-14 |
| WO2009116782A2 (ko) | 2009-09-24 |
| CN101978006B (zh) | 2014-06-04 |
| WO2009116782A3 (ko) | 2009-12-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101978006B (zh) | 多功能涂覆液组合物 | |
| CN103380466B (zh) | 制造透明导电层的方法和由该方法制造的透明导电层 | |
| US9556065B2 (en) | Transparent conductive layer and preparation method thereof | |
| US9290844B2 (en) | Method for preparing metallic thin film | |
| CN101511952B (zh) | 银纳米颗粒的制备方法和含有银纳米颗粒的银墨组合物 | |
| CN103476880B (zh) | 银墨水组合物 | |
| US9873662B2 (en) | Metal precursor and metal precursor ink using the same | |
| CN102202820B (zh) | 金属薄片的制造方法 | |
| CN104822767B (zh) | 金属粒子分散体及使用该金属粒子分散体的物品，烧结膜及烧结膜的制造方法 | |
| US9683123B2 (en) | Silver ink | |
| CN107250292A (zh) | 银粒子涂料组合物 | |
| CN109071924A (zh) | 高级质感的复合树脂组合物及涂覆有所述复合树脂组合物的镀锌钢板 | |
| JP5560458B2 (ja) | 金属ナノ粒子の合成方法 | |
| KR101433682B1 (ko) | 은 잉크 | |
| JP6127943B2 (ja) | 水性銀コロイド液及びその製造方法、並びに水性銀コロイド液を用いた塗料 | |
| JP6384207B2 (ja) | 銀含有組成物及び銀要素形成基材 | |
| JP5293204B2 (ja) | 金属ナノ粒子の合成方法 | |
| JP5293202B2 (ja) | 金属ナノ粒子の合成方法 | |
| JP5293201B2 (ja) | 金属ナノ粒子の合成方法 | |
| WO2024006882A2 (en) | Conductive ink compositions comprising gold complexes | |
| JPH01298008A (ja) | 金属硫化物の製造方法 | |
| JP5293203B2 (ja) | 金属ナノ粒子の合成方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |