CN101888901B - 用于制备直链α-烯烃的催化剂组合物和方法 - Google Patents

用于制备直链α-烯烃的催化剂组合物和方法 Download PDF

Info

Publication number
CN101888901B
CN101888901B CN200880119552.7A CN200880119552A CN101888901B CN 101888901 B CN101888901 B CN 101888901B CN 200880119552 A CN200880119552 A CN 200880119552A CN 101888901 B CN101888901 B CN 101888901B
Authority
CN
China
Prior art keywords
catalyst composition
compound
molar ratio
organoaluminum compound
cyclic amide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN200880119552.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN101888901A (zh
Inventor
V·阿里耶夫
F·莫萨
M·阿尔哈茨米
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linde GmbH
Saudi Basic Industries Corp
Original Assignee
Linde GmbH
Saudi Basic Industries Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde GmbH, Saudi Basic Industries Corp filed Critical Linde GmbH
Publication of CN101888901A publication Critical patent/CN101888901A/zh
Application granted granted Critical
Publication of CN101888901B publication Critical patent/CN101888901B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0252—Nitrogen containing compounds with a metal-nitrogen link, e.g. metal amides, metal guanidides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/135—Halogens; Compounds thereof with titanium, zirconium, hafnium, germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN200880119552.7A 2007-12-06 2008-11-11 用于制备直链α-烯烃的催化剂组合物和方法 Expired - Fee Related CN101888901B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07023618 2007-12-06
EP07023618.7 2007-12-06
PCT/EP2008/009495 WO2009071164A1 (en) 2007-12-06 2008-11-11 Catalyst composition and process for preparing linear alpha-olefins

Publications (2)

Publication Number Publication Date
CN101888901A CN101888901A (zh) 2010-11-17
CN101888901B true CN101888901B (zh) 2014-07-02

Family

ID=40336741

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200880119552.7A Expired - Fee Related CN101888901B (zh) 2007-12-06 2008-11-11 用于制备直链α-烯烃的催化剂组合物和方法

Country Status (16)

Country Link
US (1) US9050587B2 (enExample)
EP (1) EP2070593B1 (enExample)
JP (1) JP5302329B2 (enExample)
KR (1) KR101495385B1 (enExample)
CN (1) CN101888901B (enExample)
AT (1) ATE476254T1 (enExample)
BR (1) BRPI0819972A2 (enExample)
CA (1) CA2707120C (enExample)
DE (1) DE602007008268D1 (enExample)
ES (1) ES2349441T3 (enExample)
MX (1) MX2010006217A (enExample)
MY (1) MY159611A (enExample)
RU (1) RU2456076C2 (enExample)
TW (1) TWI434733B (enExample)
WO (1) WO2009071164A1 (enExample)
ZA (1) ZA201003058B (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014139861A1 (en) 2013-03-11 2014-09-18 Universität Bayreuth Complexes for the catalytic oligomerization of olefins
CN105980053B (zh) * 2014-02-06 2019-08-02 沙特基础工业全球技术有限公司 改性有机铝助催化剂用于改善性能
CN106536044A (zh) 2014-07-18 2017-03-22 沙特基础工业全球技术有限公司 催化剂组合物和制备线性α烯烃的方法
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
IN201921051272A (enExample) * 2019-12-11 2022-01-06
US11667590B2 (en) 2021-05-26 2023-06-06 Chevron Phillips Chemical Company, Lp Ethylene oligomerization processes
EP4183486A1 (en) 2021-11-23 2023-05-24 Indian Oil Corporation Limited Process and catalyst composition for producing linear alpha olefins in high yield by ethylene oligomerization

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4783573A (en) * 1986-04-17 1988-11-08 Idemitsu Petrochemical Company Limited Process for preparing linear α-olefins
US20070161503A1 (en) * 2004-03-16 2007-07-12 Briggs John R Aluminum phosphate-supported group 6 metal amide catalysts for oligomerization of ethylene
WO2007090412A2 (en) * 2006-02-08 2007-08-16 Saudi Basic Industries Corporation A catalyst composition and a process for the oligomerization of ethylene

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3100764A (en) * 1960-08-04 1963-08-13 Sun Oil Co Control of pentane-soluble polymers in the polymerization of propylene
US3107764A (en) * 1961-08-09 1963-10-22 Little Inc A One-way clutch
NL269415A (enExample) * 1960-09-23 1964-06-25
NL124343C (enExample) * 1964-06-05
DE1720756A1 (de) * 1967-12-02 1971-07-15 Bunawerke Huels Gmbh Verfahren zur Herstellung von unvernetzten Terpolymerisaten
US3644563A (en) 1969-11-05 1972-02-22 Shell Oil Co Ethylene oligomerization
US3872072A (en) * 1973-12-13 1975-03-18 Firestone Tire & Rubber Co New hydrogenation catalyst for elastomers, and the process of hydrogenation
SU1042701A1 (ru) 1978-07-19 1983-09-23 Отделение ордена Ленина института химической физики АН СССР Катализатор дл олигомеризации этилена в высшие альфа-олефины
US4224182A (en) * 1979-03-07 1980-09-23 Exxon Research & Engineering Co. Novel hindered alkyl aluminum amide cocatalysts
FR2693455B1 (fr) 1992-07-09 1994-09-30 Inst Francais Du Petrole Procédé de fabrication d'oléfines alpha légères par oligomérisation de l'éthylène.
DE4338414C1 (de) 1993-11-10 1995-03-16 Linde Ag Verfahren zur Herstellung linearer Olefine
JP3388975B2 (ja) * 1995-03-02 2003-03-24 三菱化学株式会社 α−オレフイン低重合体の製造方法
JP3911751B2 (ja) * 1996-02-02 2007-05-09 三菱化学株式会社 α−オレフィン低重合体の製造方法
JPH10109946A (ja) * 1996-08-12 1998-04-28 Mitsubishi Chem Corp α−オレフィン低重合体の製造方法
FR2759922B1 (fr) * 1997-02-25 1999-05-07 Inst Francais Du Petrole Composition catalytique amelioree pour la conversion de l'ethylene en olefines alpha legeres
US6455648B1 (en) * 1999-12-29 2002-09-24 Chevron Phillips Chemical Company Lp Olefin production
JP5022546B2 (ja) * 2001-08-28 2012-09-12 出光興産株式会社 α−オレフィン低重合体の製造方法
ITMI20012630A1 (it) 2001-12-13 2003-06-13 Enichem Spa Complessi con leganti solfonici utilizzabili nella oligomerizzazione selettiva dell'etilene
EP1548035A4 (en) * 2002-09-11 2006-08-09 Japan Polypropylene Corp CATALYST FOR THE POLYMERIZATION OF AN α-OLEFIN AND METHOD FOR THE PREPARATION OF α-OLEFIN POLYMER BY USING THE SAME
US20060167289A1 (en) * 2003-12-05 2006-07-27 Zymes, Llc Practical, cost-effective synthesis of ubiquinones
CN1993384B (zh) * 2004-07-28 2010-11-03 三井化学株式会社 烯烃聚合用催化剂和使用该催化剂的聚合方法
ES2352741T3 (es) * 2005-08-31 2011-02-22 Saudi Basic Industries Corporation Proceso para la preparación de alfa-olefinas lineales y catalizador utilizado en el mismo.

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4783573A (en) * 1986-04-17 1988-11-08 Idemitsu Petrochemical Company Limited Process for preparing linear α-olefins
US20070161503A1 (en) * 2004-03-16 2007-07-12 Briggs John R Aluminum phosphate-supported group 6 metal amide catalysts for oligomerization of ethylene
WO2007090412A2 (en) * 2006-02-08 2007-08-16 Saudi Basic Industries Corporation A catalyst composition and a process for the oligomerization of ethylene

Also Published As

Publication number Publication date
MX2010006217A (es) 2010-06-23
EP2070593B1 (en) 2010-08-04
TWI434733B (zh) 2014-04-21
US9050587B2 (en) 2015-06-09
EP2070593A1 (en) 2009-06-17
RU2456076C2 (ru) 2012-07-20
EP2070593A8 (en) 2009-12-02
JP5302329B2 (ja) 2013-10-02
TW200930456A (en) 2009-07-16
KR101495385B1 (ko) 2015-02-24
CN101888901A (zh) 2010-11-17
MY159611A (en) 2017-01-13
RU2010127740A (ru) 2012-01-20
ZA201003058B (en) 2011-07-27
US20110054130A1 (en) 2011-03-03
ATE476254T1 (de) 2010-08-15
CA2707120A1 (en) 2009-06-11
CA2707120C (en) 2016-03-08
DE602007008268D1 (de) 2010-09-16
BRPI0819972A2 (pt) 2015-06-16
KR20100090254A (ko) 2010-08-13
ES2349441T3 (es) 2011-01-03
JP2011505244A (ja) 2011-02-24
WO2009071164A1 (en) 2009-06-11

Similar Documents

Publication Publication Date Title
CN101888902B (zh) 乙烯低聚反应的催化剂组合物、低聚反应方法及所述催化剂组合物的制备方法
US8624042B2 (en) Process for dimerization of ethylene to but-1-ene using a composition comprising a titanium-based complex and an alkoxy ligand functionalized by a heteroatom
US9260358B2 (en) Process for oligomerization of olefins that uses a catalytic composition that comprises an organometallic complex that contains a phenoxy ligand that is functionalized by a heteroatom
TWI434733B (zh) 催化劑組合物及其用於製備直鏈型α-烯烴之方法
US9309167B2 (en) Process for oligomerization of olefins that uses a catalytic composition that comprises an organometallic complex that contains an alkoxy ligand that is functionalized by a heteroatom
US10421064B2 (en) Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene
CA2500069A1 (en) Selective isomerization and linear dimerization of alpha-olefins using cobalt catalysts
EP3834932B1 (en) Process for preparation of ethylene oligomerization catalyst and oligomerization thereof
CN112374956B (zh) 1-丁烯和1-己烯制备方法
JP2538811B2 (ja) 線状α―オレフィンの製造方法
CN101569865A (zh) 一种乙烯齐聚催化体系
CN101252990B (zh) 直链α-烯烃的制备方法和其中使用的催化剂
JP3289372B2 (ja) α−オレフィンの低重合方法
TWI544962B (zh) 用於寡聚乙烯之觸媒組成物
JPH07247226A (ja) α−オレフィンの製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140702

Termination date: 20171111

CF01 Termination of patent right due to non-payment of annual fee