CN101879466B - 一种强碱性阴离子交换纤维材料及其合成方法 - Google Patents
一种强碱性阴离子交换纤维材料及其合成方法 Download PDFInfo
- Publication number
- CN101879466B CN101879466B CN2010102161071A CN201010216107A CN101879466B CN 101879466 B CN101879466 B CN 101879466B CN 2010102161071 A CN2010102161071 A CN 2010102161071A CN 201010216107 A CN201010216107 A CN 201010216107A CN 101879466 B CN101879466 B CN 101879466B
- Authority
- CN
- China
- Prior art keywords
- fiber
- fiber material
- strong caustic
- anion exchanging
- polyamines
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 150000001450 anions Chemical class 0.000 title claims abstract description 41
- 239000002657 fibrous material Substances 0.000 title claims abstract description 33
- 239000003518 caustics Substances 0.000 title claims abstract description 29
- 238000010189 synthetic method Methods 0.000 title claims abstract description 13
- 239000000835 fiber Substances 0.000 claims abstract description 59
- 238000006243 chemical reaction Methods 0.000 claims abstract description 31
- 229920002972 Acrylic fiber Polymers 0.000 claims abstract description 17
- 125000001453 quaternary ammonium group Chemical group 0.000 claims abstract description 11
- 229920000768 polyamine Polymers 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 12
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 claims description 12
- 125000003368 amide group Chemical group 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 8
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 7
- 229960001124 trientine Drugs 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 5
- 239000012046 mixed solvent Substances 0.000 claims description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 2
- QVYARBLCAHCSFJ-UHFFFAOYSA-N butane-1,1-diamine Chemical compound CCCC(N)N QVYARBLCAHCSFJ-UHFFFAOYSA-N 0.000 claims description 2
- GGHDAUPFEBTORZ-UHFFFAOYSA-N propane-1,1-diamine Chemical compound CCC(N)N GGHDAUPFEBTORZ-UHFFFAOYSA-N 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 9
- -1 poly-amino compound Chemical class 0.000 abstract description 7
- 238000001179 sorption measurement Methods 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 5
- 239000004744 fabric Substances 0.000 abstract description 4
- 239000003344 environmental pollutant Substances 0.000 abstract description 2
- 231100000719 pollutant Toxicity 0.000 abstract description 2
- 238000004065 wastewater treatment Methods 0.000 abstract description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 2
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 abstract 1
- 239000005703 Trimethylamine hydrochloride Substances 0.000 abstract 1
- 238000010828 elution Methods 0.000 abstract 1
- SZYJELPVAFJOGJ-UHFFFAOYSA-N trimethylamine hydrochloride Chemical compound Cl.CN(C)C SZYJELPVAFJOGJ-UHFFFAOYSA-N 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 8
- 238000007265 chloromethylation reaction Methods 0.000 description 6
- HRQGCQVOJVTVLU-UHFFFAOYSA-N bis(chloromethyl) ether Chemical compound ClCOCCl HRQGCQVOJVTVLU-UHFFFAOYSA-N 0.000 description 5
- 230000037396 body weight Effects 0.000 description 5
- 235000019786 weight gain Nutrition 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000005576 amination reaction Methods 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920000075 poly(4-vinylpyridine) Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- ATWLRNODAYAMQS-UHFFFAOYSA-N 1,1-dibromopropane Chemical compound CCC(Br)Br ATWLRNODAYAMQS-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005274 electrospray deposition Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010102161071A CN101879466B (zh) | 2010-07-02 | 2010-07-02 | 一种强碱性阴离子交换纤维材料及其合成方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010102161071A CN101879466B (zh) | 2010-07-02 | 2010-07-02 | 一种强碱性阴离子交换纤维材料及其合成方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101879466A CN101879466A (zh) | 2010-11-10 |
CN101879466B true CN101879466B (zh) | 2012-11-21 |
Family
ID=43051677
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2010102161071A Active CN101879466B (zh) | 2010-07-02 | 2010-07-02 | 一种强碱性阴离子交换纤维材料及其合成方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101879466B (zh) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103502527B (zh) * | 2011-04-27 | 2015-11-25 | 株式会社钟化 | 离子交换纤维及其制造方法、水中的化学物质的除去·吸附方法以及水中的化学物质的除去·吸附装置 |
CN102351335A (zh) * | 2011-07-05 | 2012-02-15 | 河南省科学院化学研究所有限公司 | 采用有机功能纤维处理电镀废水的方法 |
CN102580790A (zh) * | 2012-02-23 | 2012-07-18 | 南开大学 | 强碱性阴离子交换纤维和制备方法及应用 |
CN102720057B (zh) * | 2012-07-03 | 2014-04-30 | 河南省科学院化学研究所有限公司 | 含有季铵基的纤维材料及其合成方法 |
CN103112909A (zh) * | 2013-03-13 | 2013-05-22 | 天津市朗敦环保科技有限公司 | 一种纤维球的超亲水改性制备方法 |
CN104607159A (zh) * | 2015-01-19 | 2015-05-13 | 苏州大学 | 一种新型螯合纤维及其制备方法和用途 |
CN105369608B (zh) * | 2015-12-28 | 2018-01-02 | 河南省科学院化学研究所有限公司 | 负载铜(ii)离子的功能纤维及其合成方法 |
CN105817210A (zh) * | 2016-05-24 | 2016-08-03 | 马鞍山中创环保科技有限公司 | 一种弱碱性离子交换纤维的制备方法 |
CN105950160A (zh) * | 2016-05-25 | 2016-09-21 | 马鞍山中创环保科技有限公司 | 一种铬污染土壤的修复方法 |
CN107083264A (zh) * | 2017-07-04 | 2017-08-22 | 合肥择浚电气设备有限公司 | 一种用于工业沼气的提纯工艺 |
WO2019171311A1 (en) * | 2018-03-07 | 2019-09-12 | King's Flair Development Ltd. | Functional fibrous membrane, method for manufacturing the same, filter comprising the same |
CN109137506A (zh) * | 2018-08-02 | 2019-01-04 | 浙江菲波新材料科技有限公司 | 新型聚丙烯腈纤维材料的制备方法 |
CN112593403B (zh) * | 2020-11-28 | 2022-06-03 | 郑州大学 | 一种聚丙烯腈基强碱离子交换纤维的制备方法 |
CN113417070A (zh) * | 2021-06-21 | 2021-09-21 | 刘景峰 | 一种抑菌水刺布及其制备方法 |
CN114042437B (zh) * | 2021-11-12 | 2023-11-10 | 河南省科学院化学研究所有限公司 | 一种胺基弱碱性阴离子交换纤维制备工艺 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3661889D1 (en) * | 1985-03-12 | 1989-03-02 | Courtaulds Plc | Cationic fibres suitable for ion-exchange materials and their production |
US5414020A (en) * | 1990-06-30 | 1995-05-09 | Bayer Aktiengesellschaft | Process for the preparation of anion exchange resins of the poly(meth)acrylamide type |
CN1597118A (zh) * | 2004-07-28 | 2005-03-23 | 南京工业大学 | 一种季铵型阴离子交换剂及其制备方法 |
CN101333265A (zh) * | 2008-07-24 | 2008-12-31 | 江苏工业学院 | 一种带有长间隔臂的强碱阴离子交换树脂的制备方法 |
CN101342485A (zh) * | 2008-07-03 | 2009-01-14 | 山东大学 | 利用高纤维素含量植物制备季胺盐阳离子型吸附剂的方法 |
-
2010
- 2010-07-02 CN CN2010102161071A patent/CN101879466B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3661889D1 (en) * | 1985-03-12 | 1989-03-02 | Courtaulds Plc | Cationic fibres suitable for ion-exchange materials and their production |
US5414020A (en) * | 1990-06-30 | 1995-05-09 | Bayer Aktiengesellschaft | Process for the preparation of anion exchange resins of the poly(meth)acrylamide type |
CN1597118A (zh) * | 2004-07-28 | 2005-03-23 | 南京工业大学 | 一种季铵型阴离子交换剂及其制备方法 |
CN101342485A (zh) * | 2008-07-03 | 2009-01-14 | 山东大学 | 利用高纤维素含量植物制备季胺盐阳离子型吸附剂的方法 |
CN101333265A (zh) * | 2008-07-24 | 2008-12-31 | 江苏工业学院 | 一种带有长间隔臂的强碱阴离子交换树脂的制备方法 |
Non-Patent Citations (1)
Title |
---|
黄伟庆.弱碱性多胺基纤维的制备及结构性能研究.《高科技纤维与应用》.2010,第35卷(第3期), * |
Also Published As
Publication number | Publication date |
---|---|
CN101879466A (zh) | 2010-11-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101879466B (zh) | 一种强碱性阴离子交换纤维材料及其合成方法 | |
CN106215701B (zh) | 一种交联中空纤维阴离子交换膜及其制备方法 | |
TWI556865B (zh) | Ion exchange fiber and its manufacturing method, removal of chemical substances in water, adsorption method and removal of chemical substances in water, adsorption device | |
CN102720057B (zh) | 含有季铵基的纤维材料及其合成方法 | |
CN104311857A (zh) | 一种双季铵侧长链型阴离子交换膜的制备方法 | |
CN103372381A (zh) | 一种阴离子交换膜及其制备方法和燃料电池 | |
CN102051811B (zh) | 聚苯硫醚基强碱离子交换纤维的制备方法 | |
CN102179186B (zh) | 一种基于单体原位聚合的均相阴离子交换膜及其制备方法 | |
CN110508163A (zh) | 一种交联聚乙烯亚胺的mof膜及其制备方法 | |
CN112593403B (zh) | 一种聚丙烯腈基强碱离子交换纤维的制备方法 | |
CN102489268B (zh) | 一种胺修饰的纤维状应急吸附材料及其制备方法 | |
CN105195110A (zh) | 一种胺修饰的纤维膜状吸附材料及其制备方法 | |
CN105960280A (zh) | 无纺布状金属吸附材料及其制造方法 | |
CN104923176A (zh) | 一种树枝状高密度固态胺纤维材料及其制备方法 | |
CN102382293B (zh) | 一种聚合物阴离子交换膜及其制备方法 | |
CN106111086B (zh) | 一种吸附Pd2+金属离子的离子型高分子吸附剂及其制备方法 | |
CN106268381B (zh) | 一种耐碱解阴离子交换膜材料及其制备方法和应用 | |
CN104437120B (zh) | 一种基于碳纳米管有序排列的聚氯乙烯超滤膜及其制备方法与应用 | |
Guo et al. | Surface engineering of γ-Al2O3 nanosheets with highly dispersed poly (ionic liquids) for selective CO2 adsorption | |
CN102941070B (zh) | 一种聚乙烯-甲基丙烯酸-多乙烯多胺纤维及其制备方法 | |
CN109400720A (zh) | 一种两性纤维素吸附剂的制备方法及应用 | |
CN106492591A (zh) | 新型浓缩转轮的开发及其在VOCs治理中的应用 | |
CN108404885A (zh) | 一种纤维素季铵盐吸附剂及其制备方法与应用 | |
CN107903416A (zh) | 含二氮杂萘酮结构聚芳醚酮两性离子交换膜及其制备方法 | |
CN108461792A (zh) | 一种复合型碱性聚合物电解质膜及其制备方法和应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20191209 Address after: No.55 Fengchan Road, Jinshui District, Zhengzhou City, Henan Province 450002 Patentee after: Henan Zhongbai environmental science and Technology Research Institute Co.,Ltd. Address before: 450002 Henan city of Zhengzhou Province Red Road No. 56 Patentee before: HENAN ACADEMY OF SCIENCES CHEMICAL RESEARCH INSTITUTE Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20200917 Address after: No.55 Fengchan Road, Jinshui District, Zhengzhou City, Henan Province 450002 Patentee after: Henan Zhongbai environmental science and Technology Research Institute Co.,Ltd. Patentee after: Zhongbai (Qinyang) environmental protection equipment manufacturing Co.,Ltd. Address before: No.55 Fengchan Road, Jinshui District, Zhengzhou City, Henan Province 450002 Patentee before: Henan Zhongbai environmental science and Technology Research Institute Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
CP03 | Change of name, title or address |
Address after: 450000, 16th floor, Building B, No. 55 Fengchan Road, Jinshui District, Zhengzhou City, Henan Province, China Patentee after: Henan Zhongbai Environmental Technology Co.,Ltd. Country or region after: China Patentee after: Zhongbai (Qinyang) environmental protection equipment manufacturing Co.,Ltd. Address before: No. 55 Fengchan Road, Jinshui District, Zhengzhou City, Henan Province, 450002 Patentee before: Henan Zhongbai environmental science and Technology Research Institute Co.,Ltd. Country or region before: China Patentee before: Zhongbai (Qinyang) environmental protection equipment manufacturing Co.,Ltd. |
|
CP03 | Change of name, title or address |